JP2019513866A - エポキシ化ポリマーの製造法 - Google Patents

エポキシ化ポリマーの製造法 Download PDF

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Publication number
JP2019513866A
JP2019513866A JP2018552830A JP2018552830A JP2019513866A JP 2019513866 A JP2019513866 A JP 2019513866A JP 2018552830 A JP2018552830 A JP 2018552830A JP 2018552830 A JP2018552830 A JP 2018552830A JP 2019513866 A JP2019513866 A JP 2019513866A
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Japan
Prior art keywords
polymer
solvent
epoxidation
epoxidized
acid
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JP2018552830A
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English (en)
Japanese (ja)
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JP2019513866A5 (https=
Inventor
ソーティ，ニコラス
コルヴィン，ハワード
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Cooper Tire and Rubber Co
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Cooper Tire and Rubber Co
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Application filed by Cooper Tire and Rubber Co filed Critical Cooper Tire and Rubber Co
Publication of JP2019513866A publication Critical patent/JP2019513866A/ja
Publication of JP2019513866A5 publication Critical patent/JP2019513866A5/ja
Priority to JP2022012125A priority Critical patent/JP2022068188A/ja
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/04—Oxidation
    • C08C19/06—Epoxidation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/08—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Tires In General (AREA)
JP2018552830A 2016-04-05 2017-04-04 エポキシ化ポリマーの製造法 Pending JP2019513866A (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2022012125A JP2022068188A (ja) 2016-04-05 2022-01-28 エポキシ化ポリマーの製造法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662318387P 2016-04-05 2016-04-05
US62/318,387 2016-04-05
PCT/US2017/025857 WO2017176686A1 (en) 2016-04-05 2017-04-04 Process for producing epoxidized polymers

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2022012125A Division JP2022068188A (ja) 2016-04-05 2022-01-28 エポキシ化ポリマーの製造法

Publications (2)

Publication Number Publication Date
JP2019513866A true JP2019513866A (ja) 2019-05-30
JP2019513866A5 JP2019513866A5 (https=) 2020-07-30

Family

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JP2018552830A Pending JP2019513866A (ja) 2016-04-05 2017-04-04 エポキシ化ポリマーの製造法
JP2022012125A Pending JP2022068188A (ja) 2016-04-05 2022-01-28 エポキシ化ポリマーの製造法

Family Applications After (1)

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JP2022012125A Pending JP2022068188A (ja) 2016-04-05 2022-01-28 エポキシ化ポリマーの製造法

Country Status (8)

Country Link
US (1) US10836841B2 (https=)
EP (1) EP3440116A4 (https=)
JP (2) JP2019513866A (https=)
KR (1) KR20180123585A (https=)
CN (1) CN108884185A (https=)
CA (1) CA3018778A1 (https=)
MX (1) MX2018012259A (https=)
WO (1) WO2017176686A1 (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020132236A1 (en) 2018-12-21 2020-06-25 Bridgestone Corporation Processes for increasing the molecular weight of guayule natural rubber
KR102394623B1 (ko) * 2020-09-01 2022-05-06 김진국 에폭시화 고무의 제조방법
US20230382007A1 (en) * 2020-10-16 2023-11-30 Arizona Board Of Regents On Behalf Of The University Of Arizona Particleboards including modified guayule resins/soy protein resin blends and associated methods for forming same
CN113072652B (zh) * 2021-04-25 2022-06-28 岭南师范学院 一种定量环氧化天然橡胶及其制备方法
CN116135887A (zh) * 2021-11-17 2023-05-19 北京化工大学 一种环氧化橡胶的制备方法、环氧化橡胶及应用
CN116162296A (zh) * 2021-11-25 2023-05-26 北京化工大学 一种高性能绿色轮胎的胎面材料及其制备方法和应用
CN116162205B (zh) * 2021-11-25 2025-09-16 北京化工大学 一种环氧化溶聚丁苯橡胶及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09165418A (ja) * 1995-12-14 1997-06-24 Daicel Chem Ind Ltd エポキシ化有機系重合体の製造方法
JP2012229280A (ja) * 2011-04-22 2012-11-22 Sumitomo Rubber Ind Ltd タイヤ用ゴム組成物及び空気入りタイヤ

