CN102557808A - Method for preparing organic-inorganic potassium-calcium-silicon compound fertilizer - Google Patents
Method for preparing organic-inorganic potassium-calcium-silicon compound fertilizer Download PDFInfo
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- CN102557808A CN102557808A CN2012100623732A CN201210062373A CN102557808A CN 102557808 A CN102557808 A CN 102557808A CN 2012100623732 A CN2012100623732 A CN 2012100623732A CN 201210062373 A CN201210062373 A CN 201210062373A CN 102557808 A CN102557808 A CN 102557808A
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Abstract
The invention discloses a method for preparing an organic-inorganic potassium-calcium-silicon compound fertilizer. The organic-inorganic compound fertilizer is prepared by mixing and blending the following raw material components in part by weight: 1 to 90 parts of potassium-calcium-sulfur compound fertilizer produced by roasting mixed desulfurization ash and potassium ores and 1 to 90 parts of a biological organic fertilizer. The double benefits, i.e. recycle of industrial solid wastes and production of a novel potassium fertilizer, are achieved; the whole production process accords with an environment-friendly idea, and solid and liquid wastes are not discharged; and the fertilizer can increase the yield of crops, improve product quality and regulate the acidity and alkalinity of soil through field experiments of the crops such as rice, sugarcane, cassava, sweet corn and the like.
Description
Technical field
The present invention relates to a kind of compound manure, particularly relate to the fertile preparation method of a kind of organic-inorganic potassium calcium silicon compound.
Background technology
The microbial organic fertilizer microorganism organic fertilizer that to be organic solid waste (comprising the solid waste that organic waste, stalk, feces of livestock and poultry, grouts, agricultural fishery sub product and food-processing produce) form through microbial fermentation, deodorizing and the post-treatment that becomes thoroughly decomposed fully.The characteristics of microbial organic fertilizer are that the ecological organic fertilier nutritive element is complete, can improve the soil, and improve the soil compaction that uses chemical fertilizer to cause.Improve soil physical and chemical property, strengthen soil water-retaining, protect fertile, as to supply fertilizer ability.Useful microbe in the microbial organic fertilizer get into behind the soil with soil in mikrobe form mutual symbiosis propagation relation, suppress harmful bacteria growing and also be converted into probiotics, interact; Mutually promote; Play the synergy of colony, probiotics produces a large amount of meta-bolitess in the growth and breeding process, impel organic decomposition and inversion; Can promote and the regulation and control plant growth directly or indirectly for crop provides multiple nutrients and pungent.Improve soil porosity, penetrating exchangeability and plant survival rate, increase probiotics and soil microorganisms and population.Simultaneously, the advantage probiotics group energy that forms at crop root suppresses harmful pathogenic bacteria procreation, and the degeneration-resistant resistance against diseases of enhancing crop reduces the disease index of continuous cropping crop, uses year after year and can alleviate continuous cropping obstacle greatly.Reducing environmental pollution, to people, animal, environmental safety, nontoxic, is a kind of environment-friendly type fertilizer.
The product that utilizes the method for potassium calcium silicon composite fertilizer of phosphogypsum, carbide slag, soda ash clay-slag industrial solid castoff and the compound baked for producing of potassium ore of desulfurized gesso of flue gas and chemical industry to produce; Its limitation is also arranged; This type of fertilizer is that a quasi-mineral solubility in citric acid is fertile, and solubility in citric acid fertilizer is for water-soluble (quick-acting), is slow property material; Contained fertilizer component is difficult for all can being absorbed by crop by water-soluble mistake.Solubility in citric acid fertilizer generally is to be insoluble in water, but dissolves in poly-basic organic acid.This quasi-mineral fertilizer through experiment proof with water-soluble only can stripping wherein 1/5, most of active principle be need be under polynary acidic conditions the ability dissolved.This quasi-mineral fertilizer such as independent use are not suitable for being used as topdresses, and just as base manure.Main nutrient composition chemical examination through to this quasi-mineral fertilizer product shows that its major ingredient is trace elements such as vitriolate of tartar, solubility in citric acid quicklime, solubility in citric acid silicon-dioxide, solubility in citric acid Natural manganese dioxide, iron, zinc, boron and molybdenum, solubility in citric acid mineral substance major ingredient.Soil generally all contains organic matter, and it is present in animal, plant, the residual body of mikrobe and the soil ulmin.Constantly by biosynthesizing and decomposition, oxidation and reduction constitute the circulation of a conversion to mineral substance in soil, but because use a large amount of chemical fertilizer in recent years, agricultural chemicals makes organic matter and microbial environment in the soil receive badly damaged.
