BR112016015170B1 - Fio de aramida copolimerizado tingido em massa e método de preparação respectiva - Google Patents
Fio de aramida copolimerizado tingido em massa e método de preparação respectiva Download PDFInfo
- Publication number
- BR112016015170B1 BR112016015170B1 BR112016015170-4A BR112016015170A BR112016015170B1 BR 112016015170 B1 BR112016015170 B1 BR 112016015170B1 BR 112016015170 A BR112016015170 A BR 112016015170A BR 112016015170 B1 BR112016015170 B1 BR 112016015170B1
- Authority
- BR
- Brazil
- Prior art keywords
- copolymerized aramid
- cation
- basic
- basic blue
- yarn
- Prior art date
Links
- 229920003235 aromatic polyamide Polymers 0.000 title claims abstract description 133
- 239000004760 aramid Substances 0.000 title claims abstract description 130
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 73
- 229920000642 polymer Polymers 0.000 claims abstract description 67
- 239000003960 organic solvent Substances 0.000 claims abstract description 37
- 150000001768 cations Chemical class 0.000 claims abstract description 33
- 238000004040 coloring Methods 0.000 claims abstract description 31
- 239000000463 material Substances 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims abstract description 31
- LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 claims abstract description 28
- 125000004093 cyano group Chemical group *C#N 0.000 claims abstract description 20
- 238000009987 spinning Methods 0.000 claims abstract description 15
- 150000004984 aromatic diamines Chemical class 0.000 claims abstract description 13
- 230000001112 coagulating effect Effects 0.000 claims abstract description 8
- RFQSMLBZXQOMKK-UHFFFAOYSA-N [3-[(4,8-diamino-6-bromo-1,5-dioxonaphthalen-2-yl)amino]phenyl]-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)C1=CC=CC(NC=2C(C3=C(N)C=C(Br)C(=O)C3=C(N)C=2)=O)=C1 RFQSMLBZXQOMKK-UHFFFAOYSA-N 0.000 claims description 41
- NRZZJDPJVVRJIB-UHFFFAOYSA-N (4-aminophenyl)cyanamide Chemical compound NC1=CC=C(NC#N)C=C1 NRZZJDPJVVRJIB-UHFFFAOYSA-N 0.000 claims description 26
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 21
- 239000000975 dye Substances 0.000 claims description 13
- 239000000049 pigment Substances 0.000 claims description 6
- -1 CI Basic Black 7 Chemical compound 0.000 claims description 5
- VJDDAARZIFHSQY-UHFFFAOYSA-N basic black 2 Chemical compound [Cl-].C=1C2=[N+](C=3C=CC=CC=3)C3=CC(N(CC)CC)=CC=C3N=C2C=CC=1NN=C1C=CC(=O)C=C1 VJDDAARZIFHSQY-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- PMJXPPBTJCUKGB-UHFFFAOYSA-N 4-[(2,4-dimethyl-1,2,4-triazol-4-ium-3-yl)diazenyl]-n,n-dimethylaniline Chemical compound C1=CC(N(C)C)=CC=C1N=NC1=[N+](C)C=NN1C PMJXPPBTJCUKGB-UHFFFAOYSA-N 0.000 claims 2
- 230000008569 process Effects 0.000 abstract description 11
- 230000006866 deterioration Effects 0.000 abstract description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 80
- 238000005406 washing Methods 0.000 description 25
- 238000001035 drying Methods 0.000 description 22
- 238000004519 manufacturing process Methods 0.000 description 21
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 20
- 239000001110 calcium chloride Substances 0.000 description 20
- 229910001628 calcium chloride Inorganic materials 0.000 description 20
- 235000011148 calcium chloride Nutrition 0.000 description 20
- 239000000701 coagulant Substances 0.000 description 20
- 238000001125 extrusion Methods 0.000 description 20
- 238000010438 heat treatment Methods 0.000 description 19
- 239000012299 nitrogen atmosphere Substances 0.000 description 19
- 238000004804 winding Methods 0.000 description 19
- 229920006231 aramid fiber Polymers 0.000 description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- 239000002585 base Substances 0.000 description 10
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 9
- 239000002904 solvent Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- ZRVPOURSNDQODC-UHFFFAOYSA-M 4-[(2,4-dimethyl-1,2,4-triazol-4-ium-3-yl)diazenyl]-n,n-dimethylaniline;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(N(C)C)=CC=C1N=NC1=[N+](C)C=NN1C ZRVPOURSNDQODC-UHFFFAOYSA-M 0.000 description 5
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- MHOFGBJTSNWTDT-UHFFFAOYSA-M 2-[n-ethyl-4-[(6-methoxy-3-methyl-1,3-benzothiazol-3-ium-2-yl)diazenyl]anilino]ethanol;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(N(CCO)CC)=CC=C1N=NC1=[N+](C)C2=CC=C(OC)C=C2S1 MHOFGBJTSNWTDT-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 229910017053 inorganic salt Inorganic materials 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 2
- VAYOSLLFUXYJDT-RDTXWAMCSA-N Lysergic acid diethylamide Chemical compound C1=CC(C=2[C@H](N(C)C[C@@H](C=2)C(=O)N(CC)CC)C2)=C3C2=CNC3=C1 VAYOSLLFUXYJDT-RDTXWAMCSA-N 0.000 description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000000981 basic dye Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 1
- AGIJRRREJXSQJR-UHFFFAOYSA-N 2h-thiazine Chemical compound N1SC=CC=C1 AGIJRRREJXSQJR-UHFFFAOYSA-N 0.000 description 1
- AWHMVXSOQJUERN-UHFFFAOYSA-P CC(O)=O.CC(O)C(O)=O.CCN(CC)CCCNC1=NC(NC2=CC=C3C(=C2)C=C(C(N=NC2=CC=C(C=C2)N=NC2=CC=CC=C2)=C3O)S(O)(=O)=O)=NC(NCCC[NH+](CC)CC)=N1.CCN(CC)CCCNC1=NC(NC2=CC=C3C(=C2)C=C(C(N=NC2=CC=C(C=C2)N=NC2=CC=CC=C2)=C3O)S(O)(=O)=O)=NC(NCCC[NH+](CC)CC)=N1 Chemical compound CC(O)=O.CC(O)C(O)=O.CCN(CC)CCCNC1=NC(NC2=CC=C3C(=C2)C=C(C(N=NC2=CC=C(C=C2)N=NC2=CC=CC=C2)=C3O)S(O)(=O)=O)=NC(NCCC[NH+](CC)CC)=N1.CCN(CC)CCCNC1=NC(NC2=CC=C3C(=C2)C=C(C(N=NC2=CC=C(C=C2)N=NC2=CC=CC=C2)=C3O)S(O)(=O)=O)=NC(NCCC[NH+](CC)CC)=N1 AWHMVXSOQJUERN-UHFFFAOYSA-P 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 229910001615 alkaline earth metal halide Chemical class 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- YSVBPNGJESBVRM-UHFFFAOYSA-L