CN103002983A - 氧化石墨烯和氧化石墨催化剂及系统 - Google Patents

氧化石墨烯和氧化石墨催化剂及系统 Download PDF

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CN103002983A
CN103002983A CN2011800262352A CN201180026235A CN103002983A CN 103002983 A CN103002983 A CN 103002983A CN 2011800262352 A CN2011800262352 A CN 2011800262352A CN 201180026235 A CN201180026235 A CN 201180026235A CN 103002983 A CN103002983 A CN 103002983A
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catalyst
group
oxide
graphene oxide
acid
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克里斯多佛·W·别拉夫斯基
丹尼尔·R·德雷尔
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GRAPHEA Inc
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GRAPHEA Inc
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CN2011800262352A 2010-05-28 2011-05-27 氧化石墨烯和氧化石墨催化剂及系统 Pending CN103002983A (zh)

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US34937810P 2010-05-28 2010-05-28
US61/349,378 2010-05-28
US201161440574P 2011-02-08 2011-02-08
US61/440,574 2011-02-08
PCT/US2011/038327 WO2011150325A2 (en) 2010-05-28 2011-05-27 Graphene oxide and graphite oxide catalysts and systems

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CN2011800262530A Pending CN103025685A (zh) 2010-05-28 2011-05-27 用于化学转化的碳催化剂

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Cited By (11)

* Cited by examiner, † Cited by third party
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CN103880717A (zh) * 2014-03-21 2014-06-25 江苏傲伦达科技实业股份有限公司 二（3-烯丙基-4-羟基苯基）砜及其衍生物的制备方法
CN103977835A (zh) * 2014-06-06 2014-08-13 上海师范大学 磺化石墨烯基新型Ru(bpy)32+纳米非均相催化剂及其制备方法
CN105241571A (zh) * 2015-09-21 2016-01-13 长安大学 N和Mo用于提高氧化石墨烯温敏特性的应用
CN107418199A (zh) * 2017-06-26 2017-12-01 杭州师范大学 一种石墨烯改性的尼龙复合树脂及其粉末的制备方法与应用
CN107649112A (zh) * 2017-09-25 2018-02-02 山东大学 一种用于氟代磷腈及其衍生物工业化生产的催化剂
CN109897512A (zh) * 2019-03-27 2019-06-18 浙江中科应化科技有限公司 一种改性聚脲涂料
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CN110078064A (zh) * 2019-05-07 2019-08-02 青岛科技大学 一种可导电氧化石墨烯及其制备方法和应用
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Families Citing this family (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2576048A4 (en) * 2010-05-28 2014-01-01 Graphea Inc GRAPHIC OXIDE AND GRAPHITE OXIDE CATALYSTS AND SYSTEMS THEREWITH
CA2824428A1 (en) * 2011-02-08 2012-08-16 Christopher W. Bielawski Carbocatalysts for polymerization
JP5779721B2 (ja) 2011-09-16 2015-09-16 エンパイア テクノロジー ディベロップメント エルエルシー グラフェン欠陥を修正するための方法及びシステム
CN102491316B (zh) * 2011-12-13 2013-05-08 南京理工大学 一种热稳定性增强的石墨烯基超分子杂化材料及其制备方法
CN102578145A (zh) * 2012-01-19 2012-07-18 常州大学 一种载银氧化石墨烯抗菌材料的制备方法
US8979978B2 (en) 2012-01-26 2015-03-17 Empire Technology Development Llc Graphene membrane with regular angstrom-scale pores
CN102603446B (zh) * 2012-02-13 2014-08-06 湖南大学 一种以碳材料催化氧化有机酮制备有机内酯的方法
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US9114423B2 (en) 2012-07-25 2015-08-25 Empire Technology Development Llc Repairing graphene on a porous support
WO2014018031A1 (en) 2012-07-25 2014-01-30 Empire Technology Development Llc Graphene membrane repair
WO2014019089A1 (en) * 2012-07-30 2014-02-06 Zhongwei Chen Low cost synthesis of single material bifunctional nonprecious catalyst for electrochemical devices
CN103112850B (zh) * 2013-03-13 2015-02-18 上海二工大资产经营有限公司 一种催化氧化多次插层制备高质量石墨烯的方法
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TW201500064A (zh) 2013-06-28 2015-01-01 Nat Univ Tsing Hua 抗菌材料及其製備與使用方法
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US20160087148A1 (en) 2014-09-19 2016-03-24 National Cheng Kung University Non-metallic semiconductor quantum dot and method of carrying out chemical reaction or photoluminescence reaction by using the same
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CN104667869B (zh) * 2015-02-11 2016-10-05 四川大学 一种利用单过硫酸盐及负载钴铁双相复合氧化石墨烯去除水中内分泌干扰物的方法
CN105016330B (zh) * 2015-07-08 2017-12-22 常州市诚天电子有限公司 一种石墨烯的制备方法
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CN105289723A (zh) * 2015-10-20 2016-02-03 河南职业技术学院 使用碳催化剂的烃转化
CN107008481B (zh) * 2016-01-27 2020-09-22 中国石油化工股份有限公司 一种含杂原子纳米碳材料及其制备方法和应用以及一种烃脱氢反应方法
CN107216461B (zh) * 2016-03-22 2020-08-25 中国科学院理化技术研究所 一种以氧化石墨烯为引发剂引发环氧类单体聚合的方法
CN106467529B (zh) * 2016-08-24 2019-06-14 江苏三月光电科技有限公司 一种以9-芴酮为核心的有机电致发光材料及其应用
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JP2020536839A (ja) * 2017-10-12 2020-12-17 サウジ アラビアン オイル カンパニー ナノコンポジット架橋剤を含むポリマーゲル
WO2019090323A1 (en) * 2017-11-06 2019-05-09 Massachusetts Institute Of Technology High functionalization density graphene
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CN115106094B (zh) * 2022-08-26 2022-11-29 北京石油化工学院 一种用于催化醇类脱氢的催化剂及其制备方法和应用
PL247281B1 (pl) * 2022-12-22 2025-06-09 Univ Ostrawski Sposoby syntezy pochodnych 1,3-dioksolanów na bazie materiałów węglowych
CN118142579B (zh) * 2024-02-18 2025-06-06 中国科学院理化技术研究所 一种用于在室温下高效催化羟醛缩合反应的膜催化材料
CN118638297B (zh) * 2024-08-16 2024-10-29 山东安博瑞工程科技有限公司 一种改性聚脲树脂组合物及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009143405A2 (en) * 2008-05-22 2009-11-26 The University Of North Carolina At Chapel Hill Synthesis of graphene sheets and nanoparticle composites comprising same

