CN103442803A - 用于蒸汽重整过程的催化剂 - Google Patents

用于蒸汽重整过程的催化剂 Download PDF

Info

Publication number
CN103442803A
CN103442803A CN2012800089457A CN201280008945A CN103442803A CN 103442803 A CN103442803 A CN 103442803A CN 2012800089457 A CN2012800089457 A CN 2012800089457A CN 201280008945 A CN201280008945 A CN 201280008945A CN 103442803 A CN103442803 A CN 103442803A
Authority
CN
China
Prior art keywords
catalyst
shaped
shaped support
particulate catalyst
steam reforming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012800089457A
Other languages
English (en)
Chinese (zh)
Inventor
M·R·费维奥尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Priority to CN201610632879.0A priority Critical patent/CN106362735B/zh
Publication of CN103442803A publication Critical patent/CN103442803A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0232—Coating by pulverisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C01B2203/107—Platinum catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C01B2203/1223—Methanol
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C01B2203/1229—Ethanol
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
CN2012800089457A 2011-02-14 2012-02-06 用于蒸汽重整过程的催化剂 Pending CN103442803A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610632879.0A CN106362735B (zh) 2011-02-14 2012-02-06 用于蒸汽重整过程的催化剂

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1102502.0A GB201102502D0 (en) 2011-02-14 2011-02-14 Catalysts for use in reforming processes
GB1102502.0 2011-02-14
PCT/GB2012/050250 WO2012110781A1 (en) 2011-02-14 2012-02-06 Catalysts for use in steam reforming processes

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201610632879.0A Division CN106362735B (zh) 2011-02-14 2012-02-06 用于蒸汽重整过程的催化剂

Publications (1)

Publication Number Publication Date
CN103442803A true CN103442803A (zh) 2013-12-11

Family

ID=43859345

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2012800089457A Pending CN103442803A (zh) 2011-02-14 2012-02-06 用于蒸汽重整过程的催化剂
CN201610632879.0A Active CN106362735B (zh) 2011-02-14 2012-02-06 用于蒸汽重整过程的催化剂

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201610632879.0A Active CN106362735B (zh) 2011-02-14 2012-02-06 用于蒸汽重整过程的催化剂

Country Status (8)

Country Link
US (1) US9511351B2 (enExample)
EP (1) EP2675561B1 (enExample)
JP (2) JP5955868B2 (enExample)
CN (2) CN103442803A (enExample)
BR (1) BR112013020271B8 (enExample)
GB (1) GB201102502D0 (enExample)
RU (1) RU2580548C2 (enExample)
WO (1) WO2012110781A1 (enExample)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI611839B (zh) * 2016-09-07 2018-01-21 國立清華大學 應用於低碳烴之低溫部分氧化產氫之觸媒
CN108134102A (zh) * 2018-01-04 2018-06-08 四川天科技股份有限公司 一种用于燃料电池中甲烷蒸汽重整的催化剂
CN111450840A (zh) * 2020-01-15 2020-07-28 成都理工大学 一种用于乙酸自热重整制氢的钴铈锰复合氧化物催化剂
CN115672331A (zh) * 2021-07-23 2023-02-03 国家能源投资集团有限责任公司 甲烷化催化剂及其制备方法和应用
CN119657119A (zh) * 2024-12-17 2025-03-21 浙江大学 一种铂基催化剂及其制备方法和甲烷低温燃烧应用

