CN100530813C - 锂电池处理方法 - Google Patents
锂电池处理方法 Download PDFInfo
- Publication number
- CN100530813C CN100530813C CNB2005800205602A CN200580020560A CN100530813C CN 100530813 C CN100530813 C CN 100530813C CN B2005800205602 A CNB2005800205602 A CN B2005800205602A CN 200580020560 A CN200580020560 A CN 200580020560A CN 100530813 C CN100530813 C CN 100530813C
- Authority
- CN
- China
- Prior art keywords
- lithium
- positive electrode
- oxalic acid
- transition metal
- acid solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 200
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 198
- 238000000034 method Methods 0.000 title claims abstract description 75
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 505
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 168
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 123
- 150000003624 transition metals Chemical class 0.000 claims abstract description 123
- 239000007774 positive electrode material Substances 0.000 claims abstract description 115
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 74
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 60
- 239000010949 copper Substances 0.000 claims description 59
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 39
- 229910052802 copper Inorganic materials 0.000 claims description 38
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 37
- 229910052759 nickel Inorganic materials 0.000 claims description 35
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 34
- 239000002253 acid Substances 0.000 claims description 33
- 238000010438 heat treatment Methods 0.000 claims description 33
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 32
- 239000002131 composite material Substances 0.000 claims description 30
- 229910052782 aluminium Inorganic materials 0.000 claims description 27
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 25
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 23
- 239000003792 electrolyte Substances 0.000 claims description 22
- 238000000926 separation method Methods 0.000 claims description 22
- 230000008569 process Effects 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 18
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 17
- 125000006850 spacer group Chemical group 0.000 claims description 17
- QXDMQSPYEZFLGF-UHFFFAOYSA-L calcium oxalate Chemical compound [Ca+2].[O-]C(=O)C([O-])=O QXDMQSPYEZFLGF-UHFFFAOYSA-L 0.000 claims description 16
- 229910017052 cobalt Inorganic materials 0.000 claims description 16
- 239000010941 cobalt Substances 0.000 claims description 16
- 238000001556 precipitation Methods 0.000 claims description 16
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 10
- 239000001569 carbon dioxide Substances 0.000 claims description 10
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 10
- 238000004090 dissolution Methods 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 6
- 239000000920 calcium hydroxide Substances 0.000 claims description 6
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 6
- GBPZIFLFRULNBM-UHFFFAOYSA-N lithium;oxalic acid Chemical compound [Li].OC(=O)C(O)=O GBPZIFLFRULNBM-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 169
- 238000010306 acid treatment Methods 0.000 abstract description 49
- 238000006243 chemical reaction Methods 0.000 abstract description 41
- 238000001914 filtration Methods 0.000 abstract description 20
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 239000002905 metal composite material Substances 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 146
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 57
- 229910052751 metal Inorganic materials 0.000 description 38
- 238000012545 processing Methods 0.000 description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 37
- 239000007789 gas Substances 0.000 description 36
- 238000011084 recovery Methods 0.000 description 36
- 239000003960 organic solvent Substances 0.000 description 29
- 239000002994 raw material Substances 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 28
- 239000000203 mixture Substances 0.000 description 27
- 150000001875 compounds Chemical class 0.000 description 26
- 239000000706 filtrate Substances 0.000 description 26
- 238000003672 processing method Methods 0.000 description 26
- 238000001816 cooling Methods 0.000 description 19
- 239000008151 electrolyte solution Substances 0.000 description 18
- 239000006229 carbon black Substances 0.000 description 17
