ATE223900T1 - Verfahren zur herstellung von 4- trifluormethylnicotinsäure - Google Patents
Verfahren zur herstellung von 4- trifluormethylnicotinsäureInfo
- Publication number
- ATE223900T1 ATE223900T1 AT96107614T AT96107614T ATE223900T1 AT E223900 T1 ATE223900 T1 AT E223900T1 AT 96107614 T AT96107614 T AT 96107614T AT 96107614 T AT96107614 T AT 96107614T AT E223900 T1 ATE223900 T1 AT E223900T1
- Authority
- AT
- Austria
- Prior art keywords
- producing
- trifluormethylnicotinic
- acid
- formula
- cf3cohal
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/80—Acids; Esters in position 3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C221/00—Preparation of compounds containing amino groups and doubly-bound oxygen atoms bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C229/22—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated the carbon skeleton being further substituted by oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C229/30—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and unsaturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
- C07C251/04—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C251/06—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton
- C07C251/08—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton being acyclic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
- C07C45/455—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation with carboxylic acids or their derivatives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
- C07C49/255—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing ether groups, groups, groups, or groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyridine Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15236495 | 1995-05-26 | ||
JP22472895 | 1995-08-08 | ||
JP29624895 | 1995-10-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE223900T1 true ATE223900T1 (de) | 2002-09-15 |
Family
ID=27320266
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT96107614T ATE223900T1 (de) | 1995-05-26 | 1996-05-13 | Verfahren zur herstellung von 4- trifluormethylnicotinsäure |
AT02016317T ATE443693T1 (de) | 1995-05-26 | 1996-05-13 | Verfahren zur herstellung substituierter 1,1,1- trifluoro-3-buten-2-one |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT02016317T ATE443693T1 (de) | 1995-05-26 | 1996-05-13 | Verfahren zur herstellung substituierter 1,1,1- trifluoro-3-buten-2-one |
Country Status (9)
Country | Link |
---|---|
US (1) | US5708175A (de) |
EP (2) | EP0744400B1 (de) |
KR (1) | KR100381484B1 (de) |
AT (2) | ATE223900T1 (de) |
CA (2) | CA2176788C (de) |
DE (2) | DE69638035D1 (de) |
DK (1) | DK1254883T3 (de) |
ES (1) | ES2332037T3 (de) |
PT (1) | PT1254883E (de) |
Families Citing this family (84)
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TWI222442B (en) * | 2000-12-13 | 2004-10-21 | Aventis Cropscience Gmbh | Process for the preparation of 4-haloalkylnicotinonitriles |
DE10061967A1 (de) * | 2000-12-13 | 2002-06-20 | Aventis Cropscience Gmbh | Verfahren zur Herstellung von 4-Trifluormethylnicotinnitril |
DE10105592A1 (de) | 2001-02-06 | 2002-08-08 | Achim Goepferich | Platzhalter zur Arzneistofffreigabe in der Stirnhöhle |
DE10144410A1 (de) * | 2001-09-11 | 2003-03-27 | Bayer Cropscience Gmbh | Verfahren zur Herstellung von 4-Haloalkylnicotinsäureestern |
CN100425609C (zh) * | 2001-11-21 | 2008-10-15 | 三共农业株式会社 | N-杂芳基烟酰胺衍生物 |
IL162035A0 (en) * | 2001-11-21 | 2005-11-20 | Sankyo Agro Co Ltd | N-heteroarylnicotinamide derivatives and pesticidal compositions containing the same |
JP4376061B2 (ja) * | 2002-02-08 | 2009-12-02 | ゾルファイ フルーオル ゲゼルシャフト ミット ベシュレンクテル ハフツング | アルケノンの製造 |
DE10261471A1 (de) | 2002-02-08 | 2003-08-21 | Solvay Fluor & Derivate | Herstellung von Alkenonen |