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2994226A2 (en) 2013-05-09 2016-03-16 SABIC Global Technologies B.V. Alkaline earth metal/metal oxide supported catalysts
IN2014DE00087A (enExample) * 2014-01-13 2015-07-17 Council Scient Ind Res
PL3129142T3 (pl) * 2014-04-07 2021-05-31 Haldor Topsøe A/S Katalizator impregnowany powłoką i sposób wytwarzania korpusu z katalizatorem impregnowanym powłoką
JP6541339B2 (ja) * 2014-12-01 2019-07-10 クラリアント・プロドゥクテ・（ドイチュラント）・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング 炭化水素含有ガスの水蒸気改質触媒、水素製造装置、及び水素製造方法
JP6462448B2 (ja) * 2015-03-25 2019-01-30 株式会社大貴 吸水処理材及びその製造方法
CN107921427B (zh) 2015-07-01 2021-08-03 沙特基础工业全球技术公司 甲烷干重整反应、用于甲烷干重整反应的含镍和铈的核壳结构的催化剂及其制备
KR101799384B1 (ko) * 2015-09-21 2017-11-21 서울과학기술대학교 산학협력단 전기분무를 이용한 탄화수소 연료 개질용 촉매 제조 방법
WO2017130937A1 (ja) * 2016-01-26 2017-08-03 戸田工業株式会社 不均一系触媒構造体及びその製造方法
US9987612B1 (en) 2017-04-13 2018-06-05 Caterpillar Inc. Reactor assembly
RU2650495C1 (ru) * 2017-05-22 2018-04-16 Акционерное общество "Ангарский завод катализаторов и органического синтеза" (АО "АЗКиОС") Катализатор для паровой конверсии углеводородов
US20180353942A1 (en) * 2017-06-13 2018-12-13 Gas Technology Institute Nano-engineered catalysts for dry reforming of methane
CN110997615A (zh) 2017-07-28 2020-04-10 罗门哈斯公司 通过使用非均相催化剂进行氧化酯化来生产甲基丙烯酸甲酯的方法
WO2019022884A1 (en) 2017-07-28 2019-01-31 Rohm And Haas Company PROCESS FOR THE PRODUCTION OF METHYL METHACRYLATE BY OXIDATIVE ESTERIZATION USING A HETEROGENEOUS CATALYST
CN110997618B (zh) 2017-07-28 2023-04-04 罗门哈斯公司 通过使用非均相催化剂进行氧化酯化来生产甲基丙烯酸甲酯的方法
SG11202000684XA (en) 2017-07-28 2020-02-27 Rohm & Haas A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
CA3071184A1 (en) 2017-07-28 2019-01-31 Rohm And Haas Company A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
US10822297B2 (en) 2017-07-28 2020-11-03 Dow Global Technologies Llc Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
SG11202000744UA (en) 2017-07-28 2020-02-27 Rohm & Haas A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
CA3071239A1 (en) 2017-07-28 2019-01-31 Rohm And Haas Company Heterogeneous catalyst
CN111372910A (zh) 2017-07-28 2020-07-03 罗门哈斯公司 通过使用非均相催化剂进行氧化酯化来生产甲基丙烯酸甲酯的方法
