CN103827416B - 非水电解液和包含其的电化学电池 - Google Patents
非水电解液和包含其的电化学电池 Download PDFInfo
- Publication number
- CN103827416B CN103827416B CN201280024774.7A CN201280024774A CN103827416B CN 103827416 B CN103827416 B CN 103827416B CN 201280024774 A CN201280024774 A CN 201280024774A CN 103827416 B CN103827416 B CN 103827416B
- Authority
- CN
- China
- Prior art keywords
- fluorinated
- ester
- electrolyte
- phosphonitrile
- fluorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000008151 electrolyte solution Substances 0.000 title claims abstract description 18
- -1 fluorinated alkyl phosphates Chemical class 0.000 claims abstract description 128
- 239000003792 electrolyte Substances 0.000 claims abstract description 101
- 150000002148 esters Chemical class 0.000 claims abstract description 88
- ZSTLPJLUQNQBDQ-UHFFFAOYSA-N azanylidyne(dihydroxy)-$l^{5}-phosphane Chemical class OP(O)#N ZSTLPJLUQNQBDQ-UHFFFAOYSA-N 0.000 claims abstract description 57
- 239000002904 solvent Substances 0.000 claims abstract description 49
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 46
- 235000021317 phosphate Nutrition 0.000 claims abstract description 44
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 32
- 239000002253 acid Substances 0.000 claims abstract description 31
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000010452 phosphate Substances 0.000 claims abstract description 26
- 229910003002 lithium salt Inorganic materials 0.000 claims abstract description 19
- 159000000002 lithium salts Chemical class 0.000 claims abstract description 18
- 150000003009 phosphonic acids Chemical class 0.000 claims abstract description 18
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000002170 ethers Chemical class 0.000 claims abstract description 17
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 49
- 229910052731 fluorine Inorganic materials 0.000 claims description 34
- 239000011737 fluorine Substances 0.000 claims description 32
- 125000001424 substituent group Chemical group 0.000 claims description 24
- 150000001875 compounds Chemical class 0.000 claims description 21
- 239000000654 additive Substances 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 14
- 238000003682 fluorination reaction Methods 0.000 claims description 14
- 229910001416 lithium ion Inorganic materials 0.000 claims description 14
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 13
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 13
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 12
- 125000003545 alkoxy group Chemical group 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 229910052717 sulfur Inorganic materials 0.000 claims description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- 150000002367 halogens Chemical class 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 10
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 10
- 239000011593 sulfur Substances 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 125000005083 alkoxyalkoxy group Chemical group 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 125000001153 fluoro group Chemical group F* 0.000 claims description 7
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- 229910032387 LiCoO2 Inorganic materials 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 230000004888 barrier function Effects 0.000 claims description 4
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims description 4
- 150000005676 cyclic carbonates Chemical class 0.000 claims description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 4
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052493 LiFePO4 Inorganic materials 0.000 claims description 3
- 229910002993 LiMnO2 Inorganic materials 0.000 claims description 3
- 229910000668 LiMnPO4 Inorganic materials 0.000 claims description 3
- 229910002097 Lithium manganese(III,IV) oxide Inorganic materials 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 239000003575 carbonaceous material Substances 0.000 claims description 3