disodium;4-[(1-oxido-4-sulfonaphthalen-2-yl)diazenyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].C1=CC=C2C(N=NC3=C(C4=CC=CC=C4C(=C3)S([O-])(=O)=O)O)=CC=C(S([O-])(=O)=O)C2=C1 YSVBPNGJESBVRM-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- ASWFVRBTTRCNAK-UHFFFAOYSA-O trimethyl-[3-[[4-(methylamino)-9,10-dioxoanthracen-1-yl]amino]propyl]azanium Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NCCC[N+](C)(C)C)=CC=C2NC ASWFVRBTTRCNAK-UHFFFAOYSA-O 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/06—Dyes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
- D01F6/605—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides from aromatic polyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/80—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyamides
- D01F6/805—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyamides from aromatic copolyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/20—Physical properties optical
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polyamides (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2013-0166398 | 2013-12-30 | ||
| KR20130166398 | 2013-12-30 | ||
| PCT/KR2014/012809 WO2015102297A1 (ko) | 2013-12-30 | 2014-12-24 | 공중합 아라미드 원착사 및 그의 제조방법 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112016015170A2 BR112016015170A2 (enrdf_load_stackoverflow) | 2017-08-08 |
| BR112016015170B1 true BR112016015170B1 (pt) | 2022-01-18 |
Family
ID=53493594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112016015170-4A BR112016015170B1 (pt) | 2013-12-30 | 2014-12-24 | Fio de aramida copolimerizado tingido em massa e método de preparação respectiva |
Country Status (7)
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841199A (zh) * | 2018-05-31 | 2018-11-20 | 韩学民 | 一种酞菁蓝系列染料碱性蓝140的生产工艺 |
| CN109183179A (zh) * | 2018-09-19 | 2019-01-11 | 超美斯新材料（淮安）有限公司 | 一种间位芳纶有色纤维的制备方法 |
| CN109594177A (zh) * | 2019-02-22 | 2019-04-09 | 江苏工匠服饰科技有限公司 | 一种阻燃面料及其制备方法 |
| JP7342068B2 (ja) * | 2020-06-30 | 2023-09-11 | 住友化学株式会社 | 組成物 |
| CN112281244A (zh) * | 2020-11-23 | 2021-01-29 | 蓝星（成都）新材料有限公司 | 一种原液染色芳纶1414纤维的制备方法 |
| CN115821417B (zh) * | 2021-09-17 | 2024-12-03 | 中国石油化工股份有限公司 | 共聚自着色芳纶的制备方法及共聚自着色芳纶纤维 |
| CN116988184B (zh) * | 2023-07-21 | 2024-10-01 | 江苏新视界先进功能纤维创新中心有限公司 | 一种高分子着色方法、纺丝色浆、纺丝液及着色纤维 |
| CN117004018B (zh) * | 2023-08-22 | 2024-08-09 | 江苏新视界先进功能纤维创新中心有限公司 | 一种高分子着色方法、纺丝液及着色纤维 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2438546C3 (de) * | 1974-08-10 | 1979-08-02 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung gefärbter Fäden aus vollaromatischen Polyamiden |
| JPS6016964B2 (ja) * | 1976-08-11 | 1985-04-30 | ユニチカ株式会社 | 塩基性染料親和性を有する芳香族ポリアミドの製造法 |
| US4705527A (en) * | 1986-05-14 | 1987-11-10 | Burlington Industries, Inc. | Process for the printing of shaped articles derived from aramid fibers |
| JPH01111014A (ja) * | 1987-10-21 | 1989-04-27 | Asahi Chem Ind Co Ltd | 染料含有ポリーパラフェニレンテレフタルアミド系繊維及びその製造法 |