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3305515A (en) 1964-05-06 1967-02-21 Exxon Research Engineering Co Solvent for polybutadiene rubber
US4219627A (en) 1977-03-09 1980-08-26 The Firestone Tire & Rubber Company Process for the preparation of block copolymers
US5747598A (en) 1990-01-16 1998-05-05 Mobil Oil Corporation Epoxidized solid elastomeric copolymers
US5034470A (en) * 1990-09-04 1991-07-23 The Goodyear Tire & Rubber Company Process for the preparation of epoxidized synthetic cis-1,4-polyisoprene
US5399626A (en) 1991-04-29 1995-03-21 Shell Oil Company Viscous conjugated diene block copolymers
US5310819A (en) 1992-01-23 1994-05-10 The United States Of America As Represented By The Secretary Of The Navy Surface epoxidation of elastomers
DE69404740T2 (de) 1993-05-13 1998-01-22 Kao Corp Verfahren zur Herstellung von Rohkautschuk
KR20040039457A (ko) * 1995-12-14 2004-05-10 다이셀 화학 공업 주식회사 열가소성 수지 조성물, 프라이머 조성물, 미가류고무조성물, 고무성형물, 및 고무성형물의 제조방법
US5789512A (en) 1996-12-23 1998-08-04 Sartomer Company Method for the epoxidation of unsaturated polymers
US6242536B1 (en) 1997-12-11 2001-06-05 Bridgestone Corporation Process for preparation of block copolymers in mixed alkane/cycloalkane solvents
US6455655B1 (en) 2000-09-28 2002-09-24 The Goodyear Tire & Rubber Company Emulsion styrene-butadiene rubber
CN1113906C (zh) * 2000-10-29 2003-07-09 青岛化工学院 环氧化反式－1,4－聚异戊二烯的合成方法
WO2002038626A1 (en) 2000-11-13 2002-05-16 Daicel Chemical Industries, Ltd. Epoxidized thermoplastic polymers and processes for their production
CN1260258C (zh) 2001-05-14 2006-06-21 大赛璐化学工业株式会社 环氧化二烯烃系聚合物的制造方法
US6716925B2 (en) 2001-11-02 2004-04-06 The Goodyear Tire & Rubber Company Tire with a component made of a rubber composition comprised of a rubber having pendant hydroxyl groups and a rubber containing a nitrile moiety
US8519057B2 (en) * 2007-06-01 2013-08-27 Exxonmobil Chemical Patents Inc. Impact modification and functionalization of copolymers of olefins and dienes
TWI426090B (zh) 2011-05-31 2014-02-11 Tsrc Corp 製造環氧化聚合物的方法
CN104053677B (zh) * 2012-01-23 2017-05-17 住友橡胶工业株式会社 环氧化天然橡胶的制造方法、轮胎用橡胶组合物及充气轮胎
JP5603363B2 (ja) 2012-03-08 2014-10-08 住友ゴム工業株式会社 エポキシ化天然ゴムの製造方法、タイヤ用ゴム組成物及び空気入りタイヤ
CN103130990B (zh) * 2012-10-03 2015-02-18 大连理工大学 星形梳状聚乳酸及其制备方法
JP2016500699A (ja) * 2012-10-26 2016-01-14 ダウ グローバル テクノロジーズ エルエルシー 新規なエポキシド化合物：１，３−ジオキシラニルシクロペンタン誘導体
CN103570848B (zh) * 2013-10-24 2016-01-20 沈阳化工大学 环氧化天然杜仲胶的合成方法
FR3017393B1 (fr) * 2014-02-07 2016-02-12 Michelin & Cie Bande de roulement pour pneumatique a base de polyisoprene epoxyde
CN103910816B (zh) * 2014-04-12 2016-06-15 青岛科技大学 一种改进的环氧化反式异戊橡胶制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09165418A (ja) * 1995-12-14 1997-06-24 Daicel Chem Ind Ltd エポキシ化有機系重合体の製造方法
JP2012229280A (ja) * 2011-04-22 2012-11-22 Sumitomo Rubber Ind Ltd タイヤ用ゴム組成物及び空気入りタイヤ

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
WILLIAM W.SCHLOMAN, JR.: "Low-molecular-weight guayule natural rubber as a feedstock for epoxidized natural rubber", INDUSTRIAL CROPS AND PRODUCTS, vol. 1992, Volume 1, Issue 1, JPN6020049377, pages 35 - 39, ISSN: 0004602504 *

Also Published As

Publication number Publication date
US20190127495A1 (en) 2019-05-02
MX2018012259A (es) 2019-02-07
JP2022068188A (ja) 2022-05-09
EP3440116A1 (en) 2019-02-13
KR20180123585A (ko) 2018-11-16
WO2017176686A1 (en) 2017-10-12
EP3440116A4 (en) 2019-12-18
CN108884185A (zh) 2018-11-23
US10836841B2 (en) 2020-11-17
CA3018778A1 (en) 2017-10-12

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