JP2020528442A (ja) 2017-07-28 2020-09-24 ダウ グローバル テクノロジーズ エルエルシー 不均一触媒を使用した酸化的エステル化によるメタクリル酸メチルの製造方法
WO2019041041A1 (en) * 2017-08-30 2019-03-07 Polyvalor, Limited Partnership MICROWAVE ASSISTED CATALYTIC REACTIONS USING MODIFIED BED PARTICLES
BR112020004818B1 (pt) 2017-09-19 2023-04-11 Dow Global Technologies Llc Método para preparar metacrilato de metila a partir de metacroleína e metanol
US11123711B2 (en) * 2017-12-28 2021-09-21 University Of Kentucky Research Foundation System and method for alcohol oxidation reaction of lignins
NL2020819B1 (en) * 2018-04-24 2019-10-31 Cochise Tech Llc A co to co2 combustion promoter
JP7373506B2 (ja) 2018-06-28 2023-11-02 ダウ グローバル テクノロジーズ エルエルシー 不均一触媒
JP2021528231A (ja) 2018-06-28 2021-10-21 ダウ グローバル テクノロジーズ エルエルシー 不均一触媒
CN108993615B (zh) * 2018-08-11 2021-11-26 四川蜀泰化工科技有限公司 一种甲醇重整制氢铜基催化剂的还原、钝化方法
RU2707880C1 (ru) * 2018-12-03 2019-12-02 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН) Катализатор и способ получения обогащенной по водороду газовой смеси из диметоксиметана и воздуха
KR102287846B1 (ko) * 2018-12-21 2021-08-06 한화솔루션 주식회사 염소 제조를 위한 염화수소 산화반응용 촉매 및 이의 제조방법
CN109772372A (zh) * 2019-03-16 2019-05-21 泉州师范学院 一种基于鸡蛋壳模板的硒化铜纳米材料的制备方法和应用
GB201907062D0 (en) * 2019-05-20 2019-07-03 Johnson Matthey Plc Catalyst preparation method
KR102225612B1 (ko) * 2019-10-25 2021-03-10 한국과학기술연구원 바이오매스의 액상 개질용 불균일계 촉매, 그 제조방법, 및 이를 이용하는 고순도 수소 생산 방법
US11859133B2 (en) * 2020-10-13 2024-01-02 ExxonMobil Technology and Engineering Company Size-reversing materials for reforming in cyclic flow reactors
KR102376875B1 (ko) * 2021-11-24 2022-03-18 부경대학교 산학협력단 니켈계 촉매상에서 바이오매스 유래 오일의 수증기 개질 및 수소화 반응에 의한 수소의 생산 방법
CN115445628B (zh) * 2022-10-11 2023-12-19 中国科学院福建物质结构研究所 镍基负载型复合金属氧化物催化剂及其制备方法和应用
WO2024083780A1 (en) 2022-10-18 2024-04-25 Basf Se Improved catalyst shapes for heat transfer and pressure-drop in the syngas conversion
CN115920915B (zh) * 2023-01-12 2024-05-07 成都理工大学 用于乙酸自热重整制氢的烧绿石型镍基催化剂
CN116786117B (zh) * 2023-07-10 2025-12-16 中自科技股份有限公司 一种天然气水蒸气重整催化剂及制备方法
KR20250080152A (ko) * 2023-11-28 2025-06-05 에스케이이노베이션 주식회사 합성가스 제조용 다공질 촉매 및 이의 제조방법
KR102755420B1 (ko) * 2023-12-27 2025-01-21 한국에너지기술연구원 바이오가스 및 부생가스 개질용 전도성 촉매, 이의 제조방법 및 이를 이용한 수소 및 합성가스 제조방법
CN118002149B (zh) * 2024-04-08 2024-07-26 中自科技股份有限公司 一种天然气水蒸气重整催化剂及反应器

