CA2221162C - Photocrosslinked polymers and prepolymers thereof - Google Patents
Photocrosslinked polymers and prepolymers thereof Download PDFInfo
- Publication number
- CA2221162C CA2221162C CA002221162A CA2221162A CA2221162C CA 2221162 C CA2221162 C CA 2221162C CA 002221162 A CA002221162 A CA 002221162A CA 2221162 A CA2221162 A CA 2221162A CA 2221162 C CA2221162 C CA 2221162C
- Authority
- CA
- Canada
- Prior art keywords
- carbon atoms
- prepolymer
- alkylene
- solution
- polyvinyl alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 title claims description 44
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 66
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 64
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 54
- 238000000034 method Methods 0.000 claims abstract description 51
- 230000008569 process Effects 0.000 claims abstract description 50
- 238000000465 moulding Methods 0.000 claims abstract description 32
- 238000002360 preparation method Methods 0.000 claims abstract description 28
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 25
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 19
- 239000001257 hydrogen Substances 0.000 claims abstract description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 7
- 239000000243 solution Substances 0.000 claims description 89
- 125000002348 vinylic group Chemical group 0.000 claims description 32
- 239000007864 aqueous solution Substances 0.000 claims description 22
- 238000000108 ultra-filtration Methods 0.000 claims description 22
- 125000003342 alkenyl group Chemical group 0.000 claims description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 125000000732 arylene group Chemical group 0.000 claims description 5
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 4
- 125000004956 cyclohexylene group Chemical group 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 abstract description 21
- 238000004519 manufacturing process Methods 0.000 abstract description 15
- 229920006037 cross link polymer Polymers 0.000 abstract description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 53
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 51
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 48
- 229940068984 polyvinyl alcohol Drugs 0.000 description 38
- 150000001241 acetals Chemical class 0.000 description 30
- 150000001875 compounds Chemical class 0.000 description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 25
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 21
- -1 hexylene, pentylene, butylene, propylene, ethylene, methylene Chemical group 0.000 description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 18
- 238000004132 cross linking Methods 0.000 description 18
- 239000000203 mixture Substances 0.000 description 17
- 239000000047 product Substances 0.000 description 14
- 239000007787 solid Substances 0.000 description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 12
- 239000000470 constituent Substances 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 230000002209 hydrophobic effect Effects 0.000 description 10
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 9
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 9
- 239000007795 chemical reaction product Substances 0.000 description 9
- 239000008367 deionised water Substances 0.000 description 9
- 239000012528 membrane Substances 0.000 description 9
- 239000000178 monomer Substances 0.000 description 9
- 238000000746 purification Methods 0.000 description 9
- 239000011780 sodium chloride Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000000605 extraction Methods 0.000 description 8
- 229960000443 hydrochloric acid Drugs 0.000 description 8
- 235000011167 hydrochloric acid Nutrition 0.000 description 8
- 230000005855 radiation Effects 0.000 description 8
- 238000002955 isolation Methods 0.000 description 7
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 7
- MGARLISKINLYPI-UHFFFAOYSA-N n-(2,2-dimethoxyethyl)-2-methylprop-2-enamide Chemical compound COC(OC)CNC(=O)C(C)=C MGARLISKINLYPI-UHFFFAOYSA-N 0.000 description 7
- 239000011541 reaction mixture Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 6
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical group CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 6
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical group CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000012266 salt solution Substances 0.000 description 6
- QKWWDTYDYOFRJL-UHFFFAOYSA-N 2,2-dimethoxyethanamine Chemical compound COC(CN)OC QKWWDTYDYOFRJL-UHFFFAOYSA-N 0.000 description 5
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 5
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 5
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 230000036571 hydration Effects 0.000 description 5
- 238000006703 hydration reaction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 5
- 239000003208 petroleum Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000000875 corresponding effect Effects 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- 150000000185 1,3-diols Chemical class 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 3
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229940086542 triethylamine Drugs 0.000 description 3
- 230000001960 triggered effect Effects 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- FAPCFNWEPHTUQK-UHFFFAOYSA-N 2,2,6,6-tetramethyl-1-oxidopiperidin-1-ium-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)[NH+]1[O-] FAPCFNWEPHTUQK-UHFFFAOYSA-N 0.000 description 2
- GJKGAPPUXSSCFI-UHFFFAOYSA-N 2-Hydroxy-4'-(2-hydroxyethoxy)-2-methylpropiophenone Chemical compound CC(C)(O)C(=O)C1=CC=C(OCCO)C=C1 GJKGAPPUXSSCFI-UHFFFAOYSA-N 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 125000004036 acetal group Chemical group 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000003926 acrylamides Chemical class 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000000502 dialysis Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- RBQRWNWVPQDTJJ-UHFFFAOYSA-N methacryloyloxyethyl isocyanate Chemical compound CC(=C)C(=O)OCCN=C=O RBQRWNWVPQDTJJ-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000007152 ring opening metathesis polymerisation reaction Methods 0.000 description 2
- 238000004528 spin coating Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- JMCRDEBJJPRTPV-OWOJBTEDSA-N (e)-ethene-1,2-diol Chemical group O\C=C\O JMCRDEBJJPRTPV-OWOJBTEDSA-N 0.000 description 1
- FMQPBWHSNCRVQJ-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C(F)(F)F)C(F)(F)F FMQPBWHSNCRVQJ-UHFFFAOYSA-N 0.000 description 1
- NMFZTJOPTRNMGL-UHFFFAOYSA-N 1,1-diethoxybutan-2-amine Chemical compound CCOC(OCC)C(N)CC NMFZTJOPTRNMGL-UHFFFAOYSA-N 0.000 description 1
- 150000000180 1,2-diols Chemical class 0.000 description 1
- VDFVNEFVBPFDSB-UHFFFAOYSA-N 1,3-dioxane Chemical compound C1COCOC1 VDFVNEFVBPFDSB-UHFFFAOYSA-N 0.000 description 1
- 125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 description 1
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- CTXUTPWZJZHRJC-UHFFFAOYSA-N 1-ethenylpyrrole Chemical compound C=CN1C=CC=C1 CTXUTPWZJZHRJC-UHFFFAOYSA-N 0.000 description 1
- VOCDJQSAMZARGX-UHFFFAOYSA-N 1-ethenylpyrrolidine-2,5-dione Chemical compound C=CN1C(=O)CCC1=O VOCDJQSAMZARGX-UHFFFAOYSA-N 0.000 description 1
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical group CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 description 1
- QRIMLDXJAPZHJE-UHFFFAOYSA-N 2,3-dihydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(O)CO QRIMLDXJAPZHJE-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- ZIFLDVXQTMSDJE-UHFFFAOYSA-N 3-[[dimethyl-[3-(2-methylprop-2-enoyloxy)propyl]silyl]oxy-dimethylsilyl]propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC[Si](C)(C)O[Si](C)(C)CCCOC(=O)C(C)=C ZIFLDVXQTMSDJE-UHFFFAOYSA-N 0.000 description 1
- NWBTXZPDTSKZJU-UHFFFAOYSA-N 3-[dimethyl(trimethylsilyloxy)silyl]propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC[Si](C)(C)O[Si](C)(C)C NWBTXZPDTSKZJU-UHFFFAOYSA-N 0.000 description 1
- WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 description 1
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 238000005698 Diels-Alder reaction Methods 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- HJOVHMDZYOCNQW-UHFFFAOYSA-N Isophorone Natural products CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 244000297179 Syringa vulgaris Species 0.000 description 1
- 235000004338 Syringa vulgaris Nutrition 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
- FQUIJBQJVGXLOF-UHFFFAOYSA-N [1,1,2,3,3,4,4,5,5,6,6,7,7,8,8,8-hexadecafluoro-2-[fluoro(2,2,3,3,3-pentafluoropropanethioyl)amino]octyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(F)(F)C(F)(N(F)C(=S)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F FQUIJBQJVGXLOF-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000337 buffer salt Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001589 carboacyl group Chemical group 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 210000004087 cornea Anatomy 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000006352 cycloaddition reaction Methods 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- FYUWIEKAVLOHSE-UHFFFAOYSA-N ethenyl acetate;1-ethenylpyrrolidin-2-one Chemical compound CC(=O)OC=C.C=CN1CCCC1=O FYUWIEKAVLOHSE-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- BLZSRIYYOIZLJL-UHFFFAOYSA-N ethenyl pentanoate Chemical compound CCCCC(=O)OC=C BLZSRIYYOIZLJL-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 210000003709 heart valve Anatomy 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229940063557 methacrylate Drugs 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- CMMYGCUEJWTBCG-UHFFFAOYSA-N n-(2,2-dimethoxyethyl)prop-2-enamide Chemical compound COC(OC)CNC(=O)C=C CMMYGCUEJWTBCG-UHFFFAOYSA-N 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- NUVAJCAIFXNUAP-UHFFFAOYSA-N n-(4,4-diethoxybutyl)-2-methylprop-2-enamide Chemical compound CCOC(OCC)CCCNC(=O)C(C)=C NUVAJCAIFXNUAP-UHFFFAOYSA-N 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000010019 resist printing Methods 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00009—Production of simple or compound lenses
- B29D11/00432—Auxiliary operations, e.g. machines for filling the moulds
- B29D11/00442—Curing the lens material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C31/00—Handling, e.g. feeding of the material to be shaped, storage of plastics material before moulding; Automation, i.e. automated handling lines in plastics processing plants, e.g. using manipulators or robots
- B29C31/04—Feeding of the material to be moulded, e.g. into a mould cavity
- B29C31/041—Feeding of the material to be moulded, e.g. into a mould cavity using filling or dispensing heads placed in closed moulds or in contact with mould walls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0888—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using transparant moulds
- B29C35/0894—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using transparant moulds provided with masks or diaphragms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0003—Discharging moulded articles from the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0003—Discharging moulded articles from the mould
- B29C37/0007—Discharging moulded articles from the mould using means operable from outside the mould for moving between mould parts, e.g. robots
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/005—Compensating volume or shape change during moulding, in general
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/22—Component parts, details or accessories; Auxiliary operations
- B29C39/24—Feeding the material into the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/22—Component parts, details or accessories; Auxiliary operations
- B29C39/36—Removing moulded articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/22—Component parts, details or accessories; Auxiliary operations
- B29C39/42—Casting under special conditions, e.g. vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00009—Production of simple or compound lenses
- B29D11/00038—Production of contact lenses
- B29D11/00057—Production of contact lenses characterised by the shape or surface condition of the edge, e.g. flashless, burrless, smooth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00009—Production of simple or compound lenses
- B29D11/00038—Production of contact lenses
- B29D11/00125—Auxiliary operations, e.g. removing oxygen from the mould, conveying moulds from a storage to the production line in an inert atmosphere
- B29D11/00134—Curing of the contact lens material
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
- G02B1/043—Contact lenses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0827—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/30—Mounting, exchanging or centering
- B29C33/303—Mounting, exchanging or centering centering mould parts or halves, e.g. during mounting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2011/00—Optical elements, e.g. lenses, prisms
- B29L2011/0016—Lenses
- B29L2011/0041—Contact lenses
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/937—Utility as body contact e.g. implant, contact lens or I.U.D.
