MXPA04001483A - Mono y bis-acilfosfina oxidos y sulfuro batrocromicos y su uso como fotoiniciadores. - Google Patents

Mono y bis-acilfosfina oxidos y sulfuro batrocromicos y su uso como fotoiniciadores.

Info

Publication number
MXPA04001483A
MXPA04001483A MXPA04001483A MXPA04001483A MXPA04001483A MX PA04001483 A MXPA04001483 A MX PA04001483A MX PA04001483 A MXPA04001483 A MX PA04001483A MX PA04001483 A MXPA04001483 A MX PA04001483A MX PA04001483 A MXPA04001483 A MX PA04001483A
Authority
MX
Mexico
Prior art keywords
photoinitiators
bathochromic
sulfides
mono
bis
Prior art date
Application number
MXPA04001483A
Other languages
English (en)
Inventor
Pierre Wolf Jean
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Publication of MXPA04001483A publication Critical patent/MXPA04001483A/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32—Esters thereof
    • C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/3247—Esters of acids containing the structure -C(=X)-P(=X)(R)(XH) or NC-P(=X)(R)(XH), (X = O, S, Se)
    • C07F9/3252—Esters of acids containing the structure -C(=X)-P(=X)(R)(XH) or NC-P(=X)(R)(XH), (X = O, S, Se) containing the structure -C(=X)-P(=X)(R)(XR), (X = O, S, Se)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/5337—Phosphine oxides or thioxides containing the structure -C(=X)-P(=X) or NC-P(=X) (X = O, S, Se)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07F9/6533—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Polymerisation Methods In General (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Paints Or Removers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Dental Preparations (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Compuestos de la formula I (Ver formula) (I) en donde A e s S o O; x es 0 o 1; Q es SR10, o N(R11) (R12); R1 y R2 son alquilo C1-C24, OR10 CF3 o halogeno; R3, R4 y R5 son hidrogeno, alquilo C1-C24, OR??10, o halogeno; o dos de los radicales R1, R2, R3, R4 y/o R5 junto forman alquileno- C1-C20 que esta sin interrumpir o interrumpido por O, S o NR13; R6, R7, R8 y R9 son hidrogeno, alquilo-C1-C24; alquilo-C2-C24 que esta interrumpido una o mas veces por atomos de O no-consecutivos y que esta sin substituir o substituido por OH y/o SH; o R6, R7, R8 y R9 son OR10; halogeno; o fenilo sin substituir o substituido una o mas veces por alquilo-C1-C4; R10, R11 y R12 son por ejemplo alquilo-C1-C24, fenilo o benzilo; R13 es por ejemplo hidrogeno; OR10; R1?? y R2?? tienen uno de los significados dados para R1 y R2; R3??, R4?? y R5?? tienen uno los significados dados para R3, R4 y R5; son adecuados como fotoiniciadores, en especial para irradiacion con luz de longitudes de onda relativamente largas.
MXPA04001483A 2001-08-21 2002-08-13 Mono y bis-acilfosfina oxidos y sulfuro batrocromicos y su uso como fotoiniciadores. MXPA04001483A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH15422001 2001-08-21
PCT/EP2002/009045 WO2003019295A1 (en) 2001-08-21 2002-08-13 Bathochromic mono- and bis-acylphosphine oxides and sulfides and their use as photoinitiators

Publications (1)

Publication Number Publication Date
MXPA04001483A true MXPA04001483A (es) 2004-07-30

Family

ID=4565544

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA04001483A MXPA04001483A (es) 2001-08-21 2002-08-13 Mono y bis-acilfosfina oxidos y sulfuro batrocromicos y su uso como fotoiniciadores.

Country Status (13)

Country Link
US (1) US7148382B2 (es)
EP (1) EP1423757B1 (es)
JP (1) JP4225898B2 (es)
KR (1) KR100903939B1 (es)
CN (1) CN100437354C (es)
AT (1) ATE430329T1 (es)
BR (1) BR0211921B1 (es)
CA (1) CA2454914A1 (es)
DE (1) DE60232160D1 (es)
DK (1) DK1423757T3 (es)
ES (1) ES2324983T3 (es)
MX (1) MXPA04001483A (es)
WO (1) WO2003019295A1 (es)

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DE60232160D1 (de) 2009-06-10
BR0211921A (pt) 2004-10-26
US7148382B2 (en) 2006-12-12
DK1423757T3 (da) 2009-08-17
JP2005501124A (ja) 2005-01-13
CN1545643A (zh) 2004-11-10
US20040204613A1 (en) 2004-10-14
CA2454914A1 (en) 2003-03-06
EP1423757B1 (en) 2009-04-29
ATE430329T1 (de) 2009-05-15
CN100437354C (zh) 2008-11-26
JP4225898B2 (ja) 2009-02-18
ES2324983T3 (es) 2009-08-21
BR0211921B1 (pt) 2012-05-02

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