- MJIULRNAOLSIHL-UHFFFAOYSA-N carbonic acid;fluoroethene Chemical group FC=C.OC(O)=O MJIULRNAOLSIHL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000012744 reinforcing agent Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 3
- UXNHBGSSJKNMKN-UHFFFAOYSA-N 2,2,2-trifluoroethyl propanoate Chemical compound CCC(=O)OCC(F)(F)F UXNHBGSSJKNMKN-UHFFFAOYSA-N 0.000 claims description 2
- ZRNSSRODJSSVEJ-UHFFFAOYSA-N 2-methylpentacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(C)C ZRNSSRODJSSVEJ-UHFFFAOYSA-N 0.000 claims description 2
- BJWMSGRKJIOCNR-UHFFFAOYSA-N 4-ethenyl-1,3-dioxolan-2-one Chemical compound C=CC1COC(=O)O1 BJWMSGRKJIOCNR-UHFFFAOYSA-N 0.000 claims description 2
- HZCDANOFLILNSA-UHFFFAOYSA-N Dimethyl hydrogen phosphite Chemical class COP(=O)OC HZCDANOFLILNSA-UHFFFAOYSA-N 0.000 claims description 2
- 229910011954 Li2.6Co0.4N Inorganic materials 0.000 claims description 2
- 229910011972 Li2.6Cu0.4N Inorganic materials 0.000 claims description 2
- 229910010820 Li2B10Cl10 Inorganic materials 0.000 claims description 2
- 229910011123 Li2B12FxH(12-x) Inorganic materials 0.000 claims description 2
- 229910012330 Li3Bi Inorganic materials 0.000 claims description 2
- 229910012398 Li3Cd Inorganic materials 0.000 claims description 2
- 229910012621 Li3FeN2 Inorganic materials 0.000 claims description 2
- 229910012862 Li3Sb Inorganic materials 0.000 claims description 2
- 229910011724 Li4.4Pb Inorganic materials 0.000 claims description 2
- 229910002980 Li4.4Sn Inorganic materials 0.000 claims description 2
- 229910012019 Li4Si Inorganic materials 0.000 claims description 2
- 229910002986 Li4Ti5O12 Inorganic materials 0.000 claims description 2
- 229910010199 LiAl Inorganic materials 0.000 claims description 2
- 229910013098 LiBF2 Inorganic materials 0.000 claims description 2
- 229910013103 LiBFy Inorganic materials 0.000 claims description 2
- 229910013458 LiC6 Inorganic materials 0.000 claims description 2
- 229910000552 LiCF3SO3 Inorganic materials 0.000 claims description 2
- 229910010584 LiFeO2 Inorganic materials 0.000 claims description 2
- 229910016087 LiMn0.5Ni0.5O2 Inorganic materials 0.000 claims description 2
- 229910014071 LiMn1/3Co1/3Ni1/3O2 Inorganic materials 0.000 claims description 2
- 229910013403 LiN(SO2CmF2m+1)(SO2CnF2n+1) Inorganic materials 0.000 claims description 2
- 229910003005 LiNiO2 Inorganic materials 0.000 claims description 2
- 229910013084 LiNiPO4 Inorganic materials 0.000 claims description 2
- 229910013179 LiNixCo1-xO2 Inorganic materials 0.000 claims description 2
- 229910013171 LiNixCo1−xO2 Inorganic materials 0.000 claims description 2
- 229910013172 LiNixCoy Inorganic materials 0.000 claims description 2
- 229910013831 LiP(O2CCF2CO2)3 Inorganic materials 0.000 claims description 2
- 229910013876 LiPF2 Inorganic materials 0.000 claims description 2
- 229910013880 LiPF4 Inorganic materials 0.000 claims description 2
- 229910012231 LiPFx Inorganic materials 0.000 claims description 2
- 229910012464 LiTaF6 Inorganic materials 0.000 claims description 2
- 229910013011 LiVPO4 Inorganic materials 0.000 claims description 2
- 229910013391 LizN Inorganic materials 0.000 claims description 2
- 229910006092 SO2CmF2m+1 Inorganic materials 0.000 claims description 2
- STSCVKRWJPWALQ-UHFFFAOYSA-N TRIFLUOROACETIC ACID ETHYL ESTER Chemical compound CCOC(=O)C(F)(F)F STSCVKRWJPWALQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000010290 biphenyl Nutrition 0.000 claims description 2
- 239000004305 biphenyl Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 125000003784 fluoroethyl group Chemical group [H]C([H])(F)C([H])([H])* 0.000 claims description 2
- 229910001547 lithium hexafluoroantimonate(V) Inorganic materials 0.000 claims description 2
- 229910001540 lithium hexafluoroarsenate(V) Inorganic materials 0.000 claims description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims description 2
- 229910001537 lithium tetrachloroaluminate Inorganic materials 0.000 claims description 2
