CN104039702A - 稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途 - Google Patents

稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途 Download PDF

Info

Publication number
CN104039702A
CN104039702A CN201280058962.1A CN201280058962A CN104039702A CN 104039702 A CN104039702 A CN 104039702A CN 201280058962 A CN201280058962 A CN 201280058962A CN 104039702 A CN104039702 A CN 104039702A
Authority
CN
China
Prior art keywords
microporous crystalline
crystalline material
earth metal
sapo
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201280058962.1A
Other languages
English (en)
Chinese (zh)
Inventor
黎鸿昕
W·E·科米尔
B·莫登
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PQ Corp
Original Assignee
PQ Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=47358300&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN104039702(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by PQ Corp filed Critical PQ Corp
Priority to CN201810052873.5A priority Critical patent/CN108249454A/zh
Publication of CN104039702A publication Critical patent/CN104039702A/zh
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/88Ferrosilicates; Ferroaluminosilicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/03Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/035Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
    • B01J29/0352Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites containing iron group metals, noble metals or copper
    • B01J29/0356Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7065CHA-type, e.g. Chabazite, LZ-218
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • B01J29/763CHA-type, e.g. Chabazite, LZ-218
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/82Phosphates
    • B01J29/83Aluminophosphates [APO compounds]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/82Phosphates
    • B01J29/84Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85Silicoaluminophosphates [SAPO compounds]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026After-treatment
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/54Phosphates, e.g. APO or SAPO compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2067Urea
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/208Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • B01D2253/1085Zeolites characterized by a silicon-aluminium ratio
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/202Alkali metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/202Alkali metals
    • B01D2255/2022Potassium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/204Alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/204Alkaline earth metals
    • B01D2255/2042Barium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/204Alkaline earth metals
    • B01D2255/2045Calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/204Alkaline earth metals
    • B01D2255/2047Magnesium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/206Rare earth metals
    • B01D2255/2063Lanthanum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/206Rare earth metals
    • B01D2255/2065Cerium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/206Rare earth metals
    • B01D2255/2066Praseodymium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/206Rare earth metals
    • B01D2255/2068Neodymium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20738Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/90Physical characteristics of catalysts
    • B01D2255/92Dimensions
    • B01D2255/9205Porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/90Physical characteristics of catalysts
    • B01D2255/92Dimensions
    • B01D2255/9207Specific surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/58Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/36Steaming
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46Other types characterised by their X-ray diffraction pattern and their defined composition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
CN201280058962.1A 2011-12-02 2012-11-30 稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途 Pending CN104039702A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810052873.5A CN108249454A (zh) 2011-12-02 2012-11-30 稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161566106P 2011-12-02 2011-12-02
US61/566,106 2011-12-02
PCT/US2012/067474 WO2013082550A1 (en) 2011-12-02 2012-11-30 Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of nox

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201810052873.5A Division CN108249454A (zh) 2011-12-02 2012-11-30 稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途

Publications (1)

Publication Number Publication Date
CN104039702A true CN104039702A (zh) 2014-09-10

Family

ID=47358300

Family Applications (3)

Application Number Title Priority Date Filing Date
CN201280058962.1A Pending CN104039702A (zh) 2011-12-02 2012-11-30 稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途
CN201810052873.5A Pending CN108249454A (zh) 2011-12-02 2012-11-30 稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途
CN201280058960.2A Expired - Fee Related CN103987662B (zh) 2011-12-02 2012-11-30 稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途

Family Applications After (2)

Application Number Title Priority Date Filing Date
CN201810052873.5A Pending CN108249454A (zh) 2011-12-02 2012-11-30 稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途
CN201280058960.2A Expired - Fee Related CN103987662B (zh) 2011-12-02 2012-11-30 稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途

Country Status (7)

Country Link
US (1) US9517458B2 (https=)
EP (2) EP2785644B1 (https=)
JP (3) JP6320298B2 (https=)
KR (2) KR102078083B1 (https=)
CN (3) CN104039702A (https=)
BR (2) BR112014012818A2 (https=)
WO (2) WO2013082550A1 (https=)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104891528A (zh) * 2015-06-12 2015-09-09 杭州回水科技股份有限公司 铜胺络合物作为模板剂固相合成Cu-SAPO-34分子筛的方法
CN109071245A (zh) * 2016-02-01 2018-12-21 优美科股份公司及两合公司 用于直接合成含铁的aei-沸石催化剂的方法
CN110997138A (zh) * 2017-06-09 2020-04-10 巴斯夫公司 用于NOx减排的具有受控孔隙率的催化洗涂层
CN112236230A (zh) * 2018-05-14 2021-01-15 优美科股份公司及两合公司 稳定的小孔沸石

