CN103553832A - Method for preparing multi-element zeolite organic fertilizer from active natural zeolite - Google Patents
Method for preparing multi-element zeolite organic fertilizer from active natural zeolite Download PDFInfo
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- CN103553832A CN103553832A CN201310586741.8A CN201310586741A CN103553832A CN 103553832 A CN103553832 A CN 103553832A CN 201310586741 A CN201310586741 A CN 201310586741A CN 103553832 A CN103553832 A CN 103553832A
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Abstract
The invention discloses a method for preparing a multi-element zeolite organic fertilizer from active natural zeolite. The method comprises the following steps: activating a zeolite raw material, and preparing active zeolite; adding animal bones and Chinese medicine residues to prepare a fermentation substrate; preparing a fermentation agent from waste residues for preparing traditional Chinese medicines and animal and vegetal oil, adding mineral substances, and finally, mixing and fermenting the fermentation substrate and the fermentation agent to prepare the multi-element sodium potassium zeolite organic fertilizer. The multi-element zeolite organic fertilizer prepared by the method can serve as a fertilizer for direct application, can be prepared into a high-quality biological organic fertilizer and an organic-inorganic compound fertilizer needed by various crops with other nutrients and organic matters, has the advantages of changing wastes into valuable materials, comprehensively utilizing the materials, greening the nature environment and purifying the environment, and a virtuous circle of ecological organic agriculture is promoted. The multi-element zeolite organic fertilizer contributes to improving the soil, increasing the fertility of soil and improving the quality of crops. The method is simple in equipment, time/labor-saving, simple, practicable and suitable for rural popularization and application.
Description
Technical field
The present invention relates to fertilizer, relate in particular to organic fertilizer, in particular to produce the method for organic fertilizer by fermentation.
Background technology
As everyone knows, natural zeolite (
natural zeolite) be the very wide silicates mineral of a class distribution, molecular formula is MxOy[Alx+2ySin-(x+2y) O
2n] mH
2o.Its main kind has scolecite, heulandite, euthalite, chabazite, mordenite, oblique zeolite, erionite, ferrierite, lomontite, natrolite etc., and its goods agriculturally have all multi-usages.In recent years, the technology of more existing patent applications is for the production of zeolites fertilizer, No. 200410040915.1 < < preparation method of zeolite organism organic mixed fertilizer > > for example, 200610106523.X number < < zeolite organic-inorganic composite fertilizer > >, application and production method > > after the activated processing of No. 201010143600.5 < < zeolites in fertilizer and No. 201110369290.3 fertile technology of preparing > of < < nitric acid zeolite > etc.These zeolites fertilizer have fertilizer synergistic, improvement soil, stimulate plant growth, improve the functions such as agricultural product quality.
Natural zeolite contains abundant nitrogen, phosphorus, potassium organic matter and ore deposit trace element and ultramicro-element and organic active substance, by discharging, transform, exchanging, substitute activity enzyme directly provides comprehensively directly farm crop, Plants and Soils and nutrient indirectly, can improve water conservation, fertilizer-preserving ability; Can help the seedlings of cereal crops absorb, transmit, store the organism in soil and help the seedlings of cereal crops to absorb airborne natural nitrogenous fertilizer, to soil, decompose more mineral matter nutritional composition.Both be conducive to optimumization of soil circulating system, and can have met the nutritional need in crop plants process of growth again, truly had the effect that increases crop yield and improve product quality.Also there is soil anti-virus, degeneration-resistant, waterlogging-resistant, cold-resistant, hot-dry wind tolerance, resistant to lodging, anti-early ageing, control plant pest, regulate continuous cropping continuous cropping, keep land fertility, increase the unique effects of agriculture-countryside-farmer's economic return.
Summary of the invention
The present invention aims to provide a kind of method of producing multielement zeolite fertilizer with natural radioactivity zeolite, to realize, makes full use of the natural resources, and is ecological Organic Farming service.
The Method And Principle that contriver provides is first zeolite raw material to be passed through to activation treatment, makes activated zeolite, then is mixed with fermented substrate; Simultaneously with the castaway slag of Chinese medicine processed and various animals and plants oil foot preparation starter, interpolation mineral substance, finally by fermented substrate and starter mixed fermentation, makes the multielement sodium potassium fertilizer that boils.
