CN101127400A - 锂二次电池的正极材料、采用它的锂二次电池及制备锂二次电池正极材料的方法 - Google Patents

锂二次电池的正极材料、采用它的锂二次电池及制备锂二次电池正极材料的方法 Download PDF

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Publication number
CN101127400A
CN101127400A CNA2007101531756A CN200710153175A CN101127400A CN 101127400 A CN101127400 A CN 101127400A CN A2007101531756 A CNA2007101531756 A CN A2007101531756A CN 200710153175 A CN200710153175 A CN 200710153175A CN 101127400 A CN101127400 A CN 101127400A
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lithium
bismuth
boron
positive electrode
secondary battery
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Chinese (zh)
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菊地一宽
岛耕司
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Mitsubishi Chemical Corp
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Mitsubishi Chemical Corp
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1228—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/50—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (MnO2)n-, e.g. Li(CoxMn1-x)O2 or Li(MyCoxMn1-x-y)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C01G53/502—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C01G53/502—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt
    • C01G53/504—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.5, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.5
    • H—ELECTRICITY
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
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    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
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  • Chemical & Material Sciences (AREA)
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  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
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  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
CNA2007101531756A 2002-03-28 2003-03-19 锂二次电池的正极材料、采用它的锂二次电池及制备锂二次电池正极材料的方法 Pending CN101127400A (zh)

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CNB038121220A Expired - Lifetime CN100359725C (zh) 2002-03-28 2003-03-19 锂二次电池的正极材料、采用它的锂二次电池及制备锂二次电池正极材料的方法

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EP (1) EP1492180A4 (enExample)
JP (1) JP5257272B2 (enExample)
CN (2) CN101127400A (enExample)
AU (1) AU2003221108A1 (enExample)
WO (1) WO2003083969A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104885266A (zh) * 2012-12-21 2015-09-02 杰富意矿物股份有限公司 锂二次电池用正极材料
CN113454032A (zh) * 2019-02-22 2021-09-28 住友金属矿山株式会社 锂离子二次电池用正极活性物质、锂离子二次电池用正极活性物质的制造方法、锂离子二次电池

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4859487B2 (ja) * 2005-03-09 2012-01-25 パナソニック株式会社 非水電解質二次電池
EP2239230A4 (en) * 2007-12-25 2017-01-04 Kao Corporation Burned composite metal oxide and process for producing the same
JP5490457B2 (ja) * 2009-07-13 2014-05-14 日本化学工業株式会社 リチウム二次電池用正極活物質、その製造方法及びリチウム二次電池
JP5218782B2 (ja) * 2009-11-27 2013-06-26 戸田工業株式会社 非水電解質二次電池用Ｌｉ−Ｎｉ複合酸化物粒子粉末及びその製造方法、並びに非水電解質二次電池
CN102823033A (zh) 2010-04-01 2012-12-12 三菱化学株式会社 锂二次电池用正极材料及其制造方法、以及锂二次电池用正极及锂二次电池
TWI468367B (zh) * 2011-03-29 2015-01-11 Ｊｘ日鑛日石金屬股份有限公司 Production method of positive electrode active material for lithium ion battery and positive electrode active material for lithium ion battery
KR101443500B1 (ko) 2013-02-15 2014-09-22 삼성정밀화학 주식회사 리튬금속산화물 및 이를 포함하는 리튬이차전지
CN103159264B (zh) * 2013-03-18 2015-05-20 昆明理工大学 一种纯固相法制备锂离子电池正极材料nca的方法
CN104549930A (zh) * 2013-10-28 2015-04-29 无锡华臻新能源科技有限公司 表面加入增强纤维的锂离子电池电极及涂布方式
CN104311022B (zh) * 2014-10-16 2016-04-06 桂林理工大学 超低介电常数微波介电陶瓷Li2Bi3V7O23及其制备方法
KR102133916B1 (ko) * 2016-12-28 2020-07-15 주식회사 엘지화학 이차전지용 양극 활물질, 그 제조방법 및 이를 포함하는 리튬 이차전지
JP7060336B2 (ja) * 2017-04-27 2022-04-26 トヨタ自動車株式会社 正極活物質、リチウムイオン二次電池および正極活物質の製造方法
EP3652112B1 (en) * 2017-07-14 2021-05-19 Basf Se Process for making an electrode active material
US11024850B2 (en) * 2017-09-27 2021-06-01 Xilectric, Inc. Li-ion batteries with improved abuse tolerance and performance
CN115485878A (zh) 2020-02-21 2022-12-16 株式会社杰士汤浅国际 非水电解质蓄电元件和非水电解质蓄电元件的制造方法
JP7696122B2 (ja) * 2020-05-29 2025-06-20 パナソニックＩｐマネジメント株式会社 非水電解質二次電池用正極活物質および非水電解質二次電池
CN116741950A (zh) * 2022-03-03 2023-09-12 江苏翔鹰新能源科技有限公司 一种单晶型钠离子电池正极活性物质及其制备方法和用途
WO2026105730A1 (ja) * 2024-11-15 2026-05-21 三井金属株式会社 正極活物質及びその製造方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2586747B2 (ja) * 1991-01-29 1997-03-05 株式会社ユアサコーポレーション リチウム二次電池
US5503930A (en) * 1994-03-07 1996-04-02 Tdk Corporation Layer structure oxide
JP3307510B2 (ja) * 1994-03-07 2002-07-24 ティーディーケイ株式会社 層状構造酸化物および二次電池
JP3195175B2 (ja) * 1994-11-11 2001-08-06 株式会社東芝 非水溶媒二次電池
TW363940B (en) * 1996-08-12 1999-07-11 Toda Kogyo Corp A lithium-nickle-cobalt compound oxide, process thereof and anode active substance for storage battery
JPH10316431A (ja) * 1997-05-14 1998-12-02 Fuji Chem Ind Co Ltd リチウムニッケル複合酸化物及びその製造方法並びにリチウム二次電池用正極活物質
JP3524762B2 (ja) * 1998-03-19 2004-05-10 三洋電機株式会社 リチウム二次電池
JP4110435B2 (ja) * 1998-11-04 2008-07-02 戸田工業株式会社 リチウムイオン二次電池用正極活物質
JP2000251887A (ja) * 1999-02-24 2000-09-14 Sony Corp 非水電解質電池
JP3503688B2 (ja) * 1999-12-27 2004-03-08 株式会社ユアサコーポレーション リチウム二次電池
WO2002073718A1 (en) * 2001-03-14 2002-09-19 Yuasa Corporation Positive electrode active material and nonaqueous electrolyte secondary cell comprising the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104885266A (zh) * 2012-12-21 2015-09-02 杰富意矿物股份有限公司 锂二次电池用正极材料
CN113454032A (zh) * 2019-02-22 2021-09-28 住友金属矿山株式会社 锂离子二次电池用正极活性物质、锂离子二次电池用正极活性物质的制造方法、锂离子二次电池
CN113454032B (zh) * 2019-02-22 2023-05-30 住友金属矿山株式会社 锂离子二次电池用正极活性物质、锂离子二次电池用正极活性物质的制造方法、锂离子二次电池

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AU2003221108A1 (en) 2003-10-13
JP2009245949A (ja) 2009-10-22
CN1656633A (zh) 2005-08-17
WO2003083969A1 (en) 2003-10-09
JP5257272B2 (ja) 2013-08-07
EP1492180A1 (en) 2004-12-29
EP1492180A4 (en) 2010-06-23
CN100359725C (zh) 2008-01-02

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