DE10223274A1 (de) * | 2002-05-24 | 2003-12-04 | Bayer Cropscience Gmbh | Verfahren zur Herstellung von 4-Haloalkylnicotinsäureamiden |
US8317816B2 (en) | 2002-09-30 | 2012-11-27 | Acclarent, Inc. | Balloon catheters and methods for treating paranasal sinuses |
DE10325715A1 (de) | 2003-06-06 | 2004-12-23 | Solvay Fluor Und Derivate Gmbh | Vereinfachte Herstellung von Alkenonen |
US8146400B2 (en) | 2004-04-21 | 2012-04-03 | Acclarent, Inc. | Endoscopic methods and devices for transnasal procedures |
US7410480B2 (en) * | 2004-04-21 | 2008-08-12 | Acclarent, Inc. | Devices and methods for delivering therapeutic substances for the treatment of sinusitis and other disorders |
US20190314620A1 (en) | 2004-04-21 | 2019-10-17 | Acclarent, Inc. | Apparatus and methods for dilating and modifying ostia of paranasal sinuses and other intranasal or paranasal structures |
US10188413B1 (en) | 2004-04-21 | 2019-01-29 | Acclarent, Inc. | Deflectable guide catheters and related methods |
US8932276B1 (en) | 2004-04-21 | 2015-01-13 | Acclarent, Inc. | Shapeable guide catheters and related methods |
US20110004057A1 (en) * | 2004-04-21 | 2011-01-06 | Acclarent, Inc. | Systems and methods for transnasal dilation of passageways in the ear, nose or throat |
US7559925B2 (en) | 2006-09-15 | 2009-07-14 | Acclarent Inc. | Methods and devices for facilitating visualization in a surgical environment |
US7419497B2 (en) | 2004-04-21 | 2008-09-02 | Acclarent, Inc. | Methods for treating ethmoid disease |
US8894614B2 (en) | 2004-04-21 | 2014-11-25 | Acclarent, Inc. | Devices, systems and methods useable for treating frontal sinusitis |
US9554691B2 (en) | 2004-04-21 | 2017-01-31 | Acclarent, Inc. | Endoscopic methods and devices for transnasal procedures |
US20060063973A1 (en) | 2004-04-21 | 2006-03-23 | Acclarent, Inc. | Methods and apparatus for treating disorders of the ear, nose and throat |
US7803150B2 (en) | 2004-04-21 | 2010-09-28 | Acclarent, Inc. | Devices, systems and methods useable for treating sinusitis |
US20060004323A1 (en) | 2004-04-21 | 2006-01-05 | Exploramed Nc1, Inc. | Apparatus and methods for dilating and modifying ostia of paranasal sinuses and other intranasal or paranasal structures |
US9101384B2 (en) | 2004-04-21 | 2015-08-11 | Acclarent, Inc. | Devices, systems and methods for diagnosing and treating sinusitis and other disorders of the ears, Nose and/or throat |
US7361168B2 (en) | 2004-04-21 | 2008-04-22 | Acclarent, Inc. | Implantable device and methods for delivering drugs and other substances to treat sinusitis and other disorders |
US8702626B1 (en) | 2004-04-21 | 2014-04-22 | Acclarent, Inc. | Guidewires for performing image guided procedures |
US9089258B2 (en) | 2004-04-21 | 2015-07-28 | Acclarent, Inc. | Endoscopic methods and devices for transnasal procedures |
US8764729B2 (en) | 2004-04-21 | 2014-07-01 | Acclarent, Inc. | Frontal sinus spacer |
US8747389B2 (en) | 2004-04-21 | 2014-06-10 | Acclarent, Inc. | Systems for treating disorders of the ear, nose and throat |
US20070167682A1 (en) | 2004-04-21 | 2007-07-19 | Acclarent, Inc. | Endoscopic methods and devices for transnasal procedures |
US7462175B2 (en) | 2004-04-21 | 2008-12-09 | Acclarent, Inc. | Devices, systems and methods for treating disorders of the ear, nose and throat |
US20070208252A1 (en) * | 2004-04-21 | 2007-09-06 | Acclarent, Inc. | Systems and methods for performing image guided procedures within the ear, nose, throat and paranasal sinuses |
US9399121B2 (en) | 2004-04-21 | 2016-07-26 | Acclarent, Inc. | Systems and methods for transnasal dilation of passageways in the ear, nose or throat |
US8414473B2 (en) | 2004-04-21 | 2013-04-09 | Acclarent, Inc. | Methods and apparatus for treating disorders of the ear nose and throat |
