CN101696132B - Multi-mineral organotrophic fertilizer and preparation method thereof - Google Patents
Multi-mineral organotrophic fertilizer and preparation method thereof Download PDFInfo
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- CN101696132B CN101696132B CN2009101126970A CN200910112697A CN101696132B CN 101696132 B CN101696132 B CN 101696132B CN 2009101126970 A CN2009101126970 A CN 2009101126970A CN 200910112697 A CN200910112697 A CN 200910112697A CN 101696132 B CN101696132 B CN 101696132B
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- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 108
- 239000011707 mineral Substances 0.000 title claims abstract description 108
- 239000003337 fertilizer Substances 0.000 title claims abstract description 41
- 230000000972 organotrophic effect Effects 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 43
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000001354 calcination Methods 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 11
- -1 compound amino acid Chemical class 0.000 claims abstract description 10
- 239000003513 alkali Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 3
- 230000007062 hydrolysis Effects 0.000 claims description 61
- 238000006460 hydrolysis reaction Methods 0.000 claims description 61
- 241001465754 Metazoa Species 0.000 claims description 37
- 235000001014 amino acid Nutrition 0.000 claims description 35
- 239000007795 chemical reaction product Substances 0.000 claims description 34
- 229920001184 polypeptide Polymers 0.000 claims description 34
- 102000004196 processed proteins & peptides Human genes 0.000 claims description 34
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 34
- 239000000126 substance Substances 0.000 claims description 34
- 150000001413 amino acids Chemical class 0.000 claims description 33
- 239000002253 acid Substances 0.000 claims description 32
- 150000007524 organic acids Chemical class 0.000 claims description 26
- 241000196324 Embryophyta Species 0.000 claims description 23
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 22
- 238000010298 pulverizing process Methods 0.000 claims description 21
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 claims description 20
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 20
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 18
- 230000003301 hydrolyzing effect Effects 0.000 claims description 17
- 239000010451 perlite Substances 0.000 claims description 16
- 235000019362 perlite Nutrition 0.000 claims description 16
- 239000004575 stone Substances 0.000 claims description 16
- 239000010455 vermiculite Substances 0.000 claims description 16
- 229910052902 vermiculite Inorganic materials 0.000 claims description 16
- 235000019354 vermiculite Nutrition 0.000 claims description 16
- 108010059892 Cellulase Proteins 0.000 claims description 15
- 229940106157 cellulase Drugs 0.000 claims description 15
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 11
- 229910017604 nitric acid Inorganic materials 0.000 claims description 11
- 108091005804 Peptidases Proteins 0.000 claims description 10
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 10
- 239000003818 cinder Substances 0.000 claims description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 7
- 108010064851 Plant Proteins Proteins 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 6
- 235000021118 plant-derived protein Nutrition 0.000 claims description 6
- 102000035195 Peptidases Human genes 0.000 claims description 5
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 5
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 5
- 239000004365 Protease Substances 0.000 claims description 5
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 5
- 239000010828 animal waste Substances 0.000 claims description 5
- 210000000988 bone and bone Anatomy 0.000 claims description 5
- 210000002421 cell wall Anatomy 0.000 claims description 5
- 235000013372 meat Nutrition 0.000 claims description 5
- 210000003205 muscle Anatomy 0.000 claims description 5
- 241001517315 Habenaria Species 0.000 claims description 4
- 210000002784 stomach Anatomy 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000012216 screening Methods 0.000 abstract 1
- 235000010755 mineral Nutrition 0.000 description 64
- 239000002689 soil Substances 0.000 description 20
- 235000013399 edible fruits Nutrition 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 229910052698 phosphorus Inorganic materials 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 230000035558 fertility Effects 0.000 description 5
- 244000005700 microbiome Species 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 240000007594 Oryza sativa Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 235000016709 nutrition Nutrition 0.000 description 4
- 230000035764 nutrition Effects 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 230000035479 physiological effects, processes and functions Effects 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 239000011573 trace mineral Substances 0.000 description 4
- 235000013619 trace mineral Nutrition 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 238000009395 breeding Methods 0.000 description 3
- 230000001488 breeding effect Effects 0.000 description 3
- 229940088598 enzyme Drugs 0.000 description 3
- 210000003608 fece Anatomy 0.000 description 3