The concrete technology of the inventive method is as follows:
(1) prepare activated zeolite
Get zeolite raw material, add mineral acid to make its reaction, after stirring, filter; Then in the material after filtering, add alkali lye to regulate pH value, obtain activated zeolite, standby;
(2) prepare fermented substrate
Get activated zeolite obtained in the previous step and add the assorted bone of animal and Chinese medicine slag, mix, pulverize, stir, sieve, make fermented substrate;
(3) prepare starter
Get vegeto-animal oil foot and add animals and plants waste, Chinese medicine slag, with any quality proportioning, mix, be mixed with starter;
(4) add mineral substance
In the starter making in previous step, add industrial residue as mineral origin, according to starter and mineral substance quality (70-90): proportioning (30-10) is mixed, pulverize, add water and stir;
(5) multielement zeolite fertilizer is produced in fermentation
Get respectively the mixture of fermented substrate, starter and mineral substance, according to fermented substrate and described mixture with (50-80): quality proportioning (10-40) is mixed, pulverizes, is added water and stirs evenly, stacks fermentation, through being cooled to normal temperature, be prepared into multielement zeolite fertilizer again.
In (1) step of aforesaid method, described zeolite is natural natrolite, scolecite, heulandite, euthalite, chabazite, mordenite, oblique a kind of in zeolite, erionite, ferrierite, lomontite; Described mineral acid is one or more in sulfuric acid, nitric acid, hydrochloric acid, silicofluoric acid, phosphoric acid: described alkali lye is one or more of soda ash solution, lime aqueous solution, caustic soda soln; After described adjusting, the pH value of material is 3.5~4.5.
In (2) step of aforesaid method, described animal bone is the bone of domestic animal, poultry or wildlife; The mix quality proportioning of bone, Chinese medicine slag of described activated zeolite and animal is (150~200): (90~98): (10~2); After described pulverizing, the material fineness of sieving is 80~200 orders.
In (3) step of aforesaid method, described vegeto-animal oil foot is animal oil foot and vegetable oil residue, and wherein, animal oil foot comprises the pig oil foot of mixing, or butter oil foot, or sheep oil oil foot; Vegetable oil residue comprises Oil foot of Brassica campestris, soybean oil foot, tea-seed oil oil foot, peanut oil residuals, also comprises Clean products filter residue, soap stock; Described animals and plants waste comprises the internal organ of animal, and the rhizome of plant, fruit and branches and leaves, tobacco give up leaf, bancoul nuts shell, weeds.
In (4) step of aforesaid method, described industrial residue comprises potassium permanganate filter residue, kiln potassium ash, electrolytic manganese dioxide slag, yellow phosphorus furnace slag, ammonium molybdate slag, ferrous sulfate slag, zinc ore slag, sulfate slag, ferro-silicon slag, phosphorus ammonium pin slag, cement chimney soot, one or more of steel-making ash, ironmaking ash; Fineness of materials after described pulverizing is 80~200 orders; The described quality that adds water is 1 times of mineral substance quality.
In (5) step of aforesaid method, described fermenting process is to be warming up to 80 ℃ from normal temperature, continues heap 35~40 days, described in add water quality be 1~3 times of fermentation materials.
Contriver points out, the active natural zeolite that the present invention adopts contains metal ion and the silicon ions such as abundant zeolite potassium, sodium, magnesium, iron, aluminium, after fermentation activity natrolite matrix and the direct mixed-stacking of starter, metallics ionization, has possessed the natural condition that enzyme produces.In this process, grow and to be that cell pleurodiaphragmatic in terspace is shaft-like, ovum shape potassium bacterium.Owing to containing sufficient SiO in active natrolite
2, A1
20
3, Fe
2o
3, K
2o, MgO, MnO
2and various trace elements, under katalysis, mycetocyte energy free permeation and diffusion.In animal and vegetable oil filter pin slag in starter, Clean products filter residue, soap pin slag, contain respectively a large amount of phosphatide, albumen etc., therefrom self-assembling formation phosphatide stem cell.Under the interaction of fermentation natrolite matrix and starter, form ferment enzyme state, natrolite potassium bacterium is bred, along with piling up the increase of time and the carrying out of fermentation, the rising gradually of temperature of charge, this kind of bacterium bred rapidly.In the whole process of lowering the temperature again after 15 ℃~80 ℃ intensifications, fermentation zeolite potassium bacterium increases by geometric progression.It is more that zeolite potassium and zeolite sodium produce bacterium, fermentation zeolite potassium is higher with the ratio of fermentation zeolite sodium, make in zeolite potassium indissoluble potassium and zeolite sodium produce bacterium more, fermentation zeolite potassium decomposes, become the acid soluble potassium and sodium and the multiple soluble trace elements that are easily absorbed by plants, jointly complete fermenting process, thereby obtain multielement zeolite fertilizer.