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6177381B1 (en) * 1998-11-03 2001-01-23 Uop Llc Layered catalyst composition and processes for preparing and using the composition
US7176159B1 (en) * 2001-08-15 2007-02-13 Iowa State University Research Foundation, Inc. Catalyst and sorbent material for the production of hydrogen
CN101151228A (zh) * 2005-09-14 2008-03-26 环球油品公司 用于包含二甲苯的进料流的非异构化平衡的方法
US20080248199A1 (en) * 2005-12-20 2008-10-09 Gajda Gregory J Selective Hydrogenation Process Using Layered Catalyst Composition and Preparation of Said Catalyst

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5355492A (en) * 1976-10-29 1978-05-19 Kobe Steel Ltd Pellet-like catalyst
DE2805801A1 (de) 1978-02-11 1979-08-16 Driam Metallprodukt Gmbh & Co Vorrichtung zum beschichten von granulaten wie drageekerne mit einer huelle und zum antrocknen der huelle durch trocknungsluft
DE3125062C2 (de) 1981-06-26 1984-11-22 Degussa Ag, 6000 Frankfurt Verfahren zur Herstellung von abriebfesten Schalenkatalysatoren und Verwendung eines so erhaltenen Katalysators
JP3307976B2 (ja) * 1992-02-07 2002-07-29 ズードケミー触媒株式会社 炭化水素水蒸気改質触媒
US5532199A (en) * 1992-06-19 1996-07-02 Mitsubishi Rayon Co., Ltd. Carrier-supported catalyst for the synthesis of unsaturated aldehydes and unsaturated carboxylic acids and process for preparing the same
JP3276984B2 (ja) * 1992-06-19 2002-04-22 三菱レイヨン株式会社 不飽和アルデヒド及び不飽和カルボン酸合成用担持触媒及びその製造法
JPH0631173A (ja) * 1992-07-10 1994-02-08 N E Chemcat Corp 排気ガス浄化用触媒及び排気ガスの浄化方法
JP3347767B2 (ja) 1992-07-10 2002-11-20 フロイント産業株式会社 パンコーティング装置
US6274113B1 (en) * 1994-01-04 2001-08-14 Chevron Phillips Chemical Company Lp Increasing production in hydrocarbon conversion processes
WO1999028027A1 (fr) * 1996-11-28 1999-06-10 Idemitsu Kosan Co., Ltd. Catalyseur au ruthenium a support d'alumine
JP3743995B2 (ja) * 1999-12-15 2006-02-08 日産自動車株式会社 メタノール改質触媒
JP2004344752A (ja) * 2003-05-21 2004-12-09 Nissan Motor Co Ltd 発泡担体触媒
RU2329100C2 (ru) * 2003-06-13 2008-07-20 Яра Интернэшнл Аса Способ получения оксидных катализаторов на подложке
JP4332724B2 (ja) * 2004-02-13 2009-09-16 戸田工業株式会社 オートサーマルリフォーミング触媒及びその製造方法、並びに該オートサーマルリフォーミング触媒を用いた水素の製造方法
GB0420245D0 (en) * 2004-09-13 2004-10-13 Johnson Matthey Plc Improvements in catalyst coatings
US20060204614A1 (en) * 2005-03-09 2006-09-14 Rapp Knut M Pan coating process
JP4684639B2 (ja) * 2004-12-09 2011-05-18 日揮ユニバーサル株式会社 炭化水素改質触媒、該触媒の製造方法、及び該触媒による改質方法
WO2007014464A1 (en) 2005-08-03 2007-02-08 The University Of Western Ontario Direct coating solid dosage forms using powdered materials
EP1922146A1 (en) * 2005-09-08 2008-05-21 Evonik Degussa GmbH The production and use of supported activated base metal catalysts for organic transformation
US7541309B2 (en) * 2006-05-16 2009-06-02 Headwaters Technology Innovation, Llc Reforming nanocatalysts and methods of making and using such catalysts
BRPI0622112A2 (pt) * 2006-10-23 2011-12-27 Bp Plc processo e catalisador para a conversço de hidrocarbonetos
KR101504776B1 (ko) * 2007-07-19 2015-03-20 도다 고교 가부시끼가이샤 탄화수소를 분해하는 촉매, 상기 촉매를 이용한 혼합 개질 가스의 제조 방법 및 연료 전지 시스템
JP2009165904A (ja) * 2008-01-10 2009-07-30 Honda Motor Co Ltd 排ガス浄化装置
JP5009419B2 (ja) * 2008-09-24 2012-08-22 新日本製鐵株式会社 タール含有ガスの改質用触媒の製造方法、タール改質方法及びタール含有ガスの改質用触媒の再生方法
GB0907539D0 (en) 2009-05-01 2009-06-10 Johnson Matthey Plc Catalyst preparation method
JP2010279911A (ja) * 2009-06-05 2010-12-16 Nippon Shokubai Co Ltd 水素製造用触媒、その触媒の製造方法およびその触媒を用いた水素の製造方法
GB0914272D0 (en) 2009-08-17 2009-09-30 Johnson Matthey Plc Sorbent
JP5537960B2 (ja) * 2010-01-15 2014-07-02 日揮ユニバーサル株式会社 炭化水素改質触媒、該触媒の製造方法および該触媒を用いる改質方法
JP5355492B2 (ja) 2010-05-14 2013-11-27 リンナイ株式会社 グリルバーナ装置

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6177381B1 (en) * 1998-11-03 2001-01-23 Uop Llc Layered catalyst composition and processes for preparing and using the composition
US7176159B1 (en) * 2001-08-15 2007-02-13 Iowa State University Research Foundation, Inc. Catalyst and sorbent material for the production of hydrogen
CN101151228A (zh) * 2005-09-14 2008-03-26 环球油品公司 用于包含二甲苯的进料流的非异构化平衡的方法
US20080248199A1 (en) * 2005-12-20 2008-10-09 Gajda Gregory J Selective Hydrogenation Process Using Layered Catalyst Composition and Preparation of Said Catalyst

