JP6189325B2 - エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 - Google Patents
エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 Download PDFInfo
- Publication number
- JP6189325B2 JP6189325B2 JP2014548874A JP2014548874A JP6189325B2 JP 6189325 B2 JP6189325 B2 JP 6189325B2 JP 2014548874 A JP2014548874 A JP 2014548874A JP 2014548874 A JP2014548874 A JP 2014548874A JP 6189325 B2 JP6189325 B2 JP 6189325B2
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- JP
- Japan
- Prior art keywords
- independently
- atom
- hydrocarbyl
- heterohydrocarbyl
- unsubstituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161577720P | 2011-12-20 | 2011-12-20 | |
| US61/577,720 | 2011-12-20 | ||
| US201261731891P | 2012-11-30 | 2012-11-30 | |
| US61/731,891 | 2012-11-30 | ||
| PCT/US2012/070859 WO2013096573A1 (en) | 2011-12-20 | 2012-12-20 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015500920A JP2015500920A (ja) | 2015-01-08 |
| JP6189325B2 true JP6189325B2 (ja) | 2017-08-30 |
Family
ID=47559697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014548874A Active JP6189325B2 (ja) | 2011-12-20 | 2012-12-20 | エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9422383B2 (enExample) |
| EP (1) | EP2794693B1 (enExample) |
| JP (1) | JP6189325B2 (enExample) |
| KR (1) | KR101989206B1 (enExample) |
| CN (1) | CN104169313B (enExample) |
| BR (1) | BR112014014855B1 (enExample) |
| ES (1) | ES2835807T3 (enExample) |
| IN (1) | IN2014CN04444A (enExample) |
| WO (1) | WO2013096573A1 (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112014014855B1 (pt) | 2011-12-20 | 2022-01-11 | Dow Global Technologies Llc | Processo de polimerização em solução para formar um interpolímero de etileno/aolefina/polieno não conjugado |
| JP5946331B2 (ja) * | 2012-06-01 | 2016-07-06 | 三井化学株式会社 | エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット |
| BR112015010919B1 (pt) * | 2012-11-30 | 2021-08-17 | Dow Global Technologies Llc | Composição, composição reticulada e artigo |
| KR20150100694A (ko) * | 2012-12-27 | 2015-09-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 촉매계 |
| KR102038178B1 (ko) | 2013-01-18 | 2019-10-29 | 다우 글로벌 테크놀로지스 엘엘씨 | 고분자량 폴리올레핀을 위한 중합 방법 |
| RU2723019C2 (ru) * | 2014-05-31 | 2020-06-08 | Бриджстоун Корпорейшн | Интерполимер и содержащая его композиция |
| US10301412B2 (en) | 2014-12-04 | 2019-05-28 | Dow Global Technologies Llc | Five-coordinate bis-phenylphenoxy catalysts for the preparation of ethylene-based polymers |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| KR102456431B1 (ko) * | 2014-12-29 | 2022-10-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/알파-올레핀 인터폴리머를 형성하는 방법 |
| JP6718453B2 (ja) * | 2014-12-29 | 2020-07-08 | ダウ グローバル テクノロジーズ エルエルシー | 油含有エチレン系ポリマーを形成する方法 |
| US10450394B2 (en) | 2015-03-31 | 2019-10-22 | Dow Global Technologies Llc | Processes for the production of high molecular weight ethylene/alpha-olefin/non-conjugated interpolymers with low levels of long chain branching |
| EP3303427B1 (en) * | 2015-05-28 | 2023-11-29 | Dow Global Technologies LLC | Process to form ethylene/alpha-olefin/diene interpolymers |