US9351750B2 (en) | 2004-04-21 | 2016-05-31 | Acclarent, Inc. | Devices and methods for treating maxillary sinus disease |
US7654997B2 (en) | 2004-04-21 | 2010-02-02 | Acclarent, Inc. | Devices, systems and methods for diagnosing and treating sinusitus and other disorders of the ears, nose and/or throat |
US8951225B2 (en) | 2005-06-10 | 2015-02-10 | Acclarent, Inc. | Catheters with non-removable guide members useable for treatment of sinusitis |
US8114113B2 (en) | 2005-09-23 | 2012-02-14 | Acclarent, Inc. | Multi-conduit balloon catheter |
US20070179518A1 (en) * | 2006-02-02 | 2007-08-02 | Becker Bruce B | Balloon Catheters and Methods for Treating Paranasal Sinuses |
US8190389B2 (en) | 2006-05-17 | 2012-05-29 | Acclarent, Inc. | Adapter for attaching electromagnetic image guidance components to a medical device |
US9820688B2 (en) | 2006-09-15 | 2017-11-21 | Acclarent, Inc. | Sinus illumination lightwire device |
US8439687B1 (en) | 2006-12-29 | 2013-05-14 | Acclarent, Inc. | Apparatus and method for simulated insertion and positioning of guidewares and other interventional devices |
WO2008124787A2 (en) | 2007-04-09 | 2008-10-16 | Acclarent, Inc. | Ethmoidotomy system and implantable spacer devices having therapeutic substance delivery capability for treatment of paranasal sinusitis |
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US8485199B2 (en) | 2007-05-08 | 2013-07-16 | Acclarent, Inc. | Methods and devices for protecting nasal turbinate during surgery |
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US20090030409A1 (en) * | 2007-07-27 | 2009-01-29 | Eric Goldfarb | Methods and devices for facilitating visualization in a surgical environment |
US10206821B2 (en) | 2007-12-20 | 2019-02-19 | Acclarent, Inc. | Eustachian tube dilation balloon with ventilation path |
US8182432B2 (en) | 2008-03-10 | 2012-05-22 | Acclarent, Inc. | Corewire design and construction for medical devices |
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KR101652539B1 (ko) | 2008-07-04 | 2016-08-30 | 솔베이(소시에떼아노님) | 알케논의 제조 방법 |
EP2664350B1 (de) | 2008-07-30 | 2019-08-28 | Acclarent, Inc. | Vorrichtungen zur Ortung von Nasennebenhöhlen |
GB0903749D0 (en) | 2009-03-04 | 2009-04-15 | Syngenta Participations Ag | Chemical process |
US20100241155A1 (en) | 2009-03-20 | 2010-09-23 | Acclarent, Inc. | Guide system with suction |
US8435290B2 (en) | 2009-03-31 | 2013-05-07 | Acclarent, Inc. | System and method for treatment of non-ventilating middle ear by providing a gas pathway through the nasopharynx |
US7978742B1 (en) | 2010-03-24 | 2011-07-12 | Corning Incorporated | Methods for operating diode lasers |
ES2565332T3 (es) | 2009-07-06 | 2016-04-04 | Solvay Sa | Proceso para la fabricación de alquenonas |
KR101805932B1 (ko) | 2009-07-06 | 2017-12-06 | 솔베이(소시에떼아노님) | 용매 존재 하에서 알케논의 할로겐화 전구체를 제조하는 방법 |
EP2451765B1 (de) | 2009-07-06 | 2016-12-28 | Solvay Sa | Verfahren zur Herstellung halogenierter Vorläufer von Alkenonen unter spezifischen Bedingungen |
US8957254B2 (en) | 2009-07-06 | 2015-02-17 | Solvay Sa | Process for chemical synthesis from an alkenone made from a halogenated precursor |
US20110160740A1 (en) * | 2009-12-28 | 2011-06-30 | Acclarent, Inc. | Tissue Removal in The Paranasal Sinus and Nasal Cavity |
WO2012025548A1 (en) | 2010-08-27 | 2012-03-01 | Solvay Sa | Process for the preparation of alkenones |
US9155492B2 (en) | 2010-09-24 | 2015-10-13 | Acclarent, Inc. | Sinus illumination lightwire device |
EP2646416B9 (de) * | 2010-12-03 | 2016-12-21 | Dow AgroSciences LLC | Verbessertes verfahren zur herstellung von 2-trifluormethyl-5-(1-substituierten) alkylpyridinen |
WO2012085195A1 (en) | 2010-12-23 | 2012-06-28 | Solvay Sa | Environmental friendly purification of an organic solution of etfbo |
