CN101689680B - 含有镁离子的非水性电解质及其制备方法以及电化学装置 - Google Patents

含有镁离子的非水性电解质及其制备方法以及电化学装置 Download PDF

Info

Publication number
CN101689680B
CN101689680B CN200880023395XA CN200880023395A CN101689680B CN 101689680 B CN101689680 B CN 101689680B CN 200880023395X A CN200880023395X A CN 200880023395XA CN 200880023395 A CN200880023395 A CN 200880023395A CN 101689680 B CN101689680 B CN 101689680B
Authority
CN
China
Prior art keywords
ion
magnesium
electrolytic solution
compound
ions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN200880023395XA
Other languages
English (en)
Chinese (zh)
Other versions
CN101689680A (zh
Inventor
中山有理
山本贤太
工藤喜弘
大木荣干
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Murata Northeast China
Murata Manufacturing Co Ltd
Original Assignee
Sony Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sony Corp filed Critical Sony Corp
Publication of CN101689680A publication Critical patent/CN101689680A/zh
Application granted granted Critical
Publication of CN101689680B publication Critical patent/CN101689680B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/46—Alloys based on magnesium or aluminium
    • H01M4/466—Magnesium based
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Primary Cells (AREA)
CN200880023395XA 2007-07-11 2008-06-05 含有镁离子的非水性电解质及其制备方法以及电化学装置 Active CN101689680B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP182495/2007 2007-07-11
JP2007182495A JP5245108B2 (ja) 2007-07-11 2007-07-11 マグネシウムイオン含有非水電解液及びその製造方法、並びに電気化学デバイス
PCT/JP2008/060344 WO2009008232A1 (ja) 2007-07-11 2008-06-05 マグネシウムイオン含有非水電解液及びその製造方法、並びに電気化学デバイス

Publications (2)

Publication Number Publication Date
CN101689680A CN101689680A (zh) 2010-03-31
CN101689680B true CN101689680B (zh) 2012-08-22

Family

ID=40228411

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200880023395XA Active CN101689680B (zh) 2007-07-11 2008-06-05 含有镁离子的非水性电解质及其制备方法以及电化学装置

Country Status (6)

