JP6189325B2 - エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 - Google Patents
エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 Download PDFInfo
- Publication number
- JP6189325B2 JP6189325B2 JP2014548874A JP2014548874A JP6189325B2 JP 6189325 B2 JP6189325 B2 JP 6189325B2 JP 2014548874 A JP2014548874 A JP 2014548874A JP 2014548874 A JP2014548874 A JP 2014548874A JP 6189325 B2 JP6189325 B2 JP 6189325B2
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- JP
- Japan
- Prior art keywords
- independently
- atom
- hydrocarbyl
- heterohydrocarbyl
- unsubstituted
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161577720P | 2011-12-20 | 2011-12-20 | |
| US61/577,720 | 2011-12-20 | ||
| US201261731891P | 2012-11-30 | 2012-11-30 | |
| US61/731,891 | 2012-11-30 | ||
| PCT/US2012/070859 WO2013096573A1 (en) | 2011-12-20 | 2012-12-20 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015500920A JP2015500920A (ja) | 2015-01-08 |
| JP6189325B2 true JP6189325B2 (ja) | 2017-08-30 |
Family
ID=47559697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014548874A Active JP6189325B2 (ja) | 2011-12-20 | 2012-12-20 | エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9422383B2 (enExample) |
| EP (1) | EP2794693B1 (enExample) |
| JP (1) | JP6189325B2 (enExample) |
| KR (1) | KR101989206B1 (enExample) |
| CN (1) | CN104169313B (enExample) |
| BR (1) | BR112014014855B1 (enExample) |
| ES (1) | ES2835807T3 (enExample) |
| IN (1) | IN2014CN04444A (enExample) |
| WO (1) | WO2013096573A1 (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2794693B1 (en) | 2011-12-20 | 2020-09-23 | Dow Global Technologies LLC | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
| JP5946331B2 (ja) * | 2012-06-01 | 2016-07-06 | 三井化学株式会社 | エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット |
| US10160819B2 (en) * | 2012-11-30 | 2018-12-25 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene based compositions |
| WO2014105411A1 (en) * | 2012-12-27 | 2014-07-03 | Dow Global Technologies Llc | Catalyst systems for olefin polymerization |
| CN104884483B (zh) | 2013-01-18 | 2018-10-09 | 陶氏环球技术有限责任公司 | 高分子量聚合物的聚合方法 |
| EP3738927A1 (en) | 2014-05-31 | 2020-11-18 | Bridgestone Corporation | Metallic complex catalyst, polymerization methods employing same and polymer products thereof |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| ES2780004T3 (es) | 2014-12-04 | 2020-08-21 | Dow Global Technologies Llc | Catalizadores de bis-fenilfenoxi pentacoordinados para la preparación de polímeros basados en etileno |
| SG11201705225QA (en) | 2014-12-29 | 2017-07-28 | Dow Global Technologies Llc | Process to form oil containing ethylene-based polymers |
| JP6752794B2 (ja) * | 2014-12-29 | 2020-09-09 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/アルファ−オレフィンインターポリマーを形成する方法 |
| KR102603126B1 (ko) * | 2015-03-31 | 2023-11-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 낮은 수준의 장쇄 분지화를 갖는 고분자량 에틸렌/알파-올레핀/비-접합된 인터폴리머의 생산 방법 |
| JP6815333B2 (ja) * | 2015-05-28 | 2021-01-20 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/アルファ−オレフィンインターポリマーを形成する方法 |
