CN104169313B - 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 - Google Patents
乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 Download PDFInfo
- Publication number
- CN104169313B CN104169313B CN201280063427.5A CN201280063427A CN104169313B CN 104169313 B CN104169313 B CN 104169313B CN 201280063427 A CN201280063427 A CN 201280063427A CN 104169313 B CN104169313 B CN 104169313B
- Authority
- CN
- China
- Prior art keywords
- alkyl
- independently
- atom
- miscellaneous
- alkylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161577720P | 2011-12-20 | 2011-12-20 | |
| US61/577,720 | 2011-12-20 | ||
| US201261731891P | 2012-11-30 | 2012-11-30 | |
| US61/731,891 | 2012-11-30 | ||
| PCT/US2012/070859 WO2013096573A1 (en) | 2011-12-20 | 2012-12-20 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104169313A CN104169313A (zh) | 2014-11-26 |
| CN104169313B true CN104169313B (zh) | 2016-09-21 |
Family
ID=47559697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280063427.5A Active CN104169313B (zh) | 2011-12-20 | 2012-12-20 | 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9422383B2 (enExample) |
| EP (1) | EP2794693B1 (enExample) |
| JP (1) | JP6189325B2 (enExample) |
| KR (1) | KR101989206B1 (enExample) |
| CN (1) | CN104169313B (enExample) |
| BR (1) | BR112014014855B1 (enExample) |
| ES (1) | ES2835807T3 (enExample) |
| IN (1) | IN2014CN04444A (enExample) |
| WO (1) | WO2013096573A1 (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IN2014CN04444A (enExample) | 2011-12-20 | 2015-09-04 | Dow Global Technologies Llc | |
| JP5946331B2 (ja) * | 2012-06-01 | 2016-07-06 | 三井化学株式会社 | エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット |
| US10160819B2 (en) * | 2012-11-30 | 2018-12-25 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene based compositions |
| CN104870489B (zh) * | 2012-12-27 | 2018-03-09 | 陶氏环球技术有限责任公司 | 用于烯烃聚合的催化剂系统 |
| KR102038178B1 (ko) | 2013-01-18 | 2019-10-29 | 다우 글로벌 테크놀로지스 엘엘씨 | 고분자량 폴리올레핀을 위한 중합 방법 |
| US10457765B2 (en) * | 2014-05-31 | 2019-10-29 | Bridgestone Corporation | Metallic complex catalyst, polymerization methods employing same and polymer products thereof |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| WO2016089935A1 (en) * | 2014-12-04 | 2016-06-09 | Dow Global Technologies Llc | Five-coordinate bis-phenylphenoxy catalysts for the preparation of ethylene-based polymers |
| EP3240808B1 (en) * | 2014-12-29 | 2020-05-13 | Dow Global Technologies LLC | Process to form ethylene/alpha-olefin interpolymers |
| US10370471B2 (en) | 2014-12-29 | 2019-08-06 | Dow Global Technologies Llc | Process to form oil containing ethylene-based polymers |
| CN107428878B (zh) * | 2015-03-31 | 2020-08-28 | 陶氏环球技术有限责任公司 | 用于制备具有低含量长链支化的高分子量乙烯/α-烯烃/非共轭互聚物的方法 |
| WO2016191076A1 (en) * | 2015-05-28 | 2016-12-01 | Dow Global Technologies Llc | Process to form ethylene/alpha-olefin interpolymers |
| CN108140448B (zh) * | 2015-09-02 | 2022-07-01 | 陶氏环球技术有限责任公司 | 柔性交联电缆绝缘材料和其制造方法 |
| EP3344694B1 (en) * | 2015-09-02 | 2022-05-18 | Dow Global Technologies LLC | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| KR102606652B1 (ko) * | 2015-10-29 | 2023-11-28 | 다우 글로벌 테크놀로지스 엘엘씨 | 가요성 가교결합된 케이블 절연체용 가교결합성 폴리머 조성물 및 가요성 가교결합된 케이블 절연체를 제조하는 방법 |
| WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
| WO2017206008A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
| BR112018077391B1 (pt) | 2016-06-30 | 2023-01-03 | Dow Global Technologies Llc. | Composição, composição reticulada e artigo |