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2419209A1 (en) * 2009-04-17 2012-02-22 Johnson Matthey Public Limited Company Small pore molecular sieve supported copper catalysts durable against lean/rich aging for the reduction of nitrogen oxides
PL2428659T3 (pl) * 2010-09-13 2017-01-31 Umicore Ag & Co. Kg Katalizator do usuwania tlenków azotu ze spalin silników wysokoprężnych
US8795626B2 (en) * 2010-12-28 2014-08-05 Tosoh Corporation Zeolite having copper and alkali earth metal supported thereon
US9981256B2 (en) * 2011-12-02 2018-05-29 Pq Corporation Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of NOx
US9517458B2 (en) * 2011-12-02 2016-12-13 Pq Corporation Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of NOx
US10245582B2 (en) * 2012-04-11 2019-04-02 Johnson Matthey Public Limited Company Zeolite catalyst containing metals
WO2014062952A1 (en) * 2012-10-19 2014-04-24 Basf Corporation 8-ring small pore molecular sieve with promoter to improve low temperature performance
BR112016004021B1 (pt) * 2013-08-30 2021-01-12 Johnson Matthey Public Limited Company catalisador para tratamento de um gás de escape, artigo de catalisador para tratamento de gás de escape, e, método para tratamento de gás de escape
US9283548B2 (en) 2013-11-19 2016-03-15 Toyota Motor Engineering & Manufacturing North America, Inc. Ceria-supported metal catalysts for the selective reduction of NOx
BR112016021805B1 (pt) * 2014-03-24 2022-05-17 Johnson Matthey Public Limited Company Método para redução de emissões de n2o em um gás de escape, e, sistema para tratamento de um gás de escape
US9561469B2 (en) 2014-03-24 2017-02-07 Johnson Matthey Public Limited Company Catalyst for treating exhaust gas
DE102014205783A1 (de) * 2014-03-27 2015-10-01 Johnson Matthey Public Limited Company Katalysator sowie Verfahren zum Herstellen eines Katalysator
JP5740040B1 (ja) * 2014-07-07 2015-06-24 イビデン株式会社 ゼオライト、ハニカム触媒及び排ガス浄化装置
JP5732170B1 (ja) * 2014-07-07 2015-06-10 イビデン株式会社 ゼオライト、ハニカム触媒及び排ガス浄化装置
US10807082B2 (en) * 2014-10-13 2020-10-20 Johnson Matthey Public Limited Company Zeolite catalyst containing metals
US10226754B2 (en) * 2015-03-03 2019-03-12 Basf Corporation Lean NOx trap with enhanced high and low temperature performance
JP6503473B2 (ja) * 2015-04-09 2019-04-17 ピーキュー コーポレイション 安定化されたマイクロポーラス結晶性物質、それを作成する方法、およびNOxの選択的触媒還元のためのその使用
US10377638B2 (en) * 2015-04-09 2019-08-13 Pq Corporation Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of NOx
JP6599637B2 (ja) * 2015-05-13 2019-10-30 イビデン株式会社 ゼオライト、該ゼオライトの製造方法、該ゼオライトを使用したハニカム触媒及び排ガス浄化装置
JP6780650B2 (ja) * 2015-11-27 2020-11-04 三菱ケミカル株式会社 酸素8員環ゼオライト及びaei型ゼオライトの製造方法
US11014077B2 (en) 2016-05-03 2021-05-25 Umicore Ag & Co. Kg Active SCR catalyst
CN121800199A (zh) * 2016-06-08 2026-04-07 巴斯夫公司 来自无有机模板的合成的cha骨架结构的铜助催化沸石材料及其在nox的选择性催化还原中的用途
WO2018025244A1 (en) * 2016-08-05 2018-02-08 Basf Corporation Selective catalytic reduction articles and systems
JP7164591B2 (ja) * 2017-07-11 2022-11-01 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Noxおよびn20の変換における触媒およびその使用方法
RU2020102868A (ru) 2017-07-11 2021-08-11 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализатор и способ его применения
JP7410048B2 (ja) * 2018-03-21 2024-01-09 ビーエーエスエフ コーポレーション Chaゼオライト材料および関連する合成方法
KR102755650B1 (ko) * 2018-05-25 2025-01-20 바스프 모바일 에미션스 카탈리스츠 엘엘씨 희토류 원소를 함유하는 알루미늄-풍부 제올라이트 물질
US11878293B2 (en) * 2018-09-11 2024-01-23 Basf Corporation Process for preparing a zeolitic material having framework type AEI
EP3872034A4 (en) * 2018-10-23 2022-07-20 N.E. Chemcat Corporation CU-P-CO-SUPPORTED ZEOLITE, SELECTIVE REDUCTION CATALYST AND EXHAUST CATALYST WITH IT
CN112585090B (zh) * 2018-10-23 2023-12-15 N.E.化学株式会社 Cu-P共负载沸石的制造方法、能够用于其的催化剂前体组合物及处理液、以及层叠催化剂的制造方法
CN109622029A (zh) * 2019-01-21 2019-04-16 黑龙江大学 选择性催化还原氮氧化物的催化剂的制备方法及应用
US12264076B2 (en) 2019-05-15 2025-04-01 Basf Mobile Emissions Catalysts Llc Process for the production of the CHA-AFT zeolite intergrowth COE-10 and use thereof in heterogeneous catalysis
CN110193378B (zh) * 2019-05-27 2022-02-11 天津大学 一种CuM/SAPO-34分子筛的制备方法及其应用
EP4007737A4 (en) * 2019-08-02 2024-02-28 BASF Corporation CHABAZITE SYNTHESIS PROCESS USING ORGANIC AND INORGANIC STRUCTURAL DIRECTORS AND CHABAZITE ZEOLITE WITH FLAKE-LIKE MORPHOLOGY
EP3812034A1 (en) * 2019-10-24 2021-04-28 Dinex A/S Durable copper-scr catalyst
CN111252781B (zh) * 2020-02-05 2022-01-07 浙江大学 无有机模板剂晶种法合成高硅kfi沸石分子筛的方法
CN111762795B (zh) * 2020-07-13 2022-10-14 包头稀土研究院 含有稀土元素的分子筛及其生产方法
KR20220060316A (ko) * 2020-11-04 2022-05-11 현대자동차주식회사 NOx 저장용 촉매 및 이의 제조 방법
JP7320568B2 (ja) * 2021-08-04 2023-08-03 株式会社キャタラー 排ガス浄化触媒
CN115055206A (zh) * 2021-08-27 2022-09-16 华中科技大学 一种酸性位保护改性的Cu-SAPO-34催化剂及其制备方法和应用
JP7372302B2 (ja) 2021-12-06 2023-10-31 株式会社キャタラー 排ガス浄化触媒装置
CN117065787B (zh) * 2023-06-26 2025-12-16 东风商用车有限公司 一氧化二氮吸附分解催化剂、制备方法及催化剂结构
KR102918664B1 (ko) 2023-11-02 2026-01-28 한국화학연구원 Aei형 제올라이트 및 이의 제조방법