Country Link
US (1) US8993178B2 (enExample)
EP (1) EP2169755B1 (enExample)
JP (1) JP5245108B2 (enExample)
KR (1) KR101495938B1 (enExample)
CN (1) CN101689680B (enExample)
WO (1) WO2009008232A1 (enExample)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5162822B2 (ja) * 2005-12-02 2013-03-13 ソニー株式会社 電気化学デバイス
JP2007234580A (ja) * 2006-02-02 2007-09-13 Sony Corp 色素増感型光電変換装置
JP5034799B2 (ja) * 2007-09-07 2012-09-26 ソニー株式会社 マグネシウムイオン含有非水電解液及びその製造方法、並びに電気化学デバイス
JP5320710B2 (ja) * 2007-09-07 2013-10-23 ソニー株式会社 正極活物質及びその製造方法、並びに電気化学デバイス
JP2011142048A (ja) * 2010-01-08 2011-07-21 Sumitomo Electric Ind Ltd 電解液、マグネシウムイオン２次電池、および電力システム
US8318354B2 (en) * 2010-04-27 2012-11-27 Toyota Motor Engineering & Manufacturing North America Electrochemical device with a magnesium anode and a stable, safe electrolyte compatible with sulfur
CN102074736B (zh) * 2010-06-07 2012-09-05 中国科学院广州能源研究所 含聚醚链有机硅胺电解质材料及其在锂电池电解液中的应用
US8877383B2 (en) 2010-06-21 2014-11-04 Toyota Motor Engineering & Manufacturing North America, Inc. Magnesium-based battery
JP5977236B2 (ja) * 2010-08-09 2016-08-24 エルジー・ケム・リミテッド プライマーでコーティングされたカソード集電体及びそれを備えたマグネシウム二次電池
JP5471972B2 (ja) * 2010-08-25 2014-04-16 国立大学法人山口大学 マグネシウム二次電池用電解液及びそれを用いたマグネシウム二次電池
US8541133B2 (en) * 2010-10-27 2013-09-24 Toyota Motor Engineering & Manufacturing North America, Inc. Electrochemical device with a magnesium anode and a stable, safe electrolyte compatible with sulfur
KR101334186B1 (ko) * 2010-12-30 2013-11-28 삼성전자주식회사 전해액 및 이를 채용한 마그네슘 전지
CN102651485B (zh) * 2011-02-28 2016-03-30 丰田自动车株式会社 可充镁电池、电解液在可充镁电池中的应用、以及用于可充镁电池的电解液
US8361661B2 (en) * 2011-03-08 2013-01-29 Pellion Technologies Inc. Rechargeable magnesium ion cell components and assembly
US8951680B2 (en) 2011-03-08 2015-02-10 Pellion Technologies, Inc. Rechargeable magnesium ion cell components and assembly
US8361651B2 (en) 2011-04-29 2013-01-29 Toyota Motor Engineering & Manufacturing North America, Inc. Active material for rechargeable battery
US8685564B2 (en) 2011-06-22 2014-04-01 Toyota Motor Engineering & Manufacturing North America, Inc. Active material for rechargeable battery
EP2795703B1 (en) * 2011-12-22 2018-10-10 Pellion Technologies Inc. Non-aqueous electrolyte for rechargeable magnesium ion cell
US9293790B2 (en) * 2012-03-20 2016-03-22 Pellion Technologies, Inc. High voltage rechargeable magnesium batteries having a non-aqueous electrolyte
WO2013157187A1 (ja) 2012-04-16 2013-10-24 パナソニック株式会社 電気化学素子用非水電解質、その製造方法およびそれを用いた電気化学素子
WO2013157189A1 (ja) 2012-04-16 2013-10-24 パナソニック株式会社 電気化学エネルギー蓄積デバイスおよびこれに用いる活物質とその製造法
US8673493B2 (en) 2012-05-29 2014-03-18 Toyota Motor Engineering & Manufacturing North America, Inc. Indium-tin binary anodes for rechargeable magnesium-ion batteries
US8647770B2 (en) 2012-05-30 2014-02-11 Toyota Motor Engineering & Manufacturing North America, Inc. Bismuth-tin binary anodes for rechargeable magnesium-ion batteries
US9318775B2 (en) 2012-08-02 2016-04-19 Toyota Motor Engineering & Manufacturing North America, Inc. Magnesium borohydride and its derivatives as magnesium ion transfer media
JP5758859B2 (ja) * 2012-08-21 2015-08-05 トヨタ自動車株式会社 電極体、及び当該電極体を備える電池
JP5861606B2 (ja) 2012-09-28 2016-02-16 ソニー株式会社 電解液、電解液の製造方法および電気化学デバイス
US20140170506A1 (en) * 2012-12-19 2014-06-19 Panasonic Corporation Nonaqueous solvent for electricity storage device, nonaqueous electrolytic solution and electricity storage device and lithium secondary battery using the same
KR101969850B1 (ko) * 2012-12-21 2019-04-17 삼성전자주식회사 마그네슘 화합물, 마그네슘전지용 전해액, 및 이를 포함하는 마그네슘전지
US9525191B2 (en) * 2013-04-08 2016-12-20 Battelle Memorial Institute Magnesium-based energy storage systems and methods having improved electrolytes
US20140302354A1 (en) * 2013-04-08 2014-10-09 Battelle Memorial Institute Electrodes for Magnesium Energy Storage Devices
EP2824751B1 (en) * 2013-07-12 2016-04-20 Karlsruher Institut für Technologie Bisamide-based electrolyte for magnesium battery
JP6229199B2 (ja) * 2013-08-07 2017-11-15 株式会社デンソー マグネシウムイオン含有電解液
JP2015041572A (ja) * 2013-08-23 2015-03-02 株式会社豊田中央研究所 無機マグネシウム固体電解質、マグネシウム電池、電気化学デバイス及び無機マグネシウム固体電解質の製造方法
JP6277811B2 (ja) 2014-03-24 2018-02-14 アイシン精機株式会社 非水電解液
CN107078326B (zh) * 2014-05-12 2021-07-06 乔纳·莱迪 镧系元素和锕系元素电化学
CN107534180B (zh) * 2014-10-08 2021-04-27 国立研究开发法人产业技术综合研究所 非水电解质镁系二次电池
CN106916173B (zh) * 2015-12-28 2019-03-08 中国科学院苏州纳米技术与纳米仿生研究所 单核镁阳离子化盐、其制备方法及应用
WO2017113053A1 (zh) * 2015-12-28 2017-07-06 中国科学院苏州纳米技术与纳米仿生研究所 单核镁阳离子化盐、其制备方法及应用
TWI735558B (zh) * 2016-04-01 2021-08-11 日商富士軟片和光純藥股份有限公司 含有鎂離子的電解液
US10862169B2 (en) * 2016-05-27 2020-12-08 Fujifilm Wako Pure Chemical Corporation Phosphorus electrolytic solution containing magnesium ions
CN105932326A (zh) * 2016-06-20 2016-09-07 江苏瀚海芯云网络科技有限公司 一种镁电池的制备工艺
JP6775209B1 (ja) * 2018-12-05 2020-10-28 パナソニックＩｐマネジメント株式会社 マグネシウム二次電池用非水電解液及びそれを用いたマグネシウム二次電池
WO2021005249A1 (es) * 2019-07-10 2021-01-14 Buendia Mellado Andres Batería secundaria de doble electrolito de magnesio/cobre
JP7710197B2 (ja) * 2019-11-22 2025-07-18 パナソニックＩｐマネジメント株式会社 マグネシウム二次電池及びマグネシウム二次電池用非水電解液
US11929462B2 (en) 2020-01-21 2024-03-12 Utah State University Stable, non-corrosive electrolyte with high performance for rechargeable ion batteries
CN111564591B (zh) * 2020-04-30 2021-10-26 北京航空航天大学 一种锂金属电池隔膜改性浆料及其应用
CN118352606A (zh) * 2024-04-17 2024-07-16 苏州科技大学 一种镁二次电池电解液及其制备方法和应用
CN120545570B (zh) * 2025-07-28 2025-10-17 东北大学 一种镁电池稀土氯化物电解液及其制备方法与使用方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1411083A (zh) * 2002-11-01 2003-04-16 南开大学 可充镁电池
CN1905251A (zh) * 2006-03-01 2007-01-31 南开大学 镁二次电池