| EP3344694B1 (en) * | 2015-09-02 | 2022-05-18 | Dow Global Technologies LLC | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| US10490319B2 (en) | 2015-09-02 | 2019-11-26 | Dow Global Technologies Llc | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| MX392441B (es) | 2015-10-29 | 2025-03-21 | Dow Global Technologies Llc | Composiciones polimericas reticulables para aislamiento de cable reticulado flexible y metodos para la fabricacion de aislamiento de cable reticulado flexible. |
| WO2017206008A1 (en) * | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
| WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
| CN109601004B (zh) * | 2016-06-30 | 2022-08-09 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃/多烯互聚物以及含有其的组合物 |
| EP3478762A1 (en) * | 2016-06-30 | 2019-05-08 | Dow Global Technologies, LLC | Ethylene/alpha-olefin/polyene based compositions |
| CN109641989B (zh) | 2016-07-13 | 2022-05-03 | 埃克森美孚化学专利公司 | 双金属茂催化剂共聚物组合物 |
| WO2018013284A2 (en) | 2016-07-13 | 2018-01-18 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| WO2018013285A1 (en) | 2016-07-14 | 2018-01-18 | Exxonmobil Chemical Patents Inc. | Dual metallocene-catalyzed bimodal copolymer compositions |
| WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| KR102413982B1 (ko) * | 2016-07-29 | 2022-06-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중모드 엘라스토머 생산용 혼합 촉매 시스템 |
| US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| EP3559114B1 (en) * | 2016-12-26 | 2024-04-17 | Dow Global Technologies LLC | Ethylene/a-olefin/nonconjugated polyene interpolymer compositions and articles prepared from the same |
| BR112019020417B1 (pt) * | 2017-03-31 | 2023-04-04 | Dow Global Technologies Llc | Sistema catalisador e processo de polimerização para produzir um polímero à base de etileno |
| US11390704B2 (en) | 2017-06-14 | 2022-07-19 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
| CN111148641B (zh) | 2017-08-24 | 2023-03-31 | 陶氏环球技术有限责任公司 | 乙烯/C5-C10α-烯烃/多烯互聚物 |
| BR112020016302A2 (pt) * | 2018-02-14 | 2020-12-15 | Dow Global Technologies Llc | Composições de interpolímero de etileno/alfa-olefina com desempenho de envelhecimento térmico a longo prazo melhorado |
| WO2020046597A1 (en) | 2018-08-29 | 2020-03-05 | Exxonmobil Chemical Patents Inc. | Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes |
| KR102538844B1 (ko) * | 2018-12-21 | 2023-06-01 | 주식회사 엘지화학 | 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법 |
| EP3940009A4 (en) | 2019-03-12 | 2023-03-15 | Mitsui Chemicals, Inc. | OLEFIN-BASED RESIN, CROSSLINKER THEREOF, AND METHODS OF PRODUCTION THEREOF |
| CN115667389B (zh) * | 2019-03-29 | 2024-05-07 | 陶氏环球技术有限责任公司 | 用于热塑性硫化橡胶的充油团粒形式的乙烯α-烯烃二烯互聚物 |
| JP7408687B2 (ja) | 2019-04-30 | 2024-01-05 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/プロピレン/非共役ジエンインターポリマー組成物 |
| EP4034578A1 (en) * | 2019-09-24 | 2022-08-03 | Dow Global Technologies LLC | Polymer compositions for extruded profiles |
| BR112022005433A2 (pt) | 2019-09-24 | 2022-06-21 | Dow Global Technologies Llc | Composição, composição reticulada, e, artigo |
| KR20220066152A (ko) | 2019-09-24 | 2022-05-23 | 다우 글로벌 테크놀로지스 엘엘씨 | 우수한 전기적 특성 및 기계적 특성을 갖는 중합체 조성물 |
| JP2023508667A (ja) * | 2019-12-27 | 2023-03-03 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/ブテンマルチブロックコポリマー及びその製造のためのプロセス |
| JP2021147420A (ja) * | 2020-03-16 | 2021-09-27 | 三井化学株式会社 | オレフィン・環状オレフィン共重合体の製造方法 |