- 229940088597 hormone Drugs 0.000 description 3
- 239000005556 hormone Substances 0.000 description 3
- 230000000243 photosynthetic effect Effects 0.000 description 3
- 230000002786 root growth Effects 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 240000003553 Leptospermum scoparium Species 0.000 description 2
- 235000015459 Lycium barbarum Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
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- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
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- 230000003053 immunization Effects 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- 235000008935 nutritious Nutrition 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000021384 green leafy vegetables Nutrition 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- 230000000050 nutritive effect Effects 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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- Fertilizers (AREA)
Abstract
The invention relates to multi--mineral organotrophic fertilizer and a preparation method thereof. The multi-mineral organotrophic fertilizer comprises the following raw materials in mass proportion: 100 parts of mineral, 0.2-0.5 part of compound amino acid, 20-30 parts of ingredient and 6-8 parts of water. The preparation method comprises the following steps of: cleaning minerals with NaOH, and then washing the minerals with water to remove remaining alkali; crashing the raw materials until the diameter is no more than 0.1 mm and calcining, and then screening the crashed materials to 50-200 meshes to obtain mineral powder; transferring the powder into a chemical reaction furnace, adding water to immerse the surface of the minerals, adding the compound amino acids and the ingredients, and stirring to enable the pH to be equal to 1-1.2; heating the obtained product to 100-120 DEG C, and then cooling to 30-40 DEG C; separating liquid from dregs, taking a clear solution and adding the compound amino acids and the ingredients to obtain the multi- mineral organotrophic fertilizer.
Description
Technical field
The present invention relates to a kind of fertilizer, especially relate to a kind of multi-mineral organotrophic fertilizer and preparation method thereof.
Background technology
There is downward trend in current global agricultural product quality, and one of reason is trace and a ultramicro-element poorness in the soil.As everyone knows, the agricultural-food that traditional agriculture is produced, quality is high, tasty mouthfeel, but yield poorly.And the agricultural output of modern (chemistry) agriculture prodn is high, but quality is low.Both form sharp-pointed contradiction, and modern agriculture is used chemical fertilizer (several kinds of N, P, K etc.) in a large number, and farm manure goes out of use after purifying treatment.In the soil except that several kinds of chemical fertilizer; Tens kinds of trace and ultramicro-element can not get replenishing; Cause original trace of soil and ultramicro-element; Be absorbed with the farm crop plantation that repeats year after year, the original trace of soil and a ultramicro-element generation are lacked than a generation and poor, cause the agricultural product quality reduction.In order to improve the quality of agricultural-food, must be fertile to the ultra polynary high-quality quick-acting green nourishings of soil application, to satisfy the serious hope of the universe to agricultural product quality.Then provide the soil useful microbe enough nutrition in addition, recover breeding of soil microorganisms population and the multifarious formation of all kinds of biocenological eubiosis promotion soil organisms, thereby strengthen soil fertility to the ultra polynary high-quality quick-acting green nourishing fertilizer of soil application.
Trace of the present invention and ultramicro-element it to be rich in kind of element surplus in the of 40 be should have in the primary soil but the element that extremely lacks today, it is that other trace element is irreplaceable for the quality institute of improving agricultural-food.
Publication number is that the application for a patent for invention of CN1368490 discloses a kind of nutritive organic amino acid fertilizer; Utilize the compounded amino acid product to be raw material; According to specific crop to demand rule and the various total free aminoacids of various total free aminoacidss and trace element in the intravital Physiology and biochemistry effect of crop; Ratio through various total free aminoacidss and trace element in the adjustment fertilizer is processed, and its use can promote the growth of crop, improves crop yield, quality and resistance; Reducing the consumption of chemical fertilizer and agricultural chemicals, is the fertilizer product of a kind of not only economy but also environmental protection.
Notification number is that to disclose a kind of be main raw material with nitrogen, phosphorus, potassium to the patent of invention of CN1310152; The multiple-element organic nutritious fertilizer organic and inorganic, that mikrobe combines the ratio of each component is: the nitrogen raw material is 5%～20%, and the phosphorus raw material is 3%～16%; The potassium raw material is 3%～20%; Humic acids is 1%～5%, and organic matter is 4%～30%, and middle trace element is 0.1%～0.4%.
