JP6189325B2 - エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 - Google Patents
エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 Download PDFInfo
- Publication number
- JP6189325B2 JP6189325B2 JP2014548874A JP2014548874A JP6189325B2 JP 6189325 B2 JP6189325 B2 JP 6189325B2 JP 2014548874 A JP2014548874 A JP 2014548874A JP 2014548874 A JP2014548874 A JP 2014548874A JP 6189325 B2 JP6189325 B2 JP 6189325B2
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- JP
- Japan
- Prior art keywords
- independently
- atom
- hydrocarbyl
- heterohydrocarbyl
- unsubstituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161577720P | 2011-12-20 | 2011-12-20 | |
| US61/577,720 | 2011-12-20 | ||
| US201261731891P | 2012-11-30 | 2012-11-30 | |
| US61/731,891 | 2012-11-30 | ||
| PCT/US2012/070859 WO2013096573A1 (en) | 2011-12-20 | 2012-12-20 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015500920A JP2015500920A (ja) | 2015-01-08 |
| JP6189325B2 true JP6189325B2 (ja) | 2017-08-30 |
Family
ID=47559697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014548874A Active JP6189325B2 (ja) | 2011-12-20 | 2012-12-20 | エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9422383B2 (enExample) |
| EP (1) | EP2794693B1 (enExample) |
| JP (1) | JP6189325B2 (enExample) |
| KR (1) | KR101989206B1 (enExample) |
| CN (1) | CN104169313B (enExample) |
| BR (1) | BR112014014855B1 (enExample) |
| ES (1) | ES2835807T3 (enExample) |
| IN (1) | IN2014CN04444A (enExample) |
| WO (1) | WO2013096573A1 (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104169313B (zh) | 2011-12-20 | 2016-09-21 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 |
| JP5946331B2 (ja) * | 2012-06-01 | 2016-07-06 | 三井化学株式会社 | エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット |
| EP2925798B1 (en) * | 2012-11-30 | 2019-04-24 | Dow Global Technologies LLC | Ethylene/alpha-olefin/polyene based compositions |
| JP6393693B2 (ja) * | 2012-12-27 | 2018-09-19 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合のための触媒系 |
| US9534070B2 (en) | 2013-01-18 | 2017-01-03 | Dow Global Technologies Llc | Polymerization processes for high molecular weight polymers |
| EP3738927A1 (en) * | 2014-05-31 | 2020-11-18 | Bridgestone Corporation | Metallic complex catalyst, polymerization methods employing same and polymer products thereof |
| ES2780004T3 (es) * | 2014-12-04 | 2020-08-21 | Dow Global Technologies Llc | Catalizadores de bis-fenilfenoxi pentacoordinados para la preparación de polímeros basados en etileno |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| US10167383B2 (en) | 2014-12-29 | 2019-01-01 | Dow Global Technologies Llc | Process to form ethylene/alpha-olefin interpolymers |
| CN107108792B (zh) * | 2014-12-29 | 2021-07-16 | 陶氏环球技术有限责任公司 | 用于形成含有油的乙烯类聚合物的方法 |
| KR102603126B1 (ko) * | 2015-03-31 | 2023-11-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 낮은 수준의 장쇄 분지화를 갖는 고분자량 에틸렌/알파-올레핀/비-접합된 인터폴리머의 생산 방법 |
| BR112017025453B1 (pt) | 2015-05-28 | 2022-01-04 | Dow Global Technologies Llc | Processo para formar interpolímeros de etileno/alfa-olefina |
| US11155693B2 (en) | 2015-09-02 | 2021-10-26 | Dow Global Technologies Llc | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| BR112018003299B1 (pt) | 2015-09-02 | 2022-06-28 | Dow Global Technologies Llc | Composição polimérica reticulável, composição polimérica reticulada e condutor revestido |
