BR112017025913A2 - processo para preparação de uma composição de ácido purificado. - Google Patents

processo para preparação de uma composição de ácido purificado.

Info

Publication number
BR112017025913A2
BR112017025913A2 BR112017025913A BR112017025913A BR112017025913A2 BR 112017025913 A2 BR112017025913 A2 BR 112017025913A2 BR 112017025913 A BR112017025913 A BR 112017025913A BR 112017025913 A BR112017025913 A BR 112017025913A BR 112017025913 A2 BR112017025913 A2 BR 112017025913A2
Authority
BR
Brazil
Prior art keywords
fdca
esters
oxidation product
solution
ffca
Prior art date
Application number
BR112017025913A
Other languages
English (en)
Other versions
BR112017025913B1 (pt
Inventor
Rita Martins Guerreiro Rocha ALMEIDA Ana
Sofia Vagueiro De Sousa Dias Ana
Dacil Gonzalez Jimenez Ines
Mathilda Pieter Zieverink Martinus
Original Assignee
Synvina C V
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Synvina C V filed Critical Synvina C V
Publication of BR112017025913A2 publication Critical patent/BR112017025913A2/pt
Publication of BR112017025913B1 publication Critical patent/BR112017025913B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B31/00—Reduction in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B33/00—Oxidation in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00—Purification; Separation; Stabilisation; Use of additives
    • C07B63/02—Purification; Separation; Stabilisation; Use of additives by treatment giving rise to a chemical modification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/13—Crystalline forms, e.g. polymorphs

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)

Abstract

uma composição de ácido purificado compreendendo ácido 2,5-furancarboxílico é preparada em um processo, compreendendo (i) oxidar uma matéria ?prima contendo 5-alcóximetilfurfural em um produto de oxidação compreendendo ácido 2,5-furandicarboxílico (fdca) e ácido 2-formil-furan-5-carboxílico (ffca) e ésteres de fdca e, opcionalmente, ésteres de ffca; (ii) opcionalmente, dissolver pelo menos parte do produto de oxidação em um solvente polar para obter uma solução do produto de oxidação, compreendendo fdca, ffca e ésteres de fdca e, opcionalmente, ésteres de ffca; (iii) hidrolisar a pelo menos uma parte do produto de oxidação na presença de água, assim, hidrolisando pelo menos ésteres de fdca e, opcionalmente, ésteres de ffca para obter uma solução aquosa de uma composição ácida compreendendo fdca, ffca e éster de fdca em uma quantidade abaixo da quantidade de éster de fdca na solução do produto de oxidação; (iv) colocar pelo menos uma parte da solução da composição ácida obtida na etapa (iii) em contato com hidrogênio na presença de um catalisador de hidrogenação para hidrogenar ffca em produtos de hidrogenação, produzindo uma solução hidrogenada; e (v) separar pelo menos uma porção do fdca de pelo menos parte da solução hidrogenada por cristalização.
BR112017025913-3A 2015-06-05 2016-06-06 Processo para preparação de uma composição de ácido purificado BR112017025913B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL2014923 2015-06-05
NL2014923 2015-06-05
PCT/NL2016/050405 WO2016195500A1 (en) 2015-06-05 2016-06-06 Process for the preparation of a purified acid composition

Publications (2)

Publication Number Publication Date
BR112017025913A2 true BR112017025913A2 (pt) 2018-08-14
BR112017025913B1 BR112017025913B1 (pt) 2022-08-23

Family

ID=53502805

Family Applications (2)

Application Number Title Priority Date Filing Date
BR112017025913-3A BR112017025913B1 (pt) 2015-06-05 2016-06-06 Processo para preparação de uma composição de ácido purificado
BR112017025910-9A BR112017025910B1 (pt) 2015-06-05 2016-06-06 Processo para preparação de uma composição de ácido purificado

Family Applications After (1)

Application Number Title Priority Date Filing Date
BR112017025910-9A BR112017025910B1 (pt) 2015-06-05 2016-06-06 Processo para preparação de uma composição de ácido purificado

Country Status (11)

Country Link
US (2) US10351544B2 (pt)
EP (2) EP3303310B1 (pt)
JP (2) JP6615231B2 (pt)
KR (2) KR102067718B1 (pt)
CN (2) CN107848999B (pt)
AU (2) AU2016271834B2 (pt)
BR (2) BR112017025913B1 (pt)
CA (2) CA2988307C (pt)
ES (2) ES2833165T3 (pt)
MX (2) MX2017015720A (pt)
WO (2) WO2016195499A1 (pt)

