CN104169313B - 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 - Google Patents
乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 Download PDFInfo
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- CN104169313B CN104169313B CN201280063427.5A CN201280063427A CN104169313B CN 104169313 B CN104169313 B CN 104169313B CN 201280063427 A CN201280063427 A CN 201280063427A CN 104169313 B CN104169313 B CN 104169313B
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- Prior art keywords
- alkyl
- independently
- atom
- miscellaneous
- alkylene
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161577720P | 2011-12-20 | 2011-12-20 | |
| US61/577,720 | 2011-12-20 | ||
| US201261731891P | 2012-11-30 | 2012-11-30 | |
| US61/731,891 | 2012-11-30 | ||
| PCT/US2012/070859 WO2013096573A1 (en) | 2011-12-20 | 2012-12-20 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104169313A CN104169313A (zh) | 2014-11-26 |
| CN104169313B true CN104169313B (zh) | 2016-09-21 |
Family
ID=47559697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280063427.5A Active CN104169313B (zh) | 2011-12-20 | 2012-12-20 | 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9422383B2 (enExample) |
| EP (1) | EP2794693B1 (enExample) |
| JP (1) | JP6189325B2 (enExample) |
| KR (1) | KR101989206B1 (enExample) |
| CN (1) | CN104169313B (enExample) |
| BR (1) | BR112014014855B1 (enExample) |
| ES (1) | ES2835807T3 (enExample) |
| IN (1) | IN2014CN04444A (enExample) |
| WO (1) | WO2013096573A1 (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9422383B2 (en) | 2011-12-20 | 2016-08-23 | Dow Global Technologies Llc | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
| JP5946331B2 (ja) * | 2012-06-01 | 2016-07-06 | 三井化学株式会社 | エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット |
| EP2925798B1 (en) * | 2012-11-30 | 2019-04-24 | Dow Global Technologies LLC | Ethylene/alpha-olefin/polyene based compositions |
| KR20150100694A (ko) * | 2012-12-27 | 2015-09-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 촉매계 |
| BR112015013530B1 (pt) | 2013-01-18 | 2021-10-13 | Dow Global Technologies Llc | Processo para formar um polímero à base de etileno e complexo metálico |
| JP6673596B2 (ja) * | 2014-05-31 | 2020-03-25 | 株式会社ブリヂストン | 金属錯体触媒、それを使用した重合方法、及びそのポリマー生成物 |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| BR112017010799B1 (pt) | 2014-12-04 | 2021-02-02 | Dow Global Technologies Llc | complexo de metal de transição molecular e processo para formar um polímero baseado em etileno |
| SG11201705239SA (en) * | 2014-12-29 | 2017-07-28 | Dow Global Technologies Llc | Process to form ethylene/alpha-olefin interpolymers |
| WO2016109265A1 (en) | 2014-12-29 | 2016-07-07 | Dow Global Technologies Llc | Process to form oil containing ethylene-based polymers |
| BR112017020525B1 (pt) * | 2015-03-31 | 2022-07-19 | Dow Global Technologies Llc | Processo para formar uma composição de polímero |
| WO2016191076A1 (en) * | 2015-05-28 | 2016-12-01 | Dow Global Technologies Llc | Process to form ethylene/alpha-olefin interpolymers |
| JP6804519B6 (ja) * | 2015-09-02 | 2021-01-20 | ダウ グローバル テクノロジーズ エルエルシー | 可撓性架橋ケーブル絶縁体、及び可撓性架橋ケーブル絶縁体を作製するための方法 |
| JP6868007B2 (ja) | 2015-09-02 | 2021-05-12 | ダウ グローバル テクノロジーズ エルエルシー | 可撓性架橋ケーブル絶縁体、及び可撓性架橋ケーブル絶縁体を作製するための方法 |