Its importance of microbial organic fertilizer extensively is familiar with by people; And so much probiotics and fertilizer production technology thereof have been developed both at home and abroad; But why the microbial fertilizer application quantity only accounts for the very little part of fertilizer amount in China; Can't form main flow and promote weak? Discover that the composition nutrient content of the domestic overwhelming majority's microbial organic fertilizer is not enough, most nutrient aequum that all is not enough to satisfy plant-growth; This fertilizer kind can not be taken on alone in agriculture prodn as main fertile the use, increases amount of application only if disregard cost.Generally speaking, they can only play the effect of making something perfect even more perfect as the supporting role of main fertile (chemical fertilizer).But also stress to avoid using simultaneously (this had both increased the fertilising cost, had also changed common fertilising custom) in the use with chemical fertilizer.
So; Why can not microorganism fertilizer use with chemical fertilizer simultaneously? Perhaps simply in the fertiliser prodn process, just in advance microorganism fertilizer and chemical fertilizer are mixed to come together and use? Reason is; Bacterial classification in most in the market microorganism fertilizers is with in chemical fertilizer compound, can't resist killing of " high osmotic pressure " that chemical fertilizer produces.Therefore, people are with compound being referred to as " dead compound " of microbial organic fertilizer and chemical fertilizer.Like this; No matter how excellent bacterial classification is in the function aspects of fixed nitrogen, phosphorus decomposing, potassium decomposing; No matter how outstanding bacterial classification is in function aspects such as improvement soil properties, if can't solve killing of anti-high osmotic pressure, also just can't solve with the chemical fertilizer one in the problem that coexists; Just can't come into the market as main flow fertilizer, the peasant also can not use it on a large scale.
Summary of the invention
In order to improve mikrobe organic matter and the nutrient element that increases in the soil in the soil; The object of the present invention is to provide a kind of preparation method of organic-inorganic potassium calcium silicon composite fertilizer; Bacterial classification in solving microorganism fertilizer with eutrophic and various trace elements fertilizer compound in; Eliminate compound " high osmotic pressure " produced to the killing of mikrobe mattress kind, be combined into new composite fertilizer.
The object of the invention and solve its technical problem and adopt following technical scheme to realize.According to the fertile preparation method of a kind of organic-inorganic potassium calcium silicon compound that the present invention proposes, it comprises each feed composition of following weight part:
1～50 part of potassium ore;
1～45 part of desulfurization ash;
0～32 part in Wingdale;
1～5 part of sodium salt compound;
1～90 part of biological organic fertilizer;
Above-mentioned potassium ore, desulfurization ash, Wingdale and sodium salt compound are admixed in above-mentioned weight part ratio; Through grinding, and is under 1000～1050 ℃ of conditions in temperature with material, roasting time 2～3 hours; Again through cooling, ball mill pulverizing; After obtaining potassium calcium silicon composite fertilizer, carry out blending in proportion with biological organic fertilizer again, process compound organic and inorganic fertilizer.
The preparation method that above-mentioned organic-inorganic potassium calcium silicon compound is fertile, said improved grinding to 200～250 orders.
The preparation method that above-mentioned organic-inorganic potassium calcium silicon compound is fertile, said sodium salt compound is sodium sulfate, Sodium Fluoride or sodium-chlor; The preferred proportion scope is at the 1-4 weight part.
By technique scheme, the present invention has following advantage and beneficial effect:
(1) the present invention utilizes the method institute operating mine material fertilizer product of potassium calcium silicon composite fertilizer of industrial solid castoff such as phosphogypsum, carbide slag and the compound baked for producing of potassium ore of desulfurized gesso of flue gas and chemical industry; With the microorganism organic fertilizer that forms through microbial fermentation, deodorizing and the post-treatment that becomes thoroughly decomposed fully with organic solid waste (comprising the solid waste that organic waste, stalk, feces of livestock and poultry, grouts, agricultural fishery sub product and food-processing produce); The two mixes use; The strong point of the two is well brought into play, but their weakness also is able to improve simultaneously simultaneously.
(2) microbial organic fertilizer " high osmotic pressure " killing microorganism strains do not occur in the fertile back of mixing of quasi-mineral therewith; Very friendly after the mixing; Because mineral substance fertilizer is the dry powder class; Therefore with the large quantity of moisture of having drawn microbial organic fertilizer after microbial organic fertilizer mixes, also avoided microbial organic fertilizer simultaneously because the bad phenomenon such as drying cost that the moisture height Secondary Fermentation occurs or increases for the moisture of reduction microbial organic fertilizer.
(3) the present invention has the double benefit of industrial solid castoff recycling and novel potash fertilizer.Whole process of production meets environmental protection concept, does not have the discharging of solid and liquid debris; Through the field experiment to farm crop such as paddy rice, sugarcane, cassava and sweet corns, this fertilizer can increase crop yield, improves product quality, regulate soil acidity or alkalinity.
