ZA200302305B - Method for the dehydrogenation of hydrocarbons. - Google Patents
Method for the dehydrogenation of hydrocarbons. Download PDFInfo
- Publication number
- ZA200302305B ZