GB993921A - Improvements in or relating to the production of unsaturated aliphatic aldehydes - Google Patents

Improvements in or relating to the production of unsaturated aliphatic aldehydes

Info

Publication number
GB993921A
GB993921A GB1224063A GB1224063A GB993921A GB 993921 A GB993921 A GB 993921A GB 1224063 A GB1224063 A GB 1224063A GB 1224063 A GB1224063 A GB 1224063A GB 993921 A GB993921 A GB 993921A
Authority
GB
United Kingdom
Prior art keywords
arsenic
catalyst
oxide
oxygen
antimony
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1224063A
Inventor
Edward James Gasson
Rowland Harris Jenkins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical Distillers Co Yeast Ltd
Priority to GB1224063A priority Critical patent/GB993921A/en
Publication of GB993921A publication Critical patent/GB993921A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Acrolein or methacrolein is produced by reacting at elevated temperatures in the vapour phase propylene or isobutene with molecular oxygen in the presence of arsenic or an arsenic oxide over an oxide composition containing tungsten and oxygen with antimony or titanium. The arsenic or arsenic oxide may be supplied either in admixture with the reactant feed or may be in admixture with the catalyst. In the latter case, arsenic lost by evaporation may be replaced by introducing fresh arsenic oxide or elemental arsenic with the reactants. The catalyst may be supported e.g. on graphite alumina or silica. An inert diluent may be added, e.g. nitrogen, propane, butane, isobutane, carbon dioxide, steam or mixtures thereof.ALSO:A catalyst for oxidizing olefines to unsaturated aldehydes comprises an oxide composition containing tungsten and oxygen with antimony or titanium and may also contain arsenic or an arsenic oxide. The catalyst may be made by mixing the oxides together e.g. in aqueous suspension, followed by heat treatment and addition of arsenic or an arsenic oxide. Alternately the arsenic-containing catalyst may be prepared by coprecipitation from mixed solutions of arsenic salts and the catalyst metal salts. The catalyst may be deposited on a support, e.g. alumina, silica, or graphite.
GB1224063A 1963-03-28 1963-03-28 Improvements in or relating to the production of unsaturated aliphatic aldehydes Expired GB993921A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1224063A GB993921A (en) 1963-03-28 1963-03-28 Improvements in or relating to the production of unsaturated aliphatic aldehydes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1224063A GB993921A (en) 1963-03-28 1963-03-28 Improvements in or relating to the production of unsaturated aliphatic aldehydes

Publications (1)

Publication Number Publication Date
GB993921A true GB993921A (en) 1965-06-02

Family

ID=10000962

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1224063A Expired GB993921A (en) 1963-03-28 1963-03-28 Improvements in or relating to the production of unsaturated aliphatic aldehydes

Country Status (1)

Country Link
GB (1) GB993921A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2480914A (en) * 2010-05-28 2011-12-07 Univ Texas Carbocatalysts for chemical transformations

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2480914A (en) * 2010-05-28 2011-12-07 Univ Texas Carbocatalysts for chemical transformations
GB2480914B (en) * 2010-05-28 2013-08-21 Univ Texas Carbocatalysts for chemical transformations

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