CN100379784C - 高生产率的斯潘德克斯弹性纤维生产方法和产品 - Google Patents

高生产率的斯潘德克斯弹性纤维生产方法和产品 Download PDF

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Publication number
CN100379784C
CN100379784C CNB2004800120347A CN200480012034A CN100379784C CN 100379784 C CN100379784 C CN 100379784C CN B2004800120347 A CNB2004800120347 A CN B2004800120347A CN 200480012034 A CN200480012034 A CN 200480012034A CN 100379784 C CN100379784 C CN 100379784C
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CN
China
Prior art keywords
glycol
mdi
moles
spandex
spinning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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CNB2004800120347A
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English (en)
Chinese (zh)
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CN1784443A (zh
Inventor
G·W·塞林
N·E·豪泽
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INVISTA TECHNOLOGIES Sarl
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INVISTA TECHNOLOGIES Sarl
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Publication of CN1784443A publication Critical patent/CN1784443A/zh
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Publication of CN100379784C publication Critical patent/CN100379784C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S528/906—Fiber or elastomer prepared from an isocyanate reactant

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Knitting Of Fabric (AREA)
CNB2004800120347A 2003-05-05 2004-03-05 高生产率的斯潘德克斯弹性纤维生产方法和产品 Expired - Lifetime CN100379784C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/430,060 US6916896B2 (en) 2003-05-05 2003-05-05 High productivity spandex fiber process and product
US10/430,060 2003-05-05

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN200810003050XA Division CN101195935B (zh) 2003-05-05 2004-03-05 高生产率的斯潘德克斯弹性纤维生产方法和产品

Publications (2)

Publication Number Publication Date
CN1784443A CN1784443A (zh) 2006-06-07
CN100379784C true CN100379784C (zh) 2008-04-09

Family

ID=33416170

Family Applications (2)

Application Number Title Priority Date Filing Date
CNB2004800120347A Expired - Lifetime CN100379784C (zh) 2003-05-05 2004-03-05 高生产率的斯潘德克斯弹性纤维生产方法和产品
CN200810003050XA Expired - Lifetime CN101195935B (zh) 2003-05-05 2004-03-05 高生产率的斯潘德克斯弹性纤维生产方法和产品

Family Applications After (1)

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CN200810003050XA Expired - Lifetime CN101195935B (zh) 2003-05-05 2004-03-05 高生产率的斯潘德克斯弹性纤维生产方法和产品

Country Status (10)