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101674885A (zh) * 2007-03-26 2010-03-17 Pq公司 包含具有8元环开孔结构的分子筛或沸石的新型微孔结晶材料及其制备方法和应用
CN101730575A (zh) * 2007-04-26 2010-06-09 约翰逊马西有限公司 过渡金属/沸石scr催化剂
CN101983103A (zh) * 2008-01-31 2011-03-02 巴斯夫公司 利用具有cha晶体结构的非沸石的含金属分子筛的催化剂、系统和方法
CN102029175A (zh) * 2009-10-07 2011-04-27 福特环球技术公司 选择性催化还原剂及其制备方法
CN102215960A (zh) * 2008-11-06 2011-10-12 巴斯夫公司 具有低二氧化硅与氧化铝比率的菱沸石催化剂

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0676204B2 (ja) * 1988-12-20 1994-09-28 ユニオン・カーバイド・コーポレーション モレキュラーシーブの製造方法
US5026532A (en) 1989-04-06 1991-06-25 Air Products And Chemicals, Inc. Process for the preparation of an improved chabazite for the purification of bulk gases
US6689709B1 (en) * 2000-11-15 2004-02-10 Engelhard Corporation Hydrothermally stable metal promoted zeolite beta for NOx reduction
US6793911B2 (en) * 2002-02-05 2004-09-21 Abb Lummus Global Inc. Nanocrystalline inorganic based zeolite and method for making same
EP2419209A1 (en) * 2009-04-17 2012-02-22 Johnson Matthey Public Limited Company Small pore molecular sieve supported copper catalysts durable against lean/rich aging for the reduction of nitrogen oxides
EP2687284A1 (en) * 2009-06-08 2014-01-22 Basf Se Cu containing silicoaluminophosphate (Cu-SAPO-34)
JP5797749B2 (ja) 2010-05-21 2015-10-21 ピーキュー コーポレイション NOx還元のための新規の金属含有ゼオライトベータ
PL2428659T3 (pl) * 2010-09-13 2017-01-31 Umicore Ag & Co. Kg Katalizator do usuwania tlenków azotu ze spalin silników wysokoprężnych
KR101948254B1 (ko) * 2011-04-18 2019-02-14 피큐 코포레이션 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법
US9517458B2 (en) * 2011-12-02 2016-12-13 Pq Corporation Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of NOx