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI611839B (zh) * 2016-09-07 2018-01-21 國立清華大學 應用於低碳烴之低溫部分氧化產氫之觸媒
CN108134102A (zh) * 2018-01-04 2018-06-08 四川天科技股份有限公司 一种用于燃料电池中甲烷蒸汽重整的催化剂
CN108134102B (zh) * 2018-01-04 2020-10-09 西南化工研究设计院有限公司 一种用于燃料电池中甲烷蒸汽重整的催化剂
CN111450840A (zh) * 2020-01-15 2020-07-28 成都理工大学 一种用于乙酸自热重整制氢的钴铈锰复合氧化物催化剂
CN111450840B (zh) * 2020-01-15 2020-11-20 成都理工大学 一种用于乙酸自热重整制氢的钴铈锰复合氧化物催化剂
CN115672331A (zh) * 2021-07-23 2023-02-03 国家能源投资集团有限责任公司 甲烷化催化剂及其制备方法和应用
CN119657119A (zh) * 2024-12-17 2025-03-21 浙江大学 一种铂基催化剂及其制备方法和甲烷低温燃烧应用

Also Published As

Publication number Publication date
EP2675561A1 (en) 2013-12-25
GB201102502D0 (en) 2011-03-30
JP5955868B2 (ja) 2016-07-20
RU2013142164A (ru) 2015-03-27
CN106362735A (zh) 2017-02-01
US9511351B2 (en) 2016-12-06
JP2014507274A (ja) 2014-03-27
JP2017013049A (ja) 2017-01-19
RU2580548C2 (ru) 2016-04-10
JP6247344B2 (ja) 2017-12-13
BR112013020271B8 (pt) 2019-12-10
BR112013020271B1 (pt) 2019-11-05
EP2675561B1 (en) 2019-10-02
WO2012110781A1 (en) 2012-08-23
CN106362735B (zh) 2019-07-02
BR112013020271A2 (pt) 2016-10-18
US20140005042A1 (en) 2014-01-02

Similar Documents

Publication Publication Date Title
CN106362735B (zh) 用于蒸汽重整过程的催化剂
Alvarez-Galvan et al. Partial oxidation of methane to syngas over nickel-based catalysts: influence of support type, addition of rhodium, and preparation method
Han et al. Highly active and anticoke Ni/CeO2 with ultralow Ni loading in chemical looping dry reforming via the strong metal–support interaction
Freni et al. Hydrogen production from methane through catalytic partial oxidation reactions
KR101994152B1 (ko) 탄소 침적의 감소를 위해, 금속이온이 치환된 페로브스카이트 금속산화물 촉매 및 이의 제조 방법, 그리고 이를 이용한 메탄 개질 반응 방법
US8043530B2 (en) Fuel reformer catalyst
US20160257564A1 (en) Catalyst and process for thermo-neutral reforming of liquid hydrocarbons
US20050112056A1 (en) Fuel reformer catalyst and absorbent materials
CN106029558A (zh) 重整烃和二氧化碳的混合物的方法
CA2415833A1 (en) Catalytic oxidation process
WO2005053831A2 (en) Fuel reformer catalyst and absorbent materials
JP5327323B2 (ja) 炭化水素系ガス改質用触媒、その製造方法、および合成ガスの製造方法
US11311860B2 (en) Nickel catalyst for dry and low temperature steam reforming of methane
KR20230050314A (ko) 스팀 개질
Xie et al. Autothermal reforming and partial oxidation of n-hexadecane via Pt/Ni bimetallic catalysts on ceria-based supports
Phuong et al. Effect of support on stability and coke resistance of Ni-based catalyst in combined steam and CO2 reforming of CH4
EP3256249A1 (en) Use of nickel-manganese olivine and nickel-manganese spinel as bulk metal catalysts for carbon dioxide reforming of methane
KR102092736B1 (ko) 탄소 침적을 감소시킬 수 있는, 금속이온이 치환된 페로브스카이트 금속산화물 촉매의 제조 방법 및 이를 이용한 메탄 개질 반응 방법
Hong Phuong et al. Effect of support on stability and coke resistance of Ni-based catalyst in combined steam and CO2 reforming of CH4
JP2007516825A (ja) 改質触媒
JP2023544675A (ja) 水素化方法
JP2004322001A (ja) 炭化水素部分酸化用触媒及び該触媒の製造方法、並びに該触媒を用いた水素含有ガスの製造方法
JP4799312B2 (ja) 合成ガス製造触媒
Kamata et al. Steam Reforming of Dimethyl Ether over Cu/ZnO/ZrO2 and γ-Al2O3 Mixed Catalyst Prepared by Extrusion
WO2001034517A1 (en) Chromium-based catalysts and process for converting hydrocarbons to synthesis gas

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20131211