Country Link
US (1) US6916896B2 (enExample)
EP (1) EP1622958B1 (enExample)
JP (1) JP4764335B2 (enExample)
KR (1) KR101092088B1 (enExample)
CN (2) CN100379784C (enExample)
AT (1) ATE486897T1 (enExample)
BR (1) BRPI0409052B1 (enExample)
DE (1) DE602004029882D1 (enExample)
ES (1) ES2353758T3 (enExample)
WO (1) WO2004099282A1 (enExample)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7838617B2 (en) * 2003-05-05 2010-11-23 Invista North America S.àr.l. Dyeable spandex
KR101322054B1 (ko) 2005-05-09 2013-10-25 인비스타 테크놀러지스 에스.에이.알.엘. 고속 방사용 스판덱스 조성물
JP2008540765A (ja) * 2005-05-09 2008-11-20 インヴィスタ テクノロジー エスアエルエル 高エチレンエーテル含有率を有するポリ（テトラメチレン−コ−エチレンエーテル）グリコールからのスパンデックス
US9441314B2 (en) * 2005-11-22 2016-09-13 Invista North America S.A.R.L. Spandex from high molecular weight poly (tetramethylene-co-ethyleneether) glycols
ES2403419T3 (es) * 2005-11-22 2013-05-17 Invista Technologies S.À.R.L. Elastano obtenido a partir de poli(tetrametilén-co-etilén éter)glicoles mezclados con glicoles poliméricos
US20070117949A1 (en) * 2005-11-22 2007-05-24 Palmer Charles F Jr Spandex from poly(tetramethylene-co-ethyleneether) glycols having low ethyleneether content
CN101484496B (zh) * 2006-07-12 2012-06-27 三菱化学株式会社 聚氨酯的制造方法及由该制造方法得到的聚氨酯的用途
AU2008200020B2 (en) * 2007-01-29 2013-07-11 Bayer Intellectual Property Gmbh Polyurethanes cured with amines and their preparation
KR100942359B1 (ko) * 2007-11-06 2010-02-12 주식회사 효성 열세트성이 향상된 폴리우레탄우레아 탄성사의 제조방법
WO2009118112A2 (de) * 2008-03-28 2009-10-01 Bayer Materialscience Ag 2,2'-mdi-basierte isocyanat-mischungen und ihre herstellung sowie verwendung
CN102899740B (zh) * 2012-11-09 2014-05-21 浙江华峰氨纶股份有限公司 一种制备低温定型聚氨酯弹性纤维的方法
WO2014210378A2 (en) * 2013-06-28 2014-12-31 Invista Technologies S.A.R.L. Polyurethaneurea fiber including glycol blend
WO2015088060A1 (ko) * 2013-12-10 2015-06-18 주식회사 효성 열세트성이 향상된 폴리우레탄우레아 탄성사 및 그 제조 방법
WO2015088059A1 (ko) * 2013-12-10 2015-06-18 주식회사 효성 열세트성이 향상된 폴리우레탄우레아 탄성사 및 그 제조 방법
CN103710786B (zh) * 2013-12-18 2015-08-12 浙江华峰氨纶股份有限公司 一种用于高速纺丝的聚氨酯原液的制备方法
CN104153037B (zh) * 2014-08-13 2016-03-02 浙江华峰氨纶股份有限公司 具有吸湿放湿性能的聚氨酯弹性纤维的制备方法
WO2017122879A1 (ko) * 2016-01-15 2017-07-20 (주)효성 해사성 개선 및 핫멜트 접착제와의 접착특성이 향상된 스판덱스 및 이의 제조방법
CN106884332B (zh) * 2017-03-27 2019-01-22 浙江鸿辰新材料科技有限公司 一种聚氨酯弹性丝纤维及其制备方法
WO2019139217A1 (ko) * 2018-01-11 2019-07-18 효성 티앤씨 주식회사 인성이 양호한 폴리우레탄우레아 탄성사 및 그 제조방법
WO2019168807A1 (en) 2018-03-02 2019-09-06 Carbon, Inc. Sustainable additive manufacturing resins and methods of recycling
KR20200024053A (ko) * 2018-08-27 2020-03-06 효성티앤씨 주식회사 염색성이 향상된 폴리우레탄우레아 탄성사
KR20200024054A (ko) * 2018-08-27 2020-03-06 효성티앤씨 주식회사 염색성이 개선된 폴리우레탄우레아 탄성사 및 이의 제조방법
WO2021146237A1 (en) 2020-01-17 2021-07-22 Carbon, Inc. Chemical recycling of additively manufactured objects
JP2023517945A (ja) * 2020-03-11 2023-04-27 ザ ライクラ カンパニー ユーケー リミテッド 目寄れ防止性能を有する弾性繊維、複合ヤーンおよび布地
CN112899809A (zh) * 2021-02-25 2021-06-04 汪宜春 一种耐热高伸长率氨纶纤维生产工艺
CN120882922A (zh) * 2022-05-13 2025-10-31 莱卡有限责任公司 具有改进的低温热定型性的氨纶纤维
EP4306586A1 (en) * 2022-07-11 2024-01-17 Cap Iii B.V. Process for the recovery of spandex and nylon from spandex and nylon comprising materials
WO2025042846A1 (en) * 2023-08-18 2025-02-27 The Lycra Company Llc Recyclable and recycled spandex fibers and method of manufacturing

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3557044A (en) * 1962-06-07 1971-01-19 Du Pont Process for making spandex polymers
JPH08176268A (ja) * 1994-12-26 1996-07-09 Mitsui Toatsu Chem Inc ポリウレタンウレア成形物の製造方法
CN1239971A (zh) * 1996-10-11 1999-12-29 阿科化学技术公司 改进的氨纶弹性体
US6472494B2 (en) * 2000-04-26 2002-10-29 E. I. Du Pont De Nemours And Company Spandex with high heat-set efficiency