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB993921A (en) * 1963-03-28 1965-06-02 Distillers Co Yeast Ltd Improvements in or relating to the production of unsaturated aliphatic aldehydes
JPS4936642A (https=) * 1972-08-11 1974-04-05
GB1565074A (en) * 1976-11-03 1980-04-16 British Petroleum Co Process for the production of ammonia
DE2738269C3 (de) * 1977-08-25 1980-02-21 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Herstellung von Aceton aus Isobutyraldehyd
US5876687A (en) * 1997-04-04 1999-03-02 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Elemental metals or oxides distributed on a carbon substrate or self-supported and the manufacturing process using graphite oxide as template
DE10046957A1 (de) * 2000-09-21 2002-04-11 Basf Ag Verfahren zur Herstellung eines Multimetalloxid-Katalysators, Verfahren zur Herstellung ungesättigter Aldehyde und/oder Carbonsäuren und Bandcalziniervorrichtung
JP3882072B2 (ja) * 2001-12-25 2007-02-14 独立行政法人産業技術総合研究所 多孔質グラファイト複合材料及びその製造方法
JP2003238131A (ja) * 2002-02-08 2003-08-27 Mitsubishi Gas Chem Co Inc 炭素からなる骨格を持つ薄膜状粒子のランダム凝集体
US7550611B2 (en) * 2002-11-14 2009-06-23 Catalytic Materials, Llc Carbon nanochips as catalyst supports for metals and metal oxides
TWI267219B (en) * 2005-08-29 2006-11-21 Ind Tech Res Inst Composition, complex and method for enhancing catalysts utilization
US7914844B2 (en) * 2005-11-18 2011-03-29 Northwestern University Stable dispersions of polymer-coated graphitic nanoplatelets
WO2007089017A1 (ja) * 2006-02-03 2007-08-09 Daikin Industries, Ltd. －ｓｏ３ｈ基含有フルオロポリマー製造方法及び－ｓｏ３ｈ基含有フルオロポリマー
CN101385978B (zh) * 2007-09-12 2011-04-20 上海华谊丙烯酸有限公司 一种合成甲基丙烯醛的催化剂及其制备方法
WO2009085015A1 (en) * 2008-01-03 2009-07-09 National University Of Singapore Functionalised graphene oxide
WO2009134492A2 (en) * 2008-02-05 2009-11-05 Aksay Ilhan A Functionalized graphene sheets having high carbon to oxygen ratios
US9039938B2 (en) * 2008-02-05 2015-05-26 The Trustees Of Princeton University Coatings containing functionalized graphene sheets and articles coated therewith
JP5077795B2 (ja) * 2008-03-10 2012-11-21 独立行政法人科学技術振興機構 カルボニル化合物の製造方法
JP5661618B2 (ja) * 2008-07-02 2015-01-28 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 幾何学的酸化物成形体の製造方法
CN102112424A (zh) * 2008-08-05 2011-06-29 陶氏技术投资有限公司 用于制备烷撑二醇的两级气相方法
CN101337878B (zh) * 2008-08-13 2011-04-06 华南理工大学 一种催化氧化环己烷直接生产己二酸的方法
JP5549067B2 (ja) * 2008-10-22 2014-07-16 株式会社豊田中央研究所 糖又はその誘導体の製造方法
CN101670269B (zh) * 2009-09-18 2011-05-11 淮阴师范学院 负载型氧化石墨/羟基硝酸氧铋复合材料的合成方法
JP2011224499A (ja) * 2010-04-21 2011-11-10 Toyota Central R&D Labs Inc 糖又はその誘導体の製造方法
EP2576048A4 (en) * 2010-05-28 2014-01-01 Graphea Inc GRAPHIC OXIDE AND GRAPHITE OXIDE CATALYSTS AND SYSTEMS THEREWITH