| WO2017040088A1 (en) | 2015-09-02 | 2017-03-09 | Dow Global Technologies Llc | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| CN108140448B (zh) * | 2015-09-02 | 2022-07-01 | 陶氏环球技术有限责任公司 | 柔性交联电缆绝缘材料和其制造方法 |
| BR112018006725B1 (pt) * | 2015-10-29 | 2022-04-19 | Dow Global Technologies Llc | Composição polimérica reticulável e condutor revestido |
| WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
| WO2017206008A1 (en) * | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
| JP6998899B2 (ja) * | 2016-06-30 | 2022-01-18 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/α-オレフィン/ポリエン系組成物 |
| US11098144B2 (en) | 2016-06-30 | 2021-08-24 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene interpolymers and compositions containing the same |
| US10808049B2 (en) | 2016-07-13 | 2020-10-20 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| CN109641989B (zh) | 2016-07-13 | 2022-05-03 | 埃克森美孚化学专利公司 | 双金属茂催化剂共聚物组合物 |
| JP6936303B2 (ja) | 2016-07-14 | 2021-09-15 | エクソンモービル・ケミカル・パテンツ・インク | 2元メタロセン触媒で重合されたバイモーダルのコポリマー組成物 |
| EP3491033B1 (en) * | 2016-07-29 | 2020-05-13 | Dow Global Technologies LLC | Mixed catalyst systems for producing multimodal elastomers |
| WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| CN110234701B (zh) * | 2016-12-26 | 2023-06-06 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃/非共轭多烯互聚物组合物和由其制备的制品 |
| BR112019020417B1 (pt) * | 2017-03-31 | 2023-04-04 | Dow Global Technologies Llc | Sistema catalisador e processo de polimerização para produzir um polímero à base de etileno |
| CN111032772B (zh) * | 2017-06-14 | 2022-07-15 | 埃克森美孚化学专利公司 | 用于交联应用的乙烯共聚物共混物 |
| US11345797B2 (en) | 2017-08-24 | 2022-05-31 | Dow Global Technologies Llc | Ethylene/C5-C10 alpha-olefin/ polyene interpolymers |
| US11970602B2 (en) * | 2018-02-14 | 2024-04-30 | Dow Global Technologies Llc | Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance |
| WO2020046597A1 (en) | 2018-08-29 | 2020-03-05 | Exxonmobil Chemical Patents Inc. | Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes |
| KR102538844B1 (ko) * | 2018-12-21 | 2023-06-01 | 주식회사 엘지화학 | 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법 |
| JP7186856B2 (ja) | 2019-03-12 | 2022-12-09 | 三井化学株式会社 | オレフィン系樹脂、その架橋物およびそれらの製造方法 |
| US12378391B2 (en) * | 2019-03-29 | 2025-08-05 | Dow Global Technologies Llc | Oil-extended pellet form ethylene alpha-olefin diene interpolymers for thermoplastic vulcanizates |
| US12098268B2 (en) | 2019-04-30 | 2024-09-24 | Dow Global Technologies Llc | Ethylene/propylene/nonconjugated diene interpolymer composition |
| CN114514280B (zh) | 2019-09-24 | 2024-09-06 | 陶氏环球技术有限责任公司 | 用于挤出型材的聚合物组合物 |
| US20220298344A1 (en) | 2019-09-24 | 2022-09-22 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene interpolymer compositions |
| BR112022005584A2 (pt) | 2019-09-24 | 2022-06-21 | Dow Global Technologies Llc | Composição, e, artigo |
| US20230074326A1 (en) * | 2019-12-27 | 2023-03-09 | Dow Global Technologies Llc | Ethylene/Butene Multi-Block Copolymer and Process for Producing Same |
| JP2021147420A (ja) * | 2020-03-16 | 2021-09-27 | 三井化学株式会社 | オレフィン・環状オレフィン共重合体の製造方法 |
| CN115397875B (zh) * | 2020-03-27 | 2025-03-11 | 陶氏环球技术有限责任公司 | 用于产生长链支化基于乙烯的聚合物的方法 |