Landscapes
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Ophthalmology & Optometry (AREA)
- Robotics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Toxicology (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Eyeglasses (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Materials For Medical Uses (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Control Of Driving Devices And Active Controlling Of Vehicle (AREA)
- Ceramic Products (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
- Polyethers (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Peptides Or Proteins (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH235093 | 1993-08-06 | ||
| CH2350/93-0 | 1993-08-06 | ||
| CA002129461A CA2129461C (en) | 1993-08-06 | 1994-08-04 | Photocrosslinked polymers |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002129461A Division CA2129461C (en) | 1993-08-06 | 1994-08-04 | Photocrosslinked polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2221162A1 CA2221162A1 (en) | 1995-02-07 |
| CA2221162C true CA2221162C (en) | 2003-10-07 |
Family
ID=4231738
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002221162A Expired - Lifetime CA2221162C (en) | 1993-08-06 | 1994-08-04 | Photocrosslinked polymers and prepolymers thereof |
| CA002129461A Expired - Lifetime CA2129461C (en) | 1993-08-06 | 1994-08-04 | Photocrosslinked polymers |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002129461A Expired - Lifetime CA2129461C (en) | 1993-08-06 | 1994-08-04 | Photocrosslinked polymers |
Country Status (26)
| Country | Link |
|---|---|
| US (4) | US5508317A (enExample) |
| EP (2) | EP0790258B1 (enExample) |
| JP (1) | JP2914872B2 (enExample) |
| KR (1) | KR100336138B1 (enExample) |
| CN (1) | CN1062513C (enExample) |
| AT (2) | ATE162814T1 (enExample) |
| AU (2) | AU680507B2 (enExample) |
| BR (1) | BR9403174A (enExample) |
| CA (2) | CA2221162C (enExample) |
| CZ (2) | CZ289627B6 (enExample) |
| DE (2) | DE59410329D1 (enExample) |
| DK (2) | DK0790258T3 (enExample) |
| ES (2) | ES2112503T3 (enExample) |
| FI (2) | FI114714B (enExample) |
| GR (1) | GR3026098T3 (enExample) |
| HK (1) | HK1005338A1 (enExample) |
| HU (2) | HU221056B1 (enExample) |
| IL (3) | IL110487A (enExample) |
| NO (3) | NO309381B1 (enExample) |
| NZ (2) | NZ286397A (enExample) |
| PL (1) | PL178192B1 (enExample) |
| PT (1) | PT790258E (enExample) |
| RU (1) | RU2141896C1 (enExample) |
| SG (1) | SG49623A1 (enExample) |
| TW (1) | TW272976B (enExample) |
| ZA (1) | ZA945872B (enExample) |
Families Citing this family (291)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5800373A (en) * | 1995-03-23 | 1998-09-01 | Focal, Inc. | Initiator priming for improved adherence of gels to substrates |
| US6800225B1 (en) | 1994-07-14 | 2004-10-05 | Novartis Ag | Process and device for the manufacture of mouldings and mouldings manufactured in accordance with that process |
| US6407145B1 (en) * | 1994-08-04 | 2002-06-18 | Novartis Ag | Photocrosslinkable materials and applications |
| AU702612B2 (en) * | 1995-02-02 | 1999-02-25 | Novartis Ag | Process for the manufacture of moulded articles that are partly coloured or have regions of different colours |
| AU698933B2 (en) * | 1995-02-03 | 1998-11-12 | Novartis Ag | Crosslinked polymers containing photoinitiators |
| TW349967B (en) * | 1995-02-03 | 1999-01-11 | Novartis Ag | Process for producing contact lenses and a cross-linkable polyvinylalcohol used therefor |
| TW425410B (en) * | 1995-02-03 | 2001-03-11 | Novartis Ag | Preparation of the crosslinked tinted polymers and their moldings |
| AU4438696A (en) * | 1995-02-03 | 1996-08-21 | Novartis Ag | Crosslinked polymers |
| TW360671B (en) * | 1995-02-03 | 1999-06-11 | Novartis Ag | Process for producing mold body and the cross-linkable polymer used therein |
| ATE178414T1 (de) * | 1995-02-03 | 1999-04-15 | Novartis Ag | Vernetzte polymere enthaltend ester- oder amidgruppen |
| JP4209941B2 (ja) * | 1995-03-23 | 2009-01-14 | ジェンザイム・コーポレーション | ゲルの基材への改善された接着性のための下塗り用のレドックスおよび光開始剤システム |
| US5900245A (en) | 1996-03-22 | 1999-05-04 | Focal, Inc. | Compliant tissue sealants |
| WO1997005185A2 (en) | 1995-07-28 | 1997-02-13 | Focal, Inc. | Multiblock biodegradable hydrogels for use as controlled release agents for drugs delivery and tissue treatment agents |
| TW448205B (en) * | 1996-05-23 | 2001-08-01 | Novartis Ag | Process for the manufacture of storage-stable hydrogel-moldings |
| ID17663A (id) * | 1996-07-26 | 1998-01-15 | Novartis Ag | Pembuatan cetakan-cetakan |
| AR008108A1 (es) * | 1996-08-01 | 1999-12-09 | Novartis Ag | Un metodo para formar un articulo polimerico absorbente de radiacion, un articulo polimerico asi formado, y un metodo para formar un tintepolimerico |
| ZA978537B (en) | 1996-09-23 | 1998-05-12 | Focal Inc | Polymerizable biodegradable polymers including carbonate or dioxanone linkages. |
| AR011459A1 (es) * | 1997-03-25 | 2000-08-16 | Novartis Ag | Proceso para la produccion de una pluralidad de moldeos, proceso para limpiar un molde oftalmico, proceso para centrar un molde oftalmico sobre unamitad de molde hembra, proceso para asegurar que un lente oftalmico se localice sobre una mitad de molde seleccionada, proceso para inspeccionar las area |
| US6113817A (en) * | 1997-03-25 | 2000-09-05 | Novartis Ag | Molding processes |
| WO1998054603A1 (en) * | 1997-05-27 | 1998-12-03 | Novartis Ag | Composite ophthalmic lens |
| US6265509B1 (en) * | 1997-07-30 | 2001-07-24 | Novartis Ag | Crosslinked polymers |
| US6402995B1 (en) * | 1997-07-31 | 2002-06-11 | Seed Co., Ltd. | Process for preparing polyvinyl alcohol contact lenses |
| AU734885B2 (en) * | 1997-08-28 | 2001-06-28 | Biocure, Inc. | Method and composition for incorporating radiation-absorbing agents into polymers |
| IL135635A0 (en) * | 1997-11-14 | 2001-05-20 | Novartis Ag | Methods and compositions for manufacturing tinted ophthalmic lenses |
| US6139147A (en) * | 1998-11-20 | 2000-10-31 | Novartis Ag | Actively controllable multifocal lens |
| US5997140A (en) * | 1997-12-29 | 1999-12-07 | Novartis Ag | Actively controllable multifocal lens |
| US6139146A (en) * | 1997-12-29 | 2000-10-31 | Novartis Ag | Programmable corrective lenses |
| US5981617A (en) * | 1998-01-20 | 1999-11-09 | Kim; Hee Jung | Irradiation of gas permeable contact lenses by far infrared light |
| US6217171B1 (en) | 1998-05-26 | 2001-04-17 | Novartis Ag | Composite ophthamic lens |
| US6149692A (en) * | 1998-08-27 | 2000-11-21 | Novartis Ag | Method and composition for incorporating radiation-absorbing agents into polymers |
