CN101497682A - 聚硅氧烷(甲基)丙烯酸酯颗粒、其制备方法和用途 - Google Patents
聚硅氧烷(甲基)丙烯酸酯颗粒、其制备方法和用途 Download PDFInfo
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- CN101497682A CN101497682A CNA2008101909853A CN200810190985A CN101497682A CN 101497682 A CN101497682 A CN 101497682A CN A2008101909853 A CNA2008101909853 A CN A2008101909853A CN 200810190985 A CN200810190985 A CN 200810190985A CN 101497682 A CN101497682 A CN 101497682A
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- polysiloxane
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- acrylate
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- 239000002245 particle Substances 0.000 title claims abstract description 149
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 121
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title claims abstract description 63
- 238000000034 method Methods 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 230000008569 process Effects 0.000 title claims description 31
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- 239000006185 dispersion Substances 0.000 claims abstract description 30
- 239000003999 initiator Substances 0.000 claims abstract description 25
- 239000002537 cosmetic Substances 0.000 claims abstract description 20
- 239000012074 organic phase Substances 0.000 claims abstract description 19
- 239000012071 phase Substances 0.000 claims abstract description 19
- 229920000642 polymer Polymers 0.000 claims abstract description 18
- 239000007787 solid Substances 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000008346 aqueous phase Substances 0.000 claims abstract description 14
- 239000000049 pigment Substances 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 10
- 238000004140 cleaning Methods 0.000 claims abstract description 8
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 8
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- 125000000217 alkyl group Chemical group 0.000 claims description 7
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 44
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- 238000009472 formulation Methods 0.000 description 11
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 10
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 10
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
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- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
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- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
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- A61K8/062—Oil-in-water emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C09D151/085—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds on to polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/08—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C09J151/085—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds on to polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
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- Chemical & Material Sciences (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
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- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Cosmetics (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
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Applications Claiming Priority (2)
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| DE200710058713 DE102007058713A1 (de) | 2007-12-06 | 2007-12-06 | Silicon(meth-)acrylat-Partikel, Verfahren zu deren Herstellung sowie deren Verwendung |
| DE102007058713.0 | 2007-12-06 |
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| CN101497682A true CN101497682A (zh) | 2009-08-05 |
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| US (1) | US8653214B2 (enExample) |
| EP (1) | EP2067811B1 (enExample) |
| JP (1) | JP5590539B2 (enExample) |
| CN (1) | CN101497682A (enExample) |
| CA (1) | CA2645956C (enExample) |
| DE (1) | DE102007058713A1 (enExample) |
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| JP2003002973A (ja) | 2001-04-18 | 2003-01-08 | Ge Toshiba Silicones Co Ltd | 球状シリコーン微粒子の製造方法 |
