CN108884023B - 双酚m双邻苯二甲腈醚树脂、双酚p双邻苯二甲腈醚树脂、它们的制备方法、树脂共混物以及双组分体系 - Google Patents

双酚m双邻苯二甲腈醚树脂、双酚p双邻苯二甲腈醚树脂、它们的制备方法、树脂共混物以及双组分体系 Download PDF

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CN108884023B
CN108884023B CN201780021402.1A CN201780021402A CN108884023B CN 108884023 B CN108884023 B CN 108884023B CN 201780021402 A CN201780021402 A CN 201780021402A CN 108884023 B CN108884023 B CN 108884023B
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bisphenol
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resin
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bisphthalonitrile
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CN108884023A (zh
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B·J·安德森
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3M Innovative Properties Co
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G16/00Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
    • C08G16/02Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
    • C08G16/0212Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds
    • C08G16/0218Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen
    • C08G16/0231Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/49Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/54Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and etherified hydroxy groups bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/31Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C07C323/32Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to an acyclic carbon atom of the carbon skeleton
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
CN201780021402.1A 2016-03-31 2017-03-24 双酚m双邻苯二甲腈醚树脂、双酚p双邻苯二甲腈醚树脂、它们的制备方法、树脂共混物以及双组分体系 Active CN108884023B (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US201662316248P 2016-03-31 2016-03-31
US62/316,248 2016-03-31
US201662348477P 2016-06-10 2016-06-10
US62/348,477 2016-06-10
US201762475396P 2017-03-23 2017-03-23
US62/475,396 2017-03-23
PCT/US2017/024006 WO2017172515A1 (en) 2016-03-31 2017-03-24 Bisphenol m diphthalonitrile ether resin, bisphenol p diphthalonitrile ether resin, methods of making same, resin blends, and two component systems

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CN108884023A CN108884023A (zh) 2018-11-23
CN108884023B true CN108884023B (zh) 2022-02-25

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CN201780021278.9A Active CN108884222B (zh) 2016-03-31 2017-03-30 树脂共混物
CN201780021374.3A Expired - Fee Related CN109071808B (zh) 2016-03-31 2017-03-31 包含填料的双酚m双邻苯二甲腈醚树脂共混物,以及制品

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Families Citing this family (15)

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Publication number Priority date Publication date Assignee Title
CN108884023B (zh) * 2016-03-31 2022-02-25 3M创新有限公司 双酚m双邻苯二甲腈醚树脂、双酚p双邻苯二甲腈醚树脂、它们的制备方法、树脂共混物以及双组分体系
CN110461814B (zh) * 2017-03-23 2023-04-14 3M创新有限公司 含有邻苯二甲腈反应性稀释剂和双邻苯二甲腈树脂的树脂共混物、预浸料和制品
WO2020060262A1 (ko) * 2018-09-21 2020-03-26 주식회사 엘지화학 프탈로니트릴 올리고머를 포함하는 경화성 수지 조성물 및 이의 프리폴리머
KR102340253B1 (ko) * 2018-09-21 2021-12-15 주식회사 엘지화학 프탈로니트릴 올리고머를 포함하는 경화성 수지 조성물 및 이의 프리폴리머
KR102323553B1 (ko) * 2018-09-21 2021-11-05 주식회사 엘지화학 프탈로니트릴 올리고머를 포함하는 3차원 프린팅용 잉크
RU2695606C1 (ru) * 2018-11-08 2019-07-24 Акционерное Общество "Институт Новых Углеродных Материалов И Технологий" Композиция фталонитрильного связующего для полимерных композиционных материалов, способ ее получения, способ получения полимерного композиционного материала и материал, полученный этим способом
EP3887428A4 (en) * 2018-11-30 2022-08-24 3M Innovative Properties Company RESIN BLENDS WITH PHTHALONITRILE RESIN AND THIADIAZOLE-SUBSTITUTED PHTHALONITRILE COMPOUND, OBJECTS, COMPOUNDS AND METHODS
BR112022005606A2 (pt) * 2019-10-31 2022-07-19 Huntsman Advanced Mat Americas Llc Composição termoendurecível polimerizável, polímero termoendurecido, processo para produzir um artigo de compósito, e, métodos para produzir um artigo de compósito em um sistema
WO2021165797A1 (en) 2020-02-21 2021-08-26 3M Innovative Properties Company Polymerizable compositions including a phthalonitrile resin and a polyoxometalate, articles, and methods
RU2767683C2 (ru) * 2020-09-09 2022-03-18 Федеральное государственное бюджетное образовательное учреждение высшего образования «Московский государственный университет имени М.В.Ломоносова» (МГУ) Защитное покрытие на основе фторсодержащих фталонитрильных олигомеров для полимерных композиционных материалов
US12187908B2 (en) * 2020-10-20 2025-01-07 The Boeing Company Phthalonitrile-based high temperature resistive inks
CN112778525A (zh) * 2020-12-31 2021-05-11 中硅艾德(厦门)新材料科技有限公司 一种常温下为液态的邻苯二甲腈单体及其合成方法
CN115368563B (zh) * 2021-05-21 2023-12-15 北京化工大学 无溶剂法制备含醛亚胺键双邻苯二甲腈化合物、聚合物及其应用
CN113968878B (zh) * 2021-11-10 2023-07-07 中国科学院宁波材料技术与工程研究所 超支化硼酸改性的酞腈单体及其制备方法与应用
CN115353621B (zh) * 2022-09-13 2023-07-25 中国人民解放军国防科技大学 一种低温快速固化的含胺基结构氰酸酯树脂及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108884222A (zh) * 2016-03-31 2018-11-23 3M创新有限公司 间苯二酚二邻苯二甲腈醚与双酚m二邻苯二甲腈醚和/或双酚t二邻苯二甲腈醚的树脂共混物