| JPH01139814A (ja) * | 1987-11-27 | 1989-06-01 | Kuraray Co Ltd | 原着された全芳香族ポリアミド繊維とその製造法 |
| JP3696273B2 (ja) * | 1993-11-26 | 2005-09-14 | 帝人テクノプロダクツ株式会社 | 染色されたパラ系芳香族ポリアミド繊維の製造方法 |
| JP3450075B2 (ja) * | 1995-01-19 | 2003-09-22 | 帝人株式会社 | 吸湿寸法安定性アラミド繊維の製造方法 |
| KR0171994B1 (ko) * | 1995-07-13 | 1999-03-30 | 구광시 | 방향족 폴리아미드, 광학적 이방성 도우프와 성형물, 및 이들의 제조방법 |
| JP2001336025A (ja) * | 2000-05-26 | 2001-12-07 | Du Pont Toray Co Ltd | 全芳香族ポリアミド繊維、染色された全芳香族ポリアミドおよびその製造方法 |
| KR20040089069A (ko) * | 2002-02-13 | 2004-10-20 | 바스프 코포레이션 | 양이온적으로 염색된 섬유 및 이를 함유하는 물품 |
| CN100422401C (zh) * | 2006-04-13 | 2008-10-01 | 烟台氨纶股份有限公司 | 原液着色间位芳纶短纤维及其制备方法 |
| US7528217B2 (en) * | 2006-10-06 | 2009-05-05 | E.I. Du Pont De Nemours And Company | Polymers and fibers formed therefrom |
| FR2914656A1 (fr) * | 2007-04-03 | 2008-10-10 | Commissariat Energie Atomique | Procede de modification de fibres d'aramide et procede de teinture de ces fibres |
| KR20100126678A (ko) * | 2008-02-11 | 2010-12-02 | 바스프 에스이 | 폴리아미드의 제조 방법 |
| KR100910537B1 (ko) | 2008-05-27 | 2009-07-31 | 주식회사 코오롱 | 아라미드 섬유의 제조방법 |
| JP2010156083A (ja) * | 2008-12-29 | 2010-07-15 | Teijin Techno Products Ltd | 防護服 |
| KR101067338B1 (ko) * | 2009-04-16 | 2011-09-23 | 경북대학교 산학협력단 | 방향족 폴리아미드와 비결정성 고분자의 분자 혼화성 블렌드 용액과 그 제조방법, 이를 이용한 방향족 폴리아미드 블렌드 섬유 및 그 염색방법 |
| JP4804590B1 (ja) * | 2010-04-14 | 2011-11-02 | 帝人テクノプロダクツ株式会社 | メタ型全芳香族ポリアミド繊維 |
| US8933152B2 (en) * | 2010-10-28 | 2015-01-13 | Teijin Aramid B.V. | Spun-dyed aramid fibers |
| KR20120077714A (ko) * | 2010-12-31 | 2012-07-10 | 금오공과대학교 산학협력단 | 염색성이 향상된 메타 아라미드 성형물 및 이의 제조방법 |
| KR101432874B1 (ko) * | 2011-12-07 | 2014-08-27 | 코오롱인더스트리 주식회사 | 아라미드 섬유 및 그 제조방법 |
| JP5993177B2 (ja) * | 2012-03-30 | 2016-09-14 | 帝人株式会社 | 高品位、高堅牢性芳香族ポリアミド繊維染色布帛および染色方法 |
| CN103046401B (zh) * | 2012-12-07 | 2014-06-18 | 常熟市宝沣特种纤维有限公司 | 芳纶的无载体染色方法 |
-
2014
- 2014-12-23 KR KR1020140187039A patent/KR102070137B1/ko active Active
- 2014-12-24 US US15/106,359 patent/US20180195207A1/en not_active Abandoned
- 2014-12-24 WO PCT/KR2014/012809 patent/WO2015102297A1/ko active Application Filing
- 2014-12-24 EP EP14877413.6A patent/EP3091107B1/en active Active
- 2014-12-24 JP JP2016544566A patent/JP6185184B2/ja active Active
- 2014-12-24 CN CN201480071976.6A patent/CN105899717B/zh active Active
- 2014-12-24 BR BR112016015170-4A patent/BR112016015170B1/pt active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CN105899717B (zh) | 2018-01-19 |
| KR102070137B1 (ko) | 2020-01-28 |
| KR20150079425A (ko) | 2015-07-08 |
| EP3091107A1 (en) | 2016-11-09 |
| WO2015102297A1 (ko) | 2015-07-09 |
| JP6185184B2 (ja) | 2017-08-23 |
| EP3091107A4 (en) | 2017-08-09 |
| JP2017504731A (ja) | 2017-02-09 |
| EP3091107B1 (en) | 2019-02-13 |
| CN105899717A (zh) | 2016-08-24 |
| BR112016015170A2 (enrdf_load_stackoverflow) | 2017-08-08 |
| US20180195207A1 (en) | 2018-07-12 |
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