| JP5127100B2 (ja) | 2001-04-26 | 2013-01-23 | 東レ・ダウコーニング株式会社 | 硬化性シリコーン組成物の水性エマルジョンの製造方法、その製造装置および硬化シリコーン粒状物の懸濁液の製造方法 |
| JP3925629B2 (ja) | 2002-04-10 | 2007-06-06 | 信越化学工業株式会社 | シリコーンエラストマー球状粉末の製造方法 |
| JP4289881B2 (ja) | 2002-12-27 | 2009-07-01 | 東レ・ダウコーニング株式会社 | 複合シリコーンゴム粒子およびその製造方法 |
| DE10359764A1 (de) * | 2003-12-19 | 2005-07-14 | Goldschmidt Ag | Polysiloxane mit über SiOC-Gruppen gebundenen (Meth)acrylsäureestergruppen, Verfahren zu deren Herstellung sowie deren Verwendung als strahlenhärtbare abhäsive Beschichtung |
| DE102004014704A1 (de) | 2004-03-25 | 2005-10-13 | Wacker-Chemie Gmbh | Partikelstabilisierte Emulsionen |
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| DE102004024009A1 (de) * | 2004-05-14 | 2005-12-01 | Goldschmidt Gmbh | Verwendung von neuen Polysiloxanen mit über SiOC-Gruppen gebundenen (Meth)acrylsäureestergruppen als Additive für strahlenhärtende Beschichtungen |
| WO2006016968A1 (en) | 2004-07-07 | 2006-02-16 | Dow Corning Corporation | Emulsions of organopolysiloxane resins produced by emulsion polymerization |
| DE102004034740A1 (de) * | 2004-07-17 | 2006-02-02 | Goldschmidt Gmbh | Polysiloxane mit über SiOC-Gruppen gebundenen (Meth)arcylsäureestergruppen und fluorierten Resten sowie deren Verwendung als strahlenhärtbare abhäsive Beschichtung |
| JP2006070378A (ja) * | 2004-09-01 | 2006-03-16 | Toray Ind Inc | ニット生地 |
| DE102004047708A1 (de) | 2004-09-30 | 2006-04-06 | Wacker Chemie Ag | Kern-Schalepartikel enthaltende Zusammensetzung und ihre Herstellung |
| DE102004053314A1 (de) | 2004-11-04 | 2006-05-11 | Wacker Chemie Ag | Verfahren zur Herstellung von mit Silikon modifizierten Polymerisaten |
| DE102005001040B4 (de) * | 2005-01-07 | 2017-06-22 | Evonik Degussa Gmbh | Mehrfachfunktionelle Polysiloxane mit über SiOC-Gruppen gebundenen (Meth)acrylsäureestergruppen und einem unmodifizierten Polysiloxan-Block, Verfahren zu deren Herstellung sowie deren Verwendung als strahlenhärtbare abhäsive Beschichtung |
| DE102005011785A1 (de) | 2005-03-11 | 2006-09-21 | Goldschmidt Gmbh | Langzeitstabile kosmetische Emulsionen |
| DE102006009841A1 (de) | 2006-03-01 | 2007-09-06 | Röhm Gmbh | Additive Baustoffmischungen mit quellbaren Polymergebilden |
| DE102006041971A1 (de) | 2006-09-07 | 2008-03-27 | Evonik Goldschmidt Gmbh | Verwendung von partikulären Emulgatoren in abhäsiven siloxanhaltigen Beschichtungsmassen |
-
2007
- 2007-12-06 DE DE200710058713 patent/DE102007058713A1/de not_active Withdrawn
-
2008
- 2008-10-06 EP EP08165900.5A patent/EP2067811B1/de not_active Not-in-force
- 2008-12-03 JP JP2008308124A patent/JP5590539B2/ja not_active Expired - Fee Related
- 2008-12-03 US US12/327,175 patent/US8653214B2/en not_active Expired - Fee Related
- 2008-12-05 CA CA2645956A patent/CA2645956C/en not_active Expired - Fee Related
- 2008-12-05 CN CNA2008101909853A patent/CN101497682A/zh active Pending
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| CN110121363A (zh) * | 2016-11-30 | 2019-08-13 | 诺克森制药有限公司 | 核酸的聚烷氧基化方法,其能够回收和再利用过量的聚烷氧基化试剂 |
| CN110121363B (zh) * | 2016-11-30 | 2023-08-29 | Tme制药股份公司 | 核酸的聚烷氧基化方法,其能够回收和再利用过量的聚烷氧基化试剂 |
| CN112512658B (zh) * | 2018-08-15 | 2022-03-22 | 瓦克化学股份公司 | 硅酮消泡剂组合物及用于通过调整ζ电势分布宽度生产硅酮消泡剂组合物的方法 |
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| CN110205821A (zh) * | 2019-06-20 | 2019-09-06 | 广州百思创科技有限公司 | 一种绿色无氟防水整理剂及其在纤维制品中的应用 |
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| CN114133688A (zh) * | 2021-11-29 | 2022-03-04 | 华南理工大学 | 改性水性有机硅氧烷-丙烯酸酯杂化树脂及其制备与应用 |
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| CN118772855A (zh) * | 2023-04-06 | 2024-10-15 | 中国石油化工股份有限公司 | 一种微纳米胶囊、其制备方法及含有其的缓释凝胶 |
| CN118772855B (zh) * | 2023-04-06 | 2025-09-26 | 中国石油化工股份有限公司 | 一种微纳米胶囊、其制备方法及含有其的缓释凝胶 |
| CN117265875A (zh) * | 2023-08-07 | 2023-12-22 | 北京马普新材料有限公司 | 处理剂及纤维织物或涂料 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102007058713A1 (de) | 2009-06-10 |
| CA2645956A1 (en) | 2009-06-06 |
| US8653214B2 (en) | 2014-02-18 |
| EP2067811A1 (de) | 2009-06-10 |
| CA2645956C (en) | 2016-07-05 |
| JP2009149880A (ja) | 2009-07-09 |
| US20090149573A1 (en) | 2009-06-11 |
| JP5590539B2 (ja) | 2014-09-17 |
| EP2067811B1 (de) | 2018-09-26 |
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