| CN115380073A (zh) | 2020-03-30 | 2022-11-22 | 埃克森美孚化学专利公司 | 梳型嵌段共聚物及其方法 |
| EP4185593A4 (en) * | 2020-12-28 | 2024-08-21 | SABIC SK Nexlene Company Pte. Ltd. | METAL LIGAND COMPLEX, CATALYST COMPOSITION FOR PRODUCING ETHYLENE-BASED POLYMER THEREOF, AND METHOD FOR PRODUCING ETHYLENE-BASED POLYMER THEREOF |
| KR20240074467A (ko) * | 2022-11-21 | 2024-05-28 | 롯데케미칼 주식회사 | 에틸렌-알파-올레핀 공중합체 제조방법 |
| WO2025117273A1 (en) | 2023-12-01 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Support-bound activators, supported catalyst systems, and processes for use thereof |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
| US6841502B2 (en) * | 2002-04-24 | 2005-01-11 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
| EP1778738B1 (en) | 2004-08-09 | 2014-05-07 | Dow Global Technologies LLC | Supported bis(hydroxyarylaryloxy) catalysts for manufacture of polymers |
| MX2008014667A (es) | 2006-05-17 | 2009-01-26 | Dow Global Technologies Inc | Proceso de polimerizacion en solucion de polietileno a alta temperatura. |
| EP2212359B1 (en) | 2007-11-19 | 2013-08-28 | Dow Global Technologies LLC | Long chain branched propylene-alpha-olefin copolymers |
| WO2010033601A1 (en) | 2008-09-16 | 2010-03-25 | Dow Global Technologies Inc. | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
| EP2448979B1 (en) | 2009-07-01 | 2013-05-01 | Dow Global Technologies LLC | Ethylenic polymer and its use |
| JP2012532231A (ja) | 2009-07-01 | 2012-12-13 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマー及びその使用 |
| JP5512812B2 (ja) | 2009-07-15 | 2014-06-04 | ダウ グローバル テクノロジーズ エルエルシー | ポリマー組成物、その製造方法及びそれから製造される物品 |
| WO2012027448A1 (en) * | 2010-08-25 | 2012-03-01 | Dow Global Technologies Llc | Process for polymerizing a polymerizable olefin and catalyst therefor |
| CN103987743B (zh) * | 2011-12-13 | 2016-05-11 | 陶氏环球技术有限责任公司 | 乙烯-丙烯-二烯互聚物组合物 |
| EP2794693B1 (en) | 2011-12-20 | 2020-09-23 | Dow Global Technologies LLC | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
-
2012
- 2012-12-20 EP EP12815929.0A patent/EP2794693B1/en active Active
- 2012-12-20 KR KR1020147016448A patent/KR101989206B1/ko active Active
- 2012-12-20 IN IN4444CHN2014 patent/IN2014CN04444A/en unknown
- 2012-12-20 JP JP2014548874A patent/JP6189325B2/ja active Active
- 2012-12-20 WO PCT/US2012/070859 patent/WO2013096573A1/en not_active Ceased
- 2012-12-20 US US14/367,478 patent/US9422383B2/en active Active
- 2012-12-20 BR BR112014014855-4A patent/BR112014014855B1/pt active IP Right Grant
- 2012-12-20 CN CN201280063427.5A patent/CN104169313B/zh active Active
- 2012-12-20 ES ES12815929T patent/ES2835807T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140107263A (ko) | 2014-09-04 |
| CN104169313A (zh) | 2014-11-26 |
| ES2835807T3 (es) | 2021-06-23 |
| US9422383B2 (en) | 2016-08-23 |
| KR101989206B1 (ko) | 2019-09-24 |
| BR112014014855A2 (pt) | 2017-06-13 |
| US20150322185A1 (en) | 2015-11-12 |
| BR112014014855B1 (pt) | 2022-01-11 |
| IN2014CN04444A (enExample) | 2015-09-04 |
| JP2015500920A (ja) | 2015-01-08 |
| EP2794693B1 (en) | 2020-09-23 |
| CN104169313B (zh) | 2016-09-21 |
| WO2013096573A1 (en) | 2013-06-27 |
| EP2794693A1 (en) | 2014-10-29 |
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