ZA200302305B - Method for the dehydrogenation of hydrocarbons. - Google Patents
Method for the dehydrogenation of hydrocarbons. Download PDFInfo
- Publication number
- ZA200302305B ZA200302305B ZA200302305A ZA200302305A ZA200302305B ZA 200302305 B ZA200302305 B ZA 200302305B ZA 200302305 A ZA200302305 A ZA 200302305A ZA 200302305 A ZA200302305 A ZA 200302305A ZA 200302305 B ZA200302305 B ZA 200302305B
- Authority
- ZA
- South Africa
- Prior art keywords
- catalyst
- dehydrogenation
- reaction
- hydrogen
- gas mixture
- Prior art date
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- 238000006356 dehydrogenation reaction Methods 0.000 title claims abstract description 108
- 238000000034 method Methods 0.000 title claims abstract description 63
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 46
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 46
- 239000003054 catalyst Substances 0.000 claims abstract description 172
- 238000006243 chemical reaction Methods 0.000 claims abstract description 65
- 239000001257 hydrogen Substances 0.000 claims abstract description 61
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 61
- 230000008569 process Effects 0.000 claims abstract description 55
- 239000000203 mixture Substances 0.000 claims abstract description 51
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 51
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000001301 oxygen Substances 0.000 claims abstract description 39
- 239000012495 reaction gas Substances 0.000 claims abstract description 36
- 238000002485 combustion reaction Methods 0.000 claims abstract description 25
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- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 23
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002841 Lewis acid Substances 0.000 claims abstract description 6
- 150000007517 lewis acids Chemical class 0.000 claims abstract description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
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Classifications
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- C—CHEMISTRY; METALLURGY
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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DE10047642A DE10047642A1 (de) | 2000-09-26 | 2000-09-26 | Verfahren zur Dehydrierung von Kohlenwasserstoffen |
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DE10211275A1 (de) | 2002-03-13 | 2003-09-25 | Basf Ag | Verfahren der kontinuierlichen heterogen katalysierten partiellen Dehydrierung |
DE10206845A1 (de) * | 2002-02-19 | 2003-08-28 | Basf Ag | Modifiziertes Verfahren zur Herstellung von Tensidalkoholen und Tensidalkoholethern, die hergestellten Produkte und ihre Verwendung |
DE10333755A1 (de) * | 2003-07-24 | 2005-03-31 | Basf Ag | Verfahren zur Dehydrierung von Carbonylverbindungen |
US7767191B2 (en) * | 2003-12-11 | 2010-08-03 | The Ohio State University | Combustion looping using composite oxygen carriers |
TWI314876B (en) * | 2004-11-18 | 2009-09-21 | Rohm And Haas Compan | Multi-staged catalyst systems and process for converting alkanes to alkenes and to their corresponding oxygenated products |
DE102005053233A1 (de) * | 2005-11-06 | 2007-05-10 | Basf Ag | Verfahren zur Aromatisierung von Nichtaromatischen Kohlenwasserstoffen mit Wasserdampf |
WO2007082790A1 (de) * | 2006-01-13 | 2007-07-26 | Basf Aktiengesellschaft | Verfahren zur regenerierung eines dehydrierkatalysators |
DE102007006647A1 (de) | 2007-02-06 | 2008-08-07 | Basf Se | Verfahren zur Regenerierung eines im Rahmen einer heterogen katalysierten partiellen Dehydrierung eines Kohlenwasserstoffs deaktivierten Katalysatorbetts |
DE602009000800D1 (de) * | 2008-07-10 | 2011-04-14 | Rohm & Haas | Autothermisches katalytisches Hybrid-Verfahren zur Umwandlung von Alkanen in Alkene und Katalysatoren dafür |
WO2010037011A2 (en) | 2008-09-26 | 2010-04-01 | The Ohio State University | Conversion of carbonaceous fuels into carbon free energy carriers |
WO2010133565A1 (en) * | 2009-05-20 | 2010-11-25 | Basf Se | Monolith catalyst and use thereof |
CN105762386A (zh) | 2009-09-08 | 2016-07-13 | 俄亥俄州国家创新基金会 | 具有集成的碳捕集的重整/水裂解和用于发电的电化学系统的集成 |
US9518236B2 (en) | 2009-09-08 | 2016-12-13 | The Ohio State University Research Foundation | Synthetic fuels and chemicals production with in-situ CO2 capture |
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CN102219632B (zh) * | 2010-04-15 | 2013-12-25 | 中国石油化工股份有限公司 | 用于丙烷脱氢过程中氢气选择氧化方法 |
CN102219631B (zh) * | 2010-04-15 | 2013-12-25 | 中国石油化工股份有限公司 | 丙烷脱氢过程中氢气选择氧化催化方法 |
CN103228354B (zh) | 2010-10-05 | 2015-08-12 | 太平洋工业发展公司 | 抗硫的催化剂载体材料 |
