CN102471471B - 聚对苯二甲酸乙二酯的制备方法 - Google Patents
聚对苯二甲酸乙二酯的制备方法 Download PDFInfo
- Publication number
- CN102471471B CN102471471B CN201080036692.5A CN201080036692A CN102471471B CN 102471471 B CN102471471 B CN 102471471B CN 201080036692 A CN201080036692 A CN 201080036692A CN 102471471 B CN102471471 B CN 102471471B
- Authority
- CN
- China
- Prior art keywords
- pet
- ppm
- catalyst system
- acid
- polycondensation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
- C08G63/86—Germanium, antimony, or compounds thereof
- C08G63/866—Antimony or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- General Chemical & Material Sciences (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09075379A EP2287225A1 (en) | 2009-08-20 | 2009-08-20 | Process for making polyethylene terephthalate |
| EP09075379.9 | 2009-08-20 | ||
| PCT/EP2010/005115 WO2011020619A1 (en) | 2009-08-20 | 2010-08-17 | Process for making polyethylene terephthalate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102471471A CN102471471A (zh) | 2012-05-23 |
| CN102471471B true CN102471471B (zh) | 2014-03-19 |
Family
ID=41259289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201080036692.5A Expired - Fee Related CN102471471B (zh) | 2009-08-20 | 2010-08-17 | 聚对苯二甲酸乙二酯的制备方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8901271B2 (enExample) |
| EP (2) | EP2287225A1 (enExample) |
| JP (1) | JP5639651B2 (enExample) |
| KR (1) | KR20120065362A (enExample) |
| CN (1) | CN102471471B (enExample) |
| TW (1) | TWI473833B (enExample) |
| WO (1) | WO2011020619A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102725444B (zh) * | 2009-12-04 | 2014-06-25 | 可乐丽股份有限公司 | 常压可染聚酯纤维及其制造方法 |
| WO2013087199A1 (en) | 2011-12-16 | 2013-06-20 | Saudi Basic Industries Corporation (Sabic) | Process for synthesizing a new catalyst complex for the production of polyethylene terephthlate |
| US8779415B2 (en) * | 2012-11-08 | 2014-07-15 | Eastman Kodak Company | Devices containing organic polymeric multi-metallic composites |
| JP6005005B2 (ja) * | 2013-07-23 | 2016-10-12 | 富士フイルム株式会社 | 二軸延伸ポリエステルフィルム及びその製造方法 |
| TW201602077A (zh) * | 2013-11-20 | 2016-01-16 | 英威達技術有限公司 | 整合純化對苯二甲酸製造及聚酯聚合反應之工廠中之汙染防治 |
| TWI629294B (zh) | 2016-07-06 | 2018-07-11 | 全能材料科技股份有限公司 | 用於製造pet樹酯之觸媒系統組合物 |
| WO2019046946A1 (en) * | 2017-09-07 | 2019-03-14 | The Governing Council Of The University Of Toronto | PRODUCTION OF GLYCOLATE FROM ETHYLENE GLYCOL AND ASSOCIATED MICROBIAL ENGINEERING |
| KR20220079915A (ko) * | 2019-10-08 | 2022-06-14 | 이스트만 케미칼 컴파니 | 결정화가능한 반응기 등급 수지를 위한 촉매 시스템 |
| JPWO2021172349A1 (enExample) * | 2020-02-26 | 2021-09-02 | ||
| WO2023044028A1 (en) * | 2021-09-16 | 2023-03-23 | Circ, LLC | Method of aging regenerated diacid crystals |
| TW202330758A (zh) | 2021-09-16 | 2023-08-01 | 美商賽克股份有限公司 | 從由廢棄材料解聚合所形成再生二酸形成聚酯之方法 |
| WO2023227209A1 (en) * | 2022-05-25 | 2023-11-30 | Equipolymers Gmbh | Method for producing a polyester |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5017680A (en) * | 1990-07-03 | 1991-05-21 | Eastman Kodak Company | Process and catalyst-inhibitor systems for preparing poly(ethylene terephthalate) |
