BR112014014855B1 - Processo de polimerização em solução para formar um interpolímero de etileno/aolefina/polieno não conjugado - Google Patents
Processo de polimerização em solução para formar um interpolímero de etileno/aolefina/polieno não conjugado Download PDFInfo
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- BR112014014855B1 BR112014014855B1 BR112014014855-4A BR112014014855A BR112014014855B1 BR 112014014855 B1 BR112014014855 B1 BR 112014014855B1 BR 112014014855 A BR112014014855 A BR 112014014855A BR 112014014855 B1 BR112014014855 B1 BR 112014014855B1
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Images
Classifications
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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| JP5946331B2 (ja) * | 2012-06-01 | 2016-07-06 | 三井化学株式会社 | エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット |
| EP2925798B1 (en) * | 2012-11-30 | 2019-04-24 | Dow Global Technologies LLC | Ethylene/alpha-olefin/polyene based compositions |
| US9751998B2 (en) * | 2012-12-27 | 2017-09-05 | Dow Global Technologies Llc | Catalyst systems for olefin polymerization |
| SG11201504578XA (en) | 2013-01-18 | 2015-08-28 | Dow Global Technologies Llc | Polymerization processes for high molecular weight polyolefins |
| CN106660819B (zh) | 2014-05-31 | 2019-06-28 | 株式会社普利司通 | 金属络合物催化剂、采用金属络合物催化剂的聚合方法及其聚合物产品 |
| ES2780004T3 (es) | 2014-12-04 | 2020-08-21 | Dow Global Technologies Llc | Catalizadores de bis-fenilfenoxi pentacoordinados para la preparación de polímeros basados en etileno |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| SG11201705225QA (en) | 2014-12-29 | 2017-07-28 | Dow Global Technologies Llc | Process to form oil containing ethylene-based polymers |
| BR112017013863B1 (pt) * | 2014-12-29 | 2021-12-14 | Dow Global Technologies Llc | Processo para formar uma primeira composição compreendendo um primeiro interpolímero de etileno/a-olefina e um segundo interpolímero de etileno/a-olefina, composição e artigo |
| SG11201707846QA (en) * | 2015-03-31 | 2017-10-30 | Dow Global Technologies Llc | Processes for the production of high molecular weight ethylene/alpha-olefin/non-conjugated interpolymers with low levels of long chain branching |
| KR102575287B1 (ko) * | 2015-05-28 | 2023-09-06 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/알파-올레핀 인터폴리머를 형성하는 방법 |
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| CA2996616C (en) | 2015-09-02 | 2023-09-26 | Dow Global Technologies Llc | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| JP6936795B2 (ja) | 2015-10-29 | 2021-09-22 | ダウ グローバル テクノロジーズ エルエルシー | 可撓性架橋ケーブル絶縁体のための架橋性ポリマー組成物、及び可撓性架橋ケーブル絶縁体を作製するための方法 |
| WO2017206008A1 (en) * | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
| WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
| EP4029886B1 (en) | 2016-06-30 | 2024-10-09 | Dow Global Technologies LLC | Ethylene/alpha-olefin/polyene interpolymers and compositions containing the same |
| US11981802B2 (en) | 2016-06-30 | 2024-05-14 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene based compositions |
| WO2018013284A2 (en) | 2016-07-13 | 2018-01-18 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| US11352451B2 (en) | 2016-07-13 | 2022-06-07 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| EP3484931A1 (en) | 2016-07-14 | 2019-05-22 | ExxonMobil Chemical Patents Inc. | Dual metallocene-catalyzed bimodal copolymer compositions |
| WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| JP6957596B2 (ja) * | 2016-07-29 | 2021-11-02 | ダウ グローバル テクノロジーズ エルエルシー | 多峰性エラストマー生成用混合触媒系 |
| US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
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| JP7173983B2 (ja) * | 2017-03-31 | 2022-11-17 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合のためのビス－ビフェニル－フェノキシ触媒 |
| WO2018231224A1 (en) * | 2017-06-14 | 2018-12-20 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
| EP3672811A1 (en) | 2017-08-24 | 2020-07-01 | Dow Global Technologies LLC | Ethylene/c5-c10 alpha-olefin/ polyene interpolymers |
| BR112020016302A2 (pt) * | 2018-02-14 | 2020-12-15 | Dow Global Technologies Llc | Composições de interpolímero de etileno/alfa-olefina com desempenho de envelhecimento térmico a longo prazo melhorado |