| EP1057730A1 (de) | 1999-05-04 | 2000-12-06 | Novartis AG | Verfahren und Vorrichtung zum Erfassen von ophthalmischen Formkörpern in einer Verpackung |
| EP1050470A1 (en) | 1999-05-04 | 2000-11-08 | Novartis AG | Detection of ophthalmic mouldings in a package |
| JP4717304B2 (ja) * | 1999-06-25 | 2011-07-06 | ノバルティス アーゲー | Ｕｖ照明装置 |
| US6638451B1 (en) * | 1999-08-31 | 2003-10-28 | Novartis Ag | Plastic casting molds |
| US7279176B1 (en) | 1999-09-02 | 2007-10-09 | Rice University | Nitric oxide-producing hydrogel materials |
| US7052711B2 (en) * | 1999-09-02 | 2006-05-30 | Rice University | Nitric oxide-producing hydrogel materials |
| WO2001019440A1 (en) * | 1999-09-15 | 2001-03-22 | Resmed Ltd. | Patient-ventilator synchronization using dual phase sensors |
| US6710126B1 (en) | 1999-11-15 | 2004-03-23 | Bio Cure, Inc. | Degradable poly(vinyl alcohol) hydrogels |
| EP1109011B1 (en) | 1999-12-03 | 2009-09-02 | Novartis AG | Method for detecting the presence of mouldings in a package |
| EP1280886A2 (en) * | 2000-01-05 | 2003-02-05 | Novartis AG | Cell growth substrate hydrogels |
| US7998412B2 (en) * | 2000-01-07 | 2011-08-16 | Smart Holograms Limited | Ophthalmic device comprising a holographic sensor |
| EP1263803B1 (en) | 2000-03-13 | 2007-09-19 | BioCure, Inc. | Embolic compositions |
| JP5460939B2 (ja) * | 2000-03-13 | 2014-04-02 | バイオコンパティブルズ ユーケー リミテッド | ヒドロゲル生物医学用製品 |
| US6652883B2 (en) * | 2000-03-13 | 2003-11-25 | Biocure, Inc. | Tissue bulking and coating compositions |
| CA2682118A1 (en) * | 2000-03-24 | 2001-09-27 | Novartis Ag | Crosslinkable or polymerizable prepolymers |
| JP5301756B2 (ja) | 2000-06-26 | 2013-09-25 | ノバルティス アーゲー | ポリウレタンヒドロゲルコンタクトレンズ |
| US6364934B1 (en) | 2000-07-31 | 2002-04-02 | Bausch & Lomb Incorporated | Method of making ocular devices |
| US6737661B2 (en) * | 2000-08-17 | 2004-05-18 | Novartis Ag | Pre-treatment of molds |
| US20020093701A1 (en) * | 2000-12-29 | 2002-07-18 | Xiaoxiao Zhang | Holographic multifocal lens |
| US6774178B2 (en) * | 2001-01-05 | 2004-08-10 | Novartis Ag | Tinted, high Dk ophthalmic molding and a method for making same |
| EP1226924B1 (en) * | 2001-01-24 | 2006-02-15 | Novartis AG | Lens Manufacturing Process |
| AR032951A1 (es) | 2001-03-07 | 2003-12-03 | Novartis Ag | Proceso para la fabricacion de articulos moldeados |
| WO2002072166A1 (en) * | 2001-03-13 | 2002-09-19 | Biocure, Inc. | Compositions for drug delivery |
| EP1245372B1 (en) * | 2001-03-26 | 2011-09-28 | Novartis AG | Mould and method for the production of ophthalmic lenses |
| DE20107040U1 (de) * | 2001-04-24 | 2002-10-02 | Novartis Ag, Basel | Dosierlanze |
| US6997693B2 (en) * | 2001-10-19 | 2006-02-14 | Novartis Ag | Casting mold half and casting mold for producing contact lenses |
| US7411008B2 (en) | 2001-11-07 | 2008-08-12 | Novartis Ag | Ink formulations and uses thereof |
| WO2003043552A1 (en) * | 2001-11-16 | 2003-05-30 | Biocure, Inc. | Methods for initiating in situ formation of hydrogels |
| US20060100408A1 (en) * | 2002-03-11 | 2006-05-11 | Powell P M | Method for forming contact lenses comprising therapeutic agents |
| US6846892B2 (en) * | 2002-03-11 | 2005-01-25 | Johnson & Johnson Vision Care, Inc. | Low polydispersity poly-HEMA compositions |
| US20030209818A1 (en) * | 2002-05-13 | 2003-11-13 | Harald Bothe | Pretreatment of contact lens moulds |
| US6936641B2 (en) | 2002-06-25 | 2005-08-30 | Johnson & Johnson Vision Care, Inc. | Macromer forming catalysts |
| AU2003258609A1 (en) | 2002-08-14 | 2004-03-03 | Novartis Ag | Radiation-curable prepolymers |
| ATE489438T1 (de) * | 2002-09-03 | 2010-12-15 | Novartis Ag | Tintenformulierung und deren anwendungen |
| US7235195B2 (en) * | 2002-09-06 | 2007-06-26 | Novartis Ag | Method for making opthalmic devices |
| US20080299179A1 (en) * | 2002-09-06 | 2008-12-04 | Osman Rathore | Solutions for ophthalmic lenses containing at least one silicone containing component |
| US7429465B2 (en) | 2002-09-13 | 2008-09-30 | Novartis Ag | Process for analyzing tear fluid |
| JP2004151691A (ja) * | 2002-09-30 | 2004-05-27 | Rohm & Haas Electronic Materials Llc | 改良フォトレジスト |
| JP2004163904A (ja) * | 2002-09-30 | 2004-06-10 | Rohm & Haas Electronic Materials Llc | 改善された光開始剤 |
| US7148265B2 (en) * | 2002-09-30 | 2006-12-12 | Rohm And Haas Electronic Materials Llc | Functional polymer |
| US20050085585A1 (en) * | 2002-10-23 | 2005-04-21 | Quinn Michael H. | Polymerizable materials |
| US7049351B2 (en) * | 2002-11-01 | 2006-05-23 | Novartis Ag | Moldings and preparation and uses thereof |
| US20050038329A1 (en) * | 2002-11-20 | 2005-02-17 | Morris Carol Ann | Methods and kits for assays of rapid screening of diabetes |
| JP2004225040A (ja) * | 2002-12-12 | 2004-08-12 | Rohm & Haas Electronic Materials Llc | 官能化されたポリマー |
| US20040161466A1 (en) * | 2003-02-14 | 2004-08-19 | Biocompatibles Uk Limited | Chemoembolisation |
| DE602004022638D1 (de) * | 2003-02-28 | 2009-10-01 | Eyesense Ag | Biomoleküle enthaltende copolymere |
| WO2004087007A2 (en) | 2003-03-25 | 2004-10-14 | Biocure, Inc. | Hydrogel string medical device |
| WO2005000109A2 (en) * | 2003-06-27 | 2005-01-06 | University Of Maryland Biotechnology Institute | Quaternary nitrogen heterocyclic compounds for detecting aqueous monosaccharides in physiological fluids |
| EP1651946A1 (en) * | 2003-07-30 | 2006-05-03 | Novartis AG | Reflection hologram sensor in contact lens |
| DE602004028020D1 (de) * | 2003-08-07 | 2010-08-19 | Eyesense Ag | Ophthalmischer sensor |
| US20050056954A1 (en) * | 2003-09-12 | 2005-03-17 | Devlin Brian Gerrard | Method for making contact lenses |
| JP4393831B2 (ja) * | 2003-09-22 | 2010-01-06 | Ｈｏｙａ株式会社 | プラスチックレンズの製造方法 |
| US8002830B2 (en) | 2004-02-06 | 2011-08-23 | Georgia Tech Research Corporation | Surface directed cellular attachment |
| AU2005212339B2 (en) | 2004-02-06 | 2010-11-25 | Georgia Tech Research Corporation | Load bearing biocompatible device |
| US20050271727A1 (en) * | 2004-06-07 | 2005-12-08 | Callisyn Pharmaceuticals, Inc. | Biodegradable and biocompatible crosslinked polymer hydrogel prepared from PVA and/or PEG macromer mixtures |
| ATE489058T1 (de) * | 2004-06-29 | 2010-12-15 | Inc Biocure | Bandscheiben-nucleus-pulposus-implantat |
| EP3085361A1 (en) | 2004-09-07 | 2016-10-26 | Biocompatibles UK Limited | Compositions comprising camptothecins in microspheres |
| US8030369B2 (en) * | 2004-10-13 | 2011-10-04 | Novartis Ag | Contact lenses with improved wearing comfort |
| EP1861069B2 (en) † | 2005-02-09 | 2013-07-03 | Safilens S.R.L. | Contact lens, method for producing same, and pack for storage and maintenance of a contact lens |
