BR112013020271B8 - método para preparar um catalisador adequado para o uso em um processo de reforma a vapor - Google Patents

método para preparar um catalisador adequado para o uso em um processo de reforma a vapor Download PDF

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Publication number
BR112013020271B8
BR112013020271B8 BR112013020271A BR112013020271A BR112013020271B8 BR 112013020271 B8 BR112013020271 B8 BR 112013020271B8 BR 112013020271 A BR112013020271 A BR 112013020271A BR 112013020271 A BR112013020271 A BR 112013020271A BR 112013020271 B8 BR112013020271 B8 BR 112013020271B8
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Prior art keywords
catalyst
steam reforming
preparing
reforming process
catalyst suitable
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BR112013020271A
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BR112013020271A2 (pt
BR112013020271B1 (pt
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Robert Feaviour Mark
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Johnson Matthey Plc
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Publication of BR112013020271B1 publication Critical patent/BR112013020271B1/pt
Publication of BR112013020271B8 publication Critical patent/BR112013020271B8/pt

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
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    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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    • C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
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Abstract

método para preparar um catalisador, catalisador, e, processo para realizar uma reação de reforma a vapor um método é descrito para preparar um catalisador adequado para o uso em um processo de reforma a vapor, que compreende as etapas de: (i) pulverizar uma pasta fluida contendo um composto catalisador particulado, que compreende um ou mais metais catalíticos selecionado do grupo gque consiste de ni, cu, pt, pd, rh, ru, e au, na superfície de um suporte conformado em um revestidor de tacho para formar um material de suporte conformado revestido tendo o metal catalítico em uma camada de superfície, (ii) secar e opcionalmente calcinar o material de suporte conformado resvestido para formar um precursor de catalisador, e (iii) opcionalmente reduzir o metal ou matais no precursor de catalisador a um estado de oxidação mais baixo para formar o catalisador. uso do catalisador de casca de ovo para realizar uma reação de reforma a vapor.
BR112013020271A 2011-02-14 2012-02-06 método para preparar um catalisador adequado para o uso em um processo de reforma a vapor BR112013020271B8 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1102502.0A GB201102502D0 (en) 2011-02-14 2011-02-14 Catalysts for use in reforming processes
PCT/GB2012/050250 WO2012110781A1 (en) 2011-02-14 2012-02-06 Catalysts for use in steam reforming processes

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Publication Number Publication Date
BR112013020271A2 BR112013020271A2 (pt) 2016-10-18
BR112013020271B1 BR112013020271B1 (pt) 2019-11-05
BR112013020271B8 true BR112013020271B8 (pt) 2019-12-10

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BR112013020271A BR112013020271B8 (pt) 2011-02-14 2012-02-06 método para preparar um catalisador adequado para o uso em um processo de reforma a vapor

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US (1) US9511351B2 (pt)
EP (1) EP2675561B1 (pt)
JP (2) JP5955868B2 (pt)
CN (2) CN106362735B (pt)
BR (1) BR112013020271B8 (pt)
GB (1) GB201102502D0 (pt)
RU (1) RU2580548C2 (pt)
WO (1) WO2012110781A1 (pt)

