CN1087973C - 废水处理用催化剂、其制造方法及使用该催化剂的废水处理方法 - Google Patents
废水处理用催化剂、其制造方法及使用该催化剂的废水处理方法 Download PDFInfo
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- CN1087973C CN1087973C CN94191812A CN94191812A CN1087973C CN 1087973 C CN1087973 C CN 1087973C CN 94191812 A CN94191812 A CN 94191812A CN 94191812 A CN94191812 A CN 94191812A CN 1087973 C CN1087973 C CN 1087973C
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- Prior art keywords
- catalyzer
- oxide
- waste water
- iron
- compound
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- 239000002351 wastewater Substances 0.000 title claims abstract description 121
- 239000003054 catalyst Substances 0.000 title claims abstract description 73
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- 238000012545 processing Methods 0.000 title description 121
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 245
- 238000009279 wet oxidation reaction Methods 0.000 claims abstract description 131
- 229910052742 iron Inorganic materials 0.000 claims abstract description 97
- 239000002131 composite material Substances 0.000 claims abstract description 94
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 91
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 91
- 239000010936 titanium Substances 0.000 claims abstract description 91
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- 239000002184 metal Substances 0.000 claims abstract description 54
- 239000001301 oxygen Substances 0.000 claims abstract description 44
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- 239000007791 liquid phase Substances 0.000 claims abstract description 10
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 7
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- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 12
- 229910002651 NO3 Inorganic materials 0.000 description 11
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 11
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 11
- 239000003513 alkali Substances 0.000 description 11
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 11
- 229960004418 trolamine Drugs 0.000 description 11
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- 241000370738 Chlorion Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
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- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
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- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- GOPYZMJAIPBUGX-UHFFFAOYSA-N [O-2].[O-2].[Mn+4] Chemical class [O-2].[O-2].[Mn+4] GOPYZMJAIPBUGX-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229940024548 aluminum oxide Drugs 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 1
- 229940099364 dichlorofluoromethane Drugs 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910052945 inorganic sulfide Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 235000018977 lysine Nutrition 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- 235000006109 methionine Nutrition 0.000 description 1
- 229940102396 methyl bromide Drugs 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- 235000008729 phenylalanine Nutrition 0.000 description 1
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- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- KOUKXHPPRFNWPP-UHFFFAOYSA-N pyrazine-2,5-dicarboxylic acid;hydrate Chemical compound O.OC(=O)C1=CN=C(C(O)=O)C=N1 KOUKXHPPRFNWPP-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- YWFDDXXMOPZFFM-UHFFFAOYSA-H rhodium(3+);trisulfate Chemical compound [Rh+3].[Rh+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O YWFDDXXMOPZFFM-UHFFFAOYSA-H 0.000 description 1
