CN104169313B - 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 - Google Patents

乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 Download PDF

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CN104169313B
CN104169313B CN201280063427.5A CN201280063427A CN104169313B CN 104169313 B CN104169313 B CN 104169313B CN 201280063427 A CN201280063427 A CN 201280063427A CN 104169313 B CN104169313 B CN 104169313B
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alkyl
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atom
miscellaneous
alkylene
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CN104169313A (zh
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C.里皮尚
T.W.卡杰拉
M.L.史密斯
L.P.斯潘瑟
J.克洛辛
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
CN201280063427.5A 2011-12-20 2012-12-20 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 Active CN104169313B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161577720P 2011-12-20 2011-12-20
US61/577,720 2011-12-20
US201261731891P 2012-11-30 2012-11-30
US61/731,891 2012-11-30
PCT/US2012/070859 WO2013096573A1 (en) 2011-12-20 2012-12-20 Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same

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CN104169313A CN104169313A (zh) 2014-11-26
CN104169313B true CN104169313B (zh) 2016-09-21

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US (1) US9422383B2 (enExample)
EP (1) EP2794693B1 (enExample)
JP (1) JP6189325B2 (enExample)
KR (1) KR101989206B1 (enExample)
CN (1) CN104169313B (enExample)
BR (1) BR112014014855B1 (enExample)
ES (1) ES2835807T3 (enExample)
IN (1) IN2014CN04444A (enExample)
WO (1) WO2013096573A1 (enExample)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IN2014CN04444A (enExample) 2011-12-20 2015-09-04 Dow Global Technologies Llc
JP5946331B2 (ja) * 2012-06-01 2016-07-06 三井化学株式会社 エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット
US10160819B2 (en) * 2012-11-30 2018-12-25 Dow Global Technologies Llc Ethylene/alpha-olefin/polyene based compositions
CN104870489B (zh) * 2012-12-27 2018-03-09 陶氏环球技术有限责任公司 用于烯烃聚合的催化剂系统
KR102038178B1 (ko) 2013-01-18 2019-10-29 다우 글로벌 테크놀로지스 엘엘씨 고분자량 폴리올레핀을 위한 중합 방법
US10457765B2 (en) * 2014-05-31 2019-10-29 Bridgestone Corporation Metallic complex catalyst, polymerization methods employing same and polymer products thereof
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
WO2016089935A1 (en) * 2014-12-04 2016-06-09 Dow Global Technologies Llc Five-coordinate bis-phenylphenoxy catalysts for the preparation of ethylene-based polymers
EP3240808B1 (en) * 2014-12-29 2020-05-13 Dow Global Technologies LLC Process to form ethylene/alpha-olefin interpolymers
US10370471B2 (en) 2014-12-29 2019-08-06 Dow Global Technologies Llc Process to form oil containing ethylene-based polymers
CN107428878B (zh) * 2015-03-31 2020-08-28 陶氏环球技术有限责任公司 用于制备具有低含量长链支化的高分子量乙烯/α-烯烃/非共轭互聚物的方法
WO2016191076A1 (en) * 2015-05-28 2016-12-01 Dow Global Technologies Llc Process to form ethylene/alpha-olefin interpolymers
CN108140448B (zh) * 2015-09-02 2022-07-01 陶氏环球技术有限责任公司 柔性交联电缆绝缘材料和其制造方法
EP3344694B1 (en) * 2015-09-02 2022-05-18 Dow Global Technologies LLC Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
KR102606652B1 (ko) * 2015-10-29 2023-11-28 다우 글로벌 테크놀로지스 엘엘씨 가요성 가교결합된 케이블 절연체용 가교결합성 폴리머 조성물 및 가요성 가교결합된 케이블 절연체를 제조하는 방법
WO2017206009A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymers compositions
WO2017206008A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymer
BR112018077391B1 (pt) 2016-06-30 2023-01-03 Dow Global Technologies Llc. Composição, composição reticulada e artigo
EP3478762A1 (en) * 2016-06-30 2019-05-08 Dow Global Technologies, LLC Ethylene/alpha-olefin/polyene based compositions
US11352451B2 (en) 2016-07-13 2022-06-07 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
WO2018013284A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
JP6936303B2 (ja) 2016-07-14 2021-09-15 エクソンモービル・ケミカル・パテンツ・インク 2元メタロセン触媒で重合されたバイモーダルのコポリマー組成物
WO2018022279A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
US10221260B2 (en) 2016-07-29 2019-03-05 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
ES2799716T3 (es) * 2016-07-29 2020-12-21 Dow Global Technologies Llc Sistemas de catalizadores mixtos para la producción de elastómeros multimodales
WO2018119570A1 (en) * 2016-12-26 2018-07-05 Dow Global Technologies Llc Ethylene/a-olefin/nonconjugated polyene interpolymer compositions and articles prepared from the same
CN110461890B (zh) * 2017-03-31 2022-11-18 陶氏环球技术有限责任公司 用于烯烃聚合的双-联苯-苯氧基催化剂
EP3638730B1 (en) * 2017-06-14 2024-05-01 ExxonMobil Chemical Patents Inc. Ethylene copolymer blends for cross-linking applications
WO2019040845A1 (en) 2017-08-24 2019-02-28 Dow Global Technologies Llc ETHYLENE / ALPHA-OLEFIN C5-C10 / POLYENE INTERPOLYMERS
US11970602B2 (en) 2018-02-14 2024-04-30 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance
CN112805329B (zh) 2018-08-29 2024-02-02 埃克森美孚化学专利公司 通过在并联方法中采用vtp和hmp催化剂体系制备具有增强弹性的聚合物组合物的方法
KR102538844B1 (ko) * 2018-12-21 2023-06-01 주식회사 엘지화학 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법
WO2020184421A1 (ja) 2019-03-12 2020-09-17 三井化学株式会社 オレフィン系樹脂、その架橋物およびそれらの製造方法
US12378391B2 (en) * 2019-03-29 2025-08-05 Dow Global Technologies Llc Oil-extended pellet form ethylene alpha-olefin diene interpolymers for thermoplastic vulcanizates
EP3963004A4 (en) 2019-04-30 2022-12-14 Dow Global Technologies LLC ETHYLENE/PROPYLENE/NON-CONJUGATED DIENE INTERPOLYMER COMPOSITION
US12448506B2 (en) 2019-09-24 2025-10-21 Dow Global Technologies Llc Polymer compositions for extruded profiles
US20220298344A1 (en) 2019-09-24 2022-09-22 Dow Global Technologies Llc Ethylene/alpha-olefin/polyene interpolymer compositions
EP4034598A1 (en) 2019-09-24 2022-08-03 Dow Global Technologies LLC Polymer compositions with excellent electrical and mechanical properties
US20230074326A1 (en) * 2019-12-27 2023-03-09 Dow Global Technologies Llc Ethylene/Butene Multi-Block Copolymer and Process for Producing Same
JP2021147420A (ja) * 2020-03-16 2021-09-27 三井化学株式会社 オレフィン・環状オレフィン共重合体の製造方法
WO2021195501A1 (en) * 2020-03-27 2021-09-30 Dow Global Technologies Llc A process for producing long-chain branched ethylene-based polymers
WO2021202091A1 (en) 2020-03-30 2021-10-07 Exxonmobil Chemical Patents Inc. Comb-block copolymers and methods thereof
EP4185593A4 (en) * 2020-12-28 2024-08-21 SABIC SK Nexlene Company Pte. Ltd. METAL LIGAND COMPLEX, CATALYST COMPOSITION FOR PRODUCING ETHYLENE-BASED POLYMER THEREOF, AND METHOD FOR PRODUCING ETHYLENE-BASED POLYMER THEREOF
KR20240074467A (ko) * 2022-11-21 2024-05-28 롯데케미칼 주식회사 에틸렌-알파-올레핀 공중합체 제조방법
WO2025117273A1 (en) 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Support-bound activators, supported catalyst systems, and processes for use thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101472952A (zh) * 2006-05-17 2009-07-01 陶氏环球技术公司 乙烯/α-烯烃/二烯溶液聚合法
CN103180347A (zh) * 2010-08-25 2013-06-26 陶氏环球技术有限责任公司 聚合可聚合烯烃的方法以及用于该方法的催化剂