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1278687B (de) 1959-04-17 1968-09-26 Bayer Ag Verfahren zur Herstellung hochelastischer Faeden oder Fasern aus Isocyanat-Polyadditionsprodukten
US3669934A (en) * 1964-05-26 1972-06-13 Celanese Corp Improved elastomeric fibers
DE1229288B (de) 1964-12-08 1966-11-24 Bayer Ag Verfahren zur Herstellung von Polyurethan-elastomeren aus der Loesung
FR1509722A (fr) 1966-02-01 1968-01-12 Du Pont Polyuréthanes et leur fabrication
NL155858B (nl) 1967-02-17 1978-02-15 Ameliotex Inc Werkwijze voor de bereiding van lineaire gesegmenteerde polyurethanen, alsmede gevormde voortbrengselen die uit aldus bereide polyurethanen zijn vervaardigd.
US5000899A (en) 1988-05-26 1991-03-19 E. I. Du Pont De Nemours And Company Spandex fiber with copolymer soft segment
US4973647A (en) 1989-05-31 1990-11-27 E. I. Du Pont De Nemours And Company Fiber from polyether-based spandex
DE3932949A1 (de) * 1989-10-03 1991-04-11 Bayer Ag Elasthanfasern hoher dehnbarkeit und festigkeit und ein verfahren zu ihrer herstellung
DE3932948A1 (de) 1989-10-03 1991-04-11 Bayer Ag Verfahren zur herstellung von segmentierten polyurethanharnstoff-elastomerloesungen, sowie faeden und folien daraus
JP3276475B2 (ja) 1993-09-10 2002-04-22 旭化成株式会社 高強力弾性糸の製造方法
US5539037A (en) 1993-09-30 1996-07-23 E. I. Du Pont De Nemours And Company Spandex containing certain alkali metal salts
JPH0820625A (ja) 1994-07-07 1996-01-23 Mitsui Toatsu Chem Inc ポリウレタンウレア溶液の製造方法
KR100239204B1 (ko) 1995-06-23 2000-01-15 야마모토 카즈모토 폴리우레탄 탄성 섬유 및 그의 제조 방법
US5644015A (en) 1996-07-24 1997-07-01 Hyosung T & C Co., Ltd. Process of manufacturing improved polyurethane fiber polymer
US5723563A (en) 1996-10-11 1998-03-03 Arco Chemical Technology, L.P. Spandex elastomers
US5708118A (en) 1996-10-11 1998-01-13 Arco Chemical Technology, L.P. Spandex elastomers
US5948875A (en) 1998-03-26 1999-09-07 E. I. Du Pont De Nemours And Company Polyurethaneureas and spandex made therefrom
US5981686A (en) 1998-03-26 1999-11-09 E. I. Du Pont De Nemours And Company Spandex made with 1,3-diaminopentane
DE19824333A1 (de) * 1998-06-02 1999-12-09 Bayer Ag Elastanfäden und Verfahren zu ihrer Herstellung
US6639041B2 (en) 1999-12-03 2003-10-28 Dupont-Toray Co. Ltd. Spandex having low set at low temperatures
WO2002086208A1 (en) 2001-04-19 2002-10-31 Kolon Industries, Inc A polyurethane type elastic fiber, and a process of preparing for the same
US7015299B2 (en) * 2001-04-30 2006-03-21 Wilkinson W Kenneth Melt spun thermoplastic polyurethanes useful as textile fibers
US6403682B1 (en) 2001-06-28 2002-06-11 E. I. Du Pont De Nemours And Company Spandex containing quaternary amine additives
KR100437988B1 (ko) 2002-04-29 2004-06-30 주식회사 두본 내염소성 및 내열성이 우수한 스판덱스 섬유 및 그제조방법
US6906163B2 (en) * 2002-05-30 2005-06-14 Bayer Materialscience Llc Prepolymer catalysts suitable for preparing spandex fibers
US6624281B1 (en) * 2002-05-30 2003-09-23 Bayer Corporation Polyurethane/ureas useful for the production of spandex and a process for their production
US6903179B2 (en) * 2002-05-30 2005-06-07 Bayer Materialscience Llc Polyurethane/ureas useful for the production of spandex and a process for their production
US6737497B2 (en) * 2002-05-30 2004-05-18 Bayer Polymers Llc Polyurethane/ureas useful for the production of spandex and a process for their production
US6720403B1 (en) * 2002-11-01 2004-04-13 E.I. Dupont De Nemours And Co. Polyurethaneurea and spandex comprising same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3557044A (en) * 1962-06-07 1971-01-19 Du Pont Process for making spandex polymers
JPH08176268A (ja) * 1994-12-26 1996-07-09 Mitsui Toatsu Chem Inc ポリウレタンウレア成形物の製造方法
CN1239971A (zh) * 1996-10-11 1999-12-29 阿科化学技术公司 改进的氨纶弹性体
US6472494B2 (en) * 2000-04-26 2002-10-29 E. I. Du Pont De Nemours And Company Spandex with high heat-set efficiency

Also Published As

Publication number Publication date
KR101092088B1 (ko) 2011-12-12
CN1784443A (zh) 2006-06-07
CN101195935B (zh) 2011-04-13
JP2006525410A (ja) 2006-11-09
US6916896B2 (en) 2005-07-12
CN101195935A (zh) 2008-06-11
EP1622958A1 (en) 2006-02-08
ATE486897T1 (de) 2010-11-15
JP4764335B2 (ja) 2011-08-31
HK1120296A1 (en) 2009-03-27
WO2004099282A1 (en) 2004-11-18
US20040225101A1 (en) 2004-11-11
DE602004029882D1 (de) 2010-12-16
ES2353758T3 (es) 2011-03-04
KR20060012279A (ko) 2006-02-07
EP1622958B1 (en) 2010-11-03
BRPI0409052A (pt) 2006-03-28
BRPI0409052B1 (pt) 2013-07-16

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Granted publication date: 20080409