IN2014CN04444A - - Google Patents
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- Publication number
- IN2014CN04444A IN2014CN04444A IN4444CHN2014A IN2014CN04444A IN 2014CN04444 A IN2014CN04444 A IN 2014CN04444A IN 4444CHN2014 A IN4444CHN2014 A IN 4444CHN2014A IN 2014CN04444 A IN2014CN04444 A IN 2014CN04444A
- Authority
- IN
- India
- Prior art keywords
- olefin
- interpolymer
- nonconjugated polyene
- ethylene
- polymerization
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Abstract
The invention provides a solution polymerization process to form an ethylene/a olefin/nonconjugated polyene interpolymer said process comprising polymerizing ethylene an a olefin and a nonconjugated polyene in at least one reactor in the presence of a catalyst selected from Formula I as described herein; and wherein the polymerization is conducted in a continuous process; and wherein the interpolymer has a rheology ratio (V0.1/V100 at 19°C) greater than or equal to 20.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161577720P | 2011-12-20 | 2011-12-20 | |
US201261731891P | 2012-11-30 | 2012-11-30 | |
PCT/US2012/070859 WO2013096573A1 (en) | 2011-12-20 | 2012-12-20 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
Publications (1)
Publication Number | Publication Date |
---|---|
IN2014CN04444A true IN2014CN04444A (en) | 2015-09-04 |
Family
ID=47559697
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IN4444CHN2014 IN2014CN04444A (en) | 2011-12-20 | 2012-12-20 |
Country Status (9)
Country | Link |
---|---|
US (1) | US9422383B2 (en) |
EP (1) | EP2794693B1 (en) |
JP (1) | JP6189325B2 (en) |
KR (1) | KR101989206B1 (en) |
CN (1) | CN104169313B (en) |
BR (1) | BR112014014855B1 (en) |
ES (1) | ES2835807T3 (en) |
IN (1) | IN2014CN04444A (en) |
WO (1) | WO2013096573A1 (en) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101989206B1 (en) | 2011-12-20 | 2019-09-24 | 다우 글로벌 테크놀로지스 엘엘씨 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
JP5946331B2 (en) * | 2012-06-01 | 2016-07-06 | 三井化学株式会社 | Ethylene / α-olefin non-conjugated polyene copolymer rubber pellets |
WO2014084893A1 (en) * | 2012-11-30 | 2014-06-05 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene based compositions |
KR20200062369A (en) * | 2012-12-27 | 2020-06-03 | 다우 글로벌 테크놀로지스 엘엘씨 | Catalyst systems for olefin polymerization |
SG11201504578XA (en) | 2013-01-18 | 2015-08-28 | Dow Global Technologies Llc | Polymerization processes for high molecular weight polyolefins |
CN106660819B (en) * | 2014-05-31 | 2019-06-28 | 株式会社普利司通 | Metal complex catalyst, polymerization and its polymeric articles using metal complex catalyst |
WO2016089935A1 (en) * | 2014-12-04 | 2016-06-09 | Dow Global Technologies Llc | Five-coordinate bis-phenylphenoxy catalysts for the preparation of ethylene-based polymers |
MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
KR102456431B1 (en) * | 2014-12-29 | 2022-10-19 | 다우 글로벌 테크놀로지스 엘엘씨 | Process to form ethylene/alpha-olefin interpolymers |
CN107108792B (en) | 2014-12-29 | 2021-07-16 | 陶氏环球技术有限责任公司 | Process for forming ethylene-based polymers containing oil |
US10450394B2 (en) | 2015-03-31 | 2019-10-22 | Dow Global Technologies Llc | Processes for the production of high molecular weight ethylene/alpha-olefin/non-conjugated interpolymers with low levels of long chain branching |