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- GBPVMEKUJUKTBA-UHFFFAOYSA-N methyl 2,2,2-trifluoroethyl carbonate Chemical compound COC(=O)OCC(F)(F)F GBPVMEKUJUKTBA-UHFFFAOYSA-N 0.000 claims description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N monofluoromethane Natural products FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 2
- 239000011815 overcharge protection agent Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 229960004692 perflenapent Drugs 0.000 claims description 2
- NJCBUSHGCBERSK-UHFFFAOYSA-N perfluoropentane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F NJCBUSHGCBERSK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004014 plasticizer Substances 0.000 claims description 2
- STBRWEWUESLURQ-UHFFFAOYSA-N propyl 2,2,2-trifluoroethyl carbonate Chemical compound CCCOC(=O)OCC(F)(F)F STBRWEWUESLURQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000008053 sultones Chemical class 0.000 claims description 2
- XPDWGBQVDMORPB-UHFFFAOYSA-N trifluoromethane acid Natural products FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 claims description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 2
- 238000005728 strengthening Methods 0.000 claims 2
- YJPJOELHSKMFPG-UHFFFAOYSA-N 4,5-dimethylidene-1,3-dioxolan-2-one Chemical compound C=C1OC(=O)OC1=C YJPJOELHSKMFPG-UHFFFAOYSA-N 0.000 claims 1
- VEAZEJOYTMHCKW-UHFFFAOYSA-N carbonic acid fluoroethane Chemical compound CCF.C(O)(O)=O VEAZEJOYTMHCKW-UHFFFAOYSA-N 0.000 claims 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 abstract description 9
- 230000004087 circulation Effects 0.000 description 16
- 230000000996 additive effect Effects 0.000 description 13
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 11
- 239000000243 solution Substances 0.000 description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 7
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000001294 propane Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 150000003457 sulfones Chemical class 0.000 description 6
- 229910001290 LiPF6 Inorganic materials 0.000 description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 5
- 229910021437 lithium-transition metal oxide Inorganic materials 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 150000001491 aromatic compounds Chemical class 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 125000004437 phosphorous atom Chemical group 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- LARLSBWABHVOTC-UHFFFAOYSA-N 1,1-bis(4-chlorophenyl)-2,2,2-trifluoroethanol Chemical compound C=1C=C(Cl)C=CC=1C(C(F)(F)F)(O)C1=CC=C(Cl)C=C1 LARLSBWABHVOTC-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 102100037528 ER membrane protein complex subunit 3 Human genes 0.000 description 3
- 101000880977 Homo sapiens ER membrane protein complex subunit 3 Proteins 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical class [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 2
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- WNVHQQDSLWEGMV-UHFFFAOYSA-N C(CCC)S(=O)(=O)CCCC.[F] Chemical compound C(CCC)S(=O)(=O)CCCC.[F] WNVHQQDSLWEGMV-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- 150000007824 aliphatic compounds Chemical group 0.000 description 2
- 125000005600 alkyl phosphonate group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 2
- NMJJFJNHVMGPGM-UHFFFAOYSA-N butyl formate Chemical compound CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 150000001768 cations Chemical group 0.000 description 2
- IKDHALVKVCXQQI-UHFFFAOYSA-N difluoro propanedioate Chemical compound FOC(=O)CC(=O)OF IKDHALVKVCXQQI-UHFFFAOYSA-N 0.000 description 2
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 2
- VONWDASPFIQPDY-UHFFFAOYSA-N dimethyl methylphosphonate Chemical compound COP(C)(=O)OC VONWDASPFIQPDY-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- OBNCKNCVKJNDBV-UHFFFAOYSA-N ethyl butyrate Chemical compound CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 125000005816 fluoropropyl group Chemical group [H]C([H])(F)C([H])([H])C([H])([H])* 0.000 description 2