Publication number is that the application for a patent for invention of CN1580007 discloses a kind of multiple-element organic nutritious fertilizer that contains organic and inanimate matter through the fermentation synthetic and preparation method thereof; Which comprises at least following components by part by weight: nitrogen content is 2%～15% nitrogenous compound (nitrogen raw material); Phosphorus content is 1%～10% P contained compound (phosphorus raw material); Potassium content is 1%～12% potassium-containing compound (potassium raw material); Comprise peat, chicken manure, cow dung, cake-shaped rape seed dregs, brown coal, peanut in withered one or more by the organic matter that contain water-soluble humic acids 63%～84.5% of any amount than combination, comprise in sulphur, iron, copper, boron, zinc, manganese, molybdenum, the magnesium one or more by any amount than middle micro-0.3%～1% of combination.
Summary of the invention
The object of the present invention is to provide a kind of multi-mineral organotrophic fertilizer and preparation method thereof.
The raw material of multi-mineral organotrophic fertilizer according to the invention is formed and is comprised mineral substance, aminoacids complex, batching and water, presses mass ratio, mineral substance: aminoacids complex: batching: water=100: (0.5～0.2): (20～30): (6～8).
Said mineral substance comprises vermiculite, biotitite, perlite and medical stone, is vermiculite 100 by the content of mass ratio, biotitite 30～60, perlite 15～40, medical stone 15～40.
Said aminoacids complex is made up of at least 3 seed amino acids.
Said batching is organic acid, mineral acid and EDTA Disodium (EDTA) etc., by mass percentage, organic acid 15%～25%, EDTA Disodium 5%～15%, surplus is mineral acid.
Said batching is preferably organic acid, mineral acid, EDTA Disodium (EDTA), hydrolyzing plant hydrolysis end product polypeptide or/and hydrolysis of animal hydrolysis end product polypeptide etc.; By mass percentage; Organic acid 15%～25%; EDTA Disodium 5%～15%, hydrolyzing plant hydrolysis end product polypeptide are or/and hydrolysis of animal hydrolysis end product polypeptide 15%～25%, and surplus is mineral acid.
Said organic acid is selected from least a in oxalic acid, Hydrocerol A, the oxysuccinic acid etc.
Said mineral acid is selected from sulfuric acid, phosphoric acid and nitric acid etc., by mass percentage, phosphoric acid 5%～10%, nitric acid 3%～5%, surplus is sulfuric acid.
The preparation method of said hydrolyzing plant hydrolysis end product polypeptide is with the plant protein raw material pulverizing, and adding its pH value of cellulase control is 8～9, and temperature is 30～50 ℃ of hydrolysis cell wallss, promptly gets hydrolyzing plant hydrolysis end product polypeptide; Said cellulase can be chosen white ant cellulase; Said plant can be selected from least a in beans, marine alga, the tenaculat Habenaria etc.
The preparation method of said hydrolysis of animal hydrolysis end product polypeptide pulverizes the aggregate in the animal proteinum raw material; The even matter of muscle and animal waste becomes rotten; Add protease hydrolysis, promptly get hydrolysis of animal hydrolysis end product polypeptide, said proteolytic enzyme can be chosen trypsinase; Stomach en-, papoid or bromeline etc.; Optional at least a in animal bone, animal meat of said animal proteinum raw material.
The preparation method of multi-mineral organotrophic fertilizer according to the invention may further comprise the steps:
1) with mineral substance biotitite, perlite, vermiculite and medical stone, clean with NaOH, the organic impurity after washing of removing mineral substance removes surplus alkali, with raw material pulverizing, calcining;
2) raw material pulverizing after will calcining is screened to 50～200 orders to diameter≤0.1mm, mineral powders;
3) with step 2) mineral powders of gained moves in the chemical-reacting furnace, adds water logging to mineral surfaces with not ing, adds batching again, and stirring makes pH=1～1.2;
4) step 3) gained material is heated to 100～120 ℃, is cooled to 30～40 ℃ again, melt cinder separates, and gets clear liquid, adds aminoacids complex again, promptly gets multi-mineral organotrophic fertilizer.
In step 1), the mass percent concentration of said NaOH can be 8%～15%, is preferably 10%; Said raw material pulverizing preferably is crushed to diameter is 1～2.5mm, and said incinerating temperature is preferably 800～1200 ℃, and the incinerating time is preferably 1～2h.
In step 4), the time of said heating is preferably 10～15h.
The gained multi-mineral organotrophic fertilizer is added water, promptly get fertilizer for spraying on leaf surface or make surface irrigation fertilizer; The said amount that adds water is 800～1500 times of multi-mineral organotrophic fertilizer by mass ratio.
