CN106116902A - A kind of additive of mandarin orange foliage fertilizer and preparation method thereof - Google Patents
A kind of additive of mandarin orange foliage fertilizer and preparation method thereof Download PDFInfo
- Publication number
- CN106116902A CN106116902A CN201610504306.XA CN201610504306A CN106116902A CN 106116902 A CN106116902 A CN 106116902A CN 201610504306 A CN201610504306 A CN 201610504306A CN 106116902 A CN106116902 A CN 106116902A
- Authority
- CN
- China
- Prior art keywords
- additive
- foliage fertilizer
- sodium selenite
- mandarin orange
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses additive of a kind of mandarin orange foliage fertilizer and preparation method thereof, be made up of the raw material of following weight portion: flyash, rice straw, sodium selenite, wood vinegar, blast furnace cinder, sodium selenite, citric acid, ground phosphate rock, limestone, shell, Kaolin, humic acid powder, glycine, aluminum sulfate, the ethanol solution of 65 ~ 75%, plant additive and appropriate water；Containing multiple a great number of elements and trace element in natural stone powder, for foliage fertilizer, the interpolation of nutrient is particularly critical, in view of the restriction absorbed, the amount that concentration controls is the least, and therefore the addition of trace element is more difficult to control, invention carries out high temperature pyrolysis to mineral nitrogen stone, recycling the aqueous solution rich in various chelating agent and carry out extraction and the chelating of element, on the one hand can successfully obtain trace element, the element after complexation the most simultaneously is easier to be absorbed.
Description
Technical field
The invention belongs to the Technology field of fertilizer, be specifically related to additive and the preparation thereof of a kind of mandarin orange foliage fertilizer
Method.
Background technology
Fertilizer is that the production of agricultural serves indispensable effect, and environment is also caused by the most substantial amounts of fertilizer simultaneously
Serious impact, utilization rate of fertilizer is low, Fertilizer nutrient proportioning uneven and discharges the variant waste causing fertilizer of frequency and dirt
Dye, not only causes planting site soil and directly affects, with the effect of current, be lost in lake, on the impact of water body the most very
Fearful, this also makes foliage fertilizer increasingly be paid close attention to by people, and liquid fertilizer can directly act on the blade of crop, stem etc.
Position, is absorbed by the pore of blade surface, directly utilizes, it is to avoid by long-time after root absorption and the active of distance
Conveying, foliar fertilizer has utilization rate height, utilizes absorption fast, effective and wastes the features such as few, protection environment.
Use that foliage fertilizer is possible to prevent nutrient in soil is fixing, the most there is not the effect such as soil denitrification, leaching loss and
Lose or reduce effectiveness and utilization rate, but the mode that blade absorbs foliage fertilizer is similar to root system, mainly passes through blade table
Entrance mesophyll cell after the pore absorption in face, then horny layer and the cellulose wall of blade face epidermis is penetrated by free diffusing effect,
The speed absorbed seems slightly slow relative to liquid level fertilizer at the rate of drying of blade surface, and the Nutrient Absorption speed of general fruit tree exists
Typically at 1 ~ 12h when reaching 50%, and greengrocery crop takes several days sometimes, but blade outermost epidermal tissue waxiness, have
Hydrophobic effect, is unfavorable for the attachment of foliage fertilizer, adds that the surface tension effects of liquid fertilizer causes being difficult to the leaf by trickle
The most how sheet pore, improve foliage fertilizer adsorption effect on blade face and to reduce the surface tension of foliage fertilizer be critical asking
Topic.
In general, mainly by alkane, aldehyde, ester, ketone, fatty alcohol, fatty acid and free fat in the waxiness of plant surface
Fat acid and the triterpene of low content, sterone and flavonoid etc. mix.