| BR112022019374A2 (pt) * | 2020-03-27 | 2022-11-16 | Dow Global Technologies Llc | Processo para polimerizar polímeros à base de etileno |
| EP4127061A1 (en) | 2020-03-30 | 2023-02-08 | ExxonMobil Chemical Patents Inc. | Comb-block copolymers and methods thereof |
| CN116261572A (zh) * | 2020-12-28 | 2023-06-13 | 沙特基础工业爱思开Nexlene私人有限公司 | 金属-配体配合物、包含其的用于制备基于乙烯的聚合物的催化剂组合物、以及使用其的基于乙烯的聚合物的制备方法 |
| KR20240074467A (ko) * | 2022-11-21 | 2024-05-28 | 롯데케미칼 주식회사 | 에틸렌-알파-올레핀 공중합체 제조방법 |
| WO2025117273A1 (en) | 2023-12-01 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Support-bound activators, supported catalyst systems, and processes for use thereof |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
| AU2003225156A1 (en) * | 2002-04-24 | 2003-11-10 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, complexes, catalysts and processes for polymerizing and poymers therefrom |
| WO2006020624A1 (en) | 2004-08-09 | 2006-02-23 | Dow Global Technologies Inc. | Supported bis(hydroxyarylaryloxy) catalysts for manufacture of polymers |
| CA2652460A1 (en) | 2006-05-17 | 2007-11-29 | Dow Global Technologies Inc. | High efficiency solution polymerization process |
| EP2212359B1 (en) | 2007-11-19 | 2013-08-28 | Dow Global Technologies LLC | Long chain branched propylene-alpha-olefin copolymers |
| US8772414B2 (en) * | 2008-09-16 | 2014-07-08 | Dow Global Technologies Llc | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
| SG178222A1 (en) | 2009-07-01 | 2012-03-29 | Dow Global Technologies Llc | Ethylenic polymer and its use |
| SG10201403765WA (en) | 2009-07-01 | 2014-09-26 | Dow Global Technologies Llc | Ethylenic Polymer And Its Use |
| CN102471551B (zh) | 2009-07-15 | 2013-09-04 | 陶氏环球技术有限责任公司 | 聚合物组合物、其制备方法、以及由该组合物制备的制品 |
| KR101865645B1 (ko) * | 2010-08-25 | 2018-06-11 | 다우 글로벌 테크놀로지스 엘엘씨 | 중합성 올레핀의 중합 방법 및 그를 위한 촉매 |
| CN103987743B (zh) * | 2011-12-13 | 2016-05-11 | 陶氏环球技术有限责任公司 | 乙烯-丙烯-二烯互聚物组合物 |
| BR112014014855B1 (pt) | 2011-12-20 | 2022-01-11 | Dow Global Technologies Llc | Processo de polimerização em solução para formar um interpolímero de etileno/aolefina/polieno não conjugado |
-
2012
- 2012-12-20 BR BR112014014855-4A patent/BR112014014855B1/pt active IP Right Grant
- 2012-12-20 JP JP2014548874A patent/JP6189325B2/ja active Active
- 2012-12-20 KR KR1020147016448A patent/KR101989206B1/ko active Active
- 2012-12-20 US US14/367,478 patent/US9422383B2/en active Active
- 2012-12-20 ES ES12815929T patent/ES2835807T3/es active Active
- 2012-12-20 EP EP12815929.0A patent/EP2794693B1/en active Active
- 2012-12-20 CN CN201280063427.5A patent/CN104169313B/zh active Active
- 2012-12-20 IN IN4444CHN2014 patent/IN2014CN04444A/en unknown
- 2012-12-20 WO PCT/US2012/070859 patent/WO2013096573A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013096573A1 (en) | 2013-06-27 |
| BR112014014855A2 (pt) | 2017-06-13 |
| ES2835807T3 (es) | 2021-06-23 |
| CN104169313A (zh) | 2014-11-26 |
| JP2015500920A (ja) | 2015-01-08 |
| EP2794693A1 (en) | 2014-10-29 |
| EP2794693B1 (en) | 2020-09-23 |
| CN104169313B (zh) | 2016-09-21 |
| IN2014CN04444A (enExample) | 2015-09-04 |
| KR101989206B1 (ko) | 2019-09-24 |
| KR20140107263A (ko) | 2014-09-04 |
| BR112014014855B1 (pt) | 2022-01-11 |
| US9422383B2 (en) | 2016-08-23 |
| US20150322185A1 (en) | 2015-11-12 |
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