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 150000002596 lactones Chemical class 0.000 description 2
- 229910001386 lithium phosphate Inorganic materials 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 239000007773 negative electrode material Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- 239000012925 reference material Substances 0.000 description 2
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 description 2
- 239000007784 solid electrolyte Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical compound CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 229910000319 transition metal phosphate Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- BLBNEWYCYZMDEK-UHFFFAOYSA-N $l^{1}-indiganyloxyindium Chemical compound [In]O[In] BLBNEWYCYZMDEK-UHFFFAOYSA-N 0.000 description 1
- CDJCWEPKSBUOBR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenyl) dihydrogen phosphate Chemical class OP(O)(=O)OC1=C(F)C(F)=C(F)C(F)=C1F CDJCWEPKSBUOBR-UHFFFAOYSA-N 0.000 description 1
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 1
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- MZNOZCNMWMZOED-UHFFFAOYSA-N 1-(difluoromethoxy)butane Chemical compound CCCCOC(F)F MZNOZCNMWMZOED-UHFFFAOYSA-N 0.000 description 1
- YBJCDTIWNDBNTM-UHFFFAOYSA-N 1-methylsulfonylethane Chemical compound CCS(C)(=O)=O YBJCDTIWNDBNTM-UHFFFAOYSA-N 0.000 description 1
- HFZLSTDPRQSZCQ-UHFFFAOYSA-N 1-pyrrolidin-3-ylpyrrolidine Chemical compound C1CCCN1C1CNCC1 HFZLSTDPRQSZCQ-UHFFFAOYSA-N 0.000 description 1
- ZKUJOCJJXCPCFS-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2,2,2-trifluoroacetate Chemical compound FC(F)(F)COC(=O)C(F)(F)F ZKUJOCJJXCPCFS-UHFFFAOYSA-N 0.000 description 1
- ZOWSJJBOQDKOHI-UHFFFAOYSA-N 2,2,2-trifluoroethyl acetate Chemical compound CC(=O)OCC(F)(F)F ZOWSJJBOQDKOHI-UHFFFAOYSA-N 0.000 description 1
- QWXXHRSQCJGYQR-UHFFFAOYSA-N 2,2,3,3-tetrafluoropropyl 2,2,2-trifluoroacetate Chemical compound FC(F)C(F)(F)COC(=O)C(F)(F)F QWXXHRSQCJGYQR-UHFFFAOYSA-N 0.000 description 1
- MGGUINIFYAWUGP-UHFFFAOYSA-N 2,2,3,3-tetrafluoropropyl formate Chemical compound FC(F)C(F)(F)COC=O MGGUINIFYAWUGP-UHFFFAOYSA-N 0.000 description 1
- UHOPWFKONJYLCF-UHFFFAOYSA-N 2-(2-sulfanylethyl)isoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(CCS)C(=O)C2=C1 UHOPWFKONJYLCF-UHFFFAOYSA-N 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- ALZLTHLQMAFAPA-UHFFFAOYSA-N 3-Methylbutyrolactone Chemical compound CC1COC(=O)C1 ALZLTHLQMAFAPA-UHFFFAOYSA-N 0.000 description 1
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 1
- KLSZDDTXTQEUSX-UHFFFAOYSA-N 4-methylidene-1,3-dioxolan-2-one Chemical compound C=C1COC(=O)O1 KLSZDDTXTQEUSX-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- NDERRIHSWCOMJJ-UHFFFAOYSA-N C(C(=C)C)(=O)OC(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(=O)(O)(O)O Chemical compound C(C(=C)C)(=O)OC(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(=O)(O)(O)O NDERRIHSWCOMJJ-UHFFFAOYSA-N 0.000 description 1
- JVSZDADEHKJNLY-UHFFFAOYSA-N C(O)(O)=O.[F] Chemical compound C(O)(O)=O.[F] JVSZDADEHKJNLY-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- QGLBZNZGBLRJGS-UHFFFAOYSA-N Dihydro-3-methyl-2(3H)-furanone Chemical compound CC1CCOC1=O QGLBZNZGBLRJGS-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 240000001624 Espostoa lanata Species 0.000 description 1
- 235000009161 Espostoa lanata Nutrition 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- JGFBQFKZKSSODQ-UHFFFAOYSA-N Isothiocyanatocyclopropane Chemical compound S=C=NC1CC1 JGFBQFKZKSSODQ-UHFFFAOYSA-N 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- 229910010882 Li2B10F10 Inorganic materials 0.000 description 1
- 229910011279 LiCoPO4 Inorganic materials 0.000 description 1
- 229910013353 LiMSiOxFy Inorganic materials 0.000 description 1
- 229910014689 LiMnO Inorganic materials 0.000 description 1