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2464685A (en) * 1946-12-02 1949-03-15 Diamond Alkali Co Continuous grignard method
US4894302A (en) 1985-06-14 1990-01-16 The Dow Chemical Company Alkaline earth metal anode-containing cell having electrolyte of organometallic alkaline earth metal salt and organic solvent
US5491039A (en) * 1994-02-04 1996-02-13 Shackle; Dale R. Solid electrolytes including organometallic ion salts and electrolytic cells produced therefrom
JP4370638B2 (ja) 1999-06-04 2009-11-25 ソニー株式会社 非水電解質電池
US6316141B1 (en) 1999-10-18 2001-11-13 Bar Ilan University High-energy, rechargeable, electrochemical cells with non-aqueous electrolytes
JP3737729B2 (ja) * 2001-09-26 2006-01-25 株式会社東芝 非水電解液電池および非水電解液
JP2004265677A (ja) * 2003-02-28 2004-09-24 Sanyo Electric Co Ltd 非水電解質電池
JP2004213991A (ja) * 2002-12-27 2004-07-29 Sanyo Electric Co Ltd 非水電池用電解質及びその製造方法並びに非水電池用電解液
JP2004259650A (ja) 2003-02-27 2004-09-16 Kanegafuchi Chem Ind Co Ltd マグネシウム二次電池
JP4839573B2 (ja) 2004-02-13 2011-12-21 ソニー株式会社 電気化学デバイス及び電極
JP5162822B2 (ja) 2005-12-02 2013-03-13 ソニー株式会社 電気化学デバイス
JP5076321B2 (ja) * 2006-01-12 2012-11-21 ソニー株式会社 電池
JP4984535B2 (ja) 2006-01-12 2012-07-25 ソニー株式会社 電池
JP2007234580A (ja) 2006-02-02 2007-09-13 Sony Corp 色素増感型光電変換装置
US9012072B2 (en) * 2007-01-25 2015-04-21 Bar-Ilan University Rechargeable magnesium battery
JP5034799B2 (ja) 2007-09-07 2012-09-26 ソニー株式会社 マグネシウムイオン含有非水電解液及びその製造方法、並びに電気化学デバイス
JP5320710B2 (ja) 2007-09-07 2013-10-23 ソニー株式会社 正極活物質及びその製造方法、並びに電気化学デバイス
JP2011236104A (ja) 2010-05-13 2011-11-24 Sony Corp 酸化チタン構造体及びその製造方法、並びに酸化チタン構造体を用いた光電変換装置

