BRPI9917883A2 - catalisador compreendendo uma sílica porosa de alta área de superfície, e, processos para preparar um catalisador, para fabricar ácidos etilenicamente insaturados ou ésteres dos mesmos e para fabricar metacrilato de metila - Google Patents
catalisador compreendendo uma sílica porosa de alta área de superfície, e, processos para preparar um catalisador, para fabricar ácidos etilenicamente insaturados ou ésteres dos mesmos e para fabricar metacrilato de metilaInfo
- Publication number
- BRPI9917883A2 BRPI9917883A2 BR9917883A BR9917883A BRPI9917883A2 BR PI9917883 A2 BRPI9917883 A2 BR PI9917883A2 BR 9917883 A BR9917883 A BR 9917883A BR 9917883 A BR9917883 A BR 9917883A BR PI9917883 A2 BRPI9917883 A2 BR PI9917883A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- making
- esters
- preparing
- processes
- Prior art date
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title 2
- 239000003054 catalyst Substances 0.000 title 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 title 1
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- 150000002148 esters Chemical class 0.000 title 1
- 239000000377 silicon dioxide Substances 0.000 title 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/14—Silica and magnesia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
- B01J23/04—Alkali metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
- C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/651—50-500 nm
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9807498.2A GB9807498D0 (en) | 1998-04-08 | 1998-04-08 | Production of unsaturated acids therfore and catalysts therfor |
PCT/GB1999/001029 WO1999052628A1 (en) | 1998-04-08 | 1999-04-01 | Production of unsaturated acids or esters thereof and catalysts therefor |
BRPI9909535-1A BR9909535B1 (pt) | 1998-04-08 | 1999-04-01 | catalisador, e, processos para preparar um catalisador, para fabricar ácidos etilenicamente insaturados ou ésteres dos mesmos e para fabricar metacrilato de metila. |
Publications (3)
Publication Number | Publication Date |
---|---|
BRPI9917883A2 true BRPI9917883A2 (pt) | 2011-05-03 |
BRPI9917883B1 BRPI9917883B1 (pt) | 2016-03-22 |
BRPI9917883B8 BRPI9917883B8 (pt) | 2017-02-07 |
Family
ID=10830021
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI9909535-1A BR9909535B1 (pt) | 1998-04-08 | 1999-04-01 | catalisador, e, processos para preparar um catalisador, para fabricar ácidos etilenicamente insaturados ou ésteres dos mesmos e para fabricar metacrilato de metila. |
BRPI9917883A BRPI9917883B8 (pt) | 1998-04-08 | 1999-04-01 | catalisador compreendendo uma sílica porosa de alta área de superfície, e, processos para preparar um catalisador, para fabricar ácidos etilenicamente insaturados ou ésteres dos mesmos e para fabricar metacrilato de metila |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI9909535-1A BR9909535B1 (pt) | 1998-04-08 | 1999-04-01 | catalisador, e, processos para preparar um catalisador, para fabricar ácidos etilenicamente insaturados ou ésteres dos mesmos e para fabricar metacrilato de metila. |
Country Status (18)
Country | Link |
---|---|
US (2) | US6544924B1 (pt) |
EP (3) | EP1179366B1 (pt) |
JP (2) | JP2002511336A (pt) |
KR (3) | KR100592857B1 (pt) |
CN (1) | CN1154537C (pt) |
AU (1) | AU750405C (pt) |
BR (2) | BR9909535B1 (pt) |
CA (1) | CA2326778C (pt) |
CZ (2) | CZ302025B6 (pt) |
DE (3) | DE69912113T2 (pt) |
ES (3) | ES2251541T3 (pt) |
GB (1) | GB9807498D0 (pt) |
MY (1) | MY119843A (pt) |
NZ (1) | NZ507249A (pt) |
PL (2) | PL206387B1 (pt) |
RU (1) | RU2203731C2 (pt) |
TW (1) | TW408032B (pt) |
WO (1) | WO1999052628A1 (pt) |
Families Citing this family (64)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6329549B1 (en) * | 2000-04-06 | 2001-12-11 | Air Products And Chemicals, Inc. | Dimethyl ether for methyl group attachment on a carbon adjacent to an electron withdrawing group |
EP1240943A1 (en) * | 2000-10-21 | 2002-09-18 | Degussa AG | Catalyst support |
US6887822B2 (en) | 2001-09-25 | 2005-05-03 | Pq Corporation | Method for making silica supported, crush-resistant catalysts |
US20040006244A1 (en) * | 2002-05-22 | 2004-01-08 | Manzer Leo Ernest | Process for making ethyencially unsaturated acids and acids |
US7094730B2 (en) * | 2002-10-31 | 2006-08-22 | Delphi Technologies, Inc. | Gas treatment device, methods for making and using the same, and a vehicle exhaust system |
JP4497457B2 (ja) * | 2003-06-03 | 2010-07-07 | 三菱レイヨン株式会社 | メタクリル酸エステル製造用触媒の製造方法 |
US7139226B2 (en) * | 2004-02-25 | 2006-11-21 | Brady Worldwide, Inc. | Long term rapid color changing time indicator |
US7983896B2 (en) | 2004-03-05 | 2011-07-19 | SDL Language Technology | In-context exact (ICE) matching |
JP4497459B2 (ja) * | 2004-06-08 | 2010-07-07 | 三菱レイヨン株式会社 | メタクリル酸エステルの製造方法 |
US7141682B2 (en) | 2004-07-27 | 2006-11-28 | E. I. Du Pont De Nemours And Company | Liquid phase synthesis of methylene lactones using oxnitride catalyst |
US7151185B2 (en) | 2004-07-27 | 2006-12-19 | E. I. Du Pont De Nemours And Company | Gas phase synthesis of methylene lactones using oxynitride catalyst |
US7153981B2 (en) | 2004-07-27 | 2006-12-26 | E. I. Du Pont De Nemours And Company | Supercritical fluid phase synthesis of methylene lactones using oxynitride catalyst |
US10352484B2 (en) * | 2004-08-05 | 2019-07-16 | Faurecia Emissions Control Technologies Germany Gmbh | Exhaust system |
US7348442B2 (en) | 2004-10-18 | 2008-03-25 | E. I. Du Pont De Nemours And Company | Gas phase synthesis of methylene lactones using catalysts derived from hydrotalcite precursors |
JP4895251B2 (ja) * | 2005-06-15 | 2012-03-14 | 三菱レイヨン株式会社 | メタクリル酸エステル製造用触媒の製造方法 |
DE102007025442B4 (de) | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
DE102007025362A1 (de) | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025223A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025443A1 (de) * | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung |
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GB0809332D0 (en) | 2008-05-22 | 2008-07-02 | Lucite Int Uk Ltd | Production of ethylenically unsaturated acids or esters thereof |
DE102008059341A1 (de) | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Katalysatorträger, Verfahren zu seiner Herstellung sowie Verwendung |
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GB201011091D0 (en) * | 2010-07-01 | 2010-08-18 | Lucite Int Uk Ltd | A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters |
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WO2013184345A1 (en) | 2012-06-04 | 2013-12-12 | Rohm And Haas Company | Process for production of methacrylic acid esters |
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US9073846B2 (en) | 2013-06-05 | 2015-07-07 | Celanese International Corporation | Integrated process for the production of acrylic acids and acrylates |
US20160102043A1 (en) * | 2013-06-26 | 2016-04-14 | Rohm And Haas Company | Process for production of methacrylic acid esters |
US9120743B2 (en) | 2013-06-27 | 2015-09-01 | Celanese International Corporation | Integrated process for the production of acrylic acids and acrylates |