Summary of the invention
The present invention, in order to improve the absorption efficiency of foliar fertilizer, adds one containing active components of plants in liquid fertilizer
Additive, have reduce surface tension of liquid and improve infiltration rate effect, the botanical components simultaneously added also has
Prevent the ability of pest and disease damage:
The additive of a kind of mandarin orange foliage fertilizer, it is characterised in that be made up of the raw material of following weight portion: flyash 6 ~ 10, growth
Element 0.2 ~ 0.3, sodium selenite 1 ~ 3, wood vinegar 3 ~ 5, blast furnace cinder 10 ~ 16, sodium selenite 4 ~ 6, citric acid 10 ~ 15, ground phosphate rock
20 ~ 30, limestone 35 ~ 40, shell 25 ~ 30, Kaolin 20 ~ 30, humic acid powder 10 ~ 16, glycine 4 ~ 8, aluminum sulfate 0.2 ~
0.5, ethanol solution 70 ~ 90, plant additive 30 ~ 40 and the appropriate water of 65 ~ 75%；
Described plant additive is the unit fresh raw material Fructus Sapindi Mukouossi 10 ~ 15 of mixing, Fructus Toosendan 5 ~ 8, Fructus Momordicae charantiae with weight (part)
Leaf 2 ~ 4, Fructus Gleditsia 15 ~ 20, Extracted From Oil-tea-cake 5 ~ 8, Folium Perillae 10 ~ 14, Radix Thalictri Trichopi 8 ~ 12, derris root 15 ~ 20, tobacco leaf 4 ~ 8 and wild crow
Chinese toon 9 ~ 14, is put in 0 ~ 4 DEG C of preservation after preliminary pulverizing standby.
The preparation method of the additive of a kind of mandarin orange foliage fertilizer, it is characterised in that include following step:
(1) first plant additive is passed through low-temperature freeze drying, then pulverized 180 ~ 200 mesh sieves, and joined 65 by solid-liquid ratio 1:4 ~ 5
In the ethanol solution of ~ 75%, ultrasonication processes to obtain serosity, and then decompression is distilled off ethanol concentrated slurry；
(2) combined lime stone, shell, Kaolin and other following residual components being not directed to, enter pyrolysis oven high temperature 900 ~
1050 DEG C of sealed pyrolysis 1.5 ~ 2.0h, ground 80 ~ 120 mesh sieves after natural cooling；
(3) mixing humic acid powder, glycine, wood vinegar, citric acid, adds to the powder described in (2), by solid-liquid ratio 1:4 ~ 5
Add water, be warming up to 60 ~ 70 DEG C of stirring 50 ~ 60min and chelate, after completing, filter to obtain supernatant；
(4) mixing (1) described serosity, auxin, sodium selenite and sodium selenite, adds to the supernatant of (3), stirring and dissolving
Rear addition flocculant aluminum sulfate stands 2 ~ 3h depositing particles, again separates to obtain supernatant and get final product.
General pesticide and foliar fertilizer all can add surfactant monomer or the surface of alkyl polyoxyethylene ether class
Activating agent postpones droplet drift, thus improves the flow of holding on blade, reduces size and the surface tension of droplet, makes foliage fertilizer
In the surface of blade deposition, stick and spread.
The present invention uses the extraction of substance additive for liquid fertilizer of plant source, for replacing traditional surface activity
Agent, a lot of plants are just grated in ancient times, and the juice obtained is for the daily washing of life, it is seen that containing the most hydrophilic in plant
With the amphiprotic activity material of oleophylic, research finds several several plant oils with amphiprotic activity material.Fructus Sapindi Mukouossi: it can be right
Gram positive bacteria, candidiasis have strong inhibitory action, have the function promoting vitamin absorption simultaneously；The tea seed cake tool of oil tea
There are good emulsifying, impervious effect, in modern chemical industry produces, may be used for the additive of cosmetics, the straight chained alkyl sulphur contained
Acid sodium, polyoxyethylenated alcohol sodium sulfate, 120,000 and ammonium sulfate etc. are all surface active ingredients, and Fructus Gleditsia also has same simultaneously
The effect of sample, invention uses Fructus Gleditsia to test, through crushed after being dried, is placed in 5L ground triangular flask, with V(ethanol): V
(deionized water)=70:30, by solid-liquid ratio 1:4 reflux, extract, 3 times, each 1h, then filtered while hot obtains the crude extract of Fructus Gleditsia,
Use flocculating agent A l(SO4)3Precipitation 2 ~ 3h, is centrifuged to obtain supernatant, detects through HPLC, by area normalization method, draw soap after concentration
The main active component Total saponin HPLC peak area of pod accounts for extract total peak area more than 70%, has the most steady bubble and foam enhancing
Effect.