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3429722A (en) 1965-07-12 1969-02-25 Carborundum Co Boron nitride fiber manufacture
US3496250A (en) 1967-02-21 1970-02-17 Borg Warner Blends of epoxy resins and acrylonitrile butadiene-styrene graft copolymers
US3956320A (en) 1972-08-18 1976-05-11 General Electric Company Aromatic bis(ether phthalis anhydride) compounds
US4223123A (en) 1979-05-29 1980-09-16 The United States Of America As Represented By The Secretary Of The Navy Aliphatic phenoxy polyphthalocyanine
US4304896A (en) 1980-08-19 1981-12-08 The United States Of America As Represented By The Secretary Of The Navy Polyphthalocyanine resins
US4408035A (en) 1981-08-24 1983-10-04 The United States Of America As Represented By The Secretary Of The Navy Phthalonitrile resin from diphthalonitrile monomer and amine
US4587325A (en) 1985-01-09 1986-05-06 The United States Of America As Represented By The Secretary Of The Navy Processable and stable conductive polymers from diether-linked bisorthodinitrile monomers
FR2587348B1 (fr) * 1985-09-16 1988-02-05 Mat Organ Technolog Centre Compositions d'oligomeres de polyaryloxypyridine a terminaisons phtalonitriles, leur preparation, leur utilisation dans la fabrication de reseaux de polyaryloxypyridine co-polyphtalocyanines, et les reseaux obtenus
US5003039A (en) 1988-11-18 1991-03-26 The United States Of America As Represented By The Secretary Of The Navy Amino phenyl containing curing agent for high performance phthalonitrile resin
US5262514A (en) 1992-03-12 1993-11-16 The United States Of America As Represented By The Secretary Of The Navy Polymer from diimido-di-phthalonitrile
US5312887A (en) 1992-12-09 1994-05-17 International Business Machines Corporation Dicyanate prepolymers, use and preparation thereof
EP0699785B1 (en) 1994-03-22 1998-07-29 Tokuyama Corporation Boron nitride fiber and process for producing the same
US6001926A (en) * 1997-10-02 1999-12-14 The United States Of America As Represented By The Secretary Of The Navy Fiber-reinforced phthalonitrile composite cured with low-reactivity aromatic amine curing agent
US6297298B1 (en) 1998-01-15 2001-10-02 The United States Of America As Represented By The Secretary Of The Navy Phthalonitrile prepolymerization composition
JP2005507011A (ja) 2001-04-02 2005-03-10 エイコス・インコーポレーテッド ポリマー系ナノコンポジット及びその製造方法
ATE512998T1 (de) * 2005-02-11 2011-07-15 Raytheon Co Verbesserte phthalonitril-verbundwerkstoffe
SE530059C2 (sv) 2006-03-06 2008-02-19 Perstorp Specialty Chem Ab Förfarande för framställning av en bis-ftalonitrilmonomer
EP2617762A1 (en) 2008-12-19 2013-07-24 3M Innovative Properties Company Nanocalcite composites
BR112012007369A2 (pt) 2009-10-21 2018-03-13 3M Innovative Properties Co processo de funcionalização isenta de solvente, moagem e composição com diluentes reativos
CN102656221B (zh) 2009-12-17 2015-03-25 3M创新有限公司 高镁表面浓度的纳米方解石复合材料
CN101831173B (zh) 2010-01-15 2012-06-27 电子科技大学 聚芳醚腈增韧的双邻苯二甲腈树脂玻纤复合材料及其制备方法
CN102887999A (zh) 2010-07-15 2013-01-23 电子科技大学 含芳醚腈链段的双酚a型双邻苯二甲腈树脂、固化物及其制备方法
CN102086168A (zh) 2010-12-16 2011-06-08 自贡鸿鹤化工股份有限公司 一种生产双邻苯二甲腈端基苯硫醚齐聚物的方法
US8859712B2 (en) * 2012-08-02 2014-10-14 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Synthesis of and curing additives for phthalonitriles
WO2014051523A1 (en) 2012-09-28 2014-04-03 Nanyang Technological University Methods of producing foams and nanocomposites of phthalonitrile based resins, and foams and nanocomposites produced thereof
CN102936466B (zh) 2012-11-28 2013-12-25 黑龙江省科学院石油化学研究院 一种改性双邻苯二甲腈树脂结构胶膜及其制备方法
CN102936340A (zh) 2012-11-30 2013-02-20 吉林大学 一种双邻苯二甲腈树脂/芳香胺有机化蒙脱土纳米复合材料及其制备方法
CN103012790B (zh) 2012-12-19 2014-11-19 成都德美精英化工有限公司 双邻苯二甲腈-氨基苯氧基邻苯二甲腈共聚物、固化物及其玻纤复合材料与制备方法
US8921510B1 (en) * 2013-10-03 2014-12-30 The United States Of America, As Represented By The Secretary Of The Navy Phthalonitrile prepolymer intermediate
WO2016099667A1 (en) * 2014-12-15 2016-06-23 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Controlling crosslinking density and processing parameters of phthalonitriles
KR101959463B1 (ko) 2015-05-22 2019-03-18 주식회사 엘지화학 프탈로니트릴 화합물
WO2017024006A1 (en) * 2015-08-03 2017-02-09 The Johns Hopkins University Personalized, allogeneic cell therapy of cancer
KR101959462B1 (ko) * 2015-09-24 2019-03-18 주식회사 엘지화학 프탈로니트릴 화합물
CN105348734A (zh) 2015-11-13 2016-02-24 安徽广源科技发展有限公司 一种印刷电路板专用耐热性环氧树脂环保材料
KR101953369B1 (ko) * 2015-12-04 2019-02-28 주식회사 엘지화학 중합성 조성물