- 235000004400 serine Nutrition 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
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- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 description 1
- 235000011182 sodium carbonates Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
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- 238000003860 storage Methods 0.000 description 1
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- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/025—Thermal hydrolysis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/06—Treatment of sludge; Devices therefor by oxidation
- C02F11/08—Wet air oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33595793 | 1993-12-28 | ||
| JP335957/93 | 1993-12-28 | ||
| JP243593/94 | 1994-10-07 | ||
| JP24359394A JP3318131B2 (ja) | 1994-10-07 | 1994-10-07 | 廃水処理用触媒およびその触媒を用いた廃水の処理方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1121322A CN1121322A (zh) | 1996-04-24 |
| CN1087973C true CN1087973C (zh) | 2002-07-24 |
Family
ID=26536334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94191812A Expired - Fee Related CN1087973C (zh) | 1993-12-28 | 1994-12-28 | 废水处理用催化剂、其制造方法及使用该催化剂的废水处理方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5770093A (OSRAM) |
| EP (1) | EP0686427B1 (OSRAM) |
| KR (1) | KR100231916B1 (OSRAM) |
| CN (1) | CN1087973C (OSRAM) |
| AT (1) | ATE214302T1 (OSRAM) |
| DE (1) | DE69430118T2 (OSRAM) |
| TW (1) | TW315315B (OSRAM) |
| WO (1) | WO1995017958A1 (OSRAM) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103787486A (zh) * | 2014-03-10 | 2014-05-14 | 武汉大学 | 一种有机废水催化氧化方法 |
| CN108745343A (zh) * | 2018-05-30 | 2018-11-06 | 江苏开放大学（江苏城市职业学院） | 一种锰、锆、钛三元复合碱渣废水催化湿式氧化催化剂及其制备方法和应用 |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2250888C (en) * | 1996-04-01 | 2006-08-01 | United States Filter Corporation | Two-stage separation process |
| CN1315739C (zh) * | 1997-04-22 | 2007-05-16 | 株式会社日本触媒 | 废水处理装置 |
| DE69815787D1 (de) * | 1997-10-21 | 2003-07-31 | Karsten Pedersen Silkeborg | Katalytisches Verfahren zur Beseitigung von organischen Schadstoffe in Gewässer |
| EP1076041A3 (en) * | 1999-08-09 | 2001-12-12 | Nippon Shokubai Co., Ltd. | Method for decomposing or oxidizing dioxins and/or poly chlorinated biphenyls contained in liquid |
| KR100451646B1 (ko) * | 2000-01-05 | 2004-10-08 | 니폰 쇼쿠바이 컴파니 리미티드 | 배수처리용 촉매, 그의 제조방법 및 배수의 처리방법 |
| KR100482204B1 (ko) * | 2000-08-18 | 2005-04-13 | 주식회사 포스코 | 폐수처리제 및 이를 이용한 폐수처리방법 |
| CN1095447C (zh) * | 2000-10-20 | 2002-12-04 | 清华大学 | 一种用于废水湿式氧化处理的催化剂 |
| JP2004098055A (ja) * | 2002-08-21 | 2004-04-02 | Fuji Photo Film Co Ltd | アミノポリカルボン酸を含有する有機廃水の処理方法 |
| US7294270B2 (en) * | 2003-05-16 | 2007-11-13 | Fujifilm Corporation | Method of treating photographic waste liquid |
| CA2555427C (en) | 2004-02-19 | 2014-07-29 | Idemitsu Kosan Co., Ltd. | Reforming catalyst for hydrocarbon, method for producing hydrogen using such reforming catalyst, and fuel cell system |
| US20060060541A1 (en) * | 2004-09-23 | 2006-03-23 | Abazajian Armen N | Waste disposal method and apparatus using wet oxidation and deep well injection |
| WO2007020218A1 (en) * | 2005-08-12 | 2007-02-22 | Akzo Nobel N.V. | Process to remove non-biodegradable compounds from an aqueous composition and apparatus therefor |
| US8216543B2 (en) * | 2005-10-14 | 2012-07-10 | Inframat Corporation | Methods of making water treatment compositions |
| CN100509137C (zh) * | 2006-02-21 | 2009-07-08 | 中国科学院生态环境研究中心 | 一种铁锰复合氧化物/硅藻土吸附剂的制备、使用及再生方法 |