| US20060192310A1 (en) * | 2005-02-23 | 2006-08-31 | Lindacher Joseph M | Method of manufacturing ophthalmic lenses using modulated energy |
| US7795359B2 (en) | 2005-03-04 | 2010-09-14 | Novartis Ag | Continuous process for production of polymeric materials |
| HUE034382T2 (en) * | 2005-03-18 | 2018-02-28 | Novartis Ag | Pad printing equipment for producing colored contact lenses |
| ATE432815T1 (de) * | 2005-04-29 | 2009-06-15 | Novartis Ag | Beschichtete linsenformen und verfahren zur herstellung von einer kontakt-linse |
| US9804295B2 (en) | 2005-05-05 | 2017-10-31 | Novartis Ag | Ophthalmic devices for sustained delivery of active compounds |
| US20070037897A1 (en) | 2005-08-12 | 2007-02-15 | Guigui Wang | Method for making contact lenses |
| US20070149641A1 (en) * | 2005-12-28 | 2007-06-28 | Goupil Dennis W | Injectable bone cement |
| EP2520287B1 (en) | 2006-02-10 | 2025-03-26 | Boston Scientific Medical Device Limited | Loading of hydrophobic drugs into hydrophilic polymer delivery systems |
| CN101394942B (zh) | 2006-02-28 | 2012-04-04 | 细胞生物工程有限公司 | 聚合物组合物和从基材上除去污染材料的方法 |
| US7858000B2 (en) * | 2006-06-08 | 2010-12-28 | Novartis Ag | Method of making silicone hydrogel contact lenses |
| PT2038310E (pt) | 2006-07-12 | 2010-08-25 | Novartis Ag | Copolímeros reticuláveis por via actínica para o fabrico de lentes de contacto |
| US20080081851A1 (en) * | 2006-09-01 | 2008-04-03 | Benz Patrick H | Optical polymers with higher refractive index |
| AR063561A1 (es) * | 2006-11-06 | 2009-02-04 | Novartis Ag | Dispositivos oculares y metodos para fabricar y utilizar los mismos |
| AR064286A1 (es) | 2006-12-13 | 2009-03-25 | Quiceno Gomez Alexandra Lorena | Produccion de dispositivos oftalmicos basados en la polimerizacion por crecimiento escalonado fotoinducida |
| US8394483B2 (en) | 2007-01-24 | 2013-03-12 | Micron Technology, Inc. | Two-dimensional arrays of holes with sub-lithographic diameters formed by block copolymer self-assembly |
| US8083953B2 (en) | 2007-03-06 | 2011-12-27 | Micron Technology, Inc. | Registered structure formation via the application of directed thermal energy to diblock copolymer films |
| US8557128B2 (en) | 2007-03-22 | 2013-10-15 | Micron Technology, Inc. | Sub-10 nm line features via rapid graphoepitaxial self-assembly of amphiphilic monolayers |
| US8071703B2 (en) | 2007-03-22 | 2011-12-06 | Novartis Ag | Silicone-containing prepolymers with dangling hydrophilic polymer chains |
| KR101482808B1 (ko) | 2007-03-22 | 2015-01-14 | 노파르티스 아게 | 현수 폴리실록산-함유 중합체 사슬이 있는 예비중합체 |
| US7959975B2 (en) * | 2007-04-18 | 2011-06-14 | Micron Technology, Inc. | Methods of patterning a substrate |
| US8097175B2 (en) | 2008-10-28 | 2012-01-17 | Micron Technology, Inc. | Method for selectively permeating a self-assembled block copolymer, method for forming metal oxide structures, method for forming a metal oxide pattern, and method for patterning a semiconductor structure |
| US8294139B2 (en) | 2007-06-21 | 2012-10-23 | Micron Technology, Inc. | Multilayer antireflection coatings, structures and devices including the same and methods of making the same |
| US8372295B2 (en) * | 2007-04-20 | 2013-02-12 | Micron Technology, Inc. | Extensions of self-assembled structures to increased dimensions via a “bootstrap” self-templating method |
| CA2686563A1 (en) * | 2007-05-11 | 2008-11-20 | Aeris Therapeutics, Llc | Lung volume reduction therapy using crosslinked non-natural polymers |
| DE102007024642A1 (de) | 2007-05-24 | 2008-11-27 | Eyesense Ag | Hydrogel-Implantat für Sensorik von Metaboliten am Auge |
| US8404124B2 (en) | 2007-06-12 | 2013-03-26 | Micron Technology, Inc. | Alternating self-assembling morphologies of diblock copolymers controlled by variations in surfaces |
| ATE505517T1 (de) * | 2007-06-19 | 2011-04-15 | Cellular Bioengineering Inc | Verfahren zum schutz von substraten und zur entfernung von verunreinigungen aus solchen substraten |
| CN101815435A (zh) * | 2007-06-19 | 2010-08-25 | 细胞生物工程有限公司 | 处理微生物和/或传染原的方法 |
| US8080615B2 (en) | 2007-06-19 | 2011-12-20 | Micron Technology, Inc. | Crosslinkable graft polymer non-preferentially wetted by polystyrene and polyethylene oxide |
| TWI551305B (zh) | 2007-08-31 | 2016-10-01 | 諾華公司 | 相對黏稠封裝溶液之用途 |
| US8044111B2 (en) | 2007-11-30 | 2011-10-25 | Novartis Ag | Actinically-crosslinkable silicone-containing block copolymers |
| WO2009073205A1 (en) * | 2007-12-07 | 2009-06-11 | Biocure, Inc. | Bone substitute |
| EP2232304B1 (en) | 2007-12-10 | 2012-04-04 | Novartis AG | Method for making silicone hydrogel contact lenses |
| US7780879B2 (en) * | 2007-12-20 | 2010-08-24 | Novartis Ag | Method for making contact lenses |
| US8999492B2 (en) | 2008-02-05 | 2015-04-07 | Micron Technology, Inc. | Method to produce nanometer-sized features with directed assembly of block copolymers |
| US8101261B2 (en) | 2008-02-13 | 2012-01-24 | Micron Technology, Inc. | One-dimensional arrays of block copolymer cylinders and applications thereof |
| US8425982B2 (en) | 2008-03-21 | 2013-04-23 | Micron Technology, Inc. | Methods of improving long range order in self-assembly of block copolymer films with ionic liquids |
| US8426313B2 (en) | 2008-03-21 | 2013-04-23 | Micron Technology, Inc. | Thermal anneal of block copolymer films with top interface constrained to wet both blocks with equal preference |
| MY156057A (en) * | 2008-04-02 | 2016-01-15 | Novartis Ag | Method for making ophthalmic devices using single mold stereolithography |
| US8114300B2 (en) | 2008-04-21 | 2012-02-14 | Micron Technology, Inc. | Multi-layer method for formation of registered arrays of cylindrical pores in polymer films |
| US8114301B2 (en) | 2008-05-02 | 2012-02-14 | Micron Technology, Inc. | Graphoepitaxial self-assembly of arrays of downward facing half-cylinders |
| JP5896404B2 (ja) | 2008-07-21 | 2016-03-30 | ノバルティス アーゲー | 加水分解性基を有するシリコーン含有ポリマー材料 |
| EP2174586B1 (de) | 2008-10-02 | 2014-12-10 | EyeSense AG | Implantierbares Sensorelement |
| EP3181123A1 (en) | 2008-12-02 | 2017-06-21 | Biocompatibles Uk Ltd. | Pancreatic tumour treatment |
| TWI506333B (zh) | 2008-12-05 | 2015-11-01 | Novartis Ag | 用以傳遞疏水性舒適劑之眼用裝置及其製造方法 |
| US8944795B2 (en) * | 2008-12-18 | 2015-02-03 | Novartis Ag | Mold release sheet |
| EP2373477B1 (en) * | 2008-12-18 | 2016-07-20 | Novartis AG | Method of making an injection molded ophthalmic lens mold and such mold |
| AU2009327484B2 (en) | 2008-12-18 | 2012-08-09 | Novartis Ag | Method for making silicone hydrogel contact lenses |