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108884222A (zh) * 2016-03-31 2018-11-23 3M创新有限公司 间苯二酚二邻苯二甲腈醚与双酚m二邻苯二甲腈醚和/或双酚t二邻苯二甲腈醚的树脂共混物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Improved synthesis of oligometric phthalonitriles and studies designed for low temperature cure;Matthew Laskoski et al.;《Journal of polymer science, part A: polymer chemistry》;20140615;第52卷(第12期);1662-1668 *

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WO2017173040A1 (en) 2017-10-05
CN108884222A (zh) 2018-11-23
CN108884023A (zh) 2018-11-23
EP3436505A1 (en) 2019-02-06
WO2017173195A1 (en) 2017-10-05
CN109071808B (zh) 2022-12-09
JP6559369B2 (ja) 2019-08-14
JP6843152B2 (ja) 2021-03-17
JP2019510117A (ja) 2019-04-11
EP3436505A4 (en) 2019-11-27
US10899865B2 (en) 2021-01-26
CN108884222B (zh) 2021-02-05
EP3436428B1 (en) 2024-07-10
EP3436428A1 (en) 2019-02-06
EP3436502B1 (en) 2021-03-24
WO2017172515A1 (en) 2017-10-05
EP3436502A1 (en) 2019-02-06
JP2019511612A (ja) 2019-04-25
US10640598B2 (en) 2020-05-05
US11401364B2 (en) 2022-08-02
US20190055338A1 (en) 2019-02-21
CN109071808A (zh) 2018-12-21
US20200299506A1 (en) 2020-09-24
JP6865230B2 (ja) 2021-04-28
EP3436502A4 (en) 2019-12-11
US20190047946A1 (en) 2019-02-14
JP2019511613A (ja) 2019-04-25
EP3436505B1 (en) 2021-11-24

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