(4) mikrobe organic potassium calcium silicon composite fertilizer of the present invention still is a kind of good soil improvement agent, the ability chessom, and soil itself is also formed by the stone weathering, stone soil homology, avidity is good; Use manyly more, the soil is loose more ventilative, helps the crop root growth.
Embodiment
A kind of organic-inorganic potassium calcium silicon compound fertilizer that the present invention proposes is to mix to admix by corresponding proportion with biological organic fertilizer 1～90 weight part and process through compound baked for producing such as desulfurization ash and potassium ore being gone out potassium calcium sulphur composite fertilizer 1-90 weight part.
Microbial organic fertilizer quasi-mineral therewith mixes and to execute kind, soil is repaired under the organic effect of mikrobe fully and has been increased the little living organic content in the soil, and good ecotope has been created in the conversion of quasi-mineral for this reason.Microbial organic fertilizer makes it contain more microbial metabolism generation polyprotonic acid during the fertile mixing of quasi-mineral is manured into soil therewith; Promote the dissolving of mineral substance such as vitriolate of tartar, solubility in citric acid quicklime, solubility in citric acid silicon-dioxide, solubility in citric acid Natural manganese dioxide, iron, zinc, boron and molybdenum; Microorganisms poly-basic organic acids (like Hydrocerol A) such as the various Pseudomonas that generate in the soil, can carry out integration, increase the solubleness of solubility in citric acid inorganic mineral with quicklime, silicon-dioxide, Natural manganese dioxide, iron ion etc.The organic mass-energy of mikrobe plays reductive action to the chemical fertilizer material of once using remaining in the soil under anoxic and acidic conditions.
Below through concrete preferred embodiment the present invention is done further explain, but the present invention is not limited in following embodiment.Wherein, the part in the formulation content is a weight part, and its unit can be g, kg or t.
Embodiment 1
16.5 parts of potassium ores
15 parts of desulfurization ashs
10.5 parts in Wingdale
1.35 parts in sodium sulfate
70 parts of biological organic fertilizers;
According to the above ratio potassium ore, desulfurization ash, Wingdale, sodium sulfate are ground to form 200 order powder respectively, mix the back and be sintered into inorganic mineral fertilizer in temperature more than 1000 ℃; Afterwards, in this inorganic mineral fertilizer, add biological organic fertilizer in proportion and mix blending, it is fertile to process organic-inorganic potassium calcium silicon compound
Embodiment 2
22 parts of potassium ores;
20 parts of desulfurization ashs;
14 parts in Wingdale;
1.8 parts of Sodium Fluorides;
60 parts of biological organic fertilizers;
According to the above ratio potassium ore, desulfurization ash, Wingdale, sodium sulfate are ground to form 200 order powder respectively, mix the back and be sintered into inorganic mineral fertilizer in temperature more than 1000 ℃; Afterwards, in this inorganic mineral fertilizer, add biological organic fertilizer in proportion and mix blending, it is fertile to process organic-inorganic potassium calcium silicon compound.
Embodiment 3
27.5 parts of potassium ores;
25 parts of desulfurization ashs;
17.5 parts in Wingdale;
2.25 parts in sodium-chlor;
50 parts of biological organic fertilizers;
According to the above ratio potassium ore, desulfurization ash, Wingdale, sodium sulfate are ground to form 220 order powder respectively, mix the back and be sintered into inorganic mineral fertilizer in temperature more than 1000 ℃; Afterwards, in this inorganic mineral fertilizer, add biological organic fertilizer in proportion and mix blending, it is fertile to process organic-inorganic potassium calcium silicon compound
Embodiment 4
40 parts of potassium ores;
50 parts of desulfurization ashs;
21 parts in Wingdale;
4 parts in sodium sulfate, Sodium Fluoride or sodium-chlor;
90 parts of biological organic fertilizers;
According to the above ratio potassium ore, desulfurization ash, Wingdale, sodium sulfate are ground to form 250 order powder respectively, mix the back and be sintered into inorganic mineral fertilizer in temperature more than 1050 ℃; Afterwards, in this inorganic mineral fertilizer, add the biological organic fertilizer that contains function yeast in proportion and mix blending, it is fertile to process organic-inorganic potassium calcium silicon compound.
Embodiment 5
50 parts of potassium ores;
30 parts of desulfurization ashs;
21 parts in Wingdale;
2.7 parts in sodium sulfate, Sodium Fluoride or sodium-chlor;
40 parts of biological organic fertilizers;
According to the above ratio potassium ore, desulfurization ash, Wingdale, sodium sulfate are ground to form 250 order powder respectively, mix the back and be sintered into inorganic mineral fertilizer in temperature more than 1000 ℃; Afterwards, in this inorganic mineral fertilizer, add the biological organic fertilizer that contains function yeast in proportion and mix blending, it is fertile to process organic-inorganic potassium calcium silicon compound.
