BR0211921A - Ëxidos e sulfetos de mono- e bis-acilfosfina batocrÈmicos e seu uso como fotoiniciadores - Google Patents
Ëxidos e sulfetos de mono- e bis-acilfosfina batocrÈmicos e seu uso como fotoiniciadoresInfo
- Publication number
- BR0211921A BR0211921A BR0211921-8A BR0211921A BR0211921A BR 0211921 A BR0211921 A BR 0211921A BR 0211921 A BR0211921 A BR 0211921A BR 0211921 A BR0211921 A BR 0211921A
- Authority
- BR
- Brazil
- Prior art keywords
- sub
- photoinitiators
- alkyl
- sulfides
- mono
- Prior art date
Links
- 150000003568 thioethers Chemical class 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical class 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 150000002431 hydrogen Chemical class 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
- C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/3247—Esters of acids containing the structure -C(=X)-P(=X)(R)(XH) or NC-P(=X)(R)(XH), (X = O, S, Se)
- C07F9/3252—Esters of acids containing the structure -C(=X)-P(=X)(R)(XH) or NC-P(=X)(R)(XH), (X = O, S, Se) containing the structure -C(=X)-P(=X)(R)(XR), (X = O, S, Se)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
- C07F9/5337—Phosphine oxides or thioxides containing the structure -C(=X)-P(=X) or NC-P(=X) (X = O, S, Se)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/572—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
- C07F9/6533—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Paints Or Removers (AREA)
- Dental Preparations (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
"OXIDOS E SULFETOS DE MONO- E BISACILFOSFINA BATOCRÈMICOS E SEU USO COMO FOTOINICIADORES". Compostos da fórmula I: em que: A é S ou O; x é 0 ou 1; Q é SR~ 10~ ou N(R~ 11~)(R~ 12~); R~ 1~ e R~ 2~ são C~ 1~C~ 24~ alquila, OR~ 10~, CF~ 3~ ou halogênio; R~ 3~, R~ 4~ e R~ 5~ são hidrogênio, C~ 1~-C~ 24~ alquila, OR~ 10~ ou halogênio; ou dois dos radicais R~ 1~, R~ 2~, R~ 3~, R~ 4~ e/ou R~ 5~ juntos formam C~ 1~-C~ 20~ alquileno não-interrompido ou interrompido por O, S ou NR~ 13~; R~ 6~, R~ 7~, R~ 8~ e R~ 9~ são hidrogênio, C~ 1~-C~ 24~ alquila; C~ 2~-C~ 24~ alquila a qual é interrompida uma ou mais vezes por átomos de O não-consecutivos e não-substituída ou substituída por OH e/ou SH; ou R~ 6~, R~ 7~, R~ 8~ e R~ 9~ são OR~ 10~; halogênio; ou fenila não-substituída ou substituída uma ou mais vezes por C~ 1~C~ 4~ alquila; R~ 10~, R~ 11~, e R~ 12~ são, por exemplo, C~ 1~-C~ 24~ alquila, fenila ou benzila; R~ 13 é, por exemplo, hidrogênio; X é, por exemplo, ou OR~ 10~; R~ 1~<39> e R~ 2~<39> têm um dos significados fornecidos para R~ 1~ e R~ 2~; e R~ 3~<39>, R~ 4~<39>e R~ 5~<39>têm um dos significados fornecidos para R~ 3~, R~ 4~ e R~ 5~; são adequados como fotoiniciadores, especialmente para irradiação com luz de comprimentos de onda relativamente longos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH15422001 | 2001-08-21 | ||
PCT/EP2002/009045 WO2003019295A1 (en) | 2001-08-21 | 2002-08-13 | Bathochromic mono- and bis-acylphosphine oxides and sulfides and their use as photoinitiators |
Publications (2)
Publication Number | Publication Date |
---|---|
BR0211921A true BR0211921A (pt) | 2004-10-26 |
BR0211921B1 BR0211921B1 (pt) | 2012-05-02 |
Family
ID=4565544
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0211921-8A BR0211921B1 (pt) | 2001-08-21 | 2002-08-13 | óxidos e sulfetos de mono- e bis-acilfosfina batocrÈmicos e seus usos, seus processos de preparação, sua composição forocurável, processo para fotopolimerização de compostos monoméricos, oligoméricos ou poliméricos não voláteis e substrato revestido. |
Country Status (13)
Country | Link |
---|---|
US (1) | US7148382B2 (pt) |
EP (1) | EP1423757B1 (pt) |
JP (1) | JP4225898B2 (pt) |
KR (1) | KR100903939B1 (pt) |
CN (1) | CN100437354C (pt) |
AT (1) | ATE430329T1 (pt) |
BR (1) | BR0211921B1 (pt) |
CA (1) | CA2454914A1 (pt) |
DE (1) | DE60232160D1 (pt) |
DK (1) | DK1423757T3 (pt) |
ES (1) | ES2324983T3 (pt) |
MX (1) | MXPA04001483A (pt) |
WO (1) | WO2003019295A1 (pt) |
Families Citing this family (94)
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2002
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- 2002-08-13 MX MXPA04001483A patent/MXPA04001483A/es active IP Right Grant
- 2002-08-13 JP JP2003523295A patent/JP4225898B2/ja not_active Expired - Lifetime
- 2002-08-13 CA CA002454914A patent/CA2454914A1/en not_active Abandoned
- 2002-08-13 CN CNB028162811A patent/CN100437354C/zh not_active Expired - Lifetime
- 2002-08-13 DK DK02796226T patent/DK1423757T3/da active
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KR100903939B1 (ko) | 2009-06-25 |
BR0211921B1 (pt) | 2012-05-02 |
ES2324983T3 (es) | 2009-08-21 |
EP1423757B1 (en) | 2009-04-29 |
KR20040028996A (ko) | 2004-04-03 |
CN100437354C (zh) | 2008-11-26 |
DE60232160D1 (de) | 2009-06-10 |
JP2005501124A (ja) | 2005-01-13 |
EP1423757A1 (en) | 2004-06-02 |
CN1545643A (zh) | 2004-11-10 |
CA2454914A1 (en) | 2003-03-06 |
MXPA04001483A (es) | 2004-07-30 |
ATE430329T1 (de) | 2009-05-15 |
JP4225898B2 (ja) | 2009-02-18 |
US7148382B2 (en) | 2006-12-12 |
US20040204613A1 (en) | 2004-10-14 |
DK1423757T3 (da) | 2009-08-17 |
WO2003019295A1 (en) | 2003-03-06 |
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