Because multi-mineral organotrophic fertilizer according to the invention adopts mineral substance, animal protein, plant protein and other batching; Through rational preparation technology; The trace and the ultramicro-element that make the multi-mineral organotrophic fertilizer of acquisition have kind surplus in the of 40 are the very important elements that improves agricultural product quality; And have well water-soluble, easy by farm crop absorption fully and in time.
For example when said multi-mineral organotrophic fertilizer was used for tea tree, a large amount of trace that are rich in the nutrition fertilizer and ultramicro-element can combine with tea tree enzyme and hormone etc., can improve the vigor of homergy and physiology vital movement; Promote that root growth is vigorous, germination and bud are many ahead of time, improve chlorophyllous content and strengthen photosynthetic capacity; It is about 20% that leaf area is not only increased, and that dark green leaf thickens is about 8%～10%, and tender; It is about 25% that the available number of sheets is increased, and tealeaves increases production more than 25%.Prior quality and the commercial grade that improves tealeaves.
When said multi-mineral organotrophic fertilizer is used for fruit tree, be rich in the nutrition fertilizer 40 surplus plant trace and ultramicro-element can with the vigor that combines raising homergy and physiology vital movement of fruit tree enzyme and hormone etc., the promotion root growth is vigorous; Germination and bud are many ahead of time, improve fruit bearing rate, anti-shedding; Improve chlorophyllous content and strengthen photosynthetic capacity; It is about 8%～12% that leaf area is increased, and that dark green leaf thickens is about 5%～10%, and tender; It is about 20% that the fruit bearing rate of fruit tree is improved, and have fruit retention, anti-shedding, pound advantage such as fruit.Simultaneously, improve the commercial grade of sugar degree, quality and the fruit of fruit.
In addition, said multi-mineral organotrophic fertilizer can make the fertility of the soil state that keeps relative stability, and kind trace and ultramicro-element surplus the soil microorganisms 40 can be provided after using, and promotes the breeding of soil microorganisms population, keeps the soil ecology balance.Thereby preservation of fertility does not wane, and improves the immunizing power of crop, cold-resistant, drought resisting disease and insect resistance etc.
When said multi-mineral organotrophic fertilizer is used for greengrocery, a large amount of trace that are rich in the nutrition fertilizer and ultramicro-element can with the vigor that combines to improve homergy and physiology vital movement of vegetables enzyme and hormone etc., the promotion root growth is vigorous; Improve chlorophyllous content and strengthen photosynthetic capacity, it is about 20% that leaf area is increased, and dark green leaf thickens about 10%～20%; And it is tender; Improve sugar degree and the quality of vegetables, tasty mouthfeel and tender can improve the commercial grade of vegetables.
For the fertility that the makes soil state that keeps relative stability, use ultra polynary high-quality quick-acting green nourishing fertilizer the soil microorganisms sufficient nutrient can be provided, promote the breeding of soil microorganisms population, keep the soil ecology balance.Thereby preservation of fertility does not wane.Just make thus fruit tree improve immunizing power, cold-resistant, drought resisting disease and insect resistance especially tool kill nematode in the soil etc.
Embodiment
Following examples are described further the present invention.
Embodiment 1
Selecting mineral substance biotitite, perlite, vermiculite, medical stone, is vermiculite 100 by the content of mass ratio, biotitite 30; Perlite 20, medical stone 25 is that 10% NaOH diluted alkaline cleans with mass percent concentration; The organic impurity after washing of removing mineral substance removes surplus alkali, is 1～2.5mm with raw material pulverizing to diameter, with 900 ℃ of calcining 1.5h; Raw material pulverizing after the calcining to diameter≤0.1mm, is screened to 50～200 orders; Mineral powders moves in the chemical-reacting furnace, adds water logging not to mineral surfaces, adds batching organic acid, mineral acid and EDTA Disodium again; Press mass ratio, mineral substance: batching is 100: 7.5, in batching; By mass percentage; Organic acid 20%, EDTA Disodium 10%, mineral acid 70%.Organic acid is selected from oxalic acid and Hydrocerol A; In the mineral acid that adds, per-cent by volume, phosphoric acid is 5%, and nitric acid is 5%, and sulfuric acid is 90%, and constantly stirs it.Make pH=1～1.2.Be heated to 110 ℃, heat-up time, 12h naturally cooled to 35 ℃; Get into its clear liquid of melt cinder separation and get the natural mineral matter liquid concentrator; Add aminoacids complex, press mass ratio, mineral substance: aminoacids complex is 100: 0.3; Said aminoacids complex is made up of minimum 3 seed amino acids, converts 800 times in water and promptly gets the polynary green organic Eco Battalion of leaf vegetables and fat up.