- 239000000470 constituent Substances 0.000 description 17
- YNQRWVCLAIUHHI-UHFFFAOYSA-L dilithium;oxalate Chemical compound [Li+].[Li+].[O-]C(=O)C([O-])=O YNQRWVCLAIUHHI-UHFFFAOYSA-L 0.000 description 17
- 150000002500 ions Chemical class 0.000 description 16
- 229910000314 transition metal oxide Inorganic materials 0.000 description 16
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 15
- 230000000694 effects Effects 0.000 description 14
- 235000011121 sodium hydroxide Nutrition 0.000 description 14
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 13
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 13
- -1 polytetrafluoroethylene Polymers 0.000 description 13
- 239000002244 precipitate Substances 0.000 description 13
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- 238000009835 boiling Methods 0.000 description 12
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 12
- 239000004810 polytetrafluoroethylene Substances 0.000 description 12
- 239000007864 aqueous solution Substances 0.000 description 11
- 229910052799 carbon Inorganic materials 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- 239000002904 solvent Substances 0.000 description 11
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- 235000011114 ammonium hydroxide Nutrition 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 238000000354 decomposition reaction Methods 0.000 description 10
- 229910001416 lithium ion Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 239000004411 aluminium Substances 0.000 description 9
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 9
- 239000007791 liquid phase Substances 0.000 description 9
- 150000003891 oxalate salts Chemical class 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- 239000006183 anode active material Substances 0.000 description 8
- 239000013049 sediment Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000011877 solvent mixture Substances 0.000 description 8
- 229910013716 LiNi Inorganic materials 0.000 description 7
- 239000005030 aluminium foil Substances 0.000 description 7
- 239000012298 atmosphere Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000002349 favourable effect Effects 0.000 description 7
- 150000002736 metal compounds Chemical class 0.000 description 7
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 6
- 239000004020 conductor Substances 0.000 description 6
- 230000006837 decompression Effects 0.000 description 6
- 230000001105 regulatory effect Effects 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000011149 active material Substances 0.000 description 5
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 5
- 150000001340 alkali metals Chemical class 0.000 description 5
- 238000000975 co-precipitation Methods 0.000 description 5
- 239000011889 copper foil Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical class CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 150000002642 lithium compounds Chemical class 0.000 description 5
- 238000006386 neutralization reaction Methods 0.000 description 5
- 239000011368 organic material Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 238000003466 welding Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 229910013870 LiPF 6 Inorganic materials 0.000 description 4
- 241000080590 Niso Species 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 4
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 150000001879 copper Chemical class 0.000 description 4
- 239000011258 core-shell material Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 239000007773 negative electrode material Substances 0.000 description 4
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 238000005191 phase separation Methods 0.000 description 4
- OBCUTHMOOONNBS-UHFFFAOYSA-N phosphorus pentafluoride Chemical compound FP(F)(F)(F)F OBCUTHMOOONNBS-UHFFFAOYSA-N 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 229910001428 transition metal ion Inorganic materials 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 229910017709 Ni Co Inorganic materials 0.000 description 3
- 229910003267 Ni-Co Inorganic materials 0.000 description 3
- 229910003262 Ni‐Co Inorganic materials 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- MULYSYXKGICWJF-UHFFFAOYSA-L cobalt(2+);oxalate Chemical class [Co+2].[O-]C(=O)C([O-])=O MULYSYXKGICWJF-UHFFFAOYSA-L 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
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- 229930195733 hydrocarbon Natural products 0.000 description 3
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- 229910052749 magnesium Inorganic materials 0.000 description 3
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- DOLZKNFSRCEOFV-UHFFFAOYSA-L nickel(2+);oxalate Chemical class [Ni+2].[O-]C(=O)C([O-])=O DOLZKNFSRCEOFV-UHFFFAOYSA-L 0.000 description 3
- NICDRCVJGXLKSF-UHFFFAOYSA-N nitric acid;trihydrochloride Chemical compound Cl.Cl.Cl.O[N+]([O-])=O NICDRCVJGXLKSF-UHFFFAOYSA-N 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 229910015724 LiNi0.85Co0.15O2 Inorganic materials 0.000 description 2
- 229910013872 LiPF Inorganic materials 0.000 description 2
- 101150058243 Lipf gene Proteins 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
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- 239000011230 binding agent Substances 0.000 description 2
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- PNEFIWYZWIQKEK-UHFFFAOYSA-N carbonic acid;lithium Chemical compound [Li].OC(O)=O PNEFIWYZWIQKEK-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 description 2
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
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- 238000007654 immersion Methods 0.000 description 2
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- 229910052738 indium Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
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- 239000002932 luster Substances 0.000 description 2
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- 229910052718 tin Inorganic materials 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
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- 229910052726 zirconium Inorganic materials 0.000 description 2
- SPEUIVXLLWOEMJ-UHFFFAOYSA-N 1,1-dimethoxyethane Chemical compound COC(C)OC SPEUIVXLLWOEMJ-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- 125000006091 1,3-dioxolane group Chemical class 0.000 description 1
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 1
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- 102000020856 Copper Transport Proteins Human genes 0.000 description 1
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- 206010013786 Dry skin Diseases 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
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- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
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- GJYLKIZKRHDRER-UHFFFAOYSA-N calcium;sulfuric acid Chemical compound [Ca].OS(O)(=O)=O GJYLKIZKRHDRER-UHFFFAOYSA-N 0.000 description 1
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- SXGDIBYXFSKCRM-UHFFFAOYSA-L dilithium hydrogen carbonate hydroxide Chemical compound [OH-].[Li+].C([O-])(O)=O.[Li+] SXGDIBYXFSKCRM-UHFFFAOYSA-L 0.000 description 1
- 238000011438 discrete method Methods 0.000 description 1
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- PQVSTLUFSYVLTO-UHFFFAOYSA-N ethyl n-ethoxycarbonylcarbamate Chemical compound CCOC(=O)NC(=O)OCC PQVSTLUFSYVLTO-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
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- 150000002641 lithium Chemical class 0.000 description 1
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 1
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium hydroxide monohydrate Substances [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 description 1
- 229940040692 lithium hydroxide monohydrate Drugs 0.000 description 1
- VROAXDSNYPAOBJ-UHFFFAOYSA-N lithium;oxido(oxo)nickel Chemical compound [Li+].[O-][Ni]=O VROAXDSNYPAOBJ-UHFFFAOYSA-N 0.000 description 1
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- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical group [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
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- H01M10/54—Reclaiming serviceable parts of waste accumulators
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- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
- C22B26/12—Obtaining lithium
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- C—CHEMISTRY; METALLURGY
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- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
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- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/16—Extraction of metal compounds from ores or concentrates by wet processes by leaching in organic solutions