- 229910015124 LiMnzNi1-zO2 Inorganic materials 0.000 description 1
- 229910011456 LiNi0.80Co0.15Al0.05O2 Inorganic materials 0.000 description 1
- 229910014422 LiNi1/3Mn1/3Co1/3O2 Inorganic materials 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 229910003092 TiS2 Inorganic materials 0.000 description 1
- DTQVDTLACAAQTR-UHFFFAOYSA-M Trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-M 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Inorganic materials O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 description 1
- 229910000411 antimony tetroxide Inorganic materials 0.000 description 1
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- YAVVGPBYBUYPSR-UHFFFAOYSA-N benzene;oxygen Chemical compound [O].C1=CC=CC=C1 YAVVGPBYBUYPSR-UHFFFAOYSA-N 0.000 description 1
- VEZXCJBBBCKRPI-UHFFFAOYSA-N beta-propiolactone Chemical compound O=C1CCO1 VEZXCJBBBCKRPI-UHFFFAOYSA-N 0.000 description 1
- 235000010338 boric acid Nutrition 0.000 description 1
- 229960002645 boric acid Drugs 0.000 description 1
- 229940043232 butyl acetate Drugs 0.000 description 1
- PWLNAUNEAKQYLH-UHFFFAOYSA-N butyric acid octyl ester Natural products CCCCCCCCOC(=O)CCC PWLNAUNEAKQYLH-UHFFFAOYSA-N 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000004651 carbonic acid esters Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- QLVWOKQMDLQXNN-UHFFFAOYSA-N dibutyl carbonate Chemical compound CCCCOC(=O)OCCCC QLVWOKQMDLQXNN-UHFFFAOYSA-N 0.000 description 1
- GADKBQVQNRVFNR-UHFFFAOYSA-N dimethyl 2,2,3,3-tetrafluoropropyl phosphate Chemical compound COP(=O)(OC)OCC(F)(F)C(F)F GADKBQVQNRVFNR-UHFFFAOYSA-N 0.000 description 1
- 229940113088 dimethylacetamide Drugs 0.000 description 1
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 229950000929 flurotyl Drugs 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- YADSGOSSYOOKMP-UHFFFAOYSA-N lead dioxide Inorganic materials O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 1
- XMFOQHDPRMAJNU-UHFFFAOYSA-N lead(II,IV) oxide Inorganic materials O1[Pb]O[Pb]11O[Pb]O1 XMFOQHDPRMAJNU-UHFFFAOYSA-N 0.000 description 1
- 239000001989 lithium alloy Substances 0.000 description 1
- 229910021450 lithium metal oxide Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
- 229910052960 marcasite Inorganic materials 0.000 description 1
- 101150003203 mec gene Proteins 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- KKQAVHGECIBFRQ-UHFFFAOYSA-N methyl propyl carbonate Chemical compound CCCOC(=O)OC KKQAVHGECIBFRQ-UHFFFAOYSA-N 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- AJFDBNQQDYLMJN-UHFFFAOYSA-N n,n-diethylacetamide Chemical compound CCN(CC)C(C)=O AJFDBNQQDYLMJN-UHFFFAOYSA-N 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- YYSONLHJONEUMT-UHFFFAOYSA-N pentan-3-yl hydrogen carbonate Chemical compound CCC(CC)OC(O)=O YYSONLHJONEUMT-UHFFFAOYSA-N 0.000 description 1
- 229920002627 poly(phosphazenes) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229960000380 propiolactone Drugs 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- CDXJNCAVPFGVNL-UHFFFAOYSA-N propyl 2,2,2-trifluoroacetate Chemical compound CCCOC(=O)C(F)(F)F CDXJNCAVPFGVNL-UHFFFAOYSA-N 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- HUAZGNHGCJGYNP-UHFFFAOYSA-N propyl butyrate Chemical compound CCCOC(=O)CCC HUAZGNHGCJGYNP-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- ARUIMKUOHIINGI-UHFFFAOYSA-N trifluoro(methylsulfonyl)methane Chemical compound CS(=O)(=O)C(F)(F)F ARUIMKUOHIINGI-UHFFFAOYSA-N 0.000 description 1
- AEXDMFVPDVVSQJ-UHFFFAOYSA-N trifluoro(trifluoromethylsulfonyl)methane Chemical compound FC(F)(F)S(=O)(=O)C(F)(F)F AEXDMFVPDVVSQJ-UHFFFAOYSA-N 0.000 description 1
- OFXXJYOIFRONMN-UHFFFAOYSA-N trifluoromethyl 2,2,2-trifluoroacetate Chemical compound FC(F)(F)OC(=O)C(F)(F)F OFXXJYOIFRONMN-UHFFFAOYSA-N 0.000 description 1
- SFENPMLASUEABX-UHFFFAOYSA-N trihexyl phosphate Chemical compound CCCCCCOP(=O)(OCCCCCC)OCCCCCC SFENPMLASUEABX-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/4911—Electric battery cell making including sealing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
