CN106116901A - A kind of additive promoting Folium Pini leaven effect and preparation method thereof - Google Patents

Abstract

The invention discloses a kind of additive promoting Folium Pini leaven effect and preparation method thereof, be made up of the raw material of following weight portion: oligosaccharide, compound sodium nitrophenolate, lecithin, attapulgite, Maifanitum, plant ash, carboxymethyl cellulose, chinaberry extracting solution, aminoacid powder, cobalt sulfide, aluminum sulfate, the ethanol solution of 65 ~ 75%, plant additive and appropriate water；The mineral nitrogen stone of pyrolysis is carried out water mill by invention, the trace element of oxidation in pyrolytic process has been hydrolyzed while water mill, again add precipitant, the microgranule in process of lapping is made to settle, obtain the limpidest foliage fertilizer additives, prevent particles holography Stoma of Leaves from causing absorption and Repiration undesirable, the vegetable active oleo stock added in invention and lecithin, carboxymethyl cellulose etc. all have the effect promoting drop attachment, binding, promote the bonding of foliar fertilizer and pinaster Folium Pini, improve the assimilation effect of foliage fertilizer.

Description

A kind of additive promoting Folium Pini leaven effect and preparation method thereof

Technical field

The invention belongs to the Technology field of fertilizer, be specifically related to a kind of additive promoting Folium Pini leaven effect And preparation method thereof.

Background technology

Fertilizer is that the production of agricultural serves indispensable effect, and environment is also caused by the most substantial amounts of fertilizer simultaneously Serious impact, utilization rate of fertilizer is low, Fertilizer nutrient proportioning uneven and discharges the variant waste causing fertilizer of frequency and dirt Dye, not only causes planting site soil and directly affects, with the effect of current, be lost in lake, on the impact of water body the most very Fearful, this also makes foliage fertilizer increasingly be paid close attention to by people, and liquid fertilizer can directly act on the blade of crop, stem etc. Position, is absorbed by the pore of blade surface, directly utilizes, it is to avoid by long-time after root absorption and the active of distance Conveying, foliar fertilizer has utilization rate height, utilizes absorption fast, effective and wastes the features such as few, protection environment.

Use that foliage fertilizer is possible to prevent nutrient in soil is fixing, the most there is not the effect such as soil denitrification, leaching loss and Lose or reduce effectiveness and utilization rate, but the mode that blade absorbs foliage fertilizer is similar to root system, mainly passes through blade table Entrance mesophyll cell after the pore absorption in face, then horny layer and the cellulose wall of blade face epidermis is penetrated by free diffusing effect, The speed absorbed seems slightly slow relative to liquid level fertilizer at the rate of drying of blade surface, and the Nutrient Absorption speed of general fruit tree exists Typically at 1 ~ 12h when reaching 50%, and greengrocery crop takes several days sometimes, but blade outermost epidermal tissue waxiness, have Hydrophobic effect, is unfavorable for the attachment of foliage fertilizer, adds that the surface tension effects of liquid fertilizer causes being difficult to the leaf by trickle The most how sheet pore, improve foliage fertilizer adsorption effect on blade face and to reduce the surface tension of foliage fertilizer be critical asking Topic.

In general, mainly by alkane, aldehyde, ester, ketone, fatty alcohol, fatty acid and free fat in the waxiness of plant surface Fat acid and the triterpene of low content, sterone and flavonoid etc. mix.

Summary of the invention

The present invention, in order to improve the absorption efficiency of foliar fertilizer, adds one containing active components of plants in liquid fertilizer Additive, have reduce surface tension of liquid and improve infiltration rate effect, the botanical components simultaneously added also has Prevent the ability of pest and disease damage:

A kind of additive promoting Folium Pini leaven effect, it is characterised in that be made up of the raw material of following weight portion: oligosaccharide 1 ~ 3, compound sodium nitrophenolate 3 ~ 6, lecithin 2 ~ 5, attapulgite 30 ~ 40, Maifanitum 25 ~ 30, plant ash 15 ~ 20, carboxymethyl cellulose 1 ~ 2, chinaberry extracting solution 5 ~ 8, aminoacid powder 10 ~ 15, cobalt sulfide 1.5 ~ 2.5, aluminum sulfate 0.2 ~ 0.5,65 ~ 75% ethanol solution 70 ~ 90, plant additive 30 ~ 40 and appropriate water；

Described plant additive is the unit fresh raw material Fructus Sapindi Mukouossi 10 ~ 15 of mixing, Fructus Toosendan 5 ~ 8, Fructus Momordicae charantiae with weight (part) Leaf 2 ~ 4, Fructus Gleditsia 15 ~ 20, Extracted From Oil-tea-cake 5 ~ 8, Folium Perillae 10 ~ 14, Radix Thalictri Trichopi 8 ~ 12, derris root 15 ~ 20, tobacco leaf 4 ~ 8 and wild crow Chinese toon 9 ~ 14, is put in 0 ~ 4 DEG C of preservation after preliminary pulverizing standby.