| KR101414243B1 (ko) * | 2007-03-30 | 2014-07-14 | 서울반도체 주식회사 | 황화물 형광체 코팅 방법 및 코팅된 황화물 형광체를채택한 발광 소자 |
| US8207087B2 (en) * | 2007-07-13 | 2012-06-26 | Research Center For Eco-Environmental Sciences, Chinese Academy Of Sciences | Method for making ferric and manganese binary oxide based adsorbent |
| WO2010109556A1 (ja) * | 2009-03-24 | 2010-09-30 | 株式会社アサカ理研 | 水処理方法及び水処理システム |
| CN102285729A (zh) * | 2010-06-18 | 2011-12-21 | 中国石油化工股份有限公司 | 一种高温湿式氧化处理废碱液的方法 |
| CN102398909B (zh) * | 2010-09-08 | 2014-11-05 | 北京赛科康仑环保科技有限公司 | 一种利用高氨氮含硫高盐废水生产硫酸铵的方法 |
| CN103359810A (zh) * | 2012-03-30 | 2013-10-23 | 中国石油化工股份有限公司 | 一种废水的处理方法 |
| EP3276013A4 (en) * | 2015-03-24 | 2018-12-19 | Clariant Catalysts (Japan) K.K. | Agent for adsorption of ruthenium from aqueous solution and method for adsorption of ruthenium from aqueous solution |
| WO2016165781A1 (en) | 2015-04-17 | 2016-10-20 | Hewlett-Packard Development Company, L.P. | Printing device and support member for printing device |
| CN105536773B (zh) * | 2015-12-11 | 2018-01-23 | 上海韬鸿化工科技有限公司 | 陶基质催化剂及其制备方法 |
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| CN119186586B (zh) * | 2024-10-12 | 2025-11-18 | 浙江工业大学 | 一种可同时强化吸附分解臭氧且可磁性分离的(Fe,Mn)Al2O4催化剂材料及其制备方法与应用 |
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| JPS5256093A (en) * | 1976-09-20 | 1977-05-09 | Kato Toshiya | Manufacture of catalysts for exhaust water purification |
| CA1301964C (en) * | 1986-08-22 | 1992-05-26 | Kiichiro Mitsui | Method for treatment of waste water |
| KR940006404B1 (ko) * | 1988-07-12 | 1994-07-20 | 닛뽕쇼꾸바이가가꾸 고오교가부시끼가이샤 | 수처리용 촉매 |
| US5145587A (en) * | 1989-12-06 | 1992-09-08 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for treatment of waste water |
| US5620610A (en) * | 1991-05-14 | 1997-04-15 | Nippon Shokubai Co., Ltd. | Catalyst for treating wastewater, process for producing it, and process for treating wastewater with the catalyst |
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- 1994-12-28 TW TW083112298A patent/TW315315B/zh active
- 1994-12-28 WO PCT/JP1994/002285 patent/WO1995017958A1/ja not_active Ceased
- 1994-12-28 EP EP95904018A patent/EP0686427B1/en not_active Expired - Lifetime
- 1994-12-28 AT AT95904018T patent/ATE214302T1/de not_active IP Right Cessation
- 1994-12-28 CN CN94191812A patent/CN1087973C/zh not_active Expired - Fee Related
- 1994-12-28 DE DE69430118T patent/DE69430118T2/de not_active Expired - Fee Related
- 1994-12-28 KR KR1019950703559A patent/KR100231916B1/ko not_active Expired - Fee Related
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1996
- 1996-05-02 US US08/641,839 patent/US5770093A/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS5912194A (ja) * | 1982-07-12 | 1984-01-21 | Teikoku Denki Seisakusho:Kk | グランドレスポンプ |
| CN1050012A (zh) * | 1989-08-18 | 1991-03-20 | 大阪瓦斯株式会社 | 处理废水的方法 |
| CN1067188A (zh) * | 1991-05-14 | 1992-12-23 | 株式会社日本触媒 | 处理废水的催化剂及其生产方法以及用此催化剂处理废水的方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103787486A (zh) * | 2014-03-10 | 2014-05-14 | 武汉大学 | 一种有机废水催化氧化方法 |
| CN108745343A (zh) * | 2018-05-30 | 2018-11-06 | 江苏开放大学（江苏城市职业学院） | 一种锰、锆、钛三元复合碱渣废水催化湿式氧化催化剂及其制备方法和应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW315315B (OSRAM) | 1997-09-11 |
| EP0686427A4 (en) | 1996-11-20 |
| US5770093A (en) | 1998-06-23 |
| DE69430118D1 (de) | 2002-04-18 |
| EP0686427B1 (en) | 2002-03-13 |
| DE69430118T2 (de) | 2002-08-29 |
| WO1995017958A1 (en) | 1995-07-06 |
| EP0686427A1 (en) | 1995-12-13 |
| CN1121322A (zh) | 1996-04-24 |
| KR100231916B1 (ko) | 1999-12-01 |
| KR960700811A (ko) | 1996-02-24 |
| ATE214302T1 (de) | 2002-03-15 |
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