组分 | 重量% | ||||
锂盐 | 5-25 | 8-20 | 10-18 | 10-15 | 12-14 |
碳酸酯溶剂 | 35-85 | 40-80 | 45-75 | 50-70 | 55-70 |
磷腈溶剂 | 0.01-15 | 0.1-8 | 1-7 | 1-6 | 2-6 |
氟化溶剂 | 0.1-30 | 1-25 | 5-20 | 10-20 | 10-15 |
有机磷酸酯/膦酸酯 | 0-20 | 1-15 | 5-20 | 10-20 | 10-15 |
Claims (25)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161473958P | 2011-04-11 | 2011-04-11 | |
US61/473,958 | 2011-04-11 | ||
PCT/US2012/032960 WO2012142060A2 (en) | 2011-04-11 | 2012-04-11 | Non-aqueous electrolytic solutions and electrochemical cells comprising the same |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103827416A CN103827416A (zh) | 2014-05-28 |
CN103827416B true CN103827416B (zh) | 2016-08-17 |
Family
ID=47009925
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201280024774.7A Active CN103827416B (zh) | 2011-04-11 | 2012-04-11 | 非水电解液和包含其的电化学电池 |
Country Status (6)
Country | Link |
---|---|
US (1) | US10056649B2 (zh) |
EP (1) | EP2697453B1 (zh) |
JP (1) | JP6230989B2 (zh) |
KR (1) | KR20140034179A (zh) |
CN (1) | CN103827416B (zh) |
WO (1) | WO2012142060A2 (zh) |
Families Citing this family (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6310848B2 (ja) * | 2012-08-10 | 2018-04-11 | 日本ケミコン株式会社 | 難燃性電解コンデンサ |
JP2014078433A (ja) * | 2012-10-11 | 2014-05-01 | Fujifilm Corp | 非水二次電池用電解液および非水電解液二次電池 |
CN103811811B (zh) * | 2012-11-06 | 2017-02-22 | 万向电动汽车有限公司 | 一种锂离子动力电池用阻燃电解液及采用其制备的锂离子动力电池 |
EP2917957B1 (en) * | 2012-11-12 | 2018-08-08 | Shenzhen Capchem Technology Co. Ltd. | Non-aqueous electrolytic solutions and electrochemical cells comprising same |
CN103275116B (zh) * | 2013-04-07 | 2015-11-18 | 深圳新宙邦科技股份有限公司 | 三-六氟异丙基磷酸酯的制备方法 |
FR3009829B1 (fr) * | 2013-08-23 | 2015-09-25 | Commissariat Energie Atomique | Composes fluores utilisables comme solvant organique pour sels de lithium |
JP6410417B2 (ja) * | 2013-08-30 | 2018-10-24 | 旭化成株式会社 | 非水系リチウム型蓄電素子 |
CN104638301A (zh) * | 2013-11-13 | 2015-05-20 | 浙江省化工研究院有限公司 | 一种高电压锂离子电池电解液 |
JPWO2015098626A1 (ja) * | 2013-12-27 | 2017-03-23 | 日立化成株式会社 | リチウムイオン二次電池 |
KR102272272B1 (ko) | 2014-07-11 | 2021-07-02 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 전해액 및 이를 포함하는 리튬 이차 전지 |
US10707526B2 (en) | 2015-03-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
KR20160135513A (ko) * | 2015-05-18 | 2016-11-28 | 주식회사 엘지화학 | 리튬이차전지용 비수 전해액 및 이를 포함한 리튬이차전지 |
CA2994808C (en) * | 2015-08-04 | 2023-12-05 | E.I. Du Pont De Nemours And Company | Nonaqueous electrolyte compositions comprising lithium oxalato phosphates |
US10468722B2 (en) | 2015-08-04 | 2019-11-05 | California Institute Of Technology | Organic synthesis applications of non-aqueous fluoride salt solutions |
US20180198160A1 (en) * | 2015-08-31 | 2018-07-12 | Sekisui Chemical Co., Ltd. | Electrolyte solution and lithium ion secondary battery |
CN105355975B (zh) * | 2015-10-20 | 2018-08-21 | 宁德新能源科技有限公司 | 电解液以及包括该电解液的锂离子电池 |
CN105655641B (zh) * | 2016-03-30 | 2019-01-08 | 宁德新能源科技有限公司 | 一种电解液及其锂离子电池 |
CN106025355A (zh) * | 2016-05-17 | 2016-10-12 | 山东海容电源材料有限公司 | 一种阻燃型高安全非水电解液及其加工方法 |
US10707531B1 (en) | 2016-09-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
WO2018165824A1 (en) | 2017-03-13 | 2018-09-20 | GM Global Technology Operations LLC | Methods to stabilize lithium titanate oxide (lto) by electrolyte pretreatment |
DE112017007080T5 (de) * | 2017-03-13 | 2019-12-05 | GM Global Technology Operations LLC | Verfahren zum stabilisieren von lithiumtitanatoxid (lto) durch oberflächenbeschichtung |
CN107293785B (zh) * | 2017-06-02 | 2020-06-19 | 山东大学 | 一种不可燃锂离子电池电解液及其制备方法 |
EP4106070A1 (en) * | 2017-07-17 | 2022-12-21 | Nohms Technologies, Inc. | Phosphorus-containing electrolytes |
US11855259B2 (en) | 2017-08-22 | 2023-12-26 | Renewable Energy Platform Co., Ltd. | Electrolyte for lithium secondary battery and lithium secondary battery comprising same |