Embodiment 2
Being to select mineral substance biotitite, perlite, vermiculite, medical stone with embodiment 1 similar its difference, is vermiculite 100 by the content of mass ratio, biotitite 35; Perlite 30, medical stone 15 is that 8% NaOH diluted alkaline cleans with mass percent concentration; The organic impurity after washing of removing mineral substance removes surplus alkali, is 1～2.5mm with raw material pulverizing to diameter, with 1000 ℃ of calcining 1.2h; Raw material pulverizing after the calcining to diameter≤0.1mm, is screened to 50～200 orders; Mineral powders moves in the chemical-reacting furnace, adds water logging not to mineral surfaces, adds batching organic acid, mineral acid, EDTA Disodium and hydrolyzing plant hydrolysis end product polypeptide again or/and hydrolysis of animal hydrolysis end product polypeptide; Press mass ratio, mineral substance: batching is 100: 6, in batching; By mass percentage; Organic acid 18%, EDTA Disodium 5%, mineral acid 77%.Organic acid is selected from oxalic acid, Hydrocerol A and oxysuccinic acid; In the mineral acid that adds, per-cent by volume, phosphoric acid is 5%, and nitric acid is 5%, and sulfuric acid is 90%, and constantly stirs it.Make pH=1～1.2.Be heated to 100 ℃, heat-up time, 15h naturally cooled to 40 ℃; Get into its clear liquid of melt cinder separation and get the natural mineral matter liquid concentrator; Add aminoacids complex, press mass ratio, mineral substance: aminoacids complex is 100: 0.5; Said aminoacids complex is made up of minimum 3 seed amino acids, converts 1000 times in water and promptly gets paddy rice and fat up with polynary green organic Eco Battalion.
The preparation method of said hydrolyzing plant hydrolysis end product polypeptide is with the plant protein raw material pulverizing, and adding its pH value of cellulase control is 8, and temperature is 40 ℃ of hydrolysis cell wallss, promptly gets hydrolyzing plant hydrolysis end product polypeptide; Said cellulase can be chosen white ant cellulase; Said plant can be selected from beans and marine alga.
The preparation method of said hydrolysis of animal hydrolysis end product polypeptide pulverizes the aggregate in the animal proteinum raw material; The even matter of muscle and animal waste becomes rotten; Add protease hydrolysis, promptly get hydrolysis of animal hydrolysis end product polypeptide, said proteolytic enzyme can be chosen trypsinase or stomach en-; Optional at least a in animal bone, animal meat of said animal proteinum raw material.
Embodiment 3
Being to select mineral substance biotitite, perlite, vermiculite, medical stone with embodiment 1 similar its difference, is vermiculite 100 by the content of mass ratio, biotitite 40; Perlite 40, medical stone 30 is that 12% NaOH diluted alkaline cleans with mass percent concentration; The organic impurity after washing of removing mineral substance removes surplus alkali, is 1～2.5mm with raw material pulverizing to diameter, with 800 ℃ of calcining 2h; Raw material pulverizing after the calcining to diameter≤0.1mm, is screened to 50～200 orders; Mineral powders moves in the chemical-reacting furnace, adds water logging not to mineral surfaces, adds batching organic acid, mineral acid, EDTA Disodium and hydrolyzing plant hydrolysis end product polypeptide again or/and hydrolysis of animal hydrolysis end product polypeptide; Press mass ratio, mineral substance: batching is 100: 7, in batching; By mass percentage; Organic acid 15%, EDTA Disodium 8%, mineral acid 77%.Organic acid is selected from oxalic acid; In the mineral acid that adds, per-cent by volume, phosphoric acid is 5%, and nitric acid is 5%, and sulfuric acid is 90%, and constantly stirs it.Make pH=1～1.2.Be heated to 120 ℃, heat-up time, 10h naturally cooled to 40 ℃; Get into its clear liquid of melt cinder separation and get the natural mineral matter liquid concentrator; Add aminoacids complex, press mass ratio, mineral substance: aminoacids complex is 100: 0.4; Said aminoacids complex is made up of minimum 3 seed amino acids, converts 1200 times in water and promptly gets paddy rice and fat up with polynary green organic Eco Battalion.