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Publication number Priority date Publication date Assignee Title
US9616414B2 (en) 2013-05-09 2017-04-11 Sabic Global Technologies B.V. Alkaline earth metal/metal oxide supported catalysts
IN2014DE00087A (pt) * 2014-01-13 2015-07-17 Council Scient Ind Res
BR112016022384B1 (pt) * 2014-04-07 2020-12-01 Haldor Topsøe A/S processo para a produção de um corpo do catalisador, corpo do catalisador e seu uso, processo para a produção de um gás de síntese e reformador
JP6541339B2 (ja) * 2014-12-01 2019-07-10 クラリアント・プロドゥクテ・（ドイチュラント）・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング 炭化水素含有ガスの水蒸気改質触媒、水素製造装置、及び水素製造方法
JP6462448B2 (ja) * 2015-03-25 2019-01-30 株式会社大貴 吸水処理材及びその製造方法
WO2017001987A1 (en) 2015-07-01 2017-01-05 Sabic Global Technologies B.V. Dry reformation of methane reaction, nickel and cerium containing core-shell structured catalysts therefor and their preparation
KR101799384B1 (ko) * 2015-09-21 2017-11-21 서울과학기술대학교 산학협력단 전기분무를 이용한 탄화수소 연료 개질용 촉매 제조 방법
WO2017130937A1 (ja) * 2016-01-26 2017-08-03 戸田工業株式会社 不均一系触媒構造体及びその製造方法
TWI611839B (zh) * 2016-09-07 2018-01-21 國立清華大學 應用於低碳烴之低溫部分氧化產氫之觸媒
US9987612B1 (en) 2017-04-13 2018-06-05 Caterpillar Inc. Reactor assembly
RU2650495C1 (ru) * 2017-05-22 2018-04-16 Акционерное общество "Ангарский завод катализаторов и органического синтеза" (АО "АЗКиОС") Катализатор для паровой конверсии углеводородов
WO2018231961A1 (en) * 2017-06-13 2018-12-20 Gas Technology Institute Nano-engineered catalysts for dry reforming of methane
SG11202000676UA (en) 2017-07-28 2020-02-27 Rohm & Haas Heterogeneous catalyst
MX2020001032A (es) 2017-07-28 2020-07-20 Dow Global Technologies Llc Método para producción de metacrilato de metilo por esterificación oxidativa mediante el uso de un catalizador heterogéneo.
KR102639234B1 (ko) 2017-07-28 2024-02-21 다우 글로벌 테크놀로지스 엘엘씨 불균일 촉매를 사용하여 산화적 에스터화에 의해 메틸 메타크릴레이트를 제조하는 방법
EP3658536A1 (en) 2017-07-28 2020-06-03 Rohm and Haas Company A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
US10745341B2 (en) 2017-07-28 2020-08-18 Dow Global Technologies Llc Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
WO2019022891A1 (en) 2017-07-28 2019-01-31 Rohm And Haas Company PROCESS FOR THE PRODUCTION OF METHYL METHACRYLATE BY OXIDATIVE ESTERIZATION USING A HETEROGENEOUS CATALYST
EP3658534A1 (en) 2017-07-28 2020-06-03 Rohm and Haas Company A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
CN111094230B (zh) 2017-07-28 2023-04-04 罗门哈斯公司 通过使用非均相催化剂进行氧化酯化来生产甲基丙烯酸甲酯的方法
CN111372910A (zh) 2017-07-28 2020-07-03 罗门哈斯公司 通过使用非均相催化剂进行氧化酯化来生产甲基丙烯酸甲酯的方法
US10829434B2 (en) 2017-07-28 2020-11-10 Dow Global Technologies Llc Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
US20200223692A1 (en) * 2017-08-30 2020-07-16 Polyvalor, Limited Partnership Microwave-assisted catalytic reactions using modified bed particles
WO2019060192A1 (en) 2017-09-19 2019-03-28 Dow Global Technologies Llc PROCESS FOR THE PRODUCTION OF METHYL METHACRYLATE BY OXIDIZING ESTERIZATION USING A HETEROGENEOUS CATALYST
US11123711B2 (en) * 2017-12-28 2021-09-21 University Of Kentucky Research Foundation System and method for alcohol oxidation reaction of lignins
CN108134102B (zh) * 2018-01-04 2020-10-09 西南化工研究设计院有限公司 一种用于燃料电池中甲烷蒸汽重整的催化剂
KR20210022621A (ko) 2018-06-28 2021-03-03 다우 글로벌 테크놀로지스 엘엘씨 불균일 촉매
WO2020005689A1 (en) 2018-06-28 2020-01-02 Dow Global Technologies Llc Heterogeneous catalyst
CN108993615B (zh) * 2018-08-11 2021-11-26 四川蜀泰化工科技有限公司 一种甲醇重整制氢铜基催化剂的还原、钝化方法
RU2707880C1 (ru) * 2018-12-03 2019-12-02 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН) Катализатор и способ получения обогащенной по водороду газовой смеси из диметоксиметана и воздуха
CN109772372A (zh) * 2019-03-16 2019-05-21 泉州师范学院 一种基于鸡蛋壳模板的硒化铜纳米材料的制备方法和应用
GB201907062D0 (en) * 2019-05-20 2019-07-03 Johnson Matthey Plc Catalyst preparation method
KR102225612B1 (ko) * 2019-10-25 2021-03-10 한국과학기술연구원 바이오매스의 액상 개질용 불균일계 촉매, 그 제조방법, 및 이를 이용하는 고순도 수소 생산 방법
CN111450840B (zh) * 2020-01-15 2020-11-20 成都理工大学 一种用于乙酸自热重整制氢的钴铈锰复合氧化物催化剂
CN115672331A (zh) * 2021-07-23 2023-02-03 国家能源投资集团有限责任公司 甲烷化催化剂及其制备方法和应用
KR102376875B1 (ko) * 2021-11-24 2022-03-18 부경대학교 산학협력단 니켈계 촉매상에서 바이오매스 유래 오일의 수증기 개질 및 수소화 반응에 의한 수소의 생산 방법
CN115445628B (zh) * 2022-10-11 2023-12-19 中国科学院福建物质结构研究所 镍基负载型复合金属氧化物催化剂及其制备方法和应用
WO2024083780A1 (en) 2022-10-18 2024-04-25 Basf Se Improved catalyst shapes for heat transfer and pressure-drop in the syngas conversion
CN115920915B (zh) * 2023-01-12 2024-05-07 成都理工大学 用于乙酸自热重整制氢的烧绿石型镍基催化剂

