JP6189325B2 - エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 - Google Patents

エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 Download PDF

Info

Publication number
JP6189325B2
JP6189325B2 JP2014548874A JP2014548874A JP6189325B2 JP 6189325 B2 JP6189325 B2 JP 6189325B2 JP 2014548874 A JP2014548874 A JP 2014548874A JP 2014548874 A JP2014548874 A JP 2014548874A JP 6189325 B2 JP6189325 B2 JP 6189325B2
Authority
JP
Japan
Prior art keywords
independently
atom
hydrocarbyl
heterohydrocarbyl
unsubstituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2014548874A
Other languages
English (en)
Japanese (ja)
Other versions
JP2015500920A (ja
Inventor
コリン・リピシャン
トーマス・ダブリュ・カージャラ
マイケル・エル・スミス
リアム・ピー・スペンサー
ジャージー・クロシン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of JP2015500920A publication Critical patent/JP2015500920A/ja
Application granted granted Critical
Publication of JP6189325B2 publication Critical patent/JP6189325B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
JP2014548874A 2011-12-20 2012-12-20 エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 Active JP6189325B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161577720P 2011-12-20 2011-12-20
US61/577,720 2011-12-20
US201261731891P 2012-11-30 2012-11-30
US61/731,891 2012-11-30
PCT/US2012/070859 WO2013096573A1 (en) 2011-12-20 2012-12-20 Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same

Publications (2)

Publication Number Publication Date
JP2015500920A JP2015500920A (ja) 2015-01-08
JP6189325B2 true JP6189325B2 (ja) 2017-08-30

Family

ID=47559697

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2014548874A Active JP6189325B2 (ja) 2011-12-20 2012-12-20 エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法

Country Status (9)