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GB201617534D0 (en) * | 2016-10-14 | 2016-11-30 | Lucite International Uk Limited | A process for the production of Ethylenically unsaturated carboxylic acid esters and a catalyst therefor |
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SG11202109990XA (en) * | 2019-03-12 | 2021-10-28 | Mitsubishi Chem Corp | Catalyst, method for preparing catalyst, and method for producing unsaturated carboxylic acid and/or unsaturated carboxylic acid ester |
GB201903455D0 (en) | 2019-03-13 | 2019-04-24 | Lucite Int Uk Ltd | A process for the protection of a catalyst, a catalyst therefrom and a process for production of ethylenically unsaturated carboxlyic acids or esters |
GB201903452D0 (en) * | 2019-03-13 | 2019-04-24 | Lucite Int Uk Ltd | A catalyst and a process for the production of ethylenically unsaturated carboxylic acids for esters |
EP3966177A4 (en) * | 2019-05-06 | 2023-01-04 | W. R. Grace & Co.-Conn. | USE OF SILICA-ZIRCONIA CATALYSTS IN PROCESSES FOR REDUCING GLYCIDOL, GLYCIDYLESTERS OR BOTH GLYCIDOL AND GLYCIDYLESTERS |
US11806694B2 (en) | 2020-03-12 | 2023-11-07 | Mitsubishi Chemical UK Limited | Catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters |
CN112844356A (zh) * | 2021-02-02 | 2021-05-28 | 中国科学院过程工程研究所 | 一种合成甲基丙烯酸甲酯的催化剂及其应用方法 |
CN112774658A (zh) * | 2021-02-02 | 2021-05-11 | 中国科学院过程工程研究所 | 一种由乙酸甲酯和甲醛合成丙烯酸甲酯的酸碱双功能催化剂及制备方法 |
EP4353355A1 (en) | 2021-06-01 | 2024-04-17 | Mitsubishi Chemical Corporation | Catalyst, method for producing catalyst, and method for producing unsaturated carboxylic acid and/or unsaturated carboxylic acid ester |
CN117654466B (zh) * | 2024-02-01 | 2024-04-23 | 浙江新和成股份有限公司 | 催化剂及其制备方法、烯属不饱和酸或其酯的制备方法 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US393888A (en) * | 1888-12-04 | Best available cop | ||
US3933888A (en) * | 1972-10-06 | 1976-01-20 | Rohm And Haas Company | Production of unsaturated acids, esters and nitriles, and catalyst therefor |
GB8318675D0 (en) | 1983-07-11 | 1983-08-10 | Ici Plc | Chemical process |
JPS6115739A (ja) * | 1984-04-25 | 1986-01-23 | Toa Nenryo Kogyo Kk | 水素化処理用触媒 |
US4845070A (en) * | 1984-07-18 | 1989-07-04 | Amoco Corporation | Catalyst for producing alpha, beta-ethylenically unsaturated aliphatic monocarboxylic acid and method of making said catalyst |
US4990662A (en) * | 1984-07-18 | 1991-02-05 | Amoco Corporation | Process for preparation of alpha, beta-unsaturated acids |
JPS62149337A (ja) * | 1985-12-23 | 1987-07-03 | Nippon Shokubai Kagaku Kogyo Co Ltd | アルカノ−ルアミン類の気相分子内脱水反応用触媒 |
AU591208B2 (en) * | 1985-12-23 | 1989-11-30 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Catalyst for vapor-phase intramolecular dehydration reaction of alkanolamines |
JPS62152539A (ja) * | 1985-12-27 | 1987-07-07 | Nippon Shokubai Kagaku Kogyo Co Ltd | アルカノ−ルアミン類の気相分子内脱水反応用触媒 |
JPS632951A (ja) * | 1986-06-23 | 1988-01-07 | Mitsubishi Gas Chem Co Inc | メチルメタアクリレ−トの製造方法 |
JPH0786672B2 (ja) * | 1987-06-23 | 1995-09-20 | 富士写真フイルム株式会社 | 画像形成方法 |
JP2637537B2 (ja) * | 1989-01-24 | 1997-08-06 | 株式会社日本触媒 | エチレンオキシド製造用銀触媒およびその製造方法 |
JP2884639B2 (ja) * | 1989-11-28 | 1999-04-19 | 三菱瓦斯化学株式会社 | 不飽和カルボン酸エステルの製造法 |
US5187132A (en) * | 1991-05-14 | 1993-02-16 | Chevron Research And Technology Company | Preparation of borosilicate zeolites |
US5258346A (en) * | 1992-07-13 | 1993-11-02 | United Catalysts Inc. | Nickel hydrogenation catalyst |
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