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1411083A (zh) * 2002-11-01 2003-04-16 南开大学 可充镁电池
CN1905251A (zh) * 2006-03-01 2007-01-31 南开大学 镁二次电池

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
焦丽芳等."可充镁电池有机电解液Mg(SnPh3)2的研究".《化学通报》.2005,第2005年卷(第9期),第714~717页.

Also Published As

Publication number Publication date
CN101689680A (zh) 2010-03-31
KR20100039295A (ko) 2010-04-15
JP5245108B2 (ja) 2013-07-24
US8993178B2 (en) 2015-03-31
EP2169755A1 (en) 2010-03-31
EP2169755B1 (en) 2014-05-07
KR101495938B1 (ko) 2015-02-25
WO2009008232A1 (ja) 2009-01-15
US20100136438A1 (en) 2010-06-03
EP2169755A4 (en) 2012-11-21
JP2009021085A (ja) 2009-01-29

Similar Documents

Publication Publication Date Title
CN101689680B (zh) 含有镁离子的非水性电解质及其制备方法以及电化学装置
Dong et al. Hydrotropic solubilization of zinc acetates for sustainable aqueous battery electrolytes
Shao et al. Coordination chemistry in magnesium battery electrolytes: how ligands affect their performance
Keyzer et al. Mg (PF6) 2-based electrolyte systems: Understanding electrolyte–electrode interactions for the development of Mg-ion batteries
CN103715455B (zh) 电解液、电解液的制造方法、以及电化学装置
RU2479077C2 (ru) Неводный электролитический раствор, содержащий ионы магния, и электрохимическое устройство с использованием этого раствора
Yoo et al. Mg rechargeable batteries: an on-going challenge
Sun et al. Non-passivating anion adsorption enables reversible magnesium redox in simple non-nucleophilic electrolytes
Xu et al. Unravelling rechargeable zinc-copper batteries by a chloride shuttle in a biphasic electrolyte
Hosaka et al. KFSA/glyme electrolytes for 4 V-class K-ion batteries
Yoo et al. Enhanced cycle stability of rechargeable Li–O2 batteries by the synergy effect of a LiF protective layer on the Li and DMTFA additive
CN103490094A (zh) 用于镁电池的电解液及含有该电解液的镁电池
JP2002110235A (ja) 電気化学ディバイス用電解質及びそれを用いた電池
Meng et al. Air-stable binary hydrated eutectic electrolytes with unique solvation structure for rechargeable aluminum-ion batteries
CN104737353B (zh) 电极体和具备该电极体的电池
JP5076321B2 (ja) 電池
Tatara et al. Structures and electrochemistry of γ-butyrolactone solvates of Na salts
Li et al. Integrating electric ambipolar effect for high-performance zinc bromide batteries
JP4984535B2 (ja) 電池
Sato et al. Improved Non-Grignard Electrolyte Based on Magnesium Borate Trichloride for Rechargeable Magnesium Batteries
Hu et al. Cost-Effective Rechargeable Magnesium Battery Based on a Fluorinated Alkoxyaluminate Electrolyte and a Carbonyl Polymer Cathode
Gofer et al. Electrolytic solutions for rechargeable magnesium batteries
US10147969B2 (en) Electrolytic solution for electrochemical devices and electrochemical device in which the electrolytic solution is used
Matsui Mg Stripping and Plating at Magnesium Metal and Intermetallic Anodes

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20180419

Address after: Kyoto Japan

Patentee after: Murata Manufacturing Co.,Ltd.

Address before: Fukushima

Patentee before: Murata, Northeast China

Effective date of registration: 20180419

Address after: Fukushima

Patentee after: Murata, Northeast China

Address before: Tokyo, Japan

Patentee before: Sony Corp.