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009143405A2 (en) * 2008-05-22 2009-11-26 The University Of North Carolina At Chapel Hill Synthesis of graphene sheets and nanoparticle composites comprising same

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103880717A (zh) * 2014-03-21 2014-06-25 江苏傲伦达科技实业股份有限公司 二（3-烯丙基-4-羟基苯基）砜及其衍生物的制备方法
CN103880717B (zh) * 2014-03-21 2015-11-04 江苏傲伦达科技实业股份有限公司 二（3-烯丙基-4-羟基苯基）砜及其衍生物的制备方法
CN103977835A (zh) * 2014-06-06 2014-08-13 上海师范大学 磺化石墨烯基新型Ru(bpy)32+纳米非均相催化剂及其制备方法
CN103977835B (zh) * 2014-06-06 2016-08-24 上海师范大学 磺化石墨烯基Ru(bpy)32+纳米非均相催化剂及其制备方法
CN105241571A (zh) * 2015-09-21 2016-01-13 长安大学 N和Mo用于提高氧化石墨烯温敏特性的应用
CN107418199A (zh) * 2017-06-26 2017-12-01 杭州师范大学 一种石墨烯改性的尼龙复合树脂及其粉末的制备方法与应用
CN107649112A (zh) * 2017-09-25 2018-02-02 山东大学 一种用于氟代磷腈及其衍生物工业化生产的催化剂
CN109943058A (zh) * 2019-03-27 2019-06-28 浙江中科应化科技有限公司 一种改性聚氨酯材料
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CN109943058B (zh) * 2019-03-27 2021-05-04 浙江中科应化科技有限公司 一种改性聚氨酯材料
CN110078064A (zh) * 2019-05-07 2019-08-02 青岛科技大学 一种可导电氧化石墨烯及其制备方法和应用
CN114436914A (zh) * 2020-10-30 2022-05-06 中国石油化工股份有限公司 一种制备亚砜的方法
CN112812754A (zh) * 2021-02-07 2021-05-18 广西师范大学 一种苯乙炔功能化石墨烯/铜复合导热材料及其制备方法
CN112812754B (zh) * 2021-02-07 2021-07-16 广西师范大学 一种苯乙炔功能化石墨烯/铜复合导热材料及其制备方法
CN114853107A (zh) * 2022-04-13 2022-08-05 锦洋高新材料股份有限公司 一种含氟废水的深度除氟工艺及铝源除氟剂
CN114853107B (zh) * 2022-04-13 2023-08-22 锦洋高新材料股份有限公司 一种含氟废水的深度除氟工艺及铝源除氟剂

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Application publication date: 20130327