CN103509422B - 一种疏水和疏油的涂层组合物 - Google Patents
一种疏水和疏油的涂层组合物 Download PDFInfo
- Publication number
- CN103509422B CN103509422B CN201210229101.7A CN201210229101A CN103509422B CN 103509422 B CN103509422 B CN 103509422B CN 201210229101 A CN201210229101 A CN 201210229101A CN 103509422 B CN103509422 B CN 103509422B
- Authority
- CN
- China
- Prior art keywords
- coating composition
- acid
- polyacrylic resin
- coating
- fluorosilicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000008199 coating composition Substances 0.000 title claims abstract description 61
- 230000002209 hydrophobic effect Effects 0.000 title abstract description 43
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 40
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 27
- 239000003960 organic solvent Substances 0.000 claims abstract description 19
- 239000002253 acid Substances 0.000 claims abstract description 18
- 239000011521 glass Substances 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 239000002184 metal Substances 0.000 claims abstract description 5
- 239000004033 plastic Substances 0.000 claims abstract description 5
- 239000010702 perfluoropolyether Substances 0.000 claims description 20
- -1 siloxanes Chemical class 0.000 claims description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 4
- 125000005909 ethyl alcohol group Chemical group 0.000 claims description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 239000000306 component Substances 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- 238000000576 coating method Methods 0.000 abstract description 46
- 239000011248 coating agent Substances 0.000 abstract description 45
- 239000000758 substrate Substances 0.000 abstract description 14
- 230000002045 lasting effect Effects 0.000 abstract description 5
- 238000007790 scraping Methods 0.000 abstract description 4
- 238000012360 testing method Methods 0.000 description 16
- 238000011156 evaluation Methods 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000003973 paint Substances 0.000 description 8
- 238000010422 painting Methods 0.000 description 6
- 230000002688 persistence Effects 0.000 description 6
- 239000002689 soil Substances 0.000 description 6
- 239000004922 lacquer Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- 239000003377 acid catalyst Substances 0.000 description 3
- 238000007665 sagging Methods 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 230000007480 spreading Effects 0.000 description 3
- 238000003892 spreading Methods 0.000 description 3
- 241000276489 Merlangius merlangus Species 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000005308 flint glass Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical compound C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000003900 soil pollution Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/092—Polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/76—Hydrophobic and oleophobic coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Surface Treatment Of Glass (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210229101.7A CN103509422B (zh) | 2012-06-29 | 2012-06-29 | 一种疏水和疏油的涂层组合物 |
| US14/411,199 US9382441B2 (en) | 2012-06-29 | 2013-06-27 | Hydrophobic and oleophobic coating composition |
| EP13888508.2A EP2882817A4 (en) | 2012-06-29 | 2013-06-27 | HYDROPHOBIC AND OLEOPHOBIC COATING COMPOSITION |
| PCT/IB2013/003262 WO2014004840A1 (en) | 2012-06-29 | 2013-06-27 | Hydrophobic and oleophobic coating composition |
| BR112014032893A BR112014032893A2 (pt) | 2012-06-29 | 2013-06-27 | composição de revestimento hidrofóbica e oleofóbica |
| JP2015542079A JP2015534601A (ja) | 2012-06-29 | 2013-06-27 | 疎水性且つ疎油性コーティング組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210229101.7A CN103509422B (zh) | 2012-06-29 | 2012-06-29 | 一种疏水和疏油的涂层组合物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103509422A CN103509422A (zh) | 2014-01-15 |
| CN103509422B true CN103509422B (zh) | 2018-07-31 |
Family
ID=49783862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210229101.7A Expired - Fee Related CN103509422B (zh) | 2012-06-29 | 2012-06-29 | 一种疏水和疏油的涂层组合物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9382441B2 (enExample) |