Country Link
US (1) US9422383B2 (enExample)
EP (1) EP2794693B1 (enExample)
JP (1) JP6189325B2 (enExample)
KR (1) KR101989206B1 (enExample)
CN (1) CN104169313B (enExample)
BR (1) BR112014014855B1 (enExample)
ES (1) ES2835807T3 (enExample)
IN (1) IN2014CN04444A (enExample)
WO (1) WO2013096573A1 (enExample)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104169313B (zh) 2011-12-20 2016-09-21 陶氏环球技术有限责任公司 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法
JP5946331B2 (ja) * 2012-06-01 2016-07-06 三井化学株式会社 エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット
JP6320407B2 (ja) * 2012-11-30 2018-05-09 ダウ グローバル テクノロジーズ エルエルシー エチレン/αオレフィン/ポリエン系組成物
EP2938643B1 (en) * 2012-12-27 2018-01-31 Dow Global Technologies LLC Catalyst systems for olefin polymerization
RU2643149C2 (ru) 2013-01-18 2018-01-31 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Способы полимеризации для высокомолекулярных полиолефинов
EP3738927A1 (en) 2014-05-31 2020-11-18 Bridgestone Corporation Metallic complex catalyst, polymerization methods employing same and polymer products thereof
WO2016089935A1 (en) * 2014-12-04 2016-06-09 Dow Global Technologies Llc Five-coordinate bis-phenylphenoxy catalysts for the preparation of ethylene-based polymers
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
SG11201705239SA (en) 2014-12-29 2017-07-28 Dow Global Technologies Llc Process to form ethylene/alpha-olefin interpolymers
KR102439497B1 (ko) 2014-12-29 2022-09-05 다우 글로벌 테크놀로지스 엘엘씨 오일 함유 에틸렌계 폴리머의 형성 방법
CN107428878B (zh) * 2015-03-31 2020-08-28 陶氏环球技术有限责任公司 用于制备具有低含量长链支化的高分子量乙烯/α-烯烃/非共轭互聚物的方法
EP3303427B1 (en) * 2015-05-28 2023-11-29 Dow Global Technologies LLC Process to form ethylene/alpha-olefin/diene interpolymers
MX2018002459A (es) * 2015-09-02 2018-06-15 Dow Global Technologies Llc Aislamiento de cable reticulado flexible y metodos para hacer el aislamiento de cable reticulado flexible.
WO2017040088A1 (en) * 2015-09-02 2017-03-09 Dow Global Technologies Llc Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
EP3368602B1 (en) 2015-10-29 2020-07-08 Dow Global Technologies, LLC Crosslinkable polymeric compositions for flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
WO2017206008A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymer
WO2017206009A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymers compositions
CN109601004B (zh) * 2016-06-30 2022-08-09 陶氏环球技术有限责任公司 乙烯/α-烯烃/多烯互聚物以及含有其的组合物
KR102396055B1 (ko) * 2016-06-30 2022-05-11 다우 글로벌 테크놀로지스 엘엘씨 에틸렌/알파-올레핀/폴리엔계 조성물
US11352451B2 (en) 2016-07-13 2022-06-07 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
US10808049B2 (en) 2016-07-13 2020-10-20 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
JP6850862B2 (ja) 2016-07-14 2021-03-31 エクソンモービル・ケミカル・パテンツ・インク 粘度調整剤として有用な、2元メタロセン触媒で重合されたバイモーダルのコポリマー組成物
BR112019001249B1 (pt) * 2016-07-29 2022-10-18 Dow Global Technologies Llc Elastômero multimodal, olefina termoplástica e método para produzir um elastômero multimodal
WO2018022279A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
US10221260B2 (en) 2016-07-29 2019-03-05 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
KR102653792B1 (ko) * 2016-12-26 2024-04-03 다우 글로벌 테크놀로지스 엘엘씨 에틸렌/α-올레핀/비공액 폴리엔 혼성 중합체 조성물 및 이로부터 제조된 물품
JP7173983B2 (ja) * 2017-03-31 2022-11-17 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合のためのビス-ビフェニル-フェノキシ触媒
US11390704B2 (en) 2017-06-14 2022-07-19 Exxonmobil Chemical Patents Inc. Ethylene copolymer blends for cross-linking applications
WO2019040845A1 (en) 2017-08-24 2019-02-28 Dow Global Technologies Llc ETHYLENE / ALPHA-OLEFIN C5-C10 / POLYENE INTERPOLYMERS
EP3752560B1 (en) * 2018-02-14 2024-09-25 Dow Global Technologies LLC Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance
WO2020046597A1 (en) 2018-08-29 2020-03-05 Exxonmobil Chemical Patents Inc. Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes
KR102538844B1 (ko) * 2018-12-21 2023-06-01 주식회사 엘지화학 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법
EP3940009A4 (en) 2019-03-12 2023-03-15 Mitsui Chemicals, Inc. OLEFIN-BASED RESIN, CROSSLINKER THEREOF, AND METHODS OF PRODUCTION THEREOF
WO2020198918A1 (en) * 2019-03-29 2020-10-08 Dow Global Technologies Llc Oil-extended pellet form ethylene alpha-olefin diene interpolymers for thermoplastic vulcanizates
CN113874439B (zh) * 2019-04-30 2024-03-29 陶氏环球技术有限责任公司 乙烯/丙烯/非共轭二烯互聚物组合物
BR112022005584A2 (pt) 2019-09-24 2022-06-21 Dow Global Technologies Llc Composição, e, artigo
WO2021061580A1 (en) 2019-09-24 2021-04-01 Dow Global Technologies Llc Polymer compositions for extruded profiles
JP2022549319A (ja) 2019-09-24 2022-11-24 ダウ グローバル テクノロジーズ エルエルシー エチレン/アルファ-オレフィン/ポリエンインターポリマー組成物
WO2021133925A1 (en) * 2019-12-27 2021-07-01 Dow Global Technologies Llc Ethylene/butene multi-block copolymer and process for producing same
JP2021147420A (ja) * 2020-03-16 2021-09-27 三井化学株式会社 オレフィン・環状オレフィン共重合体の製造方法
CN115397875B (zh) * 2020-03-27 2025-03-11 陶氏环球技术有限责任公司 用于产生长链支化基于乙烯的聚合物的方法
EP4127061A1 (en) 2020-03-30 2023-02-08 ExxonMobil Chemical Patents Inc. Comb-block copolymers and methods thereof
US20230303597A1 (en) * 2020-12-28 2023-09-28 Sabic Sk Nexlene Company Pte. Ltd. Metal-ligand complex, catalyst composition for preparing ethylene-based polymer containing the same, and preparation method of ethylene -based polymer using the same
KR20240074467A (ko) * 2022-11-21 2024-05-28 롯데케미칼 주식회사 에틸렌-알파-올레핀 공중합체 제조방법
WO2025117273A1 (en) 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Support-bound activators, supported catalyst systems, and processes for use thereof