US9095370B2 (en) | 2011-06-29 | 2015-08-04 | Cordis Corporation | System and method for dilating and adjusting flexibility in a guiding device |
EP2607343A1 (de) | 2011-12-22 | 2013-06-26 | Solvay Sa | Verfahren zur Herstellung halogenierter Vorläufer von Alkenonen und Alkenonen |
CN104583167B (zh) | 2012-08-22 | 2017-09-19 | 索尔维公司 | 用于制备烯酮的方法 |
US9433437B2 (en) | 2013-03-15 | 2016-09-06 | Acclarent, Inc. | Apparatus and method for treatment of ethmoid sinusitis |
US9629684B2 (en) | 2013-03-15 | 2017-04-25 | Acclarent, Inc. | Apparatus and method for treatment of ethmoid sinusitis |
WO2015011728A1 (en) | 2013-07-26 | 2015-01-29 | Srf Limited | Method for producing alkenone ethers |
CN107298653B (zh) * | 2017-08-01 | 2019-05-17 | 江苏建农植物保护有限公司 | 一种合成4-三氟甲基烟酸的方法 |
JP2020532524A (ja) | 2017-09-04 | 2020-11-12 | ソルヴェイ(ソシエテ アノニム) | ジフルオロアセチルクロリドの製造方法及び製造中間体 |
CN107628991A (zh) * | 2017-10-30 | 2018-01-26 | 上海赫腾精细化工有限公司 | 一种4‑三氟甲基烟酸的合成工艺 |
CN108636447A (zh) * | 2018-05-22 | 2018-10-12 | 福州华博立乐新材料科技有限公司 | 一种Pd/MCM-22催化剂及其应用 |
CN110526810A (zh) * | 2018-05-25 | 2019-12-03 | 浙江蓝天环保高科技股份有限公司 | 一种1,1,1-三氟-4-乙氧基戊-3-烯-2-酮的制备方法 |
CN109111369B (zh) * | 2018-10-12 | 2020-12-22 | 河北科技大学 | N,n-二(4-甲氧羰基-2,4-戊二烯酸甲酯-5-)氮烷的合成方法及其应用 |
CN111574440B (zh) * | 2020-05-25 | 2022-09-13 | 安徽金禾实业股份有限公司 | 一种4-三氟甲基烟酸的制备方法 |
CN112079772A (zh) * | 2020-09-26 | 2020-12-15 | 安徽金禾实业股份有限公司 | 一种4-三氟甲基烟酸中氨化反应的方法 |
CN113121374A (zh) * | 2021-04-06 | 2021-07-16 | 安徽丰本生物科技有限公司 | N-(2-甲氧基羰基乙烯基)-4,4,4-三氟-3-酮-1-丁烯胺的制备方法 |
CN113149899A (zh) * | 2021-04-25 | 2021-07-23 | 安徽丰本生物科技有限公司 | 一种制备4-三氟甲基烟酸的方法 |
CN114956969B (zh) * | 2022-07-12 | 2024-04-16 | 永农生物科学有限公司 | 一种4-乙氧基-1,1,1-三氟-3-丁烯-2-酮的制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2994182B2 (ja) * | 1992-07-23 | 1999-12-27 | 石原産業株式会社 | アミド系化合物又はその塩、それらの製造方法及びそれらを含有する有害動物防除剤 |
JPH0710841A (ja) * | 1993-06-21 | 1995-01-13 | Ishihara Sangyo Kaisha Ltd | 4−トリフルオロメチルピリジン−3−カルボキサミド系化合物又はその塩、それらの製造方法及びそれらを含有する有害動物防除剤 |
JPH0725853A (ja) * | 1993-07-14 | 1995-01-27 | Ishihara Sangyo Kaisha Ltd | アミド系化合物又はその塩、それらの製造方法及びそれらを含有する有害動物防除剤 |
-
1996
- 1996-05-13 EP EP96107614A patent/EP0744400B1/de not_active Expired - Lifetime
- 1996-05-13 PT PT02016317T patent/PT1254883E/pt unknown
- 1996-05-13 DE DE69638035T patent/DE69638035D1/de not_active Expired - Lifetime
- 1996-05-13 AT AT96107614T patent/ATE223900T1/de active
- 1996-05-13 ES ES02016317T patent/ES2332037T3/es not_active Expired - Lifetime
- 1996-05-13 DK DK02016317T patent/DK1254883T3/da active
- 1996-05-13 EP EP02016317A patent/EP1254883B1/de not_active Expired - Lifetime
- 1996-05-13 AT AT02016317T patent/ATE443693T1/de active
- 1996-05-13 DE DE69623532T patent/DE69623532T2/de not_active Expired - Lifetime
- 1996-05-16 CA CA002176788A patent/CA2176788C/en not_active Expired - Lifetime
- 1996-05-16 US US08/648,761 patent/US5708175A/en not_active Expired - Lifetime
- 1996-05-16 CA CA2562216A patent/CA2562216C/en not_active Expired - Lifetime
- 1996-05-25 KR KR1019960017889A patent/KR100381484B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DK1254883T3 (da) | 2009-11-16 |
DE69623532T2 (de) | 2003-03-20 |
CA2562216A1 (en) | 1996-11-27 |
CA2176788A1 (en) | 1996-11-27 |
DE69638035D1 (de) | 2009-11-05 |
ATE443693T1 (de) | 2009-10-15 |
EP0744400A2 (de) | 1996-11-27 |
KR100381484B1 (ko) | 2003-11-28 |
ES2332037T3 (es) | 2010-01-25 |
US5708175A (en) | 1998-01-13 |
PT1254883E (pt) | 2009-10-02 |
KR960041164A (ko) | 1996-12-19 |
CA2176788C (en) | 2007-01-09 |
EP0744400A3 (de) | 1997-02-26 |
DE69623532D1 (de) | 2002-10-17 |
EP1254883B1 (de) | 2009-09-23 |
EP0744400B1 (de) | 2002-09-11 |
CA2562216C (en) | 2010-02-23 |
EP1254883A1 (de) | 2002-11-06 |
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