CN100491242C - 一种活性碳金属氧化物基质及其制备方法 - Google Patents
一种活性碳金属氧化物基质及其制备方法 Download PDFInfo
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- CN100491242C CN100491242C CNB018204147A CN01820414A CN100491242C CN 100491242 C CN100491242 C CN 100491242C CN B018204147 A CNB018204147 A CN B018204147A CN 01820414 A CN01820414 A CN 01820414A CN 100491242 C CN100491242 C CN 100491242C
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- Prior art keywords
- carbon
- oxide
- metal
- metal oxide
- activated carbon
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N activated carbon Substances [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 138
- 229910044991 metal oxide Inorganic materials 0.000 title claims abstract description 63
- 239000011159 matrix material Substances 0.000 title claims abstract description 61
- 238000000034 method Methods 0.000 title claims abstract description 42
- -1 Activated carbon metal oxide Chemical class 0.000 title claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 56
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 46
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 36
- 150000001875 compounds Chemical class 0.000 claims abstract description 21
- 239000007789 gas Substances 0.000 claims abstract description 21
- 239000012855 volatile organic compound Substances 0.000 claims abstract description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 50
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 46
- 229910052751 metal Inorganic materials 0.000 claims description 44
- 239000002184 metal Substances 0.000 claims description 42
- 238000010521 absorption reaction Methods 0.000 claims description 26
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 229910052788 barium Inorganic materials 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000010865 sewage Substances 0.000 claims description 4
- 239000005864 Sulphur Substances 0.000 claims 3
- 239000000203 mixture Substances 0.000 abstract description 33
- 239000000463 material Substances 0.000 abstract description 7
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- 238000010000 carbonizing Methods 0.000 abstract description 2
- 230000002378 acidificating effect Effects 0.000 abstract 1
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- 238000001994 activation Methods 0.000 description 8
- 230000004913 activation Effects 0.000 description 8
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- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
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- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
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- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
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- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
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- 206010033799 Paralysis Diseases 0.000 description 1
- 206010037423 Pulmonary oedema Diseases 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
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- MIMQPJVJUKWCAV-UHFFFAOYSA-N [C].S Chemical compound [C].S MIMQPJVJUKWCAV-UHFFFAOYSA-N 0.000 description 1
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- 229910052790 beryllium Inorganic materials 0.000 description 1
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- 239000003245 coal Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
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- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 1
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- 229910002804 graphite Inorganic materials 0.000 description 1
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- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
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- 239000007788 liquid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- 229910052750 molybdenum Inorganic materials 0.000 description 1
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- 210000005036 nerve Anatomy 0.000 description 1
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- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
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- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 1
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- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
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- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
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- 239000010937 tungsten Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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- Public Health (AREA)
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- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
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Abstract
Description
Claims (24)
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US25490000P | 2000-12-11 | 2000-12-11 | |
US60/254,900 | 2000-12-11 |
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WO1996029099A1 (fr) | 1995-03-23 | 1996-09-26 | Toto Ltd. | Procede de desodorisation, desodorisant, procede d'elaboration du desodorisant, et equipement de desodorisation |
TW458807B (en) | 1995-05-26 | 2001-10-11 | Hitachi Chemical Co Ltd | Material for removing environmental pollution substances |
JPH09173829A (ja) * | 1995-12-26 | 1997-07-08 | Nippon Chem Ind Co Ltd | 空気浄化剤および空気浄化用フィルター |
JPH09192485A (ja) * | 1996-01-22 | 1997-07-29 | Kuraray Chem Corp | 金属酸化物担持活性炭成型体 |
EP0894530B1 (en) | 1997-07-28 | 2003-09-10 | Corning Incorporated | Mercury removal catalyst and method of making and using same |
EP1341719B1 (en) | 2000-12-11 | 2014-07-09 | Evoqua Water Technologies LLC | Activated carbon for odor control and method for making same |
-
2001
- 2001-12-11 EP EP01995487.4A patent/EP1341719B1/en not_active Expired - Lifetime
- 2001-12-11 EP EP10183312A patent/EP2289609A1/en not_active Withdrawn
- 2001-12-11 WO PCT/US2001/047641 patent/WO2002048032A2/en active Application Filing
- 2001-12-11 US US10/014,848 patent/US6858192B2/en not_active Expired - Fee Related
- 2001-12-11 JP JP2002549574A patent/JP2004515355A/ja active Pending
- 2001-12-11 CN CNB018204147A patent/CN100491242C/zh not_active Expired - Fee Related
- 2001-12-11 MX MXPA03005180A patent/MXPA03005180A/es active IP Right Grant
- 2001-12-11 CA CA2431314A patent/CA2431314C/en not_active Expired - Fee Related
- 2001-12-11 AU AU2002226066A patent/AU2002226066A1/en not_active Abandoned
-
2004
- 2004-12-09 US US11/008,449 patent/US7022269B2/en not_active Expired - Lifetime
- 2004-12-13 HK HK04109855.1A patent/HK1067613A1/xx not_active IP Right Cessation
-
2006
- 2006-03-29 US US11/392,169 patent/US7241430B2/en not_active Expired - Lifetime
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2007
- 2007-07-09 US US11/825,843 patent/US7563311B2/en not_active Expired - Lifetime
Also Published As
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WO2002048032A3 (en) | 2002-10-24 |
US7563311B2 (en) | 2009-07-21 |
MXPA03005180A (es) | 2004-10-14 |
US6858192B2 (en) | 2005-02-22 |
US7022269B2 (en) | 2006-04-04 |
US20060162558A1 (en) | 2006-07-27 |
US7241430B2 (en) | 2007-07-10 |
US20020082168A1 (en) | 2002-06-27 |
EP1341719A2 (en) | 2003-09-10 |
AU2002226066A1 (en) | 2002-06-24 |
US20080006157A1 (en) | 2008-01-10 |
CN1505592A (zh) | 2004-06-16 |
WO2002048032A2 (en) | 2002-06-20 |
EP2289609A1 (en) | 2011-03-02 |
JP2004515355A (ja) | 2004-05-27 |
US20050100491A1 (en) | 2005-05-12 |
CA2431314A1 (en) | 2002-06-20 |
CA2431314C (en) | 2010-04-20 |
HK1067613A1 (en) | 2005-04-15 |
EP1341719B1 (en) | 2014-07-09 |
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