Test proves: the surface activity extracted in plant that employing ethanol reflux, extract, under certain condition can be appropriate
Composition, the most in this way, is similar to Ethanol Method and extracts plant-derived disease and insect resistance composition, equally to endophytic antibacterial
And the active substance of pest-resistant useful crop plants growth has certain abstraction function, can obtain the most permissible with the stem and leaf of plant for raw material
Reduce the capillary active substance of foliage fertilizer, the material of extraction plant source insect pest that simultaneously can also be appropriate, and at liquid
State fertilizer is attached to the surface of plant leaf blade after being dried, have certain prevention, the effect of cover crop, play double effects,
Beneficial effects of the present invention: containing multiple a great number of elements and trace element in natural stone powder, for foliage fertilizer, battalion
The interpolation supporting element is particularly critical, it is contemplated that the restriction of absorption, and the amount that concentration controls is the least, and therefore the addition of trace element is more
Difficult controlling, invention carries out high temperature pyrolysis to mineral nitrogen stone, recycle the aqueous solution rich in various chelating agent carry out element extraction and
Chelating, on the one hand can successfully obtain trace element, and the element after complexation the most simultaneously is easier to be absorbed.
Detailed description of the invention
Embodiment 1:
The additive of a kind of mandarin orange foliage fertilizer, it is characterised in that be made up of the raw material of following weight portion (Kg): flyash 8, growth
Element 0.2, sodium selenite 3, wood vinegar 4, blast furnace cinder 12, sodium selenite 5, citric acid 12, ground phosphate rock 25, limestone 38, shell
28, Kaolin 25, humic acid powder 12, glycine 7, the ethanol solution 80 of aluminum sulfate 0.4,65 ~ 75%, plant additive 32 and suitable
The water of amount；
Described plant additive is the unit fresh raw material Fructus Sapindi Mukouossi 13 of mixing, Fructus Toosendan 6, Folium Momordicae Charantiae 3, soap with weight (Kg)
Pod 16, Extracted From Oil-tea-cake 7, Folium Perillae 12, Radix Thalictri Trichopi 10, derris root 18, tobacco leaf 6 and wild crow Chinese toon 10, be put in 0 ~ 4 DEG C after preliminary pulverizing
Preservation is standby.
The preparation method of the additive of a kind of mandarin orange foliage fertilizer, it is characterised in that include following step:
(1) first plant additive is passed through low-temperature freeze drying, then pulverized 180 ~ 200 mesh sieves, and joined 65 by solid-liquid ratio 1:4 ~ 5
In the ethanol solution of ~ 75%, ultrasonication processes to obtain serosity, and then decompression is distilled off ethanol concentrated slurry；
(2) combined lime stone, shell, Kaolin and other following residual components being not directed to, enter pyrolysis oven high temperature 900 ~
1050 DEG C of sealed pyrolysis 1.5 ~ 2.0h, ground 80 ~ 120 mesh sieves after natural cooling；
(3) mixing humic acid powder, glycine, wood vinegar, citric acid, adds to the powder described in (2), by solid-liquid ratio 1:4 ~ 5
Add water, be warming up to 60 ~ 70 DEG C of stirring 50 ~ 60min and chelate, after completing, filter to obtain supernatant；
(4) mixing (1) described serosity, auxin, sodium selenite and sodium selenite, adds to the supernatant of (3), stirring and dissolving
Rear addition flocculant aluminum sulfate stands 2 ~ 3h depositing particles, again separates to obtain supernatant and get final product.