The preparation method of a kind of additive promoting Folium Pini leaven effect, it is characterised in that include following step:

(1) first plant additive is passed through low-temperature freeze drying, then pulverized 180 ~ 200 mesh sieves, and joined 65 by solid-liquid ratio 1:4 ~ 5 In the ethanol solution of ~ 75%, ultrasonication processes to obtain serosity, and then decompression is distilled off ethanol concentrated slurry；

(2) proceeding to pyrolysis oven after attapulgite, Maifanitum tentatively being pulverized, under airtight condition, high temperature 1050 ~ 1200 DEG C enters Row pyrolysis 1 ~ 2h, mixes plant ash and mixes in the ratio of 1:8 ~ 10 with water, carry out water mill 30 ~ 40min, stand after completing after completing Take supernatant；

(3) mixing oligosaccharide, compound sodium nitrophenolate, lecithin and other following residual components being not directed to, join described in (2) is upper In clear liquid, stirring, to being completely dissolved, adds flocculant aluminum sulfate and stands 2 ~ 3h depositing particles, again separate to obtain supernatant；

(4) mixing serosity described in (1) and the supernatant described in (3), high speed centrifugation shear-mixed, after foaming.

General pesticide and foliar fertilizer all can add surfactant monomer or the surface of alkyl polyoxyethylene ether class Activating agent postpones droplet drift, thus improves the flow of holding on blade, reduces size and the surface tension of droplet, makes foliage fertilizer In the surface of blade deposition, stick and spread.

The present invention uses the extraction of substance additive for liquid fertilizer of plant source, for replacing traditional surface activity Agent, a lot of plants are just grated in ancient times, and the juice obtained is for the daily washing of life, it is seen that containing the most hydrophilic in plant With the amphiprotic activity material of oleophylic, research finds several several plant oils with amphiprotic activity material.Fructus Sapindi Mukouossi: it can be right Gram positive bacteria, candidiasis have strong inhibitory action, have the function promoting vitamin absorption simultaneously；The tea seed cake tool of oil tea There are good emulsifying, impervious effect, in modern chemical industry produces, may be used for the additive of cosmetics, the straight chained alkyl sulphur contained Acid sodium, polyoxyethylenated alcohol sodium sulfate, 120,000 and ammonium sulfate etc. are all surface active ingredients, and Fructus Gleditsia also has same simultaneously The effect of sample, invention uses Fructus Gleditsia to test, through crushed after being dried, is placed in 5L ground triangular flask, with V(ethanol): V (deionized water)=70:30, by solid-liquid ratio 1:4 reflux, extract, 3 times, each 1h, then filtered while hot obtains the crude extract of Fructus Gleditsia, Use flocculating agent A l(SO₄)₃Precipitation 2 ~ 3h, is centrifuged to obtain supernatant, detects through HPLC, by area normalization method, draw soap after concentration The main active component Total saponin HPLC peak area of pod accounts for extract total peak area more than 70%, has the most steady bubble and foam enhancing Effect.

Test proves: the surface activity extracted in plant that employing ethanol reflux, extract, under certain condition can be appropriate Composition, the most in this way, is similar to Ethanol Method and extracts plant-derived disease and insect resistance composition, equally to endophytic antibacterial And the active substance of pest-resistant useful crop plants growth has certain abstraction function, can obtain the most permissible with the stem and leaf of plant for raw material Reduce the capillary active substance of foliage fertilizer, the material of extraction plant source insect pest that simultaneously can also be appropriate, and at liquid State fertilizer is attached to the surface of plant leaf blade after being dried, have certain prevention, the effect of cover crop, play double effects,

Beneficial effects of the present invention: the mineral nitrogen stone of pyrolysis is carried out water mill by invention, has hydrolyzed oxygen in pyrolytic process while water mill The trace element changed, again adds precipitant, makes the microgranule in process of lapping settle, and obtains the limpidest foliage fertilizer and adds Agent, prevents particles holography Stoma of Leaves from causing absorption and Repiration undesirable, the vegetable active oleo stock added in invention and ovum Phospholipid, carboxymethyl cellulose etc. all have the effect promoting drop attachment, binding, and promotion foliar fertilizer is glutinous with pinaster Folium Pini Closing, improve the assimilation effect of foliage fertilizer, the Folium Pini of pinaster is narrower due to itself, and foliage fertilizer attachment is extremely difficult, the interpolation of invention Agent well solves this problem.