| JP2000226446A (ja) * | 1999-02-04 | 2000-08-15 | Toyobo Co Ltd | 中空成形品用ポリエステル樹脂 |
| CN1930210A (zh) * | 2004-03-11 | 2007-03-14 | 沙特基础工业公司 | 由对苯二甲酸和乙二醇制备聚对苯二甲酸乙二醇酯的催化剂组合物,及其制备方法 |
Family Cites Families (57)
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| US3404121A (en) | 1966-07-27 | 1968-10-01 | Eastman Kodak Co | Polyester catalyst-stabilizer usage |
| AT279172B (de) | 1967-12-15 | 1970-02-25 | Alpine Chemische Ag | Verfahren zur Herstellung von Polyestern und Copolyestern |
| US3929728A (en) | 1970-06-02 | 1975-12-30 | Mitsubishi Rayon Co | Process for preparing linear polyesters |
| US3907754A (en) | 1974-06-19 | 1975-09-23 | Eastman Kodak Co | Process and catalyst-inhibitor system for preparing synthetic linear polyester |
| US3962189A (en) | 1974-11-01 | 1976-06-08 | Eastman Kodak Company | Process and catalyst-inhibitor systems for preparing synthetic linear polyesters |
| US4010145A (en) | 1975-05-12 | 1977-03-01 | Eastman Kodak Company | Process and catalyst inhibitor systems for preparing synthetic linear polyesters |
| DE2559290B2 (de) | 1975-12-31 | 1979-08-02 | Davy International Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen Herstellung von hochmolekularem PoIyäthylenterephthalat |
| US4146729A (en) | 1977-04-07 | 1979-03-27 | E. I. Du Pont De Nemours And Company | Process for preparing poly(ethylene terephthalate) |
| US4161578A (en) | 1978-05-12 | 1979-07-17 | Bepex Corporation | Process for solid phase polymerization of polyester |
| JPS55149320A (en) | 1979-05-09 | 1980-11-20 | Nippon Ester Co Ltd | Polyester preparation |
| JPS568431A (en) | 1979-07-03 | 1981-01-28 | Nippon Ester Co Ltd | Production of polyester |
| US4361694A (en) | 1981-12-31 | 1982-11-30 | Union Carbide Corporation | Coordination complexes as polyesterification catalysts |
| US4356299A (en) | 1982-02-04 | 1982-10-26 | Rohm And Haas Company | Catalyst system for a polyethylene terephthalate polycondensation |
| JPH0781002B2 (ja) | 1988-12-09 | 1995-08-30 | 三菱レイヨン株式会社 | 共重合ポリエステルの製造方法 |
| US5162488A (en) | 1989-05-22 | 1992-11-10 | Hoechst Celanese Corporation | Catalyst system and process for preparing polyethylene terephthalate |
| US5008230A (en) | 1989-05-22 | 1991-04-16 | Hoechst Celanese Corporation | Catalyst for preparing high clarity, colorless polyethylene terephthalate |
| US5166311A (en) | 1989-05-22 | 1992-11-24 | Hoechst Celanese Corporation | Catalyst system and process for preparing high clarity, colorless polyethylene terephthalate |
| US5153164A (en) | 1989-05-22 | 1992-10-06 | Hoechst Celanese Corporation | Catalyst system for preparing polyethylene terephthalate |
| US5340907A (en) | 1993-06-28 | 1994-08-23 | Eastman Chemical Company | Copolyester of cyclohexanedimethanol and process for producing such polyester |
| US5372864A (en) | 1993-09-03 | 1994-12-13 | Eastman Chemical Company | Toners for polyesters |
| JP3115465B2 (ja) | 1993-10-01 | 2000-12-04 | 鐘紡株式会社 | ポリエステル組成物 |