FR3070532A1 (fr) * | 2017-08-22 | 2019-03-01 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Composition electrolytique comprenant un additif de la famille des phosphazenes utilisables pour des supercondensateurs |
US10818973B2 (en) * | 2017-10-25 | 2020-10-27 | Toyota Jidosha Kabushiki Kaisha | Electrolyte composition and lithium ion secondary battery |
JP7112419B2 (ja) | 2017-10-31 | 2022-08-03 | 関東電化工業株式会社 | 非水電解液及び非水電解液電池 |
CN108808085B (zh) * | 2018-07-12 | 2020-09-04 | 合肥国轩高科动力能源有限公司 | 一种提高锂离子电池耐热失控性能的电解液 |
WO2020092266A1 (en) * | 2018-10-30 | 2020-05-07 | Enevate Corporation | Silicon-based energy storage devices with phosphazene containing electrolyte additives |
CN109599592B (zh) * | 2018-11-07 | 2022-07-15 | 上海交通大学 | 一种二次锂硫电池用本征安全性电解液及其制备方法 |
CN109449511B (zh) * | 2018-11-12 | 2021-08-17 | 中国科学院宁波材料技术与工程研究所 | 一种锂离子电池电极的保护方法 |
CN112242562A (zh) * | 2019-07-16 | 2021-01-19 | 东莞市杉杉电池材料有限公司 | 一种阻燃型锂离子电池电解液及含该电解液的锂离子电池 |
CN112448034A (zh) * | 2019-09-05 | 2021-03-05 | 东莞市杉杉电池材料有限公司 | 一种高电压锂离子电池用非水电解液及锂离子电池 |
US11908998B2 (en) * | 2019-09-18 | 2024-02-20 | Apple Inc. | Liquid electrolyte for lithium metal battery |
CN111029651B (zh) * | 2019-12-20 | 2022-08-02 | 中国电子科技集团公司第十八研究所 | 一种锂金属电池用原位负极表面处理方法 |
CN111193070B (zh) * | 2020-01-11 | 2022-05-17 | 山东理工大学 | 一种含有聚磷腈主链的锂离子电池阻燃电解质的制备方法 |
CN113394452A (zh) * | 2020-03-13 | 2021-09-14 | 安徽盟维新能源科技有限公司 | 锂金属电池用电解液及锂金属电池 |
KR20230121111A (ko) * | 2020-12-14 | 2023-08-17 | 에스이에스 홀딩스 피티이. 엘티디. | 비플루오르화 하이브리드-에테르 공용매 시스템을 포함하는전해질, 이러한 전해질을 제조하는 방법, 및 이러한 전해질을 활용하는 전기화학 소자 |
US20240136586A1 (en) * | 2021-02-08 | 2024-04-25 | The Industry & Academic Cooperation In Chungnam National University (Iac) | Flame retardant or nonflammable electrolytic solution, and lithium secondary battery comprising same |
CN113113669B (zh) * | 2021-04-09 | 2022-05-17 | 珠海市赛纬电子材料股份有限公司 | 电解液添加剂和含有该添加剂的非水电解液及锂离子电池 |
KR20230000593A (ko) * | 2021-06-25 | 2023-01-03 | 주식회사 엘지에너지솔루션 | 리튬-황 전지용 전해액 및 이를 포함하는 리튬-황 전지 |
CN113745662A (zh) * | 2021-09-09 | 2021-12-03 | 中国科学院长春应用化学研究所 | 一种阻燃型宽温域电解液及其制备方法与应用 |
WO2023106214A1 (ja) * | 2021-12-09 | 2023-06-15 | 京セラ株式会社 | 電解液、二次電池および半固体電池 |
CN114552010B (zh) * | 2022-02-23 | 2022-12-09 | 珠海市赛纬电子材料股份有限公司 | 锂金属电池用添加剂、电解液及其锂金属电池 |
CN115000521A (zh) * | 2022-06-01 | 2022-09-02 | 哈尔滨工业大学 | 一种用于锂电池宽温度窗口运行的电解液及其制备方法和磷酸铁锂锂金属电池 |
CN117438648A (zh) * | 2022-07-15 | 2024-01-23 | 华为技术有限公司 | 局部高浓度电解液、二次电池、电子设备和移动装置 |
KR102559718B1 (ko) * | 2022-08-05 | 2023-07-25 | 충남대학교산학협력단 | 고속 충전 리튬이차전지용 전해액, 이를 포함하는 리튬이차전지 및 리튬이차전지의 제조 방법 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101057355A (zh) * | 2004-10-05 | 2007-10-17 | 株式会社普利司通 | 非水电解质和包括该非水电解质的非水电解质电池 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6168885B1 (en) * | 1998-08-21 | 2001-01-02 | Sri International | Fabrication of electrodes and devices containing electrodes |
JP2003249233A (ja) | 2002-02-25 | 2003-09-05 | Bridgestone Corp | リチウム1次電池 |
WO2005064734A1 (ja) | 2003-12-26 | 2005-07-14 | Bridgestone Corporation | 電池用非水電解液及びそれを備えた非水電解液電池、並びにポリマー電池用電解質及びそれを備えたポリマー電池 |
US20080153005A1 (en) * | 2004-10-05 | 2008-06-26 | Bridgestone Corporation | Non-Aqueous Electrolyte and Non-Aqueous Electrolyte Battery Comprising the Same |
CN101894975B (zh) * | 2004-12-16 | 2011-09-14 | U芝加哥阿谷尼有限公司 | 具有稳定电极的长寿命的锂电池 |
JP4953605B2 (ja) * | 2005-09-14 | 2012-06-13 | 株式会社ブリヂストン | 二次電池用ポリマーゲル電解質及びそれを用いたポリマー二次電池 |
JP2007200605A (ja) | 2006-01-24 | 2007-08-09 | Bridgestone Corp | 非水電解液及びそれを備えた非水電解液電池 |
WO2009028567A1 (ja) * | 2007-08-27 | 2009-03-05 | Bridgestone Corporation | 電池用非水電解液及びそれを備えた非水電解液電池 |
JP2009158460A (ja) * | 2007-12-05 | 2009-07-16 | Sony Corp | 非水電解液二次電池 |
JP2010015717A (ja) * | 2008-07-01 | 2010-01-21 | Bridgestone Corp | 電池用非水電解液及びそれを備えた非水電解液二次電池 |
US8795903B2 (en) * | 2008-08-19 | 2014-08-05 | California Institute Of Technology | Lithium-ion electrolytes containing flame retardant additives for increased safety characteristics |
JP2011054406A (ja) | 2009-09-01 | 2011-03-17 | Mitsui Chemicals Inc | 非水電解液及びそれを用いた非水電解質二次電池 |
