CN102471068A - 纳米尺寸的石墨烯类材料的制造方法及其制造设备 - Google Patents
纳米尺寸的石墨烯类材料的制造方法及其制造设备 Download PDFInfo
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- CN102471068A CN102471068A CN2009801608755A CN200980160875A CN102471068A CN 102471068 A CN102471068 A CN 102471068A CN 2009801608755 A CN2009801608755 A CN 2009801608755A CN 200980160875 A CN200980160875 A CN 200980160875A CN 102471068 A CN102471068 A CN 102471068A
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- sulfuric acid
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 180
- 239000000463 material Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 33
- 229910021389 graphene Inorganic materials 0.000 title abstract description 23
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 112
- 239000010439 graphite Substances 0.000 claims abstract description 112
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 59
- 239000011541 reaction mixture Substances 0.000 claims abstract description 38
- 239000002002 slurry Substances 0.000 claims abstract description 28
- 238000005406 washing Methods 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 10
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 110
- 239000001117 sulphuric acid Substances 0.000 claims description 28
- 239000007864 aqueous solution Substances 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 14
- 235000011149 sulphuric acid Nutrition 0.000 claims description 12
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- 238000007599 discharging Methods 0.000 claims description 6
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- 229920002472 Starch Polymers 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
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- 230000003647 oxidation Effects 0.000 abstract description 5
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- 239000012286 potassium permanganate Substances 0.000 abstract description 5
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
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- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
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- 206010013786 Dry skin Diseases 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- LUTSRLYCMSCGCS-BWOMAWGNSA-N [(3s,8r,9s,10r,13s)-10,13-dimethyl-17-oxo-1,2,3,4,7,8,9,11,12,16-decahydrocyclopenta[a]phenanthren-3-yl] acetate Chemical compound C([C@@H]12)C[C@]3(C)C(=O)CC=C3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)C)C1 LUTSRLYCMSCGCS-BWOMAWGNSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004063 acid-resistant material Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
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- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
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- 238000000407 epitaxy Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
- C01B32/19—Preparation by exfoliation
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/001—Calcining
- B01J6/004—Calcining using hot gas streams in which the material is moved
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B82Y40/00—Manufacture or treatment of nanostructures
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- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
- C01B32/19—Preparation by exfoliation
- C01B32/192—Preparation by exfoliation starting from graphitic oxides
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- C01B32/198—Graphene oxide
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- C01B2204/00—Structure or properties of graphene
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Abstract
Description
Claims (16)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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KR10-2009-0073152 | 2009-08-10 | ||
KR20090073152 | 2009-08-10 | ||
PCT/KR2009/004465 WO2011019095A1 (en) | 2009-08-10 | 2009-08-11 | A method of producing nano-size graphene-based material and an equipment for producing the same |
Publications (2)
Publication Number | Publication Date |
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CN102471068A true CN102471068A (zh) | 2012-05-23 |
CN102471068B CN102471068B (zh) | 2014-09-17 |
Family
ID=43586263
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200980160875.5A Expired - Fee Related CN102471068B (zh) | 2009-08-10 | 2009-08-11 | 纳米尺寸的石墨烯类材料的制造方法及其制造设备 |
Country Status (5)
Country | Link |
---|---|
US (1) | US8968695B2 (zh) |
EP (2) | EP2493812B1 (zh) |
KR (2) | KR101053933B1 (zh) |
CN (1) | CN102471068B (zh) |
WO (1) | WO2011019095A1 (zh) |
Cited By (12)
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CN102730677A (zh) * | 2012-07-23 | 2012-10-17 | 贵州新碳高科有限责任公司 | 制备石墨烯的设备、方法及制得的石墨烯 |
CN103935991A (zh) * | 2014-04-23 | 2014-07-23 | 中国科学院山西煤炭化学研究所 | 一种规模化连续制备高品质石墨烯的方法 |
CN104071772A (zh) * | 2013-03-25 | 2014-10-01 | 钱伟 | 一种工业化制备氧化石墨的设备 |
CN104209529A (zh) * | 2013-05-29 | 2014-12-17 | 中国科学院理化技术研究所 | 一种基于微通道混合反应系统的连续制备超细银粉的方法 |
CN104227011A (zh) * | 2014-08-29 | 2014-12-24 | 南京邮电大学 | 一种宏量制备纳米金属材料的装置及其制备方法 |
TWI474975B (zh) * | 2013-01-15 | 2015-03-01 | Micc Tec Co Ltd | 還原型氧化石墨烯之製造方法 |
CN105057122A (zh) * | 2015-07-19 | 2015-11-18 | 青岛科技大学 | 一种带有旋风分离器的碳纳米管分散设备 |
CN106882803A (zh) * | 2017-03-10 | 2017-06-23 | 江南石墨烯研究院 | 一种制备氧化石墨烯的方法及其装置 |
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CN110115964A (zh) * | 2019-05-29 | 2019-08-13 | 山东斯恩特纳米材料有限公司 | 一种快速连续进行碳纳米管表面功能化的方法及装置 |
CN112811417A (zh) * | 2021-02-10 | 2021-05-18 | 中国科学技术大学先进技术研究院 | 一种微流控制备氧化石墨烯的方法 |
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JP5364866B1 (ja) * | 2012-05-14 | 2013-12-11 | 積水化学工業株式会社 | 改質グラフェンライク炭素材料の製造方法、改質グラフェンライク炭素材料、及び改質グラフェンライク炭素材料を含む樹脂複合材料 |
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CN104209529B (zh) * | 2013-05-29 | 2016-06-01 | 中国科学院理化技术研究所 | 一种基于微通道混合反应系统的连续制备超细银粉的方法 |
CN104209529A (zh) * | 2013-05-29 | 2014-12-17 | 中国科学院理化技术研究所 | 一种基于微通道混合反应系统的连续制备超细银粉的方法 |
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CN107690419A (zh) * | 2015-09-07 | 2018-02-13 | 株式会社Lg化学 | 片材剥离装置 |
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CN112811417A (zh) * | 2021-02-10 | 2021-05-18 | 中国科学技术大学先进技术研究院 | 一种微流控制备氧化石墨烯的方法 |
CN114345268A (zh) * | 2021-12-14 | 2022-04-15 | 昆明云天墨睿科技有限公司 | 一种氧化石墨烯的工业级量产自动化生产系统及生产方法 |
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EP2495216A2 (en) | 2012-09-05 |
EP2493812A1 (en) | 2012-09-05 |
EP2495216B1 (en) | 2018-02-28 |
EP2493812A4 (en) | 2013-10-02 |
KR20110016420A (ko) | 2011-02-17 |
EP2493812B1 (en) | 2018-02-14 |
KR101337970B1 (ko) | 2013-12-06 |
US20120201738A1 (en) | 2012-08-09 |
WO2011019095A1 (en) | 2011-02-17 |
US8968695B2 (en) | 2015-03-03 |
CN102471068B (zh) | 2014-09-17 |
KR20110036721A (ko) | 2011-04-08 |
EP2495216A4 (en) | 2013-10-23 |
KR101053933B1 (ko) | 2011-08-04 |
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