| US5434239A (en) * | 1993-10-18 | 1995-07-18 | E. I. Du Pont De Nemours And Company | Continuous polyester process |
| JP3342578B2 (ja) | 1994-07-13 | 2002-11-11 | ユニチカ株式会社 | 脂肪族ポリエステルの製造方法 |
| US5608032A (en) | 1995-03-28 | 1997-03-04 | Industrial Technology Research Institute | Catalytic compositions for the proparation of poly(ethylene terephthalate) with attenuated yellow color |
| US5623047A (en) | 1995-03-28 | 1997-04-22 | Industrial Technology Research Institute | Catalytic compositions for the preparation of poly(ethylene terephthalate) with improved color |
| DE19537365C1 (de) | 1995-10-06 | 1996-12-19 | Fraunhofer Ges Forschung | Verfahren zur Stabilisierung der Schmelzeviskosität von Zinn-, Titan- und/oder Zirkoniumverbindungen als Katalysator und/oder Initiator enthaltender aliphatischer oder aromatisch-aliphatischer Homo- oder Copolyester und Verwendung einer Verbindung, die mindestens einen Tropolonring aufweist als Maskierungsmittel in Polyesterschmelzen |
| DE19537930B4 (de) | 1995-10-12 | 2006-02-23 | Zimmer Ag | Verfahren zur Herstellung von klarsichtigem Polyester |
| GB9612161D0 (en) | 1996-06-11 | 1996-08-14 | Tioxide Specialties Ltd | Esterification process |
| JP2001510493A (ja) | 1996-06-11 | 2001-07-31 | デュポン テイジン フィルムズ ユー.エス.リミテッド パートナーシップ | ポリエステル製品 |
| DE59811059D1 (de) | 1997-06-10 | 2004-04-29 | Acordis Ind Fibers Gmbh | Verfahren zur herstellung von polyestern und copolyestern |
| US5932105A (en) | 1997-10-01 | 1999-08-03 | Mobile Process Technology, Co. | Method of polyester manufacturing using crossflow membrane filtration |
| JPH11209464A (ja) | 1998-01-19 | 1999-08-03 | Teijin Ltd | 芳香族ポリエステル及びその製造方法 |
| US5981690A (en) | 1998-04-17 | 1999-11-09 | E. I. Du Pont De Nemours And Company | Poly(alkylene arylates) having improved optical properties |
| US6133404A (en) | 1998-12-26 | 2000-10-17 | National Institute Of Technology And Quality | Polyester and formation process thereof |
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| US6080834A (en) | 1999-04-16 | 2000-06-27 | E. I. Du Pont De Nemours And Company | Titanium-containing catalyst composition and processes therefor and therewith |
| JP2001081170A (ja) | 1999-07-13 | 2001-03-27 | Mitsui Chemicals Inc | ポリエステルの製造方法 |
| JP2001098064A (ja) | 1999-07-26 | 2001-04-10 | Mitsui Chemicals Inc | ポリエステルの製造方法 |
| EP1270640B1 (en) | 2000-08-22 | 2004-02-18 | Mitsui Chemicals, Inc. | Catalysts for polyester production, process for producing polyester, and polyester |
| JP2002241479A (ja) | 2001-02-21 | 2002-08-28 | Toyobo Co Ltd | ポリエステル重合触媒およびこれを用いて製造されたポリエステルならびにポリエステルの製造方法 |
| US6489433B2 (en) | 2001-02-23 | 2002-12-03 | E. I. Du Pont De Nemours And Company | Metal-containing composition and process therewith |
| JP2003171453A (ja) * | 2001-09-25 | 2003-06-20 | Toyobo Co Ltd | ポリエステルの製造方法 |
| DE60225592T2 (de) * | 2001-10-22 | 2009-04-23 | SK Chemicals Co., Ltd., Suwon | Copolyesterharz für lösungsmittelhaltige beschichtungen und die damit hergestellten beschichtungen |
| US20030203811A1 (en) | 2002-04-25 | 2003-10-30 | Putzig Donald Edward | Stable aqueous solutions comprising titanium and zinc and process therewith |