| WO2017074707A1 (en) | 2015-10-29 | 2017-05-04 | Dow Global Technologies Llc | Crosslinkable polymeric compositions for flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
| WO2017206008A1 (en) * | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
| CN109601004B (zh) * | 2016-06-30 | 2022-08-09 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃/多烯互聚物以及含有其的组合物 |
| US11981802B2 (en) | 2016-06-30 | 2024-05-14 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene based compositions |
| WO2018013284A2 (en) | 2016-07-13 | 2018-01-18 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| WO2018013283A2 (en) | 2016-07-13 | 2018-01-18 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| JP6936303B2 (ja) | 2016-07-14 | 2021-09-15 | エクソンモービル・ケミカル・パテンツ・インク | 2元メタロセン触媒で重合されたバイモーダルのコポリマー組成物 |
| WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| EP3491033B1 (en) * | 2016-07-29 | 2020-05-13 | Dow Global Technologies LLC | Mixed catalyst systems for producing multimodal elastomers |
| BR112019013212B1 (pt) * | 2016-12-26 | 2022-11-01 | Dow Global Technologies Llc | Primeira composição, composição e artigo |
| JP7173983B2 (ja) * | 2017-03-31 | 2022-11-17 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合のためのビス-ビフェニル-フェノキシ触媒 |
| CN111032772B (zh) * | 2017-06-14 | 2022-07-15 | 埃克森美孚化学专利公司 | 用于交联应用的乙烯共聚物共混物 |
| CN111148641B (zh) | 2017-08-24 | 2023-03-31 | 陶氏环球技术有限责任公司 | 乙烯/C5-C10α-烯烃/多烯互聚物 |
| BR112020016302A2 (pt) | 2018-02-14 | 2020-12-15 | Dow Global Technologies Llc | Composições de interpolímero de etileno/alfa-olefina com desempenho de envelhecimento térmico a longo prazo melhorado |
| US12006423B2 (en) | 2018-08-29 | 2024-06-11 | ExxonMobil Engineering & Technology Company | Methods of making polymer compositions with enhanced elasticity by employing VTP and HMP catalyst systems in parallel processes |
| KR102538844B1 (ko) * | 2018-12-21 | 2023-06-01 | 주식회사 엘지화학 | 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법 |
| JP7186856B2 (ja) | 2019-03-12 | 2022-12-09 | 三井化学株式会社 | オレフィン系樹脂、その架橋物およびそれらの製造方法 |
| WO2020198918A1 (en) * | 2019-03-29 | 2020-10-08 | Dow Global Technologies Llc | Oil-extended pellet form ethylene alpha-olefin diene interpolymers for thermoplastic vulcanizates |
| KR102690386B1 (ko) * | 2019-04-30 | 2024-08-05 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/프로필렌/비공액 디엔 혼성중합체 조성물 |
| CN114466891B (zh) | 2019-09-24 | 2024-06-18 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃/多烯互聚物组合物 |
| BR112022005584A2 (pt) | 2019-09-24 | 2022-06-21 | Dow Global Technologies Llc | Composição, e, artigo |
| KR20220069974A (ko) | 2019-09-24 | 2022-05-27 | 다우 글로벌 테크놀로지스 엘엘씨 | 압출 프로파일용 중합체 조성물 |
| BR112022012694A2 (pt) * | 2019-12-27 | 2022-09-06 | Dow Global Technologies Llc | Copolímero em multiblocos de etileno/buteno e processo para produzir o mesmo |
| JP2021147420A (ja) * | 2020-03-16 | 2021-09-27 | 三井化学株式会社 | オレフィン・環状オレフィン共重合体の製造方法 |
| CN115397875B (zh) * | 2020-03-27 | 2025-03-11 | 陶氏环球技术有限责任公司 | 用于产生长链支化基于乙烯的聚合物的方法 |
| US12410273B2 (en) | 2020-03-30 | 2025-09-09 | Exxonmobil Chemical Patents Inc. | Comb-block copolymers and methods thereof |
| US20230303597A1 (en) * | 2020-12-28 | 2023-09-28 | Sabic Sk Nexlene Company Pte. Ltd. | Metal-ligand complex, catalyst composition for preparing ethylene-based polymer containing the same, and preparation method of ethylene -based polymer using the same |
| KR20240074467A (ko) * | 2022-11-21 | 2024-05-28 | 롯데케미칼 주식회사 | 에틸렌-알파-올레핀 공중합체 제조방법 |
| WO2025117273A1 (en) | 2023-12-01 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Support-bound activators, supported catalyst systems, and processes for use thereof |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
| ATE492552T1 (de) * | 2002-04-24 | 2011-01-15 | Symyx Solutions Inc | Verbrückte bi-aromatische liganden, komplexe, katalysatoren, verfahren zur polymerisierung und entstehende polymere |
| KR101195320B1 (ko) | 2004-08-09 | 2012-10-29 | 다우 글로벌 테크놀로지스 엘엘씨 | 중합체를 제조하기 위한 지지된비스(하이드록시아릴아릴옥시) 촉매 |
| BRPI0711018A8 (pt) * | 2006-05-17 | 2017-09-19 | Dow Global Technologies Inc | Processo para a polimerização de etileno e uma ou mais alfa-olefinas ou diolefinas c-3-30, processo para a polimerização de etileno e uma ou mais alfa-olefinas c3-8 usando um complexo de zircônio e um cocatalizador de ativação e copolímero de etileno e uma ou mais alfa-olefinas c3-8 |
| ES2435568T3 (es) | 2007-11-19 | 2013-12-20 | Dow Global Technologies Llc | Copolímeros de propileno-alfa-olefina con ramificación de cadena larga |
| EP2328944B1 (en) | 2008-09-16 | 2018-01-24 | Dow Global Technologies LLC | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
| EP2448757B1 (en) | 2009-07-01 | 2016-06-29 | Dow Global Technologies LLC | Ethylenic polymer and its use |
| KR20120107066A (ko) | 2009-07-01 | 2012-09-28 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌계 중합체 및 그의 용도 |
| EP2454318B1 (en) | 2009-07-15 | 2014-06-25 | Dow Global Technologies LLC | Polymer compositions, methods of making the same, and articles prepared from the same |
| KR20180066258A (ko) * | 2010-08-25 | 2018-06-18 | 다우 글로벌 테크놀로지스 엘엘씨 | 중합성 올레핀의 중합 방법 및 그를 위한 촉매 |
| US9518137B2 (en) * | 2011-12-13 | 2016-12-13 | Dow Global Technologies Llc | Ethylene propylene-diene interpolymer composition |
| CN104169313B (zh) | 2011-12-20 | 2016-09-21 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 |
-
2012
- 2012-12-20 CN CN201280063427.5A patent/CN104169313B/zh active Active
- 2012-12-20 IN IN4444CHN2014 patent/IN2014CN04444A/en unknown
- 2012-12-20 ES ES12815929T patent/ES2835807T3/es active Active
- 2012-12-20 EP EP12815929.0A patent/EP2794693B1/en active Active
- 2012-12-20 KR KR1020147016448A patent/KR101989206B1/ko active Active
- 2012-12-20 JP JP2014548874A patent/JP6189325B2/ja active Active
- 2012-12-20 BR BR112014014855-4A patent/BR112014014855B1/pt active IP Right Grant
- 2012-12-20 US US14/367,478 patent/US9422383B2/en active Active
- 2012-12-20 WO PCT/US2012/070859 patent/WO2013096573A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US20150322185A1 (en) | 2015-11-12 |
| IN2014CN04444A (enExample) | 2015-09-04 |
| CN104169313A (zh) | 2014-11-26 |
| US9422383B2 (en) | 2016-08-23 |
| KR101989206B1 (ko) | 2019-09-24 |
| WO2013096573A1 (en) | 2013-06-27 |
| ES2835807T3 (es) | 2021-06-23 |
| CN104169313B (zh) | 2016-09-21 |
| BR112014014855B1 (pt) | 2022-01-11 |
| KR20140107263A (ko) | 2014-09-04 |
| EP2794693B1 (en) | 2020-09-23 |
| JP2015500920A (ja) | 2015-01-08 |
| EP2794693A1 (en) | 2014-10-29 |
| BR112014014855A2 (pt) | 2017-06-13 |
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