CN100359725C - 锂二次电池的正极材料、采用它的锂二次电池及制备锂二次电池正极材料的方法 - Google Patents

锂二次电池的正极材料、采用它的锂二次电池及制备锂二次电池正极材料的方法 Download PDF

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CN100359725C
CN100359725C CNB038121220A CN03812122A CN100359725C CN 100359725 C CN100359725 C CN 100359725C CN B038121220 A CNB038121220 A CN B038121220A CN 03812122 A CN03812122 A CN 03812122A CN 100359725 C CN100359725 C CN 100359725C
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lithium
bismuth
positive electrode
boron
secondary battery
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CN1656633A (zh
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菊地一宽
岛耕司
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Mitsubishi Chemical Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00Compounds of manganese
    • C01G45/12Complex oxides containing manganese and at least one other metal element
    • C01G45/1221Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1228Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00Compounds of cobalt
    • C01G51/40Complex oxides containing cobalt and at least one other metal element
    • C01G51/42Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/50Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (MnO2)n-, e.g. Li(CoxMn1-x)O2 or Li(MyCoxMn1-x-y)O2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/20Two-dimensional structures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/50Solid solutions
    • C01P2002/52Solid solutions containing elements as dopants
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    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/50Solid solutions
    • C01P2002/52Solid solutions containing elements as dopants
    • C01P2002/54Solid solutions containing elements as dopants one element only
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    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
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    • C01P2006/40Electric properties
    • HELECTRICITY
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    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/021Physical characteristics, e.g. porosity, surface area
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
CNB038121220A 2002-03-28 2003-03-19 锂二次电池的正极材料、采用它的锂二次电池及制备锂二次电池正极材料的方法 Expired - Lifetime CN100359725C (zh)

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JP91473/2002 2002-03-28

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CN100359725C true CN100359725C (zh) 2008-01-02

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CNA2007101531756A Pending CN101127400A (zh) 2002-03-28 2003-03-19 锂二次电池的正极材料、采用它的锂二次电池及制备锂二次电池正极材料的方法

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EP (1) EP1492180A4 (enExample)
JP (1) JP5257272B2 (enExample)
CN (2) CN100359725C (enExample)
AU (1) AU2003221108A1 (enExample)
WO (1) WO2003083969A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103159264A (zh) * 2013-03-18 2013-06-19 昆明理工大学 一种纯固相法制备锂离子电池正极材料nca的方法
CN109562957A (zh) * 2016-12-28 2019-04-02 株式会社Lg化学 二次电池用正极活性材料、其制造方法以及包括其的锂二次电池

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JP4859487B2 (ja) * 2005-03-09 2012-01-25 パナソニック株式会社 非水電解質二次電池
KR20100097222A (ko) * 2007-12-25 2010-09-02 가오 가부시키가이샤 복합 금속 산화물 소성체 및 그 제조방법
JP5490457B2 (ja) * 2009-07-13 2014-05-14 日本化学工業株式会社 リチウム二次電池用正極活物質、その製造方法及びリチウム二次電池
JP5218782B2 (ja) * 2009-11-27 2013-06-26 戸田工業株式会社 非水電解質二次電池用Li−Ni複合酸化物粒子粉末及びその製造方法、並びに非水電解質二次電池
EP2555287B1 (en) 2010-04-01 2018-05-02 Mitsubishi Chemical Corporation Positive electrode material for lithium secondary battery, positive electrode for lithium secondary battery, and lithium secondary battery
WO2012132072A1 (ja) * 2011-03-29 2012-10-04 Jx日鉱日石金属株式会社 リチウムイオン電池用正極活物質の製造方法及びリチウムイオン電池用正極活物質
JP2014123529A (ja) * 2012-12-21 2014-07-03 Jfe Mineral Co Ltd リチウム二次電池用正極材料
KR101443500B1 (ko) 2013-02-15 2014-09-22 삼성정밀화학 주식회사 리튬금속산화물 및 이를 포함하는 리튬이차전지
CN104549930A (zh) * 2013-10-28 2015-04-29 无锡华臻新能源科技有限公司 表面加入增强纤维的锂离子电池电极及涂布方式
CN104311022B (zh) * 2014-10-16 2016-04-06 桂林理工大学 超低介电常数微波介电陶瓷Li2Bi3V7O23及其制备方法
JP7060336B2 (ja) * 2017-04-27 2022-04-26 トヨタ自動車株式会社 正極活物質、リチウムイオン二次電池および正極活物質の製造方法
PL3652112T3 (pl) * 2017-07-14 2021-11-22 Basf Se Sposób wytwarzania materiału czynnego elektrody
US11024850B2 (en) * 2017-09-27 2021-06-01 Xilectric, Inc. Li-ion batteries with improved abuse tolerance and performance
US20220127160A1 (en) * 2019-02-22 2022-04-28 Sumitomo Metal Mining Co., Ltd. Positive electrode active material for lithium ion secondary battery, method of manufacturing positive electrode active material for lithium ion secondary battery, and lithium ion secondary battery
JP7696122B2 (ja) * 2020-05-29 2025-06-20 パナソニックIpマネジメント株式会社 非水電解質二次電池用正極活物質および非水電解質二次電池
CN116741950A (zh) * 2022-03-03 2023-09-12 江苏翔鹰新能源科技有限公司 一种单晶型钠离子电池正极活性物质及其制备方法和用途

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JP2001185146A (ja) * 1999-12-27 2001-07-06 Yuasa Corp リチウム二次電池
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JPH10316431A (ja) * 1997-05-14 1998-12-02 Fuji Chem Ind Co Ltd リチウムニッケル複合酸化物及びその製造方法並びにリチウム二次電池用正極活物質
JP3524762B2 (ja) * 1998-03-19 2004-05-10 三洋電機株式会社 リチウム二次電池
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EP1372202B8 (en) * 2001-03-14 2013-12-18 GS Yuasa International Ltd. Positive electrode active material and nonaqueous electrolyte secondary cell comprising the same

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JP3195175B2 (ja) * 1994-11-11 2001-08-06 株式会社東芝 非水溶媒二次電池
CN1264927A (zh) * 1999-02-24 2000-08-30 索尼株式会社 非水电解液电池
JP2001185146A (ja) * 1999-12-27 2001-07-06 Yuasa Corp リチウム二次電池

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103159264A (zh) * 2013-03-18 2013-06-19 昆明理工大学 一种纯固相法制备锂离子电池正极材料nca的方法
CN109562957A (zh) * 2016-12-28 2019-04-02 株式会社Lg化学 二次电池用正极活性材料、其制造方法以及包括其的锂二次电池
CN109562957B (zh) * 2016-12-28 2021-09-03 株式会社Lg化学 二次电池用正极活性材料、其制造方法以及包括其的锂二次电池
US11299401B2 (en) 2016-12-28 2022-04-12 Lg Energy Solution, Ltd. Positive electrode active material for secondary battery, manufacturing method thereof, and secondary battery including same
US12180088B2 (en) 2016-12-28 2024-12-31 Lg Energy Solution, Ltd. Positive electrode active material for secondary battery, manufacturing method thereof, and secondary battery including same

Also Published As

Publication number Publication date
EP1492180A1 (en) 2004-12-29
CN1656633A (zh) 2005-08-17
AU2003221108A1 (en) 2003-10-13
WO2003083969A1 (en) 2003-10-09
JP5257272B2 (ja) 2013-08-07
JP2009245949A (ja) 2009-10-22
CN101127400A (zh) 2008-02-20
EP1492180A4 (en) 2010-06-23

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