The preparation method of said hydrolyzing plant hydrolysis end product polypeptide is with the plant protein raw material pulverizing, and adding its pH value of cellulase control is 8.5, and temperature is 30 ℃ of hydrolysis cell wallss, promptly gets hydrolyzing plant hydrolysis end product polypeptide; Said cellulase can be chosen white ant cellulase; Said plant is selected from beans, marine alga and tenaculat Habenaria.
The preparation method of said hydrolysis of animal hydrolysis end product polypeptide pulverizes the aggregate in the animal proteinum raw material; The even matter of muscle and animal waste becomes rotten; Add protease hydrolysis, promptly get hydrolysis of animal hydrolysis end product polypeptide, said proteolytic enzyme can be chosen papoid or bromeline; Optional at least a in animal bone, animal meat of said animal proteinum raw material.
Embodiment 4
Being to select mineral substance biotitite, perlite, vermiculite, medical stone with embodiment 1 similar its difference, is vermiculite 100 by the content of mass ratio, biotitite 45; Perlite 15, medical stone 40 is that 13% NaOH diluted alkaline cleans with mass percent concentration; The organic impurity after washing of removing mineral substance removes surplus alkali, is 1～2.5mm with raw material pulverizing to diameter, with 1100 ℃ of calcining 1.2h; Raw material pulverizing after the calcining to diameter≤0.1mm, is screened to 50～200 orders; Mineral powders moves in the chemical-reacting furnace, adds water logging not to mineral surfaces, adds batching organic acid, mineral acid, EDTA Disodium and hydrolysis of animal hydrolysis end product polypeptide again; Press mass ratio, mineral substance: batching is 100: 6.5, in batching; By mass percentage; Organic acid 22%, EDTA Disodium 12%, mineral acid 66%.Organic acid is selected from Hydrocerol A and oxysuccinic acid; In the mineral acid that adds, per-cent by volume, phosphoric acid is 8%, and nitric acid is 5%, and sulfuric acid is 87%, and constantly stirs it.Make pH=1～1.2.Be heated to 100 ℃, heat-up time, 15h naturally cooled to 30 ℃; Get into its clear liquid of melt cinder separation and get the natural mineral matter liquid concentrator; Add aminoacids complex, press mass ratio, mineral substance: aminoacids complex is 100: 0.35; Said aminoacids complex is made up of minimum 3 seed amino acids, converts 1500 times in water and promptly gets paddy rice and fat up with polynary green organic Eco Battalion.
The preparation method of said hydrolysis of animal hydrolysis end product polypeptide pulverizes the aggregate in the animal proteinum raw material; The even matter of muscle and animal waste becomes rotten; Add protease hydrolysis, promptly get hydrolysis of animal hydrolysis end product polypeptide, said proteolytic enzyme can be chosen papoid or bromeline; Optional at least a in animal bone, animal meat of said animal proteinum raw material.
Embodiment 5
Being to select mineral substance biotitite, perlite, vermiculite, medical stone with embodiment 1 similar its difference, is vermiculite 100 by the content of mass ratio, biotitite 60; Perlite 25, medical stone 35 is 15% with mass percent concentration; The organic impurity after washing of removing mineral substance removes surplus alkali, is 1～2.5mm with raw material pulverizing to diameter, with 1200 ℃ of calcining 1h; Raw material pulverizing after the calcining to diameter≤0.1mm, is screened to 50～200 orders; Mineral powders moves in the chemical-reacting furnace, adds water logging not to mineral surfaces, adds batching organic acid, mineral acid, EDTA Disodium and hydrolyzing plant hydrolysis end product polypeptide again; Press mass ratio, mineral substance: batching is 100: 8, in batching; By mass percentage; Organic acid 25%, EDTA Disodium 15%, mineral acid 60%.Organic acid is selected from Hydrocerol A and oxysuccinic acid; In the mineral acid that adds, by volume the per-cent phosphatase 11 0%, nitric acid 3%, and sulfuric acid 87%, and constantly stir it.Make pH=1～1.2.Be heated to 115 ℃, heat-up time, 13h naturally cooled to 38 ℃; Get into its clear liquid of melt cinder separation and get the natural mineral matter liquid concentrator; Add aminoacids complex, press mass ratio, mineral substance: aminoacids complex is 100: 0.2; Said aminoacids complex is made up of minimum 3 seed amino acids, converts 1000 times in water and promptly gets paddy rice and fat up with polynary green organic Eco Battalion.