| JP2005527697A (ja) | 2002-05-09 | 2005-09-15 | イクイポリマース・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | 縮重合反応に対する触媒系 |
| JP2004107383A (ja) | 2002-09-13 | 2004-04-08 | Mitsui Chemicals Inc | ポリエステル樹脂、ポリエステル樹脂組成物およびその用途 |
| JP2004217887A (ja) | 2002-12-27 | 2004-08-05 | Mitsubishi Chemicals Corp | ポリエステル製造用触媒およびそれを用いるポリエステルの製造方法 |
| US20060205917A1 (en) * | 2003-01-23 | 2006-09-14 | Siddiqui Jamil A | Catalyst complex for catalysing esterification and trans-esterification reactions and process for esterification/trans-esterification using the same |
| GB2398073A (en) | 2003-02-03 | 2004-08-11 | Johnson Matthey Plc | Polyester manufacturing process |
| TW200418901A (en) | 2003-02-25 | 2004-10-01 | Du Pont | Process for the manufacture of polyester via hydrogenation treatment of recycled diol |
| JP2004346222A (ja) | 2003-05-23 | 2004-12-09 | Mitsui Chemicals Inc | ポリエチレンテレフタレートの製造方法 |
| JP2005179592A (ja) | 2003-12-22 | 2005-07-07 | Mitsubishi Chemicals Corp | ポリエステルの製造方法 |
| JP2005272784A (ja) | 2004-03-26 | 2005-10-06 | Toyobo Co Ltd | ポリエステル樹脂組成物およびそれからなるポリエステル成形体 |
| US20050277716A1 (en) | 2004-05-27 | 2005-12-15 | Pearson Jason C | Furyl-2-methylidene UV absorbers and compositions incorporating the UV absorbers |
| JP4578865B2 (ja) | 2004-06-08 | 2010-11-10 | 日本エステル株式会社 | 共重合ポリエステル樹脂 |
| WO2007123631A1 (en) | 2006-03-28 | 2007-11-01 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
| CA2656998C (en) * | 2006-07-11 | 2015-04-21 | Wellman, Inc. | Composite solid phase polymerization catalyst |
-
2009
- 2009-08-20 EP EP09075379A patent/EP2287225A1/en not_active Withdrawn
-
2010
- 2010-07-22 TW TW99124159A patent/TWI473833B/zh not_active IP Right Cessation
- 2010-08-17 EP EP10747008A patent/EP2467413A1/en not_active Withdrawn
- 2010-08-17 JP JP2012525092A patent/JP5639651B2/ja not_active Expired - Fee Related
- 2010-08-17 KR KR1020127007251A patent/KR20120065362A/ko not_active Ceased
- 2010-08-17 CN CN201080036692.5A patent/CN102471471B/zh not_active Expired - Fee Related
- 2010-08-17 WO PCT/EP2010/005115 patent/WO2011020619A1/en not_active Ceased
- 2010-08-17 US US13/391,432 patent/US8901271B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5017680A (en) * | 1990-07-03 | 1991-05-21 | Eastman Kodak Company | Process and catalyst-inhibitor systems for preparing poly(ethylene terephthalate) |
| JP2000226446A (ja) * | 1999-02-04 | 2000-08-15 | Toyobo Co Ltd | 中空成形品用ポリエステル樹脂 |
| CN1930210A (zh) * | 2004-03-11 | 2007-03-14 | 沙特基础工业公司 | 由对苯二甲酸和乙二醇制备聚对苯二甲酸乙二醇酯的催化剂组合物,及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2287225A1 (en) | 2011-02-23 |
| US20120161358A1 (en) | 2012-06-28 |
| KR20120065362A (ko) | 2012-06-20 |
| JP2013502469A (ja) | 2013-01-24 |
| JP5639651B2 (ja) | 2014-12-10 |
| WO2011020619A1 (en) | 2011-02-24 |
| TW201127871A (en) | 2011-08-16 |
| CN102471471A (zh) | 2012-05-23 |
| TWI473833B (zh) | 2015-02-21 |
| EP2467413A1 (en) | 2012-06-27 |
| US8901271B2 (en) | 2014-12-02 |
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