Use the foliar fertilizer additive additive as mandarin orange foliage fertilizer of the present invention, select 5 mu of mandarin orange planting districts to use
In test, being mixed in the ratio of 1:10 ~ 15 with the foliage fertilizer after dilution by the additive of the present invention, the foliage fertilizer of matched group does not does
Any process, sprays zones of different respectively, and result shows: use that sheet mandarin orange district of the Foliar Spraying of additive of the present invention
Territory, the utilization rate of foliage fertilizer improves, and saves fertilizer, and the ability of insect pest has promoted, and reduces the sprinkling of pesticide, the mandarin orange of plantation
More safety and sanitation.
Claims (2)
1. the additive of a mandarin orange foliage fertilizer, it is characterised in that be made up of the raw material of following weight portion: flyash 6 ~ 10, life
Long element 0.2 ~ 0.3, sodium selenite 1 ~ 3, wood vinegar 3 ~ 5, blast furnace cinder 10 ~ 16, sodium selenite 4 ~ 6, citric acid 10 ~ 15, phosphorus ore
Powder 20 ~ 30, limestone 35 ~ 40, shell 25 ~ 30, Kaolin 20 ~ 30, humic acid powder 10 ~ 16, glycine 4 ~ 8, aluminum sulfate 0.2 ~
0.5, ethanol solution 70 ~ 90, plant additive 30 ~ 40 and the appropriate water of 65 ~ 75%；
Described plant additive is the unit fresh raw material Fructus Sapindi Mukouossi 10 ~ 15 of mixing, Fructus Toosendan 5 ~ 8, Fructus Momordicae charantiae with weight (part)
Leaf 2 ~ 4, Fructus Gleditsia 15 ~ 20, Extracted From Oil-tea-cake 5 ~ 8, Folium Perillae 10 ~ 14, Radix Thalictri Trichopi 8 ~ 12, derris root 15 ~ 20, tobacco leaf 4 ~ 8 and wild crow
Chinese toon 9 ~ 14, is put in 0 ~ 4 DEG C of preservation after preliminary pulverizing standby.
The preparation method of the additive of a kind of mandarin orange foliage fertilizer, it is characterised in that include following several
Individual step:
(1) first plant additive is passed through low-temperature freeze drying, then pulverized 180 ~ 200 mesh sieves, and joined 65 by solid-liquid ratio 1:4 ~ 5
In the ethanol solution of ~ 75%, ultrasonication processes to obtain serosity, and then decompression is distilled off ethanol concentrated slurry；
(2) combined lime stone, shell, Kaolin and other following residual components being not directed to, enter pyrolysis oven high temperature 900 ~
1050 DEG C of sealed pyrolysis 1.5 ~ 2.0h, ground 80 ~ 120 mesh sieves after natural cooling；
(3) mixing humic acid powder, glycine, wood vinegar, citric acid, adds to the powder described in (2), by solid-liquid ratio 1:4 ~ 5
Add water, be warming up to 60 ~ 70 DEG C of stirring 50 ~ 60min and chelate, after completing, filter to obtain supernatant；
(4) mixing (1) described serosity, auxin, sodium selenite and sodium selenite, adds to the supernatant of (3), stirring and dissolving
Rear addition flocculant aluminum sulfate stands 2 ~ 3h depositing particles, again separates to obtain supernatant and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610504306.XA CN106116902A (en) | 2016-07-01 | 2016-07-01 | A kind of additive of mandarin orange foliage fertilizer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610504306.XA CN106116902A (en) | 2016-07-01 | 2016-07-01 | A kind of additive of mandarin orange foliage fertilizer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106116902A true CN106116902A (en) | 2016-11-16 |
Family
ID=57467555