- C22B3/1608—Leaching with acyclic or carbocyclic agents
- C22B3/1616—Leaching with acyclic or carbocyclic agents of a single type
- C22B3/165—Leaching with acyclic or carbocyclic agents of a single type with organic acids
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- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
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- C—CHEMISTRY; METALLURGY
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- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
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- H01M10/058—Construction or manufacture
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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| JP2004182938A JP4492222B2 (ja) | 2004-06-21 | 2004-06-21 | リチウム電池処理方法 |
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Cited By (3)
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| CN103443996A (zh) * | 2011-03-23 | 2013-12-11 | 丰田自动车株式会社 | 用于电池组的回收方法和处理装置 |
| CN105144464A (zh) * | 2013-03-29 | 2015-12-09 | 三菱综合材料株式会社 | 含氟电解液的处理方法 |
| CN108448193A (zh) * | 2017-01-25 | 2018-08-24 | 株式会社Lg化学 | 从锂二次电池回收正极活性材料的方法 |
Families Citing this family (84)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| US11316214B2 (en) * | 2019-12-20 | 2022-04-26 | Yau Fu Industry Co., Ltd. | Waste lithium battery recovery system |
| JP7242581B2 (ja) * | 2020-01-22 | 2023-03-20 | Ｊｘ金属株式会社 | リチウムイオン電池の処理方法 |
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| WO2024089266A1 (de) * | 2022-10-28 | 2024-05-02 | Kyburz Switzerland Ag | Verfahren und vorrichtung zum recyclieren von lithium-ionen-batterien |
| CN115566307B (zh) * | 2022-11-15 | 2023-03-24 | 湖南五创循环科技有限公司 | 从废旧锂电中回收高纯草酸锂和高纯氢氧化锂的方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5714129A (en) * | 1993-04-01 | 1998-02-03 | Hitachi, Ltd. | Lithium cell treating method |
| JPH09111360A (ja) * | 1995-10-17 | 1997-04-28 | Tama Kagaku Kogyo Kk | 二次電池廃材からのコバルト回収方法 |
| JPH09195071A (ja) * | 1996-01-16 | 1997-07-29 | Tama Kagaku Kogyo Kk | 二次電池の金属箔塗着廃材からの金属箔剥離方法 |
| JPH10255862A (ja) * | 1997-03-14 | 1998-09-25 | Toshiba Corp | リチウムイオン二次電池からの有価物分離方法 |
| JPH116020A (ja) | 1997-06-18 | 1999-01-12 | Nisso Kinzoku Kagaku Kk | リチウムイオン電池廃材からの高純度コバルト化合物の回収法 |
| JP3452769B2 (ja) * | 1997-09-18 | 2003-09-29 | 株式会社東芝 | 電池の処理方法 |
| JPH11293356A (ja) * | 1998-04-14 | 1999-10-26 | Hiroyuki Nakazawa | コバルト酸リチウムの溶解方法 |
| JP2002198103A (ja) * | 2000-12-22 | 2002-07-12 | Toshiba Electronic Engineering Corp | 電極構成金属の回収方法 |
| KR100448273B1 (ko) * | 2002-02-25 | 2004-09-10 | 한국지질자원연구원 | 폐리튬이온전지로부터 코발트를 회수하는 방법 |
-
2004
- 2004-06-21 JP JP2004182938A patent/JP4492222B2/ja not_active Expired - Fee Related
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2005
- 2005-06-14 CN CNB2005800205602A patent/CN100530813C/zh not_active Expired - Fee Related
- 2005-06-14 KR KR1020077001443A patent/KR100832900B1/ko not_active IP Right Cessation
- 2005-06-14 US US11/630,158 patent/US20080050295A1/en not_active Abandoned
- 2005-06-14 EP EP05751353A patent/EP1760821A4/en not_active Withdrawn
- 2005-06-14 WO PCT/JP2005/011209 patent/WO2005124921A1/ja active Application Filing
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103443996A (zh) * | 2011-03-23 | 2013-12-11 | 丰田自动车株式会社 | 用于电池组的回收方法和处理装置 |
| CN103443996B (zh) * | 2011-03-23 | 2015-12-09 | 丰田自动车株式会社 | 用于电池组的回收方法和处理装置 |
| US9509025B2 (en) | 2011-03-23 | 2016-11-29 | Toyota Jidosha Kabushiki Kaisha | Recycling method and treatment device for battery pack |
| CN105144464A (zh) * | 2013-03-29 | 2015-12-09 | 三菱综合材料株式会社 | 含氟电解液的处理方法 |
| US9843077B2 (en) | 2013-03-29 | 2017-12-12 | Mitsubishi Materials Corporation | Method for processing fluorine-containing electrolyte solution |
| CN105144464B (zh) * | 2013-03-29 | 2018-03-27 | 三菱综合材料株式会社 | 含氟电解液的处理方法 |
| CN108448193A (zh) * | 2017-01-25 | 2018-08-24 | 株式会社Lg化学 | 从锂二次电池回收正极活性材料的方法 |
| CN108448193B (zh) * | 2017-01-25 | 2021-04-02 | 株式会社Lg化学 | 从锂二次电池回收正极活性材料的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1760821A1 (en) | 2007-03-07 |
| JP4492222B2 (ja) | 2010-06-30 |
| EP1760821A4 (en) | 2009-05-20 |
| KR20070033440A (ko) | 2007-03-26 |
| JP2006004883A (ja) | 2006-01-05 |
| WO2005124921A1 (ja) | 2005-12-29 |
| KR100832900B1 (ko) | 2008-05-28 |
| CN1973399A (zh) | 2007-05-30 |
| US20080050295A1 (en) | 2008-02-28 |
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