| MX392441B (es) | 2015-10-29 | 2025-03-21 | Dow Global Technologies Llc | Composiciones polimericas reticulables para aislamiento de cable reticulado flexible y metodos para la fabricacion de aislamiento de cable reticulado flexible. |
| WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
| WO2017206008A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
| BR112018077391B1 (pt) * | 2016-06-30 | 2023-01-03 | Dow Global Technologies Llc. | Composição, composição reticulada e artigo |
| JP6998899B2 (ja) * | 2016-06-30 | 2022-01-18 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/α-オレフィン/ポリエン系組成物 |
| US10808049B2 (en) | 2016-07-13 | 2020-10-20 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| US11352451B2 (en) | 2016-07-13 | 2022-06-07 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| JP6850862B2 (ja) | 2016-07-14 | 2021-03-31 | エクソンモービル・ケミカル・パテンツ・インク | 粘度調整剤として有用な、2元メタロセン触媒で重合されたバイモーダルのコポリマー組成物 |
| WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| EP3491033B1 (en) * | 2016-07-29 | 2020-05-13 | Dow Global Technologies LLC | Mixed catalyst systems for producing multimodal elastomers |
| KR102653792B1 (ko) * | 2016-12-26 | 2024-04-03 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/α-올레핀/비공액 폴리엔 혼성 중합체 조성물 및 이로부터 제조된 물품 |
| WO2018183700A1 (en) * | 2017-03-31 | 2018-10-04 | Dow Global Technologies Llc | Bis-biphenyl-phenoxy catalysts for olefin polymerization |
| WO2018231224A1 (en) * | 2017-06-14 | 2018-12-20 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
| CN111148641B (zh) | 2017-08-24 | 2023-03-31 | 陶氏环球技术有限责任公司 | 乙烯/C5-C10α-烯烃/多烯互聚物 |
| CN111868166A (zh) * | 2018-02-14 | 2020-10-30 | 陶氏环球技术有限责任公司 | 具有改进的长期热老化性能的乙烯/α-烯烃互聚物组合物 |
| EP3841168B1 (en) | 2018-08-29 | 2024-01-17 | ExxonMobil Chemical Patents Inc. | Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes |
| KR102538844B1 (ko) * | 2018-12-21 | 2023-06-01 | 주식회사 엘지화학 | 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법 |
| WO2020184421A1 (ja) | 2019-03-12 | 2020-09-17 | 三井化学株式会社 | オレフィン系樹脂、その架橋物およびそれらの製造方法 |
| JP7463398B2 (ja) * | 2019-03-29 | 2024-04-08 | ダウ グローバル テクノロジーズ エルエルシー | 熱可塑性加硫物用の油展ペレット形態エチレンα-オレフィンジエンインターポリマー |
| WO2020220244A1 (en) | 2019-04-30 | 2020-11-05 | Dow Global Technologies Llc | Ethylene/propylene/nonconjugated diene interpolymer composition |
| JP7680436B2 (ja) | 2019-09-24 | 2025-05-20 | ダウ グローバル テクノロジーズ エルエルシー | 優れた電気的および機械的特性を有するポリマー組成物 |
| WO2021061580A1 (en) | 2019-09-24 | 2021-04-01 | Dow Global Technologies Llc | Polymer compositions for extruded profiles |
| KR20220066928A (ko) | 2019-09-24 | 2022-05-24 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/알파-올레핀/폴리엔 혼성중합체 조성물 |
| BR112022012694A2 (pt) * | 2019-12-27 | 2022-09-06 | Dow Global Technologies Llc | Copolímero em multiblocos de etileno/buteno e processo para produzir o mesmo |
| JP2021147420A (ja) * | 2020-03-16 | 2021-09-27 | 三井化学株式会社 | オレフィン・環状オレフィン共重合体の製造方法 |
| WO2021195501A1 (en) * | 2020-03-27 | 2021-09-30 | Dow Global Technologies Llc | A process for producing long-chain branched ethylene-based polymers |
| CN115380073A (zh) | 2020-03-30 | 2022-11-22 | 埃克森美孚化学专利公司 | 梳型嵌段共聚物及其方法 |