| CN102316913A (zh) | 2008-12-29 | 2012-01-11 | 斯恩蒂斯有限公司 | 用于外科位点保护的合成膜组合物及其形成方法 |
| SG172394A1 (en) | 2008-12-30 | 2011-08-29 | Novartis Ag | Tri-functional uv-absorbing compounds and use thereof |
| EP2432821B1 (en) * | 2009-05-22 | 2017-08-30 | Novartis AG | Actinically-crosslinkable siloxane-containing copolymers |
| CA2760747C (en) | 2009-05-22 | 2016-12-13 | Novartis Ag | Actinically-crosslinkable siloxane-containing copolymers |
| US8258200B2 (en) * | 2009-06-02 | 2012-09-04 | The University Of Akron | Polymer networks, process for producing same, and products made therefrom |
| MY158359A (en) | 2009-09-15 | 2016-09-30 | Novartis Ag | Prepolymers suitable for making ultra-violet absorbing contact lenses |
| US8703025B2 (en) * | 2009-11-04 | 2014-04-22 | Novartis Ag | Method for making a colored contact lens |
| EP2510051A1 (en) * | 2009-12-07 | 2012-10-17 | Novartis AG | Methods for increasing the ion permeability of contact lenses |
| TWI483996B (zh) * | 2009-12-08 | 2015-05-11 | Novartis Ag | 具有共價貼合塗層之聚矽氧水凝膠鏡片 |
| US9005492B2 (en) * | 2009-12-14 | 2015-04-14 | Novartis Ag | Methods for making silicone hydrogel lenses from water-based lens formulations |
| EP2513712B1 (en) * | 2009-12-17 | 2016-08-10 | Novartis AG | Pad transfer printing method for making colored contact lenses |
| JP5618053B2 (ja) * | 2010-03-24 | 2014-11-05 | 株式会社日本コンタクトレンズ | コンタクトレンズ、及びその製造方法 |
| US9232805B2 (en) | 2010-06-29 | 2016-01-12 | Biocure, Inc. | In-situ forming hydrogel wound dressings containing antimicrobial agents |
| JP6338856B2 (ja) | 2010-07-29 | 2018-06-06 | ノバルティス アーゲー | 着色コンタクトレンズ及びそれを製造する方法 |
| US8480227B2 (en) | 2010-07-30 | 2013-07-09 | Novartis Ag | Silicone hydrogel lenses with water-rich surfaces |
| KR101564490B1 (ko) | 2010-07-30 | 2015-10-29 | 노파르티스 아게 | Ｕｖ―흡수 안과용 렌즈의 제조 방법 |
| US8557940B2 (en) | 2010-07-30 | 2013-10-15 | Novartis Ag | Amphiphilic polysiloxane prepolymers and uses thereof |
| US8304493B2 (en) | 2010-08-20 | 2012-11-06 | Micron Technology, Inc. | Methods of forming block copolymers |
| JP5852659B2 (ja) | 2010-10-06 | 2016-02-03 | ノバルティス アーゲー | 水処理可能なシリコーン含有プレポリマー及びその使用 |
| CA2813469C (en) | 2010-10-06 | 2016-01-12 | Novartis Ag | Polymerizable chain-extended polysiloxanes with pendant hydrophilic groups |
| US8835525B2 (en) | 2010-10-06 | 2014-09-16 | Novartis Ag | Chain-extended polysiloxane crosslinkers with dangling hydrophilic polymer chains |
| US9623614B2 (en) | 2010-11-10 | 2017-04-18 | Novartis Ag | Method for making contact lenses |
| WO2012074859A1 (en) | 2010-12-01 | 2012-06-07 | Novartis Ag | Lens molds having atmospheric plasma coatings thereon |
| US9156215B2 (en) | 2010-12-06 | 2015-10-13 | Novartis Ag | Method for making silicone hydrogel contact lenses |
| SG190708A1 (en) | 2010-12-13 | 2013-07-31 | Novartis Ag | Ophthalmic lenses modified with functional groups and methods of making thereof |
| SG190327A1 (en) | 2010-12-14 | 2013-07-31 | Novartis Ag | Colored contact lens |
| EP2757964B1 (en) | 2011-05-26 | 2016-05-04 | Cartiva, Inc. | Tapered joint implant and related tools |
| KR101318211B1 (ko) | 2011-05-31 | 2013-10-15 | 한국기계연구원 | 5 자유도 운동 오차 보정 기능을 갖는 능동 보정형 스테이지 및 그 운동 오차 보정 방법 |
| TWI551646B (zh) * | 2011-06-03 | 2016-10-01 | 諾華公司 | 疏水性丙烯酸系眼內水晶體材料 |
| CN106896422B (zh) | 2011-06-09 | 2021-03-23 | 爱尔康公司 | 具有纳米纹理化表面的硅氧烷水凝胶透镜 |
| EP2742510A1 (en) | 2011-08-11 | 2014-06-18 | Cellular Bioengineering, Inc. | Polymer composition |
| HUE029018T2 (en) | 2011-10-12 | 2017-02-28 | Novartis Ag | A method for producing UV absorbing contact lenses by coating |
| US8900963B2 (en) | 2011-11-02 | 2014-12-02 | Micron Technology, Inc. | Methods of forming semiconductor device structures, and related structures |
| WO2013074535A1 (en) | 2011-11-15 | 2013-05-23 | Novartis Ag | A silicone hydrogel lens with a crosslinked hydrophilic coating |
| HUE031309T2 (hu) | 2011-11-29 | 2017-07-28 | Novartis Ag | Eljárás szemészeti lencsék öntésére szolgáló legalább egy szerszámfél lencseformázó felületének kezelésére |
| CA2857181C (en) | 2011-12-08 | 2016-10-11 | Novartis Ag | Contact lenses with enzymatically degradable coatings thereon |
| US9283718B2 (en) | 2012-05-25 | 2016-03-15 | Johnson & Johnson Vision Care, Inc. | Reduced-tilt back plastic feature for a contact lens mold |
| US9422447B2 (en) | 2012-06-14 | 2016-08-23 | Novartis Ag | Azetidinium-containing copolymers and uses thereof |
| US9395468B2 (en) | 2012-08-27 | 2016-07-19 | Ocular Dynamics, Llc | Contact lens with a hydrophilic layer |
| US9087699B2 (en) | 2012-10-05 | 2015-07-21 | Micron Technology, Inc. | Methods of forming an array of openings in a substrate, and related methods of forming a semiconductor device structure |
| CA3030638C (en) | 2012-12-14 | 2020-09-15 | Novartis Ag | Amphiphilic siloxane-containing vinylic monomers and uses thereof |
| WO2014093756A1 (en) | 2012-12-14 | 2014-06-19 | Novartis Ag | Actinically-crosslinkable amphiphilic prepolymers |
| CA2889925C (en) | 2012-12-14 | 2017-07-04 | Novartis Ag | Tris(trimethyl siloxy)silane vinylic monomers and uses thereof |
| EP2931767B1 (en) | 2012-12-14 | 2017-11-08 | Novartis AG | Amphiphilic siloxane-containing (meth)acrylamides and uses thereof |
| HUE031702T2 (en) | 2012-12-17 | 2017-07-28 | Novartis Ag | A method for producing improved UV absorbing ophthalmic lenses |
| JP6420817B2 (ja) | 2013-03-15 | 2018-11-07 | バイオコンパティブルズ ユーケー リミテッド | 結像可能な塞栓性微小球 |
| US9229328B2 (en) | 2013-05-02 | 2016-01-05 | Micron Technology, Inc. | Methods of forming semiconductor device structures, and related semiconductor device structures |
| US9950483B2 (en) | 2013-05-29 | 2018-04-24 | Novartis Ag | Method for determining the surface concentration of carboxyl groups on a lens |
| US9693833B2 (en) | 2013-08-05 | 2017-07-04 | Merit Medical Systems, Inc. | Absorbent cleaning and securement devices and methods |
| GB2519738A (en) | 2013-09-06 | 2015-05-06 | Biocompatibles Uk Ltd | Radiopaque polymers |
| GB2521997A (en) | 2013-09-06 | 2015-07-15 | Biocompatibles Uk Ltd | Radiopaque polymers |
| US9177795B2 (en) | 2013-09-27 | 2015-11-03 | Micron Technology, Inc. | Methods of forming nanostructures including metal oxides |
| WO2015048035A1 (en) | 2013-09-30 | 2015-04-02 | Novartis Ag | Method for making uv-absorbing ophthalmic lenses |
| US9568645B2 (en) | 2013-09-30 | 2017-02-14 | Novartis Ag | Silicone hydrogel lenses with relatively-long thermal stability |
| WO2015056356A1 (en) * | 2013-10-17 | 2015-04-23 | The Nippon Synthetic Chemical Industry Co., Ltd. | Crosslinkable polymer |
| EP3062979B1 (en) | 2013-10-31 | 2018-08-29 | Novartis AG | Method for producing ophthalmic lenses |
