JP5257272B2 - リチウム二次電池用正極材料およびそれを用いた二次電池ならびにリチウム二次電池用正極材料の製造方法 - Google Patents

リチウム二次電池用正極材料およびそれを用いた二次電池ならびにリチウム二次電池用正極材料の製造方法 Download PDF

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JP5257272B2
JP5257272B2 JP2009152397A JP2009152397A JP5257272B2 JP 5257272 B2 JP5257272 B2 JP 5257272B2 JP 2009152397 A JP2009152397 A JP 2009152397A JP 2009152397 A JP2009152397 A JP 2009152397A JP 5257272 B2 JP5257272 B2 JP 5257272B2
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bismuth
lithium
boron
positive electrode
secondary battery
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JP2009245949A (ja
JP2009245949A5 (enExample
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一寛 菊地
耕司 島
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Mitsubishi Chemical Corp
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Mitsubishi Chemical Corp
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1228—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/50—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (MnO2)n-, e.g. Li(CoxMn1-x)O2 or Li(MyCoxMn1-x-y)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C01G53/502—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C01G53/502—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt
    • C01G53/504—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.5, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.5
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
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    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2002/52—Solid solutions containing elements as dopants
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    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
JP2009152397A 2002-03-28 2009-06-26 リチウム二次電池用正極材料およびそれを用いた二次電池ならびにリチウム二次電池用正極材料の製造方法 Expired - Fee Related JP5257272B2 (ja)

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JP2009152397A JP5257272B2 (ja) 2002-03-28 2009-06-26 リチウム二次電池用正極材料およびそれを用いた二次電池ならびにリチウム二次電池用正極材料の製造方法

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JP2002091473 2002-03-28
JP2002091473 2002-03-28
JP2009152397A JP5257272B2 (ja) 2002-03-28 2009-06-26 リチウム二次電池用正極材料およびそれを用いた二次電池ならびにリチウム二次電池用正極材料の製造方法

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EP (1) EP1492180A4 (enExample)
JP (1) JP5257272B2 (enExample)
CN (2) CN101127400A (enExample)
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WO (1) WO2003083969A1 (enExample)

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US12597612B2 (en) 2020-02-21 2026-04-07 Gs Yuasa International Ltd. Nonaqueous electrolyte energy storage device, and method for manufacturing nonaqueous electrolyte energy storage device

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JP4859487B2 (ja) * 2005-03-09 2012-01-25 パナソニック株式会社 非水電解質二次電池
EP2239230A4 (en) * 2007-12-25 2017-01-04 Kao Corporation Burned composite metal oxide and process for producing the same
JP5490457B2 (ja) * 2009-07-13 2014-05-14 日本化学工業株式会社 リチウム二次電池用正極活物質、その製造方法及びリチウム二次電池
JP5218782B2 (ja) * 2009-11-27 2013-06-26 戸田工業株式会社 非水電解質二次電池用Ｌｉ−Ｎｉ複合酸化物粒子粉末及びその製造方法、並びに非水電解質二次電池
CN102823033A (zh) 2010-04-01 2012-12-12 三菱化学株式会社 锂二次电池用正极材料及其制造方法、以及锂二次电池用正极及锂二次电池
TWI468367B (zh) * 2011-03-29 2015-01-11 Ｊｘ日鑛日石金屬股份有限公司 Production method of positive electrode active material for lithium ion battery and positive electrode active material for lithium ion battery
JP2014123529A (ja) * 2012-12-21 2014-07-03 Jfe Mineral Co Ltd リチウム二次電池用正極材料
KR101443500B1 (ko) 2013-02-15 2014-09-22 삼성정밀화학 주식회사 리튬금속산화물 및 이를 포함하는 리튬이차전지
CN103159264B (zh) * 2013-03-18 2015-05-20 昆明理工大学 一种纯固相法制备锂离子电池正极材料nca的方法
CN104549930A (zh) * 2013-10-28 2015-04-29 无锡华臻新能源科技有限公司 表面加入增强纤维的锂离子电池电极及涂布方式
CN104311022B (zh) * 2014-10-16 2016-04-06 桂林理工大学 超低介电常数微波介电陶瓷Li2Bi3V7O23及其制备方法
KR102133916B1 (ko) * 2016-12-28 2020-07-15 주식회사 엘지화학 이차전지용 양극 활물질, 그 제조방법 및 이를 포함하는 리튬 이차전지
JP7060336B2 (ja) * 2017-04-27 2022-04-26 トヨタ自動車株式会社 正極活物質、リチウムイオン二次電池および正極活物質の製造方法
EP3652112B1 (en) * 2017-07-14 2021-05-19 Basf Se Process for making an electrode active material
US11024850B2 (en) * 2017-09-27 2021-06-01 Xilectric, Inc. Li-ion batteries with improved abuse tolerance and performance
CN113454032B (zh) * 2019-02-22 2023-05-30 住友金属矿山株式会社 锂离子二次电池用正极活性物质、锂离子二次电池用正极活性物质的制造方法、锂离子二次电池
JP7696122B2 (ja) * 2020-05-29 2025-06-20 パナソニックＩｐマネジメント株式会社 非水電解質二次電池用正極活物質および非水電解質二次電池
CN116741950A (zh) * 2022-03-03 2023-09-12 江苏翔鹰新能源科技有限公司 一种单晶型钠离子电池正极活性物质及其制备方法和用途
WO2026105730A1 (ja) * 2024-11-15 2026-05-21 三井金属株式会社 正極活物質及びその製造方法

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US12597612B2 (en) 2020-02-21 2026-04-07 Gs Yuasa International Ltd. Nonaqueous electrolyte energy storage device, and method for manufacturing nonaqueous electrolyte energy storage device

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JP2009245949A (ja) 2009-10-22
CN1656633A (zh) 2005-08-17
WO2003083969A1 (en) 2003-10-09
EP1492180A1 (en) 2004-12-29
CN101127400A (zh) 2008-02-20
EP1492180A4 (en) 2010-06-23
CN100359725C (zh) 2008-01-02

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