The application implementation example
But 1 field proportion fertilizer, but the local soil regime of ratio range root a tree name test fertilising, and combine crop-planting kind and the required nutrient rational proportion of the special growth cycle of crop;
But 2 industriallization proportionings are produced fertilizer and are become product;
Paddy rice, cassava, sugarcane field experiment through to China's south acid soil show that use mikrobe organic potassium calcium silicon composite fertilizer as base fertilizer for every mu, the stimulation ratio of crop can reach 11.12%～23.3%, average out to 15.54%.And through using this fertilizer, the starch content of cassava, the sugar degree of sugarcane all have raising in various degree.
The above; It only is preferred embodiment of the present invention; Be not that the present invention is done any pro forma restriction; Former every technical scheme content of the present invention that do not break away from, all still belongs in the scope of technical scheme of the present invention any simple modification, equivalent variations and modification that above embodiment did according to technical spirit of the present invention.
Claims (3)
1. the fertile preparation method of an organic-inorganic potassium calcium silicon compound is characterized in that it comprises each feed composition of following weight part:
1～50 part of potassium ore;
1～45 part of desulfurization ash;
0～32 part in Wingdale;
1～5 part of sodium salt compound;
1～90 part of biological organic fertilizer;
Above-mentioned potassium ore, desulfurization ash, Wingdale and sodium salt compound are admixed in above-mentioned weight part ratio; Through grinding, and is under 1000～1050 ℃ of conditions in temperature with material, roasting time 2～3 hours; Again through cooling, ball mill pulverizing; After obtaining potassium calcium silicon composite fertilizer, carry out blending in proportion with biological organic fertilizer again, process compound organic and inorganic fertilizer.
2. the preparation method that organic-inorganic potassium calcium silicon compound according to claim 1 is fertile is characterized in that: said improved grinding to 200～250 orders.
3. the preparation method that organic-inorganic potassium calcium silicon compound according to claim 2 is fertile, it is characterized in that: said sodium salt compound is sodium sulfate, Sodium Fluoride or sodium-chlor; The preferred proportion scope is at the 1-4 weight part.
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| CN2012100623732A CN102557808A (en) | 2012-03-09 | 2012-03-09 | Method for preparing organic-inorganic potassium-calcium-silicon compound fertilizer |
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| CN2012100623732A CN102557808A (en) | 2012-03-09 | 2012-03-09 | Method for preparing organic-inorganic potassium-calcium-silicon compound fertilizer |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104725163A (en) * | 2015-03-18 | 2015-06-24 | 陈广田 | Illite compound fertilizer |
| CN104973904A (en) * | 2014-04-11 | 2015-10-14 | 王忠厚 | Water-soluble Si/Ca/K mineral element ecological organic fertilizer and preparation method |
| CN105294268A (en) * | 2015-11-09 | 2016-02-03 | 根力多生物科技股份有限公司 | Compound microorganism fertilizer |
| CN108017471A (en) * | 2017-12-20 | 2018-05-11 | 江西瑞博特生物科技有限公司 | A kind of soil conditioner and preparation method thereof |
| CN108863523A (en) * | 2018-06-29 | 2018-11-23 | 铜陵祥意和贸易有限责任公司 | A kind of formula fertilizer improving Ipomoea batatas production quality |
| CN112299913A (en) * | 2020-10-09 | 2021-02-02 | 解会敏 | Mineral source chelated citric acid soluble granules and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104973904A (en) * | 2014-04-11 | 2015-10-14 | 王忠厚 | Water-soluble Si/Ca/K mineral element ecological organic fertilizer and preparation method |
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| CN104725163B (en) * | 2015-03-18 | 2017-08-08 | 陈广田 | A kind of illite compound fertilizer |
| CN105294268A (en) * | 2015-11-09 | 2016-02-03 | 根力多生物科技股份有限公司 | Compound microorganism fertilizer |
| CN108017471A (en) * | 2017-12-20 | 2018-05-11 | 江西瑞博特生物科技有限公司 | A kind of soil conditioner and preparation method thereof |
| CN108863523A (en) * | 2018-06-29 | 2018-11-23 | 铜陵祥意和贸易有限责任公司 | A kind of formula fertilizer improving Ipomoea batatas production quality |
| CN112299913A (en) * | 2020-10-09 | 2021-02-02 | 解会敏 | Mineral source chelated citric acid soluble granules and preparation method thereof |
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Application publication date: 20120711 |