| AU2014348502B2 (en) | 2013-11-15 | 2019-08-15 | Tangible Science, Inc. | Contact lens with a hydrophilic layer |
| MY183117A (en) | 2013-12-13 | 2021-02-15 | Alcon Inc | Method for making contact lenses |
| HUE038809T2 (hu) | 2013-12-17 | 2018-11-28 | Novartis Ag | Térhálósított hidrofíl bevonattal ellátott szilikon hidrogél lencse |
| WO2015095556A1 (en) | 2013-12-20 | 2015-06-25 | Novartis Ag | Reusable castings molds and method of making such molds |
| CN105873748B (zh) | 2013-12-20 | 2018-08-03 | 诺华股份有限公司 | 用于制备接触镜片的模具 |
| WO2015134449A1 (en) | 2014-03-05 | 2015-09-11 | Novartis Ag | Method for automatic inspection of contact lenses |
| CA2940581C (en) | 2014-04-08 | 2018-05-15 | Novartis Ag | Ophthalmic lenses with oxygen-generating elements therein |
| CA2940203C (en) | 2014-04-25 | 2019-08-06 | Novartis Ag | Carbosiloxane vinylic monomers |
| WO2015164582A1 (en) | 2014-04-25 | 2015-10-29 | Novartis Ag | Hydrophilized carbosiloxane vinylic monomers |
| CN106661224B (zh) | 2014-08-26 | 2019-10-11 | 诺华股份有限公司 | 聚(噁唑啉-共-乙烯亚胺)-表氯醇共聚物及其用途 |
| MY183678A (en) | 2014-08-26 | 2021-03-08 | Alcon Inc | Method for applying stable coating on silicone hydrogel contact lenses |
| US9408684B2 (en) | 2014-10-03 | 2016-08-09 | Soft Health Technologies, Llc | Systems and methods for incontinence control |
| US10160141B2 (en) | 2014-11-25 | 2018-12-25 | Novartis Ag | Molds for making contact lenses |
| CN107206119B (zh) | 2014-12-09 | 2021-01-29 | 实体科学公司 | 具有生物相容性层的医疗设备涂层 |
| EP3233448B1 (en) | 2014-12-17 | 2019-09-18 | Novartis AG | Methods of using reusable lens molds |
| CN107000344B (zh) | 2014-12-17 | 2019-06-07 | 诺华股份有限公司 | 可再使用的镜片模具及其使用方法 |
| WO2016100457A1 (en) | 2014-12-17 | 2016-06-23 | Novartis Ag | Reusable lens molds and methods of use thereof |
| US9976112B2 (en) | 2015-03-04 | 2018-05-22 | Merit Medical Systems, Inc. | Absorbent pads and methods of manufacturing |
| ES2837120T3 (es) | 2015-03-11 | 2021-06-29 | Univ Florida | Control del tamaño de malla de lubricación en hidrogeles gemini |
| US9907663B2 (en) | 2015-03-31 | 2018-03-06 | Cartiva, Inc. | Hydrogel implants with porous materials and methods |
| WO2016161026A1 (en) | 2015-03-31 | 2016-10-06 | Cartiva, Inc. | Carpometacarpal (cmc) implants and methods |
| WO2016168363A1 (en) | 2015-04-14 | 2016-10-20 | Cartiva, Inc. | Tooling for creating tapered opening in tissue and related methods |
| MX370083B (es) | 2015-05-06 | 2019-11-29 | Zoetis Services Llc | Formulacion de hidrogel con adhesion moderada. |
| MY179854A (en) | 2015-05-07 | 2020-11-18 | Alcon Inc | Method for producing contact lenses with durable lubricious coatings thereon |
| JP6591566B2 (ja) | 2015-06-02 | 2019-10-16 | ノバルティス アーゲー | 可視光光開始剤およびその使用 |
| GB201515602D0 (en) | 2015-09-03 | 2015-10-21 | Biocompatibles Uk Ltd | Polymers and microspheres |
| EP3344447B1 (en) | 2015-09-04 | 2019-12-11 | Novartis AG | Method for producing contact lenses with durable lubricious coatings thereon |
| JP6580788B2 (ja) * | 2015-12-02 | 2019-09-25 | ノバルティス アーゲー | 水溶性ｕｖ吸収化合物およびその使用 |
| JP6595120B2 (ja) | 2015-12-03 | 2019-10-23 | ノバルティス アーゲー | コンタクトレンズパッケージング溶液 |
| CN108367517A (zh) | 2015-12-15 | 2018-08-03 | 诺华股份有限公司 | 用于生产具有润滑表面的接触镜片的方法 |
| WO2017103792A1 (en) | 2015-12-15 | 2017-06-22 | Novartis Ag | Amphiphilic branched polydiorganosiloxane macromers |
| KR102604468B1 (ko) | 2015-12-15 | 2023-11-22 | 알콘 인코포레이티드 | 실리콘 하이드로겔 콘택트 렌즈 상에 안정한 코팅을 적용하기 위한 방법 |
| US10328645B2 (en) | 2015-12-17 | 2019-06-25 | Novartis Ag | Reusable lens molds and methods of use thereof |
| WO2017145022A1 (en) | 2016-02-22 | 2017-08-31 | Novartis Ag | Uv/visible-absorbing vinylic monomers and uses thereof |
| EP3419966B1 (en) | 2016-02-22 | 2020-03-25 | Alcon Inc. | Uv-absorbing vinylic monomers and uses thereof |
| JP7038111B2 (ja) | 2016-09-20 | 2022-03-17 | アルコン インク． | ヒドロゲルコンタクトレンズ上に潤滑性コーティングを有するヒドロゲルコンタクトレンズ |
| EP3516429B1 (en) | 2016-09-20 | 2021-02-17 | Alcon Inc. | Colored hydrogel contact lenses with lubricious coating thereon |
| WO2018055491A1 (en) | 2016-09-20 | 2018-03-29 | Novartis Ag | Process for producing contact lenses with durable lubricious coatings thereon |
| HUE056815T2 (hu) | 2016-09-20 | 2022-03-28 | Alcon Inc | Eljárás vízoldható, hõkezeléssel térhálósítható polimer anyag elõállítására |
| JP6777812B2 (ja) | 2016-10-19 | 2020-10-28 | アルコン インク． | ペンダントチオール基を有する親水性コポリマー |
| HUE051063T2 (hu) | 2016-10-19 | 2021-03-01 | Alcon Inc | Hidrofil kopolimer egyetlen tiol-tartalmú lánczáró csoporttal |
| US10527757B2 (en) | 2016-10-26 | 2020-01-07 | Novartis Ag | Amphiphilic branched polydiorganosiloxane macromers |
| WO2018078542A1 (en) | 2016-10-26 | 2018-05-03 | Novartis Ag | Soft contact lenses with a lubricious coating covalently-attached thereon |
| EP3532276B1 (en) | 2016-10-31 | 2021-03-03 | Alcon Inc. | Method for producing surface coated contact lenses with wearing comfort |
| EP3542193A1 (en) | 2016-11-18 | 2019-09-25 | Novartis AG | Method for making ophthalmic lenses |
| CA3055265C (en) | 2017-04-13 | 2023-12-19 | Novartis Ag | Colored contact lenses and method of making the same |
| US10156736B2 (en) | 2017-04-13 | 2018-12-18 | Novartis Ag | Colored contact lenses and method of making the same |
| EP3655448B1 (en) | 2017-07-18 | 2026-01-21 | Alcon Inc. | Phosphorylcholine-containing poly(meth)acrylamide-based copolymers |
| EP3655446B1 (en) | 2017-07-18 | 2022-08-31 | Alcon Inc. | Water-soluble, thermally-crosslinkable polymeric material comprising one or more poly(meth)acrylamide-based copolymers with carboxyl-terminated pendant chains |
| JP6423495B1 (ja) * | 2017-07-21 | 2018-11-14 | 株式会社メンテック | ノズルキャップ、それを備えたノズル装置及び薬液の散布方法 |
| US10809181B2 (en) | 2017-08-24 | 2020-10-20 | Alcon Inc. | Method and apparatus for determining a coefficient of friction at a test site on a surface of a contact lens |
| EP3676082A1 (en) | 2017-08-29 | 2020-07-08 | Alcon Inc. | Cast-molding process for producing contact lenses |
| CN117492228A (zh) | 2017-12-13 | 2024-02-02 | 爱尔康公司 | 周抛和月抛水梯度接触镜片 |
| HUE059157T2 (hu) | 2018-01-22 | 2022-10-28 | Alcon Inc | Formaöntéses eljárás UV-t elnyelõ kontaktlencse elõállítására |
| JP7485602B2 (ja) | 2018-01-30 | 2024-05-16 | アルコン インク． | その上に潤滑性コーティングを有するコンタクトレンズ |
| JP6842435B2 (ja) | 2018-02-19 | 2021-03-17 | 信越化学工業株式会社 | ラジカル硬化性オルガノシロキサングラフトポリビニルアルコール系重合体及びその製造方法 |
| WO2019198034A1 (en) | 2018-04-13 | 2019-10-17 | Alcon Inc. | Evaluation method for the coverage of a coating on a contact lens surface |
| TW202000189A (zh) | 2018-06-29 | 2020-01-01 | 英商白康帝英國有限公司 | 不透射線聚合物 |