| EP3478762A1 (en) * | 2016-06-30 | 2019-05-08 | Dow Global Technologies, LLC | Ethylene/alpha-olefin/polyene based compositions |
| US11352451B2 (en) | 2016-07-13 | 2022-06-07 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| WO2018013284A2 (en) | 2016-07-13 | 2018-01-18 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| JP6936303B2 (ja) | 2016-07-14 | 2021-09-15 | エクソンモービル・ケミカル・パテンツ・インク | 2元メタロセン触媒で重合されたバイモーダルのコポリマー組成物 |
| WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| ES2799716T3 (es) * | 2016-07-29 | 2020-12-21 | Dow Global Technologies Llc | Sistemas de catalizadores mixtos para la producción de elastómeros multimodales |
| WO2018119570A1 (en) * | 2016-12-26 | 2018-07-05 | Dow Global Technologies Llc | Ethylene/a-olefin/nonconjugated polyene interpolymer compositions and articles prepared from the same |
| CN110461890B (zh) * | 2017-03-31 | 2022-11-18 | 陶氏环球技术有限责任公司 | 用于烯烃聚合的双-联苯-苯氧基催化剂 |
| EP3638730B1 (en) * | 2017-06-14 | 2024-05-01 | ExxonMobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
| WO2019040845A1 (en) | 2017-08-24 | 2019-02-28 | Dow Global Technologies Llc | ETHYLENE / ALPHA-OLEFIN C5-C10 / POLYENE INTERPOLYMERS |
| US11970602B2 (en) | 2018-02-14 | 2024-04-30 | Dow Global Technologies Llc | Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance |
| CN112805329B (zh) | 2018-08-29 | 2024-02-02 | 埃克森美孚化学专利公司 | 通过在并联方法中采用vtp和hmp催化剂体系制备具有增强弹性的聚合物组合物的方法 |
| KR102538844B1 (ko) * | 2018-12-21 | 2023-06-01 | 주식회사 엘지화학 | 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법 |
| WO2020184421A1 (ja) | 2019-03-12 | 2020-09-17 | 三井化学株式会社 | オレフィン系樹脂、その架橋物およびそれらの製造方法 |
| US12378391B2 (en) * | 2019-03-29 | 2025-08-05 | Dow Global Technologies Llc | Oil-extended pellet form ethylene alpha-olefin diene interpolymers for thermoplastic vulcanizates |
| EP3963004A4 (en) | 2019-04-30 | 2022-12-14 | Dow Global Technologies LLC | ETHYLENE/PROPYLENE/NON-CONJUGATED DIENE INTERPOLYMER COMPOSITION |
| US12448506B2 (en) | 2019-09-24 | 2025-10-21 | Dow Global Technologies Llc | Polymer compositions for extruded profiles |
| US20220298344A1 (en) | 2019-09-24 | 2022-09-22 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene interpolymer compositions |
| EP4034598A1 (en) | 2019-09-24 | 2022-08-03 | Dow Global Technologies LLC | Polymer compositions with excellent electrical and mechanical properties |
| US20230074326A1 (en) * | 2019-12-27 | 2023-03-09 | Dow Global Technologies Llc | Ethylene/Butene Multi-Block Copolymer and Process for Producing Same |
| JP2021147420A (ja) * | 2020-03-16 | 2021-09-27 | 三井化学株式会社 | オレフィン・環状オレフィン共重合体の製造方法 |
| WO2021195501A1 (en) * | 2020-03-27 | 2021-09-30 | Dow Global Technologies Llc | A process for producing long-chain branched ethylene-based polymers |
| WO2021202091A1 (en) | 2020-03-30 | 2021-10-07 | Exxonmobil Chemical Patents Inc. | Comb-block copolymers and methods thereof |
| EP4185593A4 (en) * | 2020-12-28 | 2024-08-21 | SABIC SK Nexlene Company Pte. Ltd. | METAL LIGAND COMPLEX, CATALYST COMPOSITION FOR PRODUCING ETHYLENE-BASED POLYMER THEREOF, AND METHOD FOR PRODUCING ETHYLENE-BASED POLYMER THEREOF |
| KR20240074467A (ko) * | 2022-11-21 | 2024-05-28 | 롯데케미칼 주식회사 | 에틸렌-알파-올레핀 공중합체 제조방법 |
| WO2025117273A1 (en) | 2023-12-01 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Support-bound activators, supported catalyst systems, and processes for use thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101472952A (zh) * | 2006-05-17 | 2009-07-01 | 陶氏环球技术公司 | 乙烯/α-烯烃/二烯溶液聚合法 |
| CN103180347A (zh) * | 2010-08-25 | 2013-06-26 | 陶氏环球技术有限责任公司 | 聚合可聚合烯烃的方法以及用于该方法的催化剂 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