| EP (1) | EP2882817A4 (enExample) |
| JP (1) | JP2015534601A (enExample) |
| CN (1) | CN103509422B (enExample) |
| BR (1) | BR112014032893A2 (enExample) |
| WO (1) | WO2014004840A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6398500B2 (ja) * | 2014-09-10 | 2018-10-03 | 信越化学工業株式会社 | 含フッ素コーティング剤及び該コーティング剤で処理された物品 |
| JP6784023B2 (ja) * | 2014-12-26 | 2020-11-11 | 大日本印刷株式会社 | 組成物、該組成物を用いた部材、及びその製造方法、並びに該部材を備えたタッチパネル |
| DE102015103335A1 (de) * | 2015-03-06 | 2016-09-08 | Osram Opto Semiconductors Gmbh | Optoelektronische Vorrichtung und Verfahren zur Herstellung einer optoelektronischen Vorrichtung |
| CN104804148A (zh) * | 2015-05-05 | 2015-07-29 | 湖南晟通纳米新材料有限公司 | 氟硅丙烯酸酯乳液及其制备方法 |
| CN107922259B (zh) | 2015-09-04 | 2021-05-07 | Ａｇｃ株式会社 | 玻璃板的制造方法、玻璃板、玻璃物品的制造方法、玻璃物品以及玻璃物品的制造装置 |
| CN106189598B (zh) * | 2016-08-11 | 2018-08-14 | 无锡市虎皇漆业有限公司 | 双疏砂壁状涂料及其制备方法 |
| EP3508458B1 (en) * | 2016-09-01 | 2022-03-16 | Agc Inc. | Method for manufacturing glass product |
| CN108300303A (zh) * | 2016-09-28 | 2018-07-20 | 卢火青 | 高透射率疏水防尘的纳米涂层组合物及其制备方法和应用 |
| JP6531877B2 (ja) | 2017-02-21 | 2019-06-19 | Ａｇｃ株式会社 | ガラス板およびガラス板の製造方法 |
| CN107057542A (zh) * | 2017-06-08 | 2017-08-18 | 苏州蓝锐纳米科技有限公司 | 一种以三亚甲基碳酸酯为单体的镜面纳米涂料 |
| CN107022288A (zh) * | 2017-06-08 | 2017-08-08 | 苏州蓝锐纳米科技有限公司 | 一种电子产业用镜面抗磨纳米涂料及其制备方法 |
| CN107022287A (zh) * | 2017-06-08 | 2017-08-08 | 苏州蓝锐纳米科技有限公司 | 一种氟化疏水镜面纳米涂料及其制备方法 |
| CN111065304B (zh) | 2017-09-27 | 2022-04-12 | 金伯利-克拉克环球有限公司 | 分配器 |
| TR201807994A2 (tr) * | 2018-06-05 | 2018-06-21 | Atatuerk Ueniversitesi Bilimsel Arastirma Projeleri Birimi | Uv i̇le sertleşen, bi̇youyumlu, süperamfi̇fobi̇k kaplama |
| CN109897485A (zh) * | 2019-01-31 | 2019-06-18 | 苏州百联节能科技股份有限公司 | 一种新型隔热自洁环保涂料 |
| CN111732345A (zh) * | 2020-06-29 | 2020-10-02 | 几何智慧城市科技(广州)有限公司 | 一种常温快速制备透明超疏水复合涂层的方法 |
| CN114054319A (zh) * | 2020-07-30 | 2022-02-18 | 深圳市万普拉斯科技有限公司 | 一种涂层结构及其制备方法、包括该涂层结构的材料制品和电子产品 |
| RU2763134C1 (ru) * | 2020-09-15 | 2021-12-27 | Иван Соломонович Пятов | Фильтроэлемент для фильтрации жидкости |
| CN113121808B (zh) * | 2021-04-02 | 2022-12-13 | 汕头大学 | 氟硅改性多官能亚麻油基醇酸树脂uv固化涂料及制备与应用 |
| CN113308192A (zh) * | 2021-07-13 | 2021-08-27 | 安徽江锐新材料有限公司 | 一种耐热的有机硅耐高温底面漆及其制备工艺 |
| CN116410625B (zh) * | 2023-03-13 | 2024-04-23 | 东南大学 | 改性uv光油及基于改性光油制备透明防污涂层的方法 |
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| DE69232591T2 (de) | 1991-01-23 | 2002-08-22 | Matsushita Electric Industrial Co., Ltd. | Wasser- und Ölabweisende adsorbierte Folie |
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| TW376408B (en) * | 1995-12-01 | 1999-12-11 | Nissan Chemical Ind Ltd | Coating film having water repellency and low refractive index |
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| TWI384039B (zh) * | 2006-12-27 | 2013-02-01 | Ind Tech Res Inst | 透明疏水自潔塗料的製作方法、所製得之塗料以及塗膜 |
| JP5307004B2 (ja) | 2007-06-15 | 2013-10-02 | ダウ コーニング コーポレーション | 硬化性含フッ素ポリマー組成物 |
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| US9896549B2 (en) * | 2010-04-13 | 2018-02-20 | Aaron Kessman | Hydrophobic and oleophobic coatings |
| US8883314B2 (en) * | 2011-01-25 | 2014-11-11 | Corning Incorporated | Coated articles with improved fingerprint resistance and methods of making same |
| CN102417773A (zh) * | 2011-10-14 | 2012-04-18 | 袁志庆 | 一种超疏水丙烯酸树脂涂料 |
-
2012
- 2012-06-29 CN CN201210229101.7A patent/CN103509422B/zh not_active Expired - Fee Related
-
2013
- 2013-06-27 WO PCT/IB2013/003262 patent/WO2014004840A1/en not_active Ceased
- 2013-06-27 EP EP13888508.2A patent/EP2882817A4/en not_active Withdrawn
- 2013-06-27 BR BR112014032893A patent/BR112014032893A2/pt not_active IP Right Cessation
- 2013-06-27 JP JP2015542079A patent/JP2015534601A/ja not_active Withdrawn
- 2013-06-27 US US14/411,199 patent/US9382441B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2882817A1 (en) | 2015-06-17 |
| US20150141563A1 (en) | 2015-05-21 |
| CN103509422A (zh) | 2014-01-15 |
| WO2014004840A1 (en) | 2014-01-03 |
| JP2015534601A (ja) | 2015-12-03 |
| WO2014004840A9 (en) | 2014-10-30 |
| EP2882817A4 (en) | 2016-02-24 |
| BR112014032893A2 (pt) | 2017-06-27 |
| US9382441B2 (en) | 2016-07-05 |
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