| WO2020100090A1 (en) | 2018-11-15 | 2020-05-22 | Alcon Inc. | Contact lens with phosphorylcholine-modified polyvinylalcohols therein |
| EP3917977A1 (en) | 2019-01-28 | 2021-12-08 | Alcon Inc. | High molecular weight poly(methacrylic acid) |
| CN113727699A (zh) | 2019-03-22 | 2021-11-30 | 生物相容英国有限公司 | 栓塞微球和方法 |
| WO2020208576A1 (en) | 2019-04-10 | 2020-10-15 | Alcon Inc. | Method for producing coated contact lenses |
| MY206069A (en) | 2019-05-28 | 2024-11-27 | Alcon Inc | Pad transfer printing method for making colored contact lenses |
| HUE069794T2 (hu) | 2019-11-04 | 2025-04-28 | Alcon Inc | Eljárás különbözõ puhaságú felületekkel rendelkezõ kontaktlencsék elõállítására |
| WO2021090170A1 (en) | 2019-11-05 | 2021-05-14 | Alcon Inc. | Method for determining coating thickness on coated contact lenses |
| KR20250007692A (ko) | 2019-12-16 | 2025-01-14 | 알콘 인코포레이티드 | 습윤성 실리콘 히드로겔 콘택트 렌즈 |
| US20210271109A1 (en) | 2019-12-19 | 2021-09-02 | Alcon Inc. | Cosmetic contact lens for color blindness |
| WO2021181307A1 (en) | 2020-03-11 | 2021-09-16 | Alcon Inc. | Photochromic polydiorganosiloxane vinylic crosslinkers |
| US20240216823A1 (en) | 2020-04-28 | 2024-07-04 | Diamant Toys Ltd | Gaming kits and methods of playing with housings reconfigurable by retrievable unlocking elements |
| WO2022023966A1 (en) | 2020-07-28 | 2022-02-03 | Alcon Inc. | Contact lenses with softer lens surfaces |
| HUE069913T2 (hu) | 2020-11-04 | 2025-04-28 | Alcon Inc | Eljárás fotokróm kontaktlencsék elõállítására |
| EP4240578B1 (en) | 2020-11-04 | 2024-12-18 | Alcon Inc. | Method for making photochromic contact lenses |
| US12351688B2 (en) | 2021-02-09 | 2025-07-08 | Alcon Inc. | Hydrophilized polydiorganosiloxane vinylic crosslinkers |
| EP4285948A4 (en) * | 2021-03-02 | 2024-12-04 | Toray Industries, Inc. | Coated medical device and production method therefor |
| EP4304842B1 (en) | 2021-03-08 | 2026-05-06 | Alcon Inc. | Method for making photofunctional contact lenses |
| EP4305490B1 (en) | 2021-03-11 | 2026-04-15 | Alcon Inc. | Ophthalmic lenses with cosmetic film therein |
| WO2022201013A1 (en) | 2021-03-23 | 2022-09-29 | Alcon Inc. | Polysiloxane vinylic crosslinkers with high refractive index |
| HUE071263T2 (hu) | 2021-03-24 | 2025-08-28 | Alcon Inc | Eljárás beágyazott hidrogél kontaktlencse elõállítására |
| US12360289B2 (en) | 2021-04-01 | 2025-07-15 | Alcon Inc. | Method for making embedded hydrogel contact lenses |
| US12194699B2 (en) | 2021-04-01 | 2025-01-14 | Alcon Inc. | Embedded hydrogel contact lenses |
| WO2022224169A1 (en) | 2021-04-22 | 2022-10-27 | Alcon Inc. | Method for applying a coating onto a non-silicone hydrogel lens |
| WO2022263994A1 (en) | 2021-06-14 | 2022-12-22 | Alcon Inc. | Multifocal diffractive silicone hydrogel contact lenses |
| CN118434411A (zh) | 2021-12-23 | 2024-08-02 | 波士顿科学医疗设备有限公司 | 化学栓塞组合物及其治疗方法 |
| WO2023209569A1 (en) | 2022-04-26 | 2023-11-02 | Alcon Inc. | Method for making embedded hydrogel contact lenses |
| EP4514595A1 (en) | 2022-04-26 | 2025-03-05 | Alcon Inc. | Method for making embedded hydrogel contact lenses |
| TW202406726A (zh) | 2022-04-28 | 2024-02-16 | 瑞士商愛爾康公司 | 用於製造ｕｖ吸收性和ｈｅｖｌ吸收性眼科鏡片之方法 |
| WO2023218324A1 (en) | 2022-05-09 | 2023-11-16 | Alcon Inc. | Method for making embedded hydrogel contact lenses |
| EP4529621A1 (en) | 2022-05-23 | 2025-04-02 | Alcon Inc. | Uv/hevl-filtering contact lenses |
| EP4532187A1 (en) | 2022-05-25 | 2025-04-09 | Alcon Inc. | Method for making embedded hydrogel contact lenses |
| JP2025525733A (ja) | 2022-08-17 | 2025-08-07 | アルコン インク． | ハイドロゲルコーティングをその上に有するコンタクトレンズ |
| CN120418072A (zh) | 2023-02-02 | 2025-08-01 | 爱尔康公司 | 水梯度硅氧烷水凝胶隐形眼镜 |
| CN120569663A (zh) | 2023-02-28 | 2025-08-29 | 爱尔康公司 | 用于嵌入式隐形眼镜的彩色掩模 |
| WO2024194826A1 (en) | 2023-03-22 | 2024-09-26 | Alcon Inc. | Method for making embedded hydrogel contact lenses |
| EP4713721A1 (en) | 2023-05-18 | 2026-03-25 | Alcon Inc. | Uv/hevl-filtering silicone hydrogel contact lenses |
| EP4720728A1 (en) | 2023-05-25 | 2026-04-08 | Alcon Inc. | Coated silicone hydrogel contact lenses and method for making the same |
| US20240399686A1 (en) | 2023-06-01 | 2024-12-05 | Alcon Inc. | Method for making embedded hydrogel contact lenses |
| CN121443681A (zh) | 2023-08-07 | 2026-01-30 | 爱尔康公司 | Uv/hevl过滤性硅氧烷水凝胶隐形眼镜 |
| US20260104598A1 (en) | 2024-10-15 | 2026-04-16 | Alcon Inc. | Composite contact lenses with ultrathin objects |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1495381B2 (de) * | 1963-09-07 | 1971-06-24 | Czeskoslovenska akademie ved , Prag | Verfahren zur herstellung von kontaktlinsen oder kontakt linsenrohlingen aus quellfaehigen hydrogelen |
| NL128305C (enExample) | 1963-09-11 | |||
| JPS501246A (enExample) * | 1973-05-11 | 1975-01-08 | ||
| JPS50124608A (enExample) * | 1974-03-18 | 1975-09-30 | ||
| US4113224A (en) * | 1975-04-08 | 1978-09-12 | Bausch & Lomb Incorporated | Apparatus for forming optical lenses |
| SU558248A1 (ru) | 1974-12-17 | 1977-05-15 | Московский научно-исследовательский институт глазных болезней им. Гельмгольца | Комбинированна контактна линза и способ ее изготовлени |
| JPS5247883A (en) * | 1975-10-16 | 1977-04-16 | Kansai Paint Co Ltd | Preparation of molded product of hydrogel |
| JPS52124608A (en) * | 1976-04-10 | 1977-10-19 | Daido Shingo | Method of controlling train |
| FR2402525A1 (fr) | 1977-09-12 | 1979-04-06 | Toray Industries | Procede de fabrication de compositions de lentilles de contact molles et nouveaux produits ainsi obtenus |
| ATE10284T1 (de) | 1979-04-10 | 1984-11-15 | Kelvin Lenses Limited | Polymere, verfahren zu deren herstellung sowie daraus hergestellte geformte gegenstaende und kontaktlinsen. |
| DE3113690A1 (de) * | 1981-04-04 | 1982-10-28 | Elastogran GmbH, 2844 Lemförde | "verfahren zur herstellung von geschlossenzelligen polyurethan-formteilen mit einer verdichteten randzone" |
| US4426492A (en) * | 1981-09-03 | 1984-01-17 | Plastomedical Sciences, Inc. | Disposable, hydrogel soft contact lenses |
| JPH0234994B2 (ja) * | 1981-09-21 | 1990-08-07 | Sunstar Engineering Inc | Takoshitsuzainosekisoseikeikakoho |
| US4430458A (en) * | 1981-10-08 | 1984-02-07 | Kelvin Lenses Limited | Hydrogel-forming polymeric materials |
| JPS58104286A (ja) * | 1981-12-16 | 1983-06-21 | ジェイエスアール株式会社 | 着色された成形品の製造方法 |
| GB2144749B (en) | 1983-08-09 | 1986-10-08 | Plastomedical Sciences Inc | Disposable, hydrogel soft cantact lenses |
| CH664924A5 (de) * | 1984-12-04 | 1988-04-15 | Stella Werke Ag | Verfahren zur herstellung von duroplastmantelplatten und vorrichtung zur durchfuehrung des verfahrens. |