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JP2017190316A (ja) * 2016-04-15 2017-10-19 三菱ケミカル株式会社 ２，５−フランジカルボン酸の精製方法
EP3652161A1 (en) * 2017-07-12 2020-05-20 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
EP3444354A1 (en) * 2017-08-16 2019-02-20 Basf Se Process of separating 2,5-diformylfuran from an aqueous mixture by cooling
TWI650318B (zh) 2017-10-30 2019-02-11 財團法人工業技術研究院 以結晶法純化２，５－呋喃二甲酸的粗產物之方法與聚酯之形成方法
US11440895B2 (en) 2018-06-25 2022-09-13 Eastman Chemical Company Oxidation process to produce 5-(alkoxycarbonyl)furan-2-carboxylic acids (ACFC)
US11655334B2 (en) 2018-06-25 2023-05-23 Eastman Chemical Company Oxidation process to produce 5 methyl 5-methylfuran-2-carboxylate (MMFC)
CN109293608B (zh) * 2018-09-21 2023-06-16 中国科学技术大学 一种5-甲酰基糠酸的制备方法
TWI697488B (zh) * 2019-07-02 2020-07-01 遠東新世紀股份有限公司 粗製2,5-呋喃二甲酸的純化方法
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US11787774B2 (en) 2019-09-05 2023-10-17 Eastman Chemical Company Efficient process for producing 5-(alkoxycarbonyl)-furan-2-carboxylic acids
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JP2023507463A (ja) 2019-12-20 2023-02-22 フラニックス・テクノロジーズ・ベーフェー 精製された２，５－フランジカルボン酸の、有機酸及び熱による処理
WO2021123189A1 (en) 2019-12-20 2021-06-24 Furanix Technologies B.V. Process for producing 2,5-furandicarboxylic acid from ethers of 5-hydroxymethylfurfural
EP4341250A1 (en) * 2021-05-20 2024-03-27 Eastman Chemical Company Purge process for 5-(methoxycarbonyl)furan-2-carboxylic acid (mcfc)
BR112023024159A2 (pt) * 2021-05-20 2024-01-30 Eastman Chem Co Processo de purga para ácido 5-(alcoxicarbonil)furan-2-carboxílico (acfc)
EP4341249A1 (en) * 2021-05-20 2024-03-27 Eastman Chemical Company Mother liquor compositiion generated in mcfc process
CN115028610B (zh) * 2022-05-07 2024-03-05 浙江恒逸石化研究院有限公司 一种2,5-呋喃二甲酸的纯化方法
WO2023242150A1 (en) 2022-06-14 2023-12-21 Furanix Technologies B.V. Producing 2,5-furandicarboxylic acid in the presence of modifying acid
WO2023242152A1 (en) 2022-06-14 2023-12-21 Furanix Technologies B.V. Producing 2,5-furandicarboxylic acid from mixed feed
WO2023242151A1 (en) 2022-06-14 2023-12-21 Furanix Technologies B.V. Producing 2,5-furandicarboxylic acid with recovery of acid
WO2024062084A1 (en) 2022-09-23 2024-03-28 Furanix Technologies B.V. Oxidation of furan derivative
CN115894411A (zh) * 2022-12-29 2023-04-04 厦门大学 低沸点溶液在2,5-呋喃二甲酸纯化中的应用及其纯化方法

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Also Published As

Publication number Publication date
CA2988307C (en) 2020-04-14
BR112017025910A2 (pt) 2018-08-14
ES2833165T3 (es) 2021-06-14
AU2016271835A1 (en) 2018-01-18
KR102067718B1 (ko) 2020-01-30
BR112017025910B1 (pt) 2022-08-23
EP3303311A1 (en) 2018-04-11
EP3303310B1 (en) 2020-08-26
JP6615231B2 (ja) 2019-12-04
CA2988392C (en) 2020-04-14
US10464913B2 (en) 2019-11-05
MX2017015723A (es) 2018-04-24
CN107848998B (zh) 2022-02-01
US20180155308A1 (en) 2018-06-07
CA2988392A1 (en) 2016-12-08
WO2016195500A1 (en) 2016-12-08
JP2018521978A (ja) 2018-08-09
AU2016271834A1 (en) 2018-01-18
ES2833164T3 (es) 2021-06-14
AU2016271835B2 (en) 2019-02-21
AU2016271834B2 (en) 2019-02-21
US20180155309A1 (en) 2018-06-07
JP6615230B2 (ja) 2019-12-04
BR112017025913B1 (pt) 2022-08-23
JP2018521980A (ja) 2018-08-09
US10351544B2 (en) 2019-07-16
KR102072002B1 (ko) 2020-01-31
WO2016195499A1 (en) 2016-12-08
EP3303310A1 (en) 2018-04-11
MX2017015720A (es) 2018-04-24
CN107848998A (zh) 2018-03-27
KR20180014816A (ko) 2018-02-09
CN107848999A (zh) 2018-03-27
KR20180015720A (ko) 2018-02-13
CA2988307A1 (en) 2016-12-08
CN107848999B (zh) 2022-02-01
EP3303311B1 (en) 2020-08-26

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B25A Requested transfer of rights approved

Owner name: FURANIX TECHNOLOGIES B.V. (NL)

B350 Update of information on the portal [chapter 15.35 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

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