The fermentation multielement zeolite fertilizer that the present invention produces, at 1-3 times of observed under electron microscope, can see fermentation natrolite bacterium and mostly be staff cell, and have a large amount of pili, mycelia to contain its surface, and its nucleus, cell passage are high-visible.
The multielement zeolite fertilizer that present method is produced, both can make fertilizer directly uses, also can be mixed with required high-quality biological organic fertilizer, the organic-inorganic compound mixed fertilizer of using of all kinds of farm crop with other nutrient and organic matter, have advantages of and turn waste into wealth, fully utilize, afforest the Nature, environment purification, be conducive to the benign cycle of sustainable agriculture.Multielement zeolite fertilizer is conducive to improve soil, increases fertility, improves crops quality.Present method equipment is simple, saves time, saving of labor, processing method be simple and feasible, is suitable for rural area and applies.
Embodiment
Embodiment:
Below in conjunction with in Meitan County, Guizhou, agrotechnical school, Zun Yi implements live explanation the present invention.
The K that contains with the Mei Xian of Guizhou Province
2the natural zeolite of O 4.01%~6% is raw material, adds dilute sulphuric acid to stir, and makes its reaction, after stirring, filters; Then in the material after filtering, add lime slurry, regulate pH to 4, obtain activated zeolite; Get the discarded slag of local herbal pharmaceutical producer and mix with it, then get the activated zeolite of 285kg and the ox bone of Chinese medicine slag mixture and 15kg, through mixing, being crushed to 80 orders, be prepared into the organic original washing powder of fermentation.
Rapeseed oil residue 70kg adds pig offal 30kg, mixes, and is mixed with starter; Getting fermentation organic matrix powder 300kg, saleratus 100kg adds 10kg to contain K
2kiln potassium ash and the 10kg water of O 0.2%~0.35%, mix, and pulverizing is 80~200 orders; Add water 800kg, stir; Stack fermentation, and be warming up to 68 ℃ from normal temperature, continue to stack 35, then lower the temperature 15, be cooled to normal temperature, be prepared into multielement zeolite fertilizer, analyze after testing, containing K
2o 4.01%~5%, organic matter 6.12%, P
2o
51.36%, protein 0.68%, and total nutrient is 46.81%.Allocate conventional mineral manure into, can be made into the organic and inorganic fertilizer variety of all size.
Claims (6)
1. with natural radioactivity zeolite, produce a method for multielement zeolite fertilizer, it is characterized in that first zeolite raw material being passed through to activation treatment, make activated zeolite, then add the assorted bone of animal and Chinese medicine slag to be mixed with fermented substrate; Simultaneously with the castaway slag of Chinese medicine processed and various animals and plants oil foot preparation starter, interpolation mineral substance, finally by fermented substrate and starter mixed fermentation, makes the multielement sodium potassium fertilizer that boils; Concrete technology is as follows:
(1) prepare activated zeolite
Get zeolite raw material, add mineral acid to make its reaction, after stirring, filter; Then in the material after filtering, add alkali lye to regulate pH value, obtain activated zeolite, standby;
(2) prepare fermented substrate
Get activated zeolite obtained in the previous step and add the assorted bone of animal and Chinese medicine slag, mix, pulverize, stir, sieve, make fermented substrate;
(3) prepare starter
Get vegeto-animal oil foot and add animals and plants waste, Chinese medicine slag, with any quality proportioning, mix, be mixed with starter;
(4) add mineral substance
In the starter making in previous step, add industrial residue as mineral origin, according to starter and mineral substance quality (70~90): the proportioning of (30~10) is mixed, pulverize, add water and stir;
(5) zeolite fertilizer is produced in fermentation
Get respectively the mixture of fermented substrate, starter and mineral substance, according to fermented substrate and mixture with (50~80): the quality proportioning of (10~40) is mixed, pulverizes, is added water and stirs evenly, stacks fermentation, through being cooled to normal temperature, be prepared into multielement zeolite fertilizer again.