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5355492A (en) * 1976-10-29 1978-05-19 Kobe Steel Ltd Pellet-like catalyst
DE2805801A1 (de) * 1978-02-11 1979-08-16 Driam Metallprodukt Gmbh & Co Vorrichtung zum beschichten von granulaten wie drageekerne mit einer huelle und zum antrocknen der huelle durch trocknungsluft
DE3125062C2 (de) * 1981-06-26 1984-11-22 Degussa Ag, 6000 Frankfurt Verfahren zur Herstellung von abriebfesten Schalenkatalysatoren und Verwendung eines so erhaltenen Katalysators
JP3307976B2 (ja) * 1992-02-07 2002-07-29 ズードケミー触媒株式会社 炭化水素水蒸気改質触媒
US5532199A (en) * 1992-06-19 1996-07-02 Mitsubishi Rayon Co., Ltd. Carrier-supported catalyst for the synthesis of unsaturated aldehydes and unsaturated carboxylic acids and process for preparing the same
JP3276984B2 (ja) * 1992-06-19 2002-04-22 三菱レイヨン株式会社 不飽和アルデヒド及び不飽和カルボン酸合成用担持触媒及びその製造法
JPH0631173A (ja) * 1992-07-10 1994-02-08 N E Chemcat Corp 排気ガス浄化用触媒及び排気ガスの浄化方法
JP3347767B2 (ja) * 1992-07-10 2002-11-20 フロイント産業株式会社 パンコーティング装置
US6274113B1 (en) * 1994-01-04 2001-08-14 Chevron Phillips Chemical Company Lp Increasing production in hydrocarbon conversion processes
WO1999028027A1 (fr) * 1996-11-28 1999-06-10 Idemitsu Kosan Co., Ltd. Catalyseur au ruthenium a support d'alumine
US6177381B1 (en) * 1998-11-03 2001-01-23 Uop Llc Layered catalyst composition and processes for preparing and using the composition
JP3743995B2 (ja) * 1999-12-15 2006-02-08 日産自動車株式会社 メタノール改質触媒
US7176159B1 (en) * 2001-08-15 2007-02-13 Iowa State University Research Foundation, Inc. Catalyst and sorbent material for the production of hydrogen
JP2004344752A (ja) * 2003-05-21 2004-12-09 Nissan Motor Co Ltd 発泡担体触媒
RU2329100C2 (ru) * 2003-06-13 2008-07-20 Яра Интернэшнл Аса Способ получения оксидных катализаторов на подложке
JP4332724B2 (ja) * 2004-02-13 2009-09-16 戸田工業株式会社 オートサーマルリフォーミング触媒及びその製造方法、並びに該オートサーマルリフォーミング触媒を用いた水素の製造方法
GB0420245D0 (en) * 2004-09-13 2004-10-13 Johnson Matthey Plc Improvements in catalyst coatings
US20060204614A1 (en) * 2005-03-09 2006-09-14 Rapp Knut M Pan coating process
JP4684639B2 (ja) * 2004-12-09 2011-05-18 日揮ユニバーサル株式会社 炭化水素改質触媒、該触媒の製造方法、及び該触媒による改質方法
CA2617190C (en) * 2005-08-03 2017-07-18 The University Of Western Ontario Direct coating solid dosage forms using powdered materials
WO2007028411A1 (en) 2005-09-08 2007-03-15 Evonik Degussa Gmbh The production and use of supported activated base metal catalysts for organic transformation
US7297830B2 (en) * 2005-09-14 2007-11-20 Uop Llc Process for isomerizing non-equilibrium xylene-containing feed streams
US7453016B1 (en) * 2005-12-20 2008-11-18 Uop Llc Selective hydrogenation process using layered catalyst composition and preparation of said catalyst
US7541309B2 (en) * 2006-05-16 2009-06-02 Headwaters Technology Innovation, Llc Reforming nanocatalysts and methods of making and using such catalysts
US20100213417A1 (en) * 2006-10-23 2010-08-26 Yazhong Chen Process and catalyst for hydrocarbon conversion
KR101504776B1 (ko) * 2007-07-19 2015-03-20 도다 고교 가부시끼가이샤 탄화수소를 분해하는 촉매, 상기 촉매를 이용한 혼합 개질 가스의 제조 방법 및 연료 전지 시스템
JP2009165904A (ja) * 2008-01-10 2009-07-30 Honda Motor Co Ltd 排ガス浄化装置
JP5009419B2 (ja) * 2008-09-24 2012-08-22 新日本製鐵株式会社 タール含有ガスの改質用触媒の製造方法、タール改質方法及びタール含有ガスの改質用触媒の再生方法
GB0907539D0 (en) 2009-05-01 2009-06-10 Johnson Matthey Plc Catalyst preparation method
JP2010279911A (ja) * 2009-06-05 2010-12-16 Nippon Shokubai Co Ltd 水素製造用触媒、その触媒の製造方法およびその触媒を用いた水素の製造方法
GB0914272D0 (en) * 2009-08-17 2009-09-30 Johnson Matthey Plc Sorbent
JP5537960B2 (ja) * 2010-01-15 2014-07-02 日揮ユニバーサル株式会社 炭化水素改質触媒、該触媒の製造方法および該触媒を用いる改質方法
JP5355492B2 (ja) 2010-05-14 2013-11-27 リンナイ株式会社 グリルバーナ装置

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