EP2637777A1 (en) | 2010-11-08 | 2013-09-18 | The Ohio State University | Circulating fluidized bed with moving bed downcomers and gas sealing between reactors |
WO2012155059A1 (en) | 2011-05-11 | 2012-11-15 | The Ohio State University | Oxygen carrying materials |
CA2835419C (en) | 2011-05-11 | 2020-06-02 | Ohio State Innovation Foundation | Systems for converting fuel |
EA201490316A1 (ru) * | 2011-08-02 | 2014-11-28 | Басф Се | Непрерывный способ проведения автотермического газофазного дегидрирования |
CN102389810A (zh) * | 2011-09-28 | 2012-03-28 | 海尔集团公司 | 甲醛的氧化催化剂 |
CN103030496B (zh) * | 2011-09-29 | 2015-02-11 | 中国石油化工股份有限公司 | 丙烷脱氢过程中氢气选择性氧化方法 |
CN103028400B (zh) * | 2011-09-30 | 2015-06-10 | 中国石油化工股份有限公司 | 选择氧化催化剂及其制备方法 |
US20130158327A1 (en) * | 2011-12-16 | 2013-06-20 | Uop Llc | Hydrocarbon dehydrogenation with inert diluent |
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CN103483123B (zh) * | 2012-06-08 | 2015-05-13 | 中国石油化工股份有限公司 | 一种由正构烷烃制备丁二烯的方法 |
US10144640B2 (en) | 2013-02-05 | 2018-12-04 | Ohio State Innovation Foundation | Methods for fuel conversion |
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CN105478107B (zh) * | 2014-07-14 | 2017-12-15 | 天津大学 | 铂催化剂在丙烷制备丙烯中的应用 |
CN104258855A (zh) * | 2014-08-20 | 2015-01-07 | 南京沃来德能源科技有限公司 | 一种双功能低碳烷烃脱氢催化剂的制法和用途 |
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KR102478028B1 (ko) * | 2015-11-03 | 2022-12-16 | 에스케이이노베이션 주식회사 | 원-폿으로 합성된 전이금속-귀금속 복합산화물 탈수소화 촉매 및 이의 용도 |
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EP3648881B1 (en) | 2017-07-31 | 2023-10-25 | Ohio State Innovation Foundation | Reactor system with unequal reactor assembly operating pressures |
CN109384639B (zh) * | 2017-08-07 | 2021-05-11 | 中国石油化工股份有限公司 | 丙烷脱氢催化剂及其制备方法以及丙烷脱氢制丙烯的方法 |
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KR101981886B1 (ko) * | 2018-02-01 | 2019-05-23 | 효성화학 주식회사 | 탈수소화 촉매 |
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WO2020210396A1 (en) | 2019-04-09 | 2020-10-15 | Ohio State Innovation Foundation | Alkene generation using metal sulfide particles |
WO2020236707A1 (en) | 2019-05-17 | 2020-11-26 | Exelus, Inc. | Improved mixed metal oxide catalyst useful for paraffin dehydrogenation |
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KR20240033021A (ko) | 2021-08-11 | 2024-03-12 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 촉매를 재생하는 방법 및 알칸 및/또는 알킬 방향족 탄화수소를 업그레이드하는 방법 |
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IT1286045B1 (it) | 1996-10-25 | 1998-07-07 | Lucchini Centro Ricerche E Svi | Acciaio a grano austenitico fine risolforato migliorato e relativo procedimento per ottenerlo |
DE19654391A1 (de) * | 1996-12-27 | 1998-07-02 | Basf Ag | Katalysator zur selektiven Herstellung von Propylen aus Propan |
DE19756292C2 (de) * | 1997-12-10 | 1999-10-28 | Mannesmann Ag | Katalysator zur Umwandlung paraffinischer Kohlenwasserstoffe in korrespondierende Olefine |
DE19937106A1 (de) * | 1999-08-06 | 2001-02-08 | Basf Ag | Multikomponenten-Katalysatoren |
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- 2001-09-14 WO PCT/EP2001/010673 patent/WO2002026668A1/de active IP Right Grant
- 2001-09-14 CN CNB018163394A patent/CN1220659C/zh not_active Expired - Fee Related
- 2001-09-14 AU AU2002213917A patent/AU2002213917A1/en not_active Abandoned
- 2001-09-14 JP JP2002531057A patent/JP4846183B2/ja not_active Expired - Fee Related
- 2001-09-14 EA EA200300404A patent/EA004599B1/ru not_active IP Right Cessation
- 2001-09-14 DK DK01982292T patent/DK1322578T3/da active
- 2001-09-25 SA SA01220388A patent/SA01220388B1/ar unknown
-
2003
- 2003-03-25 ZA ZA200302305A patent/ZA200302305B/en unknown
- 2003-03-25 NO NO20031351A patent/NO20031351L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
EP1322578A1 (de) | 2003-07-02 |
EA200300404A1 (ru) | 2003-10-30 |
EA004599B1 (ru) | 2004-06-24 |
TWI286131B (en) | 2007-09-01 |
CZ2003875A3 (cs) | 2003-10-15 |
KR20030036833A (ko) | 2003-05-09 |
CN1220659C (zh) | 2005-09-28 |
ATE319670T1 (de) | 2006-03-15 |
ES2257451T3 (es) | 2006-08-01 |
EP1322578B1 (de) | 2006-03-08 |
MY128587A (en) | 2007-02-28 |
JP2004509936A (ja) | 2004-04-02 |
NO20031351D0 (no) | 2003-03-25 |
DE10047642A1 (de) | 2002-04-11 |
CN1466558A (zh) | 2004-01-07 |
US20040030214A1 (en) | 2004-02-12 |
US7087802B2 (en) | 2006-08-08 |
DE50109177D1 (de) | 2006-05-04 |
KR100770496B1 (ko) | 2007-10-25 |
AU2002213917A1 (en) | 2002-04-08 |
SA01220388B1 (ar) | 2006-11-14 |
WO2002026668A1 (de) | 2002-04-04 |
DK1322578T3 (da) | 2006-05-29 |
JP4846183B2 (ja) | 2011-12-28 |
BR0114116A (pt) | 2003-07-29 |
NO20031351L (no) | 2003-03-25 |
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