| JP4371305B2 (ja) * | 2002-04-24 | 2009-11-25 | シミックス・ソルーションズ・インコーポレーテッド | 架橋ビス芳香族リガンド、錯体、触媒、または、重合方法およびそれにより得られるポリマー |
| WO2006020624A1 (en) | 2004-08-09 | 2006-02-23 | Dow Global Technologies Inc. | Supported bis(hydroxyarylaryloxy) catalysts for manufacture of polymers |
| WO2009067337A1 (en) | 2007-11-19 | 2009-05-28 | Dow Global Technologies Inc. | Long chain branched propylene-alpha-olefin copolymers |
| WO2010033601A1 (en) | 2008-09-16 | 2010-03-25 | Dow Global Technologies Inc. | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
| CN102471403A (zh) | 2009-07-01 | 2012-05-23 | 陶氏环球技术有限责任公司 | 烯属聚合物和它的用途 |
| WO2011002986A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylenic polymer and its use |
| US9102824B2 (en) | 2009-07-15 | 2015-08-11 | Dow Global Technologies Llc | Polymer compositions, methods of making the same, and articles prepared from the same |
| CA2857290C (en) * | 2011-12-13 | 2020-02-11 | Brian W. Walther | Ethylene-propylene-diene interpolymer composition |
| IN2014CN04444A (enExample) | 2011-12-20 | 2015-09-04 | Dow Global Technologies Llc |
-
2012
- 2012-12-20 IN IN4444CHN2014 patent/IN2014CN04444A/en unknown
- 2012-12-20 BR BR112014014855-4A patent/BR112014014855B1/pt active IP Right Grant
- 2012-12-20 WO PCT/US2012/070859 patent/WO2013096573A1/en not_active Ceased
- 2012-12-20 EP EP12815929.0A patent/EP2794693B1/en active Active
- 2012-12-20 CN CN201280063427.5A patent/CN104169313B/zh active Active
- 2012-12-20 KR KR1020147016448A patent/KR101989206B1/ko active Active
- 2012-12-20 US US14/367,478 patent/US9422383B2/en active Active
- 2012-12-20 JP JP2014548874A patent/JP6189325B2/ja active Active
- 2012-12-20 ES ES12815929T patent/ES2835807T3/es active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101472952A (zh) * | 2006-05-17 | 2009-07-01 | 陶氏环球技术公司 | 乙烯/α-烯烃/二烯溶液聚合法 |
| CN103180347A (zh) * | 2010-08-25 | 2013-06-26 | 陶氏环球技术有限责任公司 | 聚合可聚合烯烃的方法以及用于该方法的催化剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6189325B2 (ja) | 2017-08-30 |
| CN104169313A (zh) | 2014-11-26 |
| EP2794693B1 (en) | 2020-09-23 |
| US9422383B2 (en) | 2016-08-23 |
| IN2014CN04444A (enExample) | 2015-09-04 |
| ES2835807T3 (es) | 2021-06-23 |
| BR112014014855A2 (pt) | 2017-06-13 |
| WO2013096573A1 (en) | 2013-06-27 |
| BR112014014855B1 (pt) | 2022-01-11 |
| KR20140107263A (ko) | 2014-09-04 |
| KR101989206B1 (ko) | 2019-09-24 |
| EP2794693A1 (en) | 2014-10-29 |
| US20150322185A1 (en) | 2015-11-12 |
| JP2015500920A (ja) | 2015-01-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104169313B (zh) | 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 | |
| RU2643149C2 (ru) | Способы полимеризации для высокомолекулярных полиолефинов | |
| US8829127B2 (en) | Process for making ethylene interpolymers and interpolymers made thereby, and compositions and electrical devices containing such interpolymers | |
| CN107207807A (zh) | 生产聚合物组合物的方法 | |
| CN101326204B (zh) | 烯烃聚合方法 | |
| US11466149B2 (en) | Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom | |
| EP3827033B1 (en) | Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom | |
| CN107108991A (zh) | 形成乙烯/α‑烯烃互聚物的方法 | |
| KR102386161B1 (ko) | 에틸렌/알파-올레핀/다이엔 혼성중합체 | |
| CN109476893A (zh) | 乙烯/α-烯烃/二烯互聚物组合物 | |
| CN111868155A (zh) | 具有改进的持续耐高温性的乙烯/α-烯烃互聚物组合物 | |
| CN111868166A (zh) | 具有改进的长期热老化性能的乙烯/α-烯烃互聚物组合物 | |
| CN107709384A (zh) | 形成乙烯/α‑烯烃互聚物的方法 | |
| CN104507981B (zh) | 使用烷基化苯酚制备基于乙烯的聚合物的自由基方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |