JP6189325B2 - エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 - Google Patents

エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 Download PDF

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Publication number
JP6189325B2
JP6189325B2 JP2014548874A JP2014548874A JP6189325B2 JP 6189325 B2 JP6189325 B2 JP 6189325B2 JP 2014548874 A JP2014548874 A JP 2014548874A JP 2014548874 A JP2014548874 A JP 2014548874A JP 6189325 B2 JP6189325 B2 JP 6189325B2
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independently
atom
hydrocarbyl
heterohydrocarbyl
unsubstituted
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JP2015500920A (ja
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コリン・リピシャン
トーマス・ダブリュ・カージャラ
マイケル・エル・スミス
リアム・ピー・スペンサー
ジャージー・クロシン
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
JP2014548874A 2011-12-20 2012-12-20 エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 Active JP6189325B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161577720P 2011-12-20 2011-12-20
US61/577,720 2011-12-20
US201261731891P 2012-11-30 2012-11-30
US61/731,891 2012-11-30
PCT/US2012/070859 WO2013096573A1 (en) 2011-12-20 2012-12-20 Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same

Publications (2)

Publication Number Publication Date
JP2015500920A JP2015500920A (ja) 2015-01-08
JP6189325B2 true JP6189325B2 (ja) 2017-08-30

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JP2014548874A Active JP6189325B2 (ja) 2011-12-20 2012-12-20 エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法

Country Status (9)

Country Link
US (1) US9422383B2 (enExample)
EP (1) EP2794693B1 (enExample)
JP (1) JP6189325B2 (enExample)
KR (1) KR101989206B1 (enExample)
CN (1) CN104169313B (enExample)
BR (1) BR112014014855B1 (enExample)
ES (1) ES2835807T3 (enExample)
IN (1) IN2014CN04444A (enExample)
WO (1) WO2013096573A1 (enExample)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104169313B (zh) 2011-12-20 2016-09-21 陶氏环球技术有限责任公司 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法
JP5946331B2 (ja) * 2012-06-01 2016-07-06 三井化学株式会社 エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット
EP2925798B1 (en) * 2012-11-30 2019-04-24 Dow Global Technologies LLC Ethylene/alpha-olefin/polyene based compositions
JP6393693B2 (ja) * 2012-12-27 2018-09-19 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合のための触媒系
US9534070B2 (en) 2013-01-18 2017-01-03 Dow Global Technologies Llc Polymerization processes for high molecular weight polymers
EP3738927A1 (en) * 2014-05-31 2020-11-18 Bridgestone Corporation Metallic complex catalyst, polymerization methods employing same and polymer products thereof
ES2780004T3 (es) * 2014-12-04 2020-08-21 Dow Global Technologies Llc Catalizadores de bis-fenilfenoxi pentacoordinados para la preparación de polímeros basados en etileno
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
US10167383B2 (en) 2014-12-29 2019-01-01 Dow Global Technologies Llc Process to form ethylene/alpha-olefin interpolymers
CN107108792B (zh) * 2014-12-29 2021-07-16 陶氏环球技术有限责任公司 用于形成含有油的乙烯类聚合物的方法
KR102603126B1 (ko) * 2015-03-31 2023-11-17 다우 글로벌 테크놀로지스 엘엘씨 낮은 수준의 장쇄 분지화를 갖는 고분자량 에틸렌/알파-올레핀/비-접합된 인터폴리머의 생산 방법
BR112017025453B1 (pt) 2015-05-28 2022-01-04 Dow Global Technologies Llc Processo para formar interpolímeros de etileno/alfa-olefina
US11155693B2 (en) 2015-09-02 2021-10-26 Dow Global Technologies Llc Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
BR112018003299B1 (pt) 2015-09-02 2022-06-28 Dow Global Technologies Llc Composição polimérica reticulável, composição polimérica reticulada e condutor revestido
WO2017074707A1 (en) 2015-10-29 2017-05-04 Dow Global Technologies Llc Crosslinkable polymeric compositions for flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
WO2017206009A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymers compositions
WO2017206008A1 (en) * 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymer
CN109601004B (zh) * 2016-06-30 2022-08-09 陶氏环球技术有限责任公司 乙烯/α-烯烃/多烯互聚物以及含有其的组合物
US11981802B2 (en) 2016-06-30 2024-05-14 Dow Global Technologies Llc Ethylene/alpha-olefin/polyene based compositions
WO2018013284A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
WO2018013283A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
JP6936303B2 (ja) 2016-07-14 2021-09-15 エクソンモービル・ケミカル・パテンツ・インク 2元メタロセン触媒で重合されたバイモーダルのコポリマー組成物
WO2018022279A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
US10221260B2 (en) 2016-07-29 2019-03-05 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
EP3491033B1 (en) * 2016-07-29 2020-05-13 Dow Global Technologies LLC Mixed catalyst systems for producing multimodal elastomers
BR112019013212B1 (pt) * 2016-12-26 2022-11-01 Dow Global Technologies Llc Primeira composição, composição e artigo
JP7173983B2 (ja) * 2017-03-31 2022-11-17 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合のためのビス-ビフェニル-フェノキシ触媒
CN111032772B (zh) * 2017-06-14 2022-07-15 埃克森美孚化学专利公司 用于交联应用的乙烯共聚物共混物
CN111148641B (zh) 2017-08-24 2023-03-31 陶氏环球技术有限责任公司 乙烯/C5-C10α-烯烃/多烯互聚物
BR112020016302A2 (pt) 2018-02-14 2020-12-15 Dow Global Technologies Llc Composições de interpolímero de etileno/alfa-olefina com desempenho de envelhecimento térmico a longo prazo melhorado
US12006423B2 (en) 2018-08-29 2024-06-11 ExxonMobil Engineering & Technology Company Methods of making polymer compositions with enhanced elasticity by employing VTP and HMP catalyst systems in parallel processes
KR102538844B1 (ko) * 2018-12-21 2023-06-01 주식회사 엘지화학 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법
JP7186856B2 (ja) 2019-03-12 2022-12-09 三井化学株式会社 オレフィン系樹脂、その架橋物およびそれらの製造方法
WO2020198918A1 (en) * 2019-03-29 2020-10-08 Dow Global Technologies Llc Oil-extended pellet form ethylene alpha-olefin diene interpolymers for thermoplastic vulcanizates
KR102690386B1 (ko) * 2019-04-30 2024-08-05 다우 글로벌 테크놀로지스 엘엘씨 에틸렌/프로필렌/비공액 디엔 혼성중합체 조성물
CN114466891B (zh) 2019-09-24 2024-06-18 陶氏环球技术有限责任公司 乙烯/α-烯烃/多烯互聚物组合物
BR112022005584A2 (pt) 2019-09-24 2022-06-21 Dow Global Technologies Llc Composição, e, artigo
KR20220069974A (ko) 2019-09-24 2022-05-27 다우 글로벌 테크놀로지스 엘엘씨 압출 프로파일용 중합체 조성물
BR112022012694A2 (pt) * 2019-12-27 2022-09-06 Dow Global Technologies Llc Copolímero em multiblocos de etileno/buteno e processo para produzir o mesmo
JP2021147420A (ja) * 2020-03-16 2021-09-27 三井化学株式会社 オレフィン・環状オレフィン共重合体の製造方法
CN115397875B (zh) * 2020-03-27 2025-03-11 陶氏环球技术有限责任公司 用于产生长链支化基于乙烯的聚合物的方法
US12410273B2 (en) 2020-03-30 2025-09-09 Exxonmobil Chemical Patents Inc. Comb-block copolymers and methods thereof
US20230303597A1 (en) * 2020-12-28 2023-09-28 Sabic Sk Nexlene Company Pte. Ltd. Metal-ligand complex, catalyst composition for preparing ethylene-based polymer containing the same, and preparation method of ethylene -based polymer using the same
KR20240074467A (ko) * 2022-11-21 2024-05-28 롯데케미칼 주식회사 에틸렌-알파-올레핀 공중합체 제조방법
WO2025117273A1 (en) 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Support-bound activators, supported catalyst systems, and processes for use thereof

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US5977251A (en) 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
US6680361B1 (en) * 1998-11-02 2004-01-20 Dupont Dow Elastomers Llc Shear thinning ethylene/α-olefin interpolymers and their preparation
ATE492552T1 (de) * 2002-04-24 2011-01-15 Symyx Solutions Inc Verbrückte bi-aromatische liganden, komplexe, katalysatoren, verfahren zur polymerisierung und entstehende polymere
KR101195320B1 (ko) 2004-08-09 2012-10-29 다우 글로벌 테크놀로지스 엘엘씨 중합체를 제조하기 위한 지지된비스(하이드록시아릴아릴옥시) 촉매
BRPI0711018A8 (pt) * 2006-05-17 2017-09-19 Dow Global Technologies Inc Processo para a polimerização de etileno e uma ou mais alfa-olefinas ou diolefinas c-3-30, processo para a polimerização de etileno e uma ou mais alfa-olefinas c3-8 usando um complexo de zircônio e um cocatalizador de ativação e copolímero de etileno e uma ou mais alfa-olefinas c3-8
ES2435568T3 (es) 2007-11-19 2013-12-20 Dow Global Technologies Llc Copolímeros de propileno-alfa-olefina con ramificación de cadena larga
EP2328944B1 (en) 2008-09-16 2018-01-24 Dow Global Technologies LLC Polymeric compositions and foams, methods of making the same, and articles prepared from the same
EP2448757B1 (en) 2009-07-01 2016-06-29 Dow Global Technologies LLC Ethylenic polymer and its use
KR20120107066A (ko) 2009-07-01 2012-09-28 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 중합체 및 그의 용도
EP2454318B1 (en) 2009-07-15 2014-06-25 Dow Global Technologies LLC Polymer compositions, methods of making the same, and articles prepared from the same
KR20180066258A (ko) * 2010-08-25 2018-06-18 다우 글로벌 테크놀로지스 엘엘씨 중합성 올레핀의 중합 방법 및 그를 위한 촉매
US9518137B2 (en) * 2011-12-13 2016-12-13 Dow Global Technologies Llc Ethylene propylene-diene interpolymer composition
CN104169313B (zh) 2011-12-20 2016-09-21 陶氏环球技术有限责任公司 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法

Also Published As

Publication number Publication date
US20150322185A1 (en) 2015-11-12
IN2014CN04444A (enExample) 2015-09-04
CN104169313A (zh) 2014-11-26
US9422383B2 (en) 2016-08-23
KR101989206B1 (ko) 2019-09-24
WO2013096573A1 (en) 2013-06-27
ES2835807T3 (es) 2021-06-23
CN104169313B (zh) 2016-09-21
BR112014014855B1 (pt) 2022-01-11
KR20140107263A (ko) 2014-09-04
EP2794693B1 (en) 2020-09-23
JP2015500920A (ja) 2015-01-08
EP2794693A1 (en) 2014-10-29
BR112014014855A2 (pt) 2017-06-13

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