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US5977251A (en) 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
US6680361B1 (en) * 1998-11-02 2004-01-20 Dupont Dow Elastomers Llc Shear thinning ethylene/α-olefin interpolymers and their preparation
JP4371305B2 (ja) * 2002-04-24 2009-11-25 シミックス・ソルーションズ・インコーポレーテッド 架橋ビス芳香族リガンド、錯体、触媒、または、重合方法およびそれにより得られるポリマー
WO2006020624A1 (en) 2004-08-09 2006-02-23 Dow Global Technologies Inc. Supported bis(hydroxyarylaryloxy) catalysts for manufacture of polymers
WO2009067337A1 (en) 2007-11-19 2009-05-28 Dow Global Technologies Inc. Long chain branched propylene-alpha-olefin copolymers
WO2010033601A1 (en) 2008-09-16 2010-03-25 Dow Global Technologies Inc. Polymeric compositions and foams, methods of making the same, and articles prepared from the same
CN102471403A (zh) 2009-07-01 2012-05-23 陶氏环球技术有限责任公司 烯属聚合物和它的用途
WO2011002986A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylenic polymer and its use
US9102824B2 (en) 2009-07-15 2015-08-11 Dow Global Technologies Llc Polymer compositions, methods of making the same, and articles prepared from the same
CA2857290C (en) * 2011-12-13 2020-02-11 Brian W. Walther Ethylene-propylene-diene interpolymer composition
IN2014CN04444A (enExample) 2011-12-20 2015-09-04 Dow Global Technologies Llc

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101472952A (zh) * 2006-05-17 2009-07-01 陶氏环球技术公司 乙烯/α-烯烃/二烯溶液聚合法
CN103180347A (zh) * 2010-08-25 2013-06-26 陶氏环球技术有限责任公司 聚合可聚合烯烃的方法以及用于该方法的催化剂

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Publication number Publication date
JP6189325B2 (ja) 2017-08-30
CN104169313A (zh) 2014-11-26
EP2794693B1 (en) 2020-09-23
US9422383B2 (en) 2016-08-23
IN2014CN04444A (enExample) 2015-09-04
ES2835807T3 (es) 2021-06-23
BR112014014855A2 (pt) 2017-06-13
WO2013096573A1 (en) 2013-06-27
BR112014014855B1 (pt) 2022-01-11
KR20140107263A (ko) 2014-09-04
KR101989206B1 (ko) 2019-09-24
EP2794693A1 (en) 2014-10-29
US20150322185A1 (en) 2015-11-12
JP2015500920A (ja) 2015-01-08

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