KR102575287B1 (en) * | 2015-05-28 | 2023-09-06 | 다우 글로벌 테크놀로지스 엘엘씨 | Methods of Forming Ethylene/Alpha-Olefin Interpolymers |
CN108137855B (en) * | 2015-09-02 | 2021-09-28 | 陶氏环球技术有限责任公司 | Flexible crosslinked cable insulation and method of making same |
KR102588903B1 (en) * | 2015-09-02 | 2023-10-16 | 다우 글로벌 테크놀로지스 엘엘씨 | Flexible crosslinked cable insulation and method of making flexible crosslinked cable insulation |
BR112018006725B1 (en) | 2015-10-29 | 2022-04-19 | Dow Global Technologies Llc | Crosslinkable polymer composition and coated conductor |
WO2017206008A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
KR102396055B1 (en) * | 2016-06-30 | 2022-05-11 | 다우 글로벌 테크놀로지스 엘엘씨 | Ethylene/alpha-olefin/polyene-based composition |
EP3478732B1 (en) * | 2016-06-30 | 2023-01-11 | Dow Global Technologies LLC | Ethylene/alpha-olefin/polyene interpolymers and compositions containing the same |
WO2018013283A2 (en) | 2016-07-13 | 2018-01-18 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
WO2018013284A2 (en) | 2016-07-13 | 2018-01-18 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
CN109661457B (en) | 2016-07-14 | 2022-06-10 | 埃克森美孚化学专利公司 | Lubricating oil compositions comprising dual metallocene-catalyzed bimodal copolymer compositions useful as viscosity modifiers |
BR112019001249B1 (en) * | 2016-07-29 | 2022-10-18 | Dow Global Technologies Llc | MULTIMODAL ELASTOMER, THERMOPLATIC OLEFIN AND METHOD TO PRODUCE A MULTIMODAL ELASTOMER |
US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
EP3559114B1 (en) * | 2016-12-26 | 2024-04-17 | Dow Global Technologies LLC | Ethylene/a-olefin/nonconjugated polyene interpolymer compositions and articles prepared from the same |
US11401354B2 (en) * | 2017-03-31 | 2022-08-02 | Dow Global Technologies Llc | Bis-biphenyl-phenoxy catalysts for olefin polymerization |
US11390704B2 (en) | 2017-06-14 | 2022-07-19 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
CN111148641B (en) | 2017-08-24 | 2023-03-31 | 陶氏环球技术有限责任公司 | ethylene/C5-C10 alpha-olefin/polyene interpolymers |
WO2019157687A1 (en) | 2018-02-14 | 2019-08-22 | Dow Global Technologies Llc | Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance |
WO2020046597A1 (en) | 2018-08-29 | 2020-03-05 | Exxonmobil Chemical Patents Inc. | Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes |
KR102538844B1 (en) * | 2018-12-21 | 2023-06-01 | 주식회사 엘지화학 | Method for preparing vinyl aromatic compound-vinylcyan compound copolymer and method for preparing thermoplastic resin composition comprising the copolymer |
CN113544173A (en) | 2019-03-12 | 2021-10-22 | 三井化学株式会社 | Olefin resin, crosslinked product thereof, and processes for producing the same |
EP3947549A4 (en) * | 2019-03-29 | 2022-10-26 | Dow Global Technologies LLC | Oil-extended pellet form ethylene alpha-olefin diene interpolymers for thermoplastic vulcanizates |
CN113874439B (en) * | 2019-04-30 | 2024-03-29 | 陶氏环球技术有限责任公司 | Ethylene/propylene/non-conjugated diene interpolymer compositions |
KR20220066928A (en) | 2019-09-24 | 2022-05-24 | 다우 글로벌 테크놀로지스 엘엘씨 | Ethylene/alpha-olefin/polyene interpolymer composition |
JP2022549317A (en) | 2019-09-24 | 2022-11-24 | ダウ グローバル テクノロジーズ エルエルシー | Polymer composition for extruded profiles |
KR20220123255A (en) * | 2019-12-27 | 2022-09-06 | 다우 글로벌 테크놀로지스 엘엘씨 | Ethylene/butene multiblock copolymer and method for preparing same |
EP4127061A1 (en) | 2020-03-30 | 2023-02-08 | ExxonMobil Chemical Patents Inc. | Comb-block copolymers and methods thereof |
KR20240074467A (en) * | 2022-11-21 | 2024-05-28 | 롯데케미칼 주식회사 | Method for preparing ethylene/alpha-olefin copolymer |
Family Cites Families (14)
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US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
ATE492552T1 (en) * | 2002-04-24 | 2011-01-15 | Symyx Solutions Inc | BRIDGED BI-AROMATIC LIGANDS, COMPLEXES, CATALYSTS, POLYMERIZATION PROCESSES AND RESULTING POLYMERS |
CN101001885B (en) | 2004-08-09 | 2011-05-25 | 陶氏环球技术公司 | Supported bis(hydroxyarylaryloxy) catalysts for manufacture of polymers |
ES2567140T3 (en) | 2006-05-17 | 2016-04-20 | Dow Global Technologies Llc | Polypropylene Solution Polymerization Procedure |
ES2435568T3 (en) | 2007-11-19 | 2013-12-20 | Dow Global Technologies Llc | Propylene-alpha-olefin copolymers with long chain branching |
WO2010033601A1 (en) | 2008-09-16 | 2010-03-25 | Dow Global Technologies Inc. | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
ES2421301T3 (en) | 2009-07-01 | 2013-08-30 | Dow Global Technologies Llc | Ethylene polymer and its use |
KR101742832B1 (en) | 2009-07-01 | 2017-06-01 | 다우 글로벌 테크놀로지스 엘엘씨 | Ethylenic polymer and its use |
US9102824B2 (en) | 2009-07-15 | 2015-08-11 | Dow Global Technologies Llc | Polymer compositions, methods of making the same, and articles prepared from the same |
US9029487B2 (en) * | 2010-08-25 | 2015-05-12 | Dow Global Technologies Llc | Process for polymerizing a polymerizable olefin and catalyst therefor |
WO2013090024A1 (en) * | 2011-12-13 | 2013-06-20 | Dow Global Technologies Llc | Ethylene-propylene-diene interpolymer composition |
KR101989206B1 (en) | 2011-12-20 | 2019-09-24 | 다우 글로벌 테크놀로지스 엘엘씨 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
-
2012
- 2012-12-20 KR KR1020147016448A patent/KR101989206B1/en active IP Right Grant
- 2012-12-20 ES ES12815929T patent/ES2835807T3/en active Active
- 2012-12-20 JP JP2014548874A patent/JP6189325B2/en active Active
- 2012-12-20 US US14/367,478 patent/US9422383B2/en active Active
- 2012-12-20 WO PCT/US2012/070859 patent/WO2013096573A1/en active Application Filing
- 2012-12-20 IN IN4444CHN2014 patent/IN2014CN04444A/en unknown
- 2012-12-20 EP EP12815929.0A patent/EP2794693B1/en active Active
- 2012-12-20 CN CN201280063427.5A patent/CN104169313B/en active Active
- 2012-12-20 BR BR112014014855-4A patent/BR112014014855B1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
CN104169313A (en) | 2014-11-26 |
CN104169313B (en) | 2016-09-21 |
JP2015500920A (en) | 2015-01-08 |
WO2013096573A1 (en) | 2013-06-27 |
ES2835807T3 (en) | 2021-06-23 |
BR112014014855A2 (en) | 2017-06-13 |
US20150322185A1 (en) | 2015-11-12 |
JP6189325B2 (en) | 2017-08-30 |
EP2794693B1 (en) | 2020-09-23 |
KR101989206B1 (en) | 2019-09-24 |
US9422383B2 (en) | 2016-08-23 |
KR20140107263A (en) | 2014-09-04 |
BR112014014855B1 (en) | 2022-01-11 |
EP2794693A1 (en) | 2014-10-29 |
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