| US4598122A (en) * | 1985-01-22 | 1986-07-01 | Ciba-Geigy Corporation | Polyoxirane crosslinked polyvinyl alcohol hydrogel contact lens |
| CA1283907C (en) | 1985-03-21 | 1991-05-07 | Robert K. Pinschmidt, Jr. | Self-and diol reactive formaldehyde-free crosslinking monomers and their derived polymers |
| US4864055A (en) * | 1985-03-21 | 1989-09-05 | Air Products And Chemicals, Inc. | Self- and diol reactive formaldehyde-free crosslinking monomers and their derived polymers |
| US4788288A (en) * | 1985-07-30 | 1988-11-29 | Air Products And Chemicals, Inc. | Self-and Hydroxyl reactive formaldehyde-free cyclic hemiamidal and hemiamide ketal crosslinking monomers |
| US4691026A (en) * | 1985-07-30 | 1987-09-01 | Air Products And Chemicals, Inc. | Self- and hydroxyl reactive formaldehyde-free cyclic hemiamidal and hemiamide ketal crosslinking monomers |
| US4665123A (en) * | 1985-12-13 | 1987-05-12 | Ciba-Geigy Corporation | Polyvinyl alcohol derivatives containing pendant (meth)acryloylvinylic monomer reaction product units bound through urethane groups and hydrogel contact lenses made therefrom |
| EP0216074B1 (en) * | 1985-07-31 | 1993-06-16 | Ciba-Geigy Ag | Polyvinyl alcohol derivatives and crosslinked hydrogel contact lenses made therefrom |
| US4663410A (en) | 1985-08-06 | 1987-05-05 | Air Products And Chemicals, Inc. | Polymers of self- and hydroxyl reactive formaldehyde-free cyclic hemiamidal and hemiamide ketal crosslinking monomers |
| US4670506A (en) * | 1985-12-23 | 1987-06-02 | Ciba-Geigy Corporation | Polyvinyl alcohol derivatives containing pendant (meth)acryloyl units bound through urethane groups and crosslinked hydrogel contact lenses made therefrom |
| JPH07100777B2 (ja) * | 1986-01-10 | 1995-11-01 | 大日本インキ化学工業株式会社 | 光又は電子線架橋型水系被覆剤 |
| JPS6334108A (ja) * | 1986-07-30 | 1988-02-13 | Hitachi Ltd | 光デイスク用基板の製造方法および装置 |
| JPH0762048B2 (ja) * | 1986-09-25 | 1995-07-05 | 工業技術院長 | 感光性樹脂 |
| US4904421A (en) * | 1987-11-25 | 1990-02-27 | Tomei Sangyo Kabushiki Kaisha | Soft ocular lens and method for its preparation |
| US4978713A (en) * | 1987-12-16 | 1990-12-18 | Ciba-Geigy Corporation | Polyvinyl alcohol derivatives containing pendant vinylic monomer reaction product units bound through ether groups and hydrogel contact lenses made therefrom |
| JPH07108627B2 (ja) * | 1988-10-20 | 1995-11-22 | 株式会社クボタ | 作業用車両のアクセル装置 |
| JPH02109792A (ja) * | 1988-10-20 | 1990-04-23 | Ishikawajima Harima Heavy Ind Co Ltd | 液化ガス運搬船 |
| JP2860388B2 (ja) * | 1990-01-19 | 1999-02-24 | 工業技術院長 | 眼内レンズ用材料 |
| JPH047302A (ja) * | 1990-04-25 | 1992-01-10 | Japan Synthetic Rubber Co Ltd | ゲルの製造方法 |
| JPH04109792A (ja) * | 1990-08-29 | 1992-04-10 | Sharp Corp | 自動販売データ収集システム |
| EP0484015B1 (en) * | 1990-10-30 | 1995-09-27 | Minnesota Mining And Manufacturing Company | Method for curing ocular devices |
| GB2263699B (en) * | 1992-02-03 | 1995-11-29 | Sericol Ltd | Photopolymerizable alcohols and compositions containing them |
| US5360864A (en) * | 1992-05-04 | 1994-11-01 | Ulano Corporation | Process for preparation of photosensitive composition |
| US5326669A (en) * | 1992-05-04 | 1994-07-05 | Ulano Corporation | Photosensitive compositions |
-
1993
- 1993-10-27 TW TW082108941A patent/TW272976B/zh not_active IP Right Cessation
-
1994
- 1994-07-26 AT AT94810444T patent/ATE162814T1/de active
- 1994-07-26 PT PT97103579T patent/PT790258E/pt unknown
- 1994-07-26 EP EP97103579A patent/EP0790258B1/de not_active Expired - Lifetime
- 1994-07-26 AT AT97103579T patent/ATE251183T1/de active
- 1994-07-26 ES ES94810444T patent/ES2112503T3/es not_active Expired - Lifetime
- 1994-07-26 DE DE59410329T patent/DE59410329D1/de not_active Expired - Lifetime
- 1994-07-26 DK DK97103579T patent/DK0790258T3/da active
- 1994-07-26 EP EP94810444A patent/EP0641806B1/de not_active Expired - Lifetime
- 1994-07-26 DE DE59405162T patent/DE59405162D1/de not_active Expired - Lifetime
- 1994-07-26 ES ES97103579T patent/ES2208779T3/es not_active Expired - Lifetime
- 1994-07-26 DK DK94810444T patent/DK0641806T3/da active
- 1994-07-26 SG SG9601209A patent/SG49623A1/en unknown
- 1994-07-28 IL IL11048794A patent/IL110487A/en not_active IP Right Cessation
- 1994-07-28 IL IL12319294A patent/IL123192A/xx not_active IP Right Cessation
- 1994-07-29 AU AU68802/94A patent/AU680507B2/en not_active Expired
- 1994-08-03 CZ CZ19941869A patent/CZ289627B6/cs not_active IP Right Cessation
- 1994-08-03 FI FI943614A patent/FI114714B/fi not_active IP Right Cessation
- 1994-08-04 JP JP6183535A patent/JP2914872B2/ja not_active Expired - Lifetime
- 1994-08-04 US US08/286,035 patent/US5508317A/en not_active Expired - Lifetime
- 1994-08-04 CA CA002221162A patent/CA2221162C/en not_active Expired - Lifetime
- 1994-08-04 CA CA002129461A patent/CA2129461C/en not_active Expired - Lifetime
- 1994-08-04 NZ NZ286397A patent/NZ286397A/en not_active IP Right Cessation
- 1994-08-04 NZ NZ264175A patent/NZ264175A/en not_active IP Right Cessation
- 1994-08-04 HU HU9402297A patent/HU221056B1/hu unknown
- 1994-08-04 HU HU0002451A patent/HU228123B1/hu unknown
- 1994-08-05 KR KR1019940019316A patent/KR100336138B1/ko not_active Expired - Lifetime
- 1994-08-05 PL PL94304580A patent/PL178192B1/pl unknown
- 1994-08-05 RU RU94028652A patent/RU2141896C1/ru active
- 1994-08-05 CN CN94115001A patent/CN1062513C/zh not_active Expired - Lifetime
- 1994-08-05 NO NO942907A patent/NO309381B1/no not_active IP Right Cessation
- 1994-08-05 NO NO942908A patent/NO942908D0/no unknown
- 1994-08-05 ZA ZA945872A patent/ZA945872B/xx unknown
- 1994-08-05 BR BR9403174A patent/BR9403174A/pt not_active IP Right Cessation
-
1995
- 1995-06-05 US US08/463,546 patent/US5583163A/en not_active Expired - Lifetime
- 1995-12-22 US US08/575,799 patent/US5789464A/en not_active Expired - Lifetime
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1996
- 1996-07-03 US US08/678,437 patent/US5849810A/en not_active Expired - Lifetime
-
1997
- 1997-05-22 AU AU23579/97A patent/AU705891B2/en not_active Expired
- 1997-09-11 NO NO19974192A patent/NO318658B1/no not_active IP Right Cessation
-
1998
- 1998-02-05 IL IL12319298A patent/IL123192A0/xx unknown
- 1998-02-11 GR GR980400267T patent/GR3026098T3/el unknown
- 1998-05-23 HK HK98104469A patent/HK1005338A1/xx not_active IP Right Cessation
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2001
- 2001-06-22 CZ CZ20012351A patent/CZ291162B6/cs not_active IP Right Cessation
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2003
- 2003-03-31 FI FI20030475A patent/FI114713B/fi not_active IP Right Cessation
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