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101674885A (zh) * 2007-03-26 2010-03-17 Pq公司 包含具有8元环开孔结构的分子筛或沸石的新型微孔结晶材料及其制备方法和应用
CN101730575A (zh) * 2007-04-26 2010-06-09 约翰逊马西有限公司 过渡金属/沸石scr催化剂
CN101983103A (zh) * 2008-01-31 2011-03-02 巴斯夫公司 利用具有cha晶体结构的非沸石的含金属分子筛的催化剂、系统和方法
CN102215960A (zh) * 2008-11-06 2011-10-12 巴斯夫公司 具有低二氧化硅与氧化铝比率的菱沸石催化剂
CN102029175A (zh) * 2009-10-07 2011-04-27 福特环球技术公司 选择性催化还原剂及其制备方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104891528A (zh) * 2015-06-12 2015-09-09 杭州回水科技股份有限公司 铜胺络合物作为模板剂固相合成Cu-SAPO-34分子筛的方法
CN109071245A (zh) * 2016-02-01 2018-12-21 优美科股份公司及两合公司 用于直接合成含铁的aei-沸石催化剂的方法
CN110997138A (zh) * 2017-06-09 2020-04-10 巴斯夫公司 用于NOx减排的具有受控孔隙率的催化洗涂层
CN112236230A (zh) * 2018-05-14 2021-01-15 优美科股份公司及两合公司 稳定的小孔沸石
CN112236230B (zh) * 2018-05-14 2024-03-19 优美科股份公司及两合公司 稳定的小孔沸石

Also Published As

Publication number Publication date
KR102170639B1 (ko) 2020-10-27
EP2785643B1 (en) 2020-07-01
BR112014012846A2 (pt) 2017-06-13
EP2785644B1 (en) 2019-05-01
WO2013082560A1 (en) 2013-06-06
US20130142727A1 (en) 2013-06-06
WO2013082550A1 (en) 2013-06-06
JP6427610B2 (ja) 2018-11-21
JP2015502909A (ja) 2015-01-29
JP6320298B2 (ja) 2018-05-09
US9517458B2 (en) 2016-12-13
CN103987662A (zh) 2014-08-13
EP2785644A1 (en) 2014-10-08
EP2785643A1 (en) 2014-10-08
JP6104270B2 (ja) 2017-03-29
BR112014012818A2 (pt) 2017-06-13
BR112014012846B1 (pt) 2021-10-26
CN108249454A (zh) 2018-07-06
KR20140107366A (ko) 2014-09-04
KR20140107365A (ko) 2014-09-04
KR102078083B1 (ko) 2020-02-20
CN103987662B (zh) 2018-10-23
JP2017141154A (ja) 2017-08-17
JP2015505290A (ja) 2015-02-19

Similar Documents

Publication Publication Date Title
CN103987662B (zh) 稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途
JP5762816B2 (ja) 8員環細孔開口構造を有するモレキュラーシーブまたはゼオライトを含んで成る新規マイクロポーラス結晶性物質およびその製法およびその使用
US9981256B2 (en) Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of NOx
JP2015502909A5 (https=)
KR20130019372A (ko) 선택적 촉매 환원을 위한 고-실리카 체바자이트, 이를 제조하는 방법 및 이를 사용하는 방법
JP2014515723A (ja) 大型結晶で有機を含まないチャバザイトと、同材料の作成方法および使用方法
CN107548380B (zh) 稳定化的微孔晶态材料、其制备方法和用于NOx的选择性催化还原的用途
CN112243427B (zh) 具有高酸度的低二氧化硅菱沸石沸石
CN104203823A (zh) 获自无有机模板合成法的含铁和铜的沸石β及其在选择性催化还原NOx中的用途
US10377638B2 (en) Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of NOx

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20140910

RJ01 Rejection of invention patent application after publication