The preparation method of said hydrolyzing plant hydrolysis end product polypeptide is with the plant protein raw material pulverizing, and adding its pH value of cellulase control is 9, and temperature is 50 ℃ of hydrolysis cell wallss, promptly gets hydrolyzing plant hydrolysis end product polypeptide; The optional ant cellulase of taking from of said cellulase; Said plant is selected from beans and tenaculat Habenaria.
Claims (6)
1. multi-mineral organotrophic fertilizer is characterized in that its raw material composition comprises mineral substance, aminoacids complex, batching and water, presses mass ratio, mineral substance: aminoacids complex: batching: water=100: (0.5～0.2): (20～30): (6～8);
Said mineral substance comprises vermiculite, biotitite, perlite and medical stone, is vermiculite 100 by the content of mass ratio, biotitite 30～60, perlite 15～40, medical stone 15～40;
Said batching is organic acid, mineral acid and EDTA Disodium, by mass percentage, organic acid 15%～25%, EDTA Disodium 5%～15%, surplus is mineral acid; Said organic acid is selected from least a in oxalic acid, Hydrocerol A, the oxysuccinic acid; Said mineral acid is sulfuric acid, phosphoric acid and nitric acid, by mass percentage, phosphoric acid 5%～10%, nitric acid 3%～5%, surplus is sulfuric acid; Or
Said batching is that organic acid, mineral acid, EDTA Disodium, hydrolyzing plant hydrolysis end product polypeptide are or/and hydrolysis of animal hydrolysis end product polypeptide; By mass percentage; Organic acid 15%～25%; EDTA Disodium 5%～15%, hydrolyzing plant hydrolysis end product polypeptide are or/and hydrolysis of animal hydrolysis end product polypeptide 15%～25%, and surplus is mineral acid; Said organic acid is selected from least a in oxalic acid, Hydrocerol A, the oxysuccinic acid; Said mineral acid is sulfuric acid, phosphoric acid and nitric acid, by mass percentage, phosphoric acid 5%～10%, nitric acid 3%～5%, surplus is sulfuric acid.
2. multi-mineral organotrophic fertilizer as claimed in claim 1 is characterized in that said aminoacids complex is made up of at least 3 seed amino acids.
3. multi-mineral organotrophic fertilizer as claimed in claim 1; The preparation method who it is characterized in that said hydrolyzing plant hydrolysis end product polypeptide is with the plant protein raw material pulverizing; Adding its pH value of cellulase control is 8～9; Temperature is 30～50 ℃ of hydrolysis cell wallss, promptly gets hydrolyzing plant hydrolysis end product polypeptide; Said cellulase is chosen white ant cellulase; Said plant is selected from least a in beans, marine alga, the tenaculat Habenaria.
4. multi-mineral organotrophic fertilizer as claimed in claim 1; The preparation method who it is characterized in that said hydrolysis of animal hydrolysis end product polypeptide pulverizes the aggregate in the animal proteinum raw material, and the even matter of muscle and animal waste becomes rotten, adds protease hydrolysis; Promptly get hydrolysis of animal hydrolysis end product polypeptide; Said proteolytic enzyme is chosen trypsinase, stomach en-, papoid or bromeline; Said animal proteinum raw material is selected from least a in animal bone, the animal meat.
5. the preparation method of multi-mineral organotrophic fertilizer as claimed in claim 1 is characterized in that may further comprise the steps:
1) with mineral substance biotitite, perlite, vermiculite and medical stone, clean with NaOH, the organic impurity after washing of removing mineral substance removes surplus alkali, with raw material pulverizing, calcining;
2) raw material pulverizing after will calcining is screened to 50～200 orders to diameter≤0.1mm, mineral powders;
3) with step 2) mineral powders of gained moves in the chemical-reacting furnace, adds water logging to mineral surfaces with not ing, adds batching again, and stirring makes pH=1～1.2;
4) step 3) gained material is heated to 100～120 ℃, is cooled to 30～40 ℃ again, melt cinder separates, and gets clear liquid, adds aminoacids complex again, promptly gets multi-mineral organotrophic fertilizer.
6. the preparation method of multi-mineral organotrophic fertilizer as claimed in claim 5 is characterized in that in step 1), and the mass percent concentration of said NaOH is 8%～15%; With raw material pulverizing to diameter is 1～2.5mm, and said incinerating temperature is 800～1200 ℃, and the incinerating time is 1～2h.
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