Detailed description of the invention

Embodiment 1:

A kind of additive promoting Folium Pini leaven effect, it is characterised in that be made up of the raw material of following weight portion (Kg): oligomerization Sugar 2, compound sodium nitrophenolate 5, lecithin 4, attapulgite 35, Maifanitum 28, plant ash 18, carboxymethyl cellulose 1, chinaberry extracting solution 7, Aminoacid powder 12, cobalt sulfide 1.5, the ethanol solution 85 of aluminum sulfate 0.4,65 ~ 75%, plant additive 36 and appropriate water；

Described plant additive is the unit fresh raw material Fructus Sapindi Mukouossi 13 of mixing, Fructus Toosendan 6, Folium Momordicae Charantiae 3, soap with weight (Kg) Pod 16, Extracted From Oil-tea-cake 7, Folium Perillae 12, Radix Thalictri Trichopi 10, derris root 18, tobacco leaf 6 and wild crow Chinese toon 10, be put in 0 ~ 4 DEG C after preliminary pulverizing Preservation is standby.

The preparation method of a kind of additive promoting Folium Pini leaven effect, it is characterised in that include following step:

(1) first plant additive is passed through low-temperature freeze drying, then pulverized 180 ~ 200 mesh sieves, and joined 65 by solid-liquid ratio 1:4 ~ 5 In the ethanol solution of ~ 75%, ultrasonication processes to obtain serosity, and then decompression is distilled off ethanol concentrated slurry；

(2) proceeding to pyrolysis oven after attapulgite, Maifanitum tentatively being pulverized, under airtight condition, high temperature 1050 ~ 1200 DEG C enters Row pyrolysis 1 ~ 2h, mixes plant ash and mixes in the ratio of 1:8 ~ 10 with water, carry out water mill 30 ~ 40min, stand after completing after completing Take supernatant；

(3) mixing oligosaccharide, compound sodium nitrophenolate, lecithin and other following residual components being not directed to, join described in (2) is upper In clear liquid, stirring, to being completely dissolved, adds flocculant aluminum sulfate and stands 2 ~ 3h depositing particles, again separate to obtain supernatant；

(4) mixing serosity described in (1) and the supernatant described in (3), high speed centrifugation shear-mixed, after foaming.

Use the foliar fertilizer additive additive as Folium Pini leaven of the present invention, select 5 mu of pinaster growing areas to use In test, being mixed in the ratio of 1:10 ~ 15 with the foliage fertilizer after dilution by the additive of the present invention, the foliage fertilizer of matched group does not does Any process, sprays zones of different respectively, and result shows: use that sheet pinaster district of the Foliar Spraying of additive of the present invention Territory, foliage fertilizer residence time on blade is longer, absorbs more preferably, improves utilization rate of fertilizer, and the generation of pest and disease damage is the most relatively Low.

Claims (2)

1. the additive promoting Folium Pini leaven effect, it is characterised in that be made up of the raw material of following weight portion: oligosaccharide 1 ~ 3, compound sodium nitrophenolate 3 ~ 6, lecithin 2 ~ 5, attapulgite 30 ~ 40, Maifanitum 25 ~ 30, plant ash 15 ~ 20, carboxymethyl cellulose 1 ~ 2, chinaberry extracting solution 5 ~ 8, aminoacid powder 10 ~ 15, cobalt sulfide 1.5 ~ 2.5, the ethanol solution 70 of aluminum sulfate 0.2 ~ 0.5,65 ~ 75% ~ 90, plant additive 30 ~ 40 and appropriate water；

Described plant additive is the unit fresh raw material Fructus Sapindi Mukouossi 10 ~ 15 of mixing, Fructus Toosendan 5 ~ 8, Fructus Momordicae charantiae with weight (part) Leaf 2 ~ 4, Fructus Gleditsia 15 ~ 20, Extracted From Oil-tea-cake 5 ~ 8, Folium Perillae 10 ~ 14, Radix Thalictri Trichopi 8 ~ 12, derris root 15 ~ 20, tobacco leaf 4 ~ 8 and wild crow Chinese toon 9 ~ 14, is put in 0 ~ 4 DEG C of preservation after preliminary pulverizing standby.

The preparation method of a kind of additive promoting Folium Pini leaven effect, it is characterised in that bag Include following step:

(1) first plant additive is passed through low-temperature freeze drying, then pulverized 180 ~ 200 mesh sieves, and joined 65 by solid-liquid ratio 1:4 ~ 5 In the ethanol solution of ~ 75%, ultrasonication processes to obtain serosity, and then decompression is distilled off ethanol concentrated slurry；

(2) proceeding to pyrolysis oven after attapulgite, Maifanitum tentatively being pulverized, under airtight condition, high temperature 1050 ~ 1200 DEG C enters Row pyrolysis 1 ~ 2h, mixes plant ash and mixes in the ratio of 1:8 ~ 10 with water, carry out water mill 30 ~ 40min, stand after completing after completing Take supernatant；

(3) mixing oligosaccharide, compound sodium nitrophenolate, lecithin and other following residual components being not directed to, join described in (2) is upper In clear liquid, stirring, to being completely dissolved, adds flocculant aluminum sulfate and stands 2 ~ 3h depositing particles, again separate to obtain supernatant；

(4) mixing serosity described in (1) and the supernatant described in (3), high speed centrifugation shear-mixed, after foaming.