| EP3841168B1 (en) | 2018-08-29 | 2024-01-17 | ExxonMobil Chemical Patents Inc. | Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes |
| KR102538844B1 (ko) * | 2018-12-21 | 2023-06-01 | 주식회사 엘지화학 | 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법 |
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| US12098268B2 (en) | 2019-04-30 | 2024-09-24 | Dow Global Technologies Llc | Ethylene/propylene/nonconjugated diene interpolymer composition |
| WO2021061580A1 (en) | 2019-09-24 | 2021-04-01 | Dow Global Technologies Llc | Polymer compositions for extruded profiles |
| BR112022005433A2 (pt) | 2019-09-24 | 2022-06-21 | Dow Global Technologies Llc | Composição, composição reticulada, e, artigo |
| JP7680436B2 (ja) | 2019-09-24 | 2025-05-20 | ダウ グローバル テクノロジーズ エルエルシー | 優れた電気的および機械的特性を有するポリマー組成物 |
| WO2021133925A1 (en) * | 2019-12-27 | 2021-07-01 | Dow Global Technologies Llc | Ethylene/butene multi-block copolymer and process for producing same |
| JP2021147420A (ja) * | 2020-03-16 | 2021-09-27 | 三井化学株式会社 | オレフィン・環状オレフィン共重合体の製造方法 |
| JP7762663B2 (ja) * | 2020-03-27 | 2025-10-30 | ダウ グローバル テクノロジーズ エルエルシー | 長鎖分岐エチレン系ポリマーを生成するためのプロセス |
| EP4127061A1 (en) | 2020-03-30 | 2023-02-08 | ExxonMobil Chemical Patents Inc. | Comb-block copolymers and methods thereof |
| EP4185593A4 (en) * | 2020-12-28 | 2024-08-21 | SABIC SK Nexlene Company Pte. Ltd. | METAL LIGAND COMPLEX, CATALYST COMPOSITION FOR PRODUCING ETHYLENE-BASED POLYMER THEREOF, AND METHOD FOR PRODUCING ETHYLENE-BASED POLYMER THEREOF |
| KR20240074467A (ko) * | 2022-11-21 | 2024-05-28 | 롯데케미칼 주식회사 | 에틸렌-알파-올레핀 공중합체 제조방법 |
| WO2025117273A1 (en) | 2023-12-01 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Support-bound activators, supported catalyst systems, and processes for use thereof |
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| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
| US6897276B2 (en) * | 2002-04-24 | 2005-05-24 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
| KR101195320B1 (ko) | 2004-08-09 | 2012-10-29 | 다우 글로벌 테크놀로지스 엘엘씨 | 중합체를 제조하기 위한 지지된비스(하이드록시아릴아릴옥시) 촉매 |
| KR101384380B1 (ko) | 2006-05-17 | 2014-04-10 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리프로필렌 용액 중합 방법 |
| WO2009067337A1 (en) | 2007-11-19 | 2009-05-28 | Dow Global Technologies Inc. | Long chain branched propylene-alpha-olefin copolymers |
| US8772414B2 (en) * | 2008-09-16 | 2014-07-08 | Dow Global Technologies Llc | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
| WO2011002998A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylenic polymer and its use |
| CN106939057B (zh) | 2009-07-01 | 2021-04-23 | 陶氏环球技术有限责任公司 | 乙烯类聚合物及其用途 |
| US9102824B2 (en) | 2009-07-15 | 2015-08-11 | Dow Global Technologies Llc | Polymer compositions, methods of making the same, and articles prepared from the same |
| CN105294905A (zh) * | 2010-08-25 | 2016-02-03 | 陶氏环球技术有限责任公司 | 聚合可聚合烯烃的方法以及用于该方法的催化剂 |
| JP6104277B2 (ja) * | 2011-12-13 | 2017-03-29 | ダウ グローバル テクノロジーズ エルエルシー | エチレン−プロピレン−ジエン共重合体組成物 |
| EP2794693B1 (en) | 2011-12-20 | 2020-09-23 | Dow Global Technologies LLC | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
-
2012
- 2012-12-20 EP EP12815929.0A patent/EP2794693B1/en active Active
- 2012-12-20 US US14/367,478 patent/US9422383B2/en active Active
- 2012-12-20 BR BR112014014855-4A patent/BR112014014855B1/pt active IP Right Grant
- 2012-12-20 CN CN201280063427.5A patent/CN104169313B/zh active Active
- 2012-12-20 WO PCT/US2012/070859 patent/WO2013096573A1/en not_active Ceased
- 2012-12-20 JP JP2014548874A patent/JP6189325B2/ja active Active
- 2012-12-20 ES ES12815929T patent/ES2835807T3/es active Active
- 2012-12-20 IN IN4444CHN2014 patent/IN2014CN04444A/en unknown
- 2012-12-20 KR KR1020147016448A patent/KR101989206B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2015500920A (ja) | 2015-01-08 |
| US9422383B2 (en) | 2016-08-23 |
| KR20140107263A (ko) | 2014-09-04 |
| BR112014014855A2 (pt) | 2017-06-13 |
| CN104169313B (zh) | 2016-09-21 |
| KR101989206B1 (ko) | 2019-09-24 |
| EP2794693A1 (en) | 2014-10-29 |
| WO2013096573A1 (en) | 2013-06-27 |
| JP6189325B2 (ja) | 2017-08-30 |
| IN2014CN04444A (enExample) | 2015-09-04 |
| US20150322185A1 (en) | 2015-11-12 |
| ES2835807T3 (es) | 2021-06-23 |
| EP2794693B1 (en) | 2020-09-23 |
| CN104169313A (zh) | 2014-11-26 |
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