| US20230303597A1 (en) * | 2020-12-28 | 2023-09-28 | Sabic Sk Nexlene Company Pte. Ltd. | Metal-ligand complex, catalyst composition for preparing ethylene-based polymer containing the same, and preparation method of ethylene -based polymer using the same |
| KR20240074467A (ko) * | 2022-11-21 | 2024-05-28 | 롯데케미칼 주식회사 | 에틸렌-알파-올레핀 공중합체 제조방법 |
| WO2025117273A1 (en) | 2023-12-01 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Support-bound activators, supported catalyst systems, and processes for use thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101472952A (zh) * | 2006-05-17 | 2009-07-01 | 陶氏环球技术公司 | 乙烯/α-烯烃/二烯溶液聚合法 |
| CN103180347A (zh) * | 2010-08-25 | 2013-06-26 | 陶氏环球技术有限责任公司 | 聚合可聚合烯烃的方法以及用于该方法的催化剂 |
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| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
| WO2003091262A1 (en) * | 2002-04-24 | 2003-11-06 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, complexes, catalysts and processes for polymerizing and poymers therefrom |
| CN101001885B (zh) | 2004-08-09 | 2011-05-25 | 陶氏环球技术公司 | 用于制备聚合物的负载型双(羟基芳基芳氧基)催化剂 |
| WO2009067337A1 (en) | 2007-11-19 | 2009-05-28 | Dow Global Technologies Inc. | Long chain branched propylene-alpha-olefin copolymers |
| WO2010033601A1 (en) | 2008-09-16 | 2010-03-25 | Dow Global Technologies Inc. | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
| SG177446A1 (en) | 2009-07-01 | 2012-02-28 | Dow Global Technologies Llc | Ethylenic polymer and its use |
| SG178222A1 (en) | 2009-07-01 | 2012-03-29 | Dow Global Technologies Llc | Ethylenic polymer and its use |
| BRPI1010079B1 (pt) | 2009-07-15 | 2019-10-08 | Dow Global Technologies Llc | Composição polimérica e artigo |
| KR101938440B1 (ko) * | 2011-12-13 | 2019-01-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌-프로필렌-디엔 혼성중합체 조성물 |
| US9422383B2 (en) | 2011-12-20 | 2016-08-23 | Dow Global Technologies Llc | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
-
2012
- 2012-12-20 US US14/367,478 patent/US9422383B2/en active Active
- 2012-12-20 IN IN4444CHN2014 patent/IN2014CN04444A/en unknown
- 2012-12-20 JP JP2014548874A patent/JP6189325B2/ja active Active
- 2012-12-20 KR KR1020147016448A patent/KR101989206B1/ko active Active
- 2012-12-20 WO PCT/US2012/070859 patent/WO2013096573A1/en not_active Ceased
- 2012-12-20 ES ES12815929T patent/ES2835807T3/es active Active
- 2012-12-20 CN CN201280063427.5A patent/CN104169313B/zh active Active
- 2012-12-20 BR BR112014014855-4A patent/BR112014014855B1/pt active IP Right Grant
- 2012-12-20 EP EP12815929.0A patent/EP2794693B1/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101472952A (zh) * | 2006-05-17 | 2009-07-01 | 陶氏环球技术公司 | 乙烯/α-烯烃/二烯溶液聚合法 |
| CN103180347A (zh) * | 2010-08-25 | 2013-06-26 | 陶氏环球技术有限责任公司 | 聚合可聚合烯烃的方法以及用于该方法的催化剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101989206B1 (ko) | 2019-09-24 |
| BR112014014855B1 (pt) | 2022-01-11 |
| ES2835807T3 (es) | 2021-06-23 |
| CN104169313A (zh) | 2014-11-26 |
| KR20140107263A (ko) | 2014-09-04 |
| EP2794693B1 (en) | 2020-09-23 |
| US20150322185A1 (en) | 2015-11-12 |
| JP6189325B2 (ja) | 2017-08-30 |
| WO2013096573A1 (en) | 2013-06-27 |
| JP2015500920A (ja) | 2015-01-08 |
| BR112014014855A2 (pt) | 2017-06-13 |
| EP2794693A1 (en) | 2014-10-29 |
| US9422383B2 (en) | 2016-08-23 |
| IN2014CN04444A (enExample) | 2015-09-04 |
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