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610504306.XA Pending CN106116902A (en) | 2016-07-01 | 2016-07-01 | A kind of additive of mandarin orange foliage fertilizer and preparation method thereof |
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| CN (1) | CN106116902A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106748214A (en) * | 2016-12-30 | 2017-05-31 | 汤广顺 | A kind of sulfydryl humin suppresses the pear tree Paste Foliage Fertilizer additive of Metal uptake |
| CN106748247A (en) * | 2017-01-05 | 2017-05-31 | 广西金臣科技有限公司 | A kind of selenium-enriched foliage fertilizer and preparation method thereof |
| CN106748215A (en) * | 2016-12-30 | 2017-05-31 | 汤广顺 | A kind of special paste foliage fertilizer additives of pear tree for adding rare earth modified shitosan |
| CN108640761A (en) * | 2018-07-17 | 2018-10-12 | 博白县百家水果专业合作社 | A kind of blood orange selenium-enriched foliar fertilizer special and preparation method thereof |
| CN108794142A (en) * | 2017-10-31 | 2018-11-13 | 河北龙庆生物科技有限公司 | A kind of vegetable fertilizer additive, preparation method and application method |
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| CN101696132A (en) * | 2009-10-27 | 2010-04-21 | 黄玉霖 | Multi-mineral organotrophic fertilizer and preparation method thereof |
| CN103342604A (en) * | 2013-07-10 | 2013-10-09 | 湖南泰谷生物科技股份有限公司 | Bio-control bacterium foliage fertilizer, and preparation method and application thereof |
| CN105110900A (en) * | 2015-08-05 | 2015-12-02 | 马鞍山科邦生态肥有限公司 | Anti-insect pest foliar fertilizer prepared from fermentation liquor and preparation method for anti-insect pest foliar fertilizer |
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2016
- 2016-07-01 CN CN201610504306.XA patent/CN106116902A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101696132A (en) * | 2009-10-27 | 2010-04-21 | 黄玉霖 | Multi-mineral organotrophic fertilizer and preparation method thereof |
| CN103342604A (en) * | 2013-07-10 | 2013-10-09 | 湖南泰谷生物科技股份有限公司 | Bio-control bacterium foliage fertilizer, and preparation method and application thereof |
| CN105110900A (en) * | 2015-08-05 | 2015-12-02 | 马鞍山科邦生态肥有限公司 | Anti-insect pest foliar fertilizer prepared from fermentation liquor and preparation method for anti-insect pest foliar fertilizer |
Non-Patent Citations (1)
| Title |
|---|
| 姜素荣: ""高效复合叶面肥制备与性能研究"", 《中国优秀硕士学位论文全文数据库（电子期刊） 工程科技Ⅰ辑》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106748214A (en) * | 2016-12-30 | 2017-05-31 | 汤广顺 | A kind of sulfydryl humin suppresses the pear tree Paste Foliage Fertilizer additive of Metal uptake |
| CN106748215A (en) * | 2016-12-30 | 2017-05-31 | 汤广顺 | A kind of special paste foliage fertilizer additives of pear tree for adding rare earth modified shitosan |
| CN106748247A (en) * | 2017-01-05 | 2017-05-31 | 广西金臣科技有限公司 | A kind of selenium-enriched foliage fertilizer and preparation method thereof |
| CN108794142A (en) * | 2017-10-31 | 2018-11-13 | 河北龙庆生物科技有限公司 | A kind of vegetable fertilizer additive, preparation method and application method |
| CN108640761A (en) * | 2018-07-17 | 2018-10-12 | 博白县百家水果专业合作社 | A kind of blood orange selenium-enriched foliar fertilizer special and preparation method thereof |
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| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161116 |
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| RJ01 | Rejection of invention patent application after publication |