CN102239596A (zh) * | 2009-09-02 | 2011-11-09 | 松下电器产业株式会社 | 非水溶剂、使用了该非水溶剂的非水电解液以及非水系二次电池 |
KR20110056150A (ko) * | 2009-11-20 | 2011-05-26 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 난연성 전해액 및 이를 포함하는 리튬 이차 전지 |
CN101826635A (zh) * | 2010-04-09 | 2010-09-08 | 广州天赐高新材料股份有限公司 | 一种锂电池用聚合物电解液及其电池的制造方法 |
JP5622424B2 (ja) * | 2010-04-14 | 2014-11-12 | 東ソー・ファインケム株式会社 | 二次電池用電解液 |
US10438753B2 (en) * | 2010-07-06 | 2019-10-08 | The United States Of America As Represented By The Secretary Of The Army | Electrolytes in support of 5V Li ion chemistry |
US9123973B2 (en) | 2010-12-22 | 2015-09-01 | Samsung Sdi Co., Ltd. | Electrolyte for lithium secondary battery and lithium secondary battery comprising the same |
-
2012
- 2012-04-11 CN CN201280024774.7A patent/CN103827416B/zh active Active
- 2012-04-11 JP JP2014505224A patent/JP6230989B2/ja active Active
- 2012-04-11 US US14/110,640 patent/US10056649B2/en active Active
- 2012-04-11 EP EP12771362.6A patent/EP2697453B1/en active Active
- 2012-04-11 KR KR1020137029438A patent/KR20140034179A/ko not_active Application Discontinuation
- 2012-04-11 WO PCT/US2012/032960 patent/WO2012142060A2/en active Application Filing
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101057355A (zh) * | 2004-10-05 | 2007-10-17 | 株式会社普利司通 | 非水电解质和包括该非水电解质的非水电解质电池 |
Non-Patent Citations (1)
Title |
---|
Application of Fluorine-containing Solvents to LiCoO2 Cathode in High Voltage Operation;Takeshi KITAGAWA et.al;《Electrochemistry》;20101231;第78卷(第5期);第345页摘要以及第345-346页第2节实验部分 * |
Also Published As
Publication number | Publication date |
---|---|
WO2012142060A2 (en) | 2012-10-18 |
US20140038059A1 (en) | 2014-02-06 |
KR20140034179A (ko) | 2014-03-19 |
CN103827416A (zh) | 2014-05-28 |
US10056649B2 (en) | 2018-08-21 |
WO2012142060A3 (en) | 2014-05-08 |
EP2697453A2 (en) | 2014-02-19 |
JP6230989B2 (ja) | 2017-11-15 |
JP2014522077A (ja) | 2014-08-28 |
EP2697453B1 (en) | 2018-10-10 |
EP2697453A4 (en) | 2015-07-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103827416B (zh) | 非水电解液和包含其的电化学电池 | |
CN100486009C (zh) | 非水电解质和包括该非水电解质的非水电解质电池 | |
CN101847750B (zh) | 阻燃电解液、可再充电锂电池及其制造方法 | |
US7638243B2 (en) | Stabilized nonaqueous electrolytes for rechargeable batteries | |
KR101201805B1 (ko) | 리튬 이온 전지용 전해액 및 이를 포함하는 리튬 이온 전지 | |
CN106558732B (zh) | 一种锂离子电池电解液和锂离子电池 | |
US20060236528A1 (en) | Non-aqueous electrolytic solution | |
EP1875540B1 (en) | Non-aqueous electrolytic solution | |
KR20110056150A (ko) | 리튬 이차 전지용 난연성 전해액 및 이를 포함하는 리튬 이차 전지 | |
CN106356558A (zh) | 可再充电锂二次电池的阻燃电解液及含其的锂二次电池 | |
WO2012161305A1 (ja) | 非水電解液及びこれを用いたリチウムイオン二次電池 | |
KR101298868B1 (ko) | 비수 전해액 및 이것을 이용한 리튬 2차 전지 | |
JP2002025615A (ja) | リチウム二次電池 | |
JP5811361B2 (ja) | 二次電池 | |
CN110970662B (zh) | 非水电解液及锂离子电池 | |
CN103403950A (zh) | 锂离子电池 | |
CN103904364A (zh) | 锂离子二次电池及其电解液 | |
Smart et al. | The evaluation of triphenyl phosphate as a flame retardant additive to improve the safety of lithium-ion battery electrolytes | |
CN110970664A (zh) | 非水电解液及锂离子电池 | |
CN104821413A (zh) | 电解液和包括该电解液的可再充电锂电池 | |
CN113809397B (zh) | 一种电解液、锂离子电池及电解液添加剂的应用 | |
CN110970663A (zh) | 非水电解液及锂离子电池 | |
CN110970659B (zh) | 非水电解液及锂离子电池 | |
WO2012174704A1 (en) | Battery electrolyte solutions containing aromatic phosphite compounds | |
CN110970652A (zh) | 非水电解液及锂离子电池 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20171201 Address after: Guangdong province Shenzhen City Pingshan sand Tang with rich industrial area Patentee after: Shenzhen Xinyubang Science and Technology Co., Ltd. Address before: new jersey Patentee before: BASF AG |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20181207 Address after: 215000 No. 15, East Suhong Road, Suzhou Industrial Park, Suzhou City, Jiangsu Province Patentee after: Noel battery material (Suzhou) Co., Ltd. Address before: 518118 Shatuo Tongfu Industrial Zone, Pingshan New District, Shenzhen City, Guangdong Province Patentee before: Shenzhen Xinyubang Science and Technology Co., Ltd. |
|
TR01 | Transfer of patent right |