2. the method for claim 1, is characterized in that in (1) step, and described zeolite is natural natrolite, scolecite, heulandite, euthalite, chabazite, mordenite, oblique a kind of in zeolite, erionite, ferrierite, lomontite; Described mineral acid is one or more in sulfuric acid, nitric acid, hydrochloric acid, silicofluoric acid, phosphoric acid: described alkali lye is one or more of soda ash solution, lime aqueous solution, caustic soda soln; After described adjusting, the pH value of material is 3.5~4.5.
3. the method for claim 1, is characterized in that in (2) step, and described animal bone is the bone of domestic animal, poultry or wildlife; The mix quality proportioning of bone, Chinese medicine slag of described activated zeolite and animal is (150~200): (90~98): (10~2); Material after the described pulverizing fineness of sieving is 80~200 orders.
4. the method for claim 1, is characterized in that in (3) step, and described vegeto-animal oil foot is animal oil foot and vegetable oil residue, and wherein, animal oil foot comprises the pig oil foot of mixing, or butter oil foot, or sheep oil oil foot; Vegetable oil residue comprises Oil foot of Brassica campestris, soybean oil foot, tea-seed oil oil foot, peanut oil residuals, and Clean products filter residue, soap stock; Described animals and plants waste comprises the internal organ of animal, and the rhizome of plant, fruit and branches and leaves, tobacco give up leaf, bancoul nuts shell, weeds.
5. the method for claim 1, it is characterized in that in (4) step, described industrial residue comprises potassium permanganate filter residue, kiln potassium ash, electrolytic manganese dioxide slag, yellow phosphorus furnace slag, ammonium molybdate slag, ferrous sulfate slag, zinc ore slag, sulfate slag, ferro-silicon slag, phosphorus ammonium pin slag, cement chimney soot, one or more of steel-making ash, ironmaking ash; Fineness of materials after described pulverizing is 80~200 orders; The described quality that adds water is 1 times of mineral substance quality.
6. the method for claim 1, is characterized in that in (5) step, and described fermenting process is to be warming up to 80 ℃ from normal temperature, continues heap 35~40 days; The described quality that adds water is 1~3 times of fermentation materials.
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Cited By (5)
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CN105272442A (en) * | 2015-09-23 | 2016-01-27 | 广西壮锦家园农业科技发展有限公司 | Chinese herbal medicine bio-fertilizer and production method |
CN106118668A (en) * | 2014-10-31 | 2016-11-16 | 马振宇 | A kind of production method of microorganism porous mineral soil remediation modifying agent |
CN106478230A (en) * | 2016-09-27 | 2017-03-08 | 孟献堡 | A kind of heulandite compoiste fertilizer and preparation method thereof |
RU2645120C2 (en) * | 2016-06-21 | 2018-02-15 | Общество с ограниченной ответственностью "РостАгроИмпэкс" | Method of obtaining the corrector of the deficiences of micro elements for plant nutrition "malham" |
CN111084417A (en) * | 2019-12-16 | 2020-05-01 | 云南中烟新材料科技有限公司 | Preparation method and application of cigarette filter stick aroma-enhancing ball |
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CN106478230A (en) * | 2016-09-27 | 2017-03-08 | 孟献堡 | A kind of heulandite compoiste fertilizer and preparation method thereof |
CN111084417A (en) * | 2019-12-16 | 2020-05-01 | 云南中烟新材料科技有限公司 | Preparation method and application of cigarette filter stick aroma-enhancing ball |
CN111084417B (en) * | 2019-12-16 | 2022-05-17 | 云南中烟新材料科技有限公司 | Preparation method and application of cigarette filter stick aroma-enhancing ball |
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Application publication date: 20140205 |