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US5977251A (en) 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
US6680361B1 (en) * 1998-11-02 2004-01-20 Dupont Dow Elastomers Llc Shear thinning ethylene/α-olefin interpolymers and their preparation
US6897276B2 (en) * 2002-04-24 2005-05-24 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
WO2006020624A1 (en) 2004-08-09 2006-02-23 Dow Global Technologies Inc. Supported bis(hydroxyarylaryloxy) catalysts for manufacture of polymers
ES2534469T3 (es) 2006-05-17 2015-04-23 Dow Global Technologies Llc Procedimiento de polimerización de polietileno en disolución a alta temperatura
ES2435568T3 (es) 2007-11-19 2013-12-20 Dow Global Technologies Llc Copolímeros de propileno-alfa-olefina con ramificación de cadena larga
US8772414B2 (en) * 2008-09-16 2014-07-08 Dow Global Technologies Llc Polymeric compositions and foams, methods of making the same, and articles prepared from the same
SG178222A1 (en) 2009-07-01 2012-03-29 Dow Global Technologies Llc Ethylenic polymer and its use
SG10201403765WA (en) 2009-07-01 2014-09-26 Dow Global Technologies Llc Ethylenic Polymer And Its Use
US9102824B2 (en) 2009-07-15 2015-08-11 Dow Global Technologies Llc Polymer compositions, methods of making the same, and articles prepared from the same
KR101865645B1 (ko) * 2010-08-25 2018-06-11 다우 글로벌 테크놀로지스 엘엘씨 중합성 올레핀의 중합 방법 및 그를 위한 촉매
EP2791190B1 (en) * 2011-12-13 2016-07-06 Dow Global Technologies LLC Ethylene-propylene-diene interpolymer composition
CN104169313B (zh) 2011-12-20 2016-09-21 陶氏环球技术有限责任公司 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法

Also Published As

Publication number Publication date
WO2013096573A1 (en) 2013-06-27
EP2794693B1 (en) 2020-09-23
KR101989206B1 (ko) 2019-09-24
KR20140107263A (ko) 2014-09-04
JP2015500920A (ja) 2015-01-08
EP2794693A1 (en) 2014-10-29
BR112014014855B1 (pt) 2022-01-11
US9422383B2 (en) 2016-08-23
BR112014014855A2 (pt) 2017-06-13
ES2835807T3 (es) 2021-06-23
CN104169313B (zh) 2016-09-21
CN104169313A (zh) 2014-11-26
IN2014CN04444A (enExample) 2015-09-04
US20150322185A1 (en) 2015-11-12

Similar Documents

Publication Publication Date Title
JP6189325B2 (ja) エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法
RU2643149C2 (ru) Способы полимеризации для высокомолекулярных полиолефинов
KR101688253B1 (ko) 이중- 또는 다중-헤드 사슬 이동제 및 그의 블록 공중합체의 제조에서의 용도
JP7523447B2 (ja) 不飽和ポリオレフィンを含む硬化性組成物
CN113454130B (zh) 遥爪聚烯烃和用于制备遥爪聚烯烃的方法
KR102880619B1 (ko) 텔레켈릭 폴리올레핀을 포함하는 경화성 조성물
CN111868166A (zh) 具有改进的长期热老化性能的乙烯/α-烯烃互聚物组合物
KR20190013901A (ko) 에틸렌/알파-올레핀/다이엔 혼성중합체
JP6180517B2 (ja) アルキル化フェノールを使用してエチレン系ポリマーを作製するためのフリーラジカルプロセス
KR102671695B1 (ko) 우수한 용융 특성을 지닌 폴리프로필렌 수지 및 그 제조 방법
KR20250118802A (ko) 폴리에틸렌 조성물 및 이를 포함하는 이축 연신 필름
KR20220073962A (ko) 용융 특성이 향상된 폴리프로필렌 중합 방법 및 상기 방법에 의해 제조된 폴리프로필렌

Legal Events

Date Code Title Description
RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20140617

RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20150121

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20150929

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20160721

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20160802

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20161101

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20170110

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170510

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20170517

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20170704

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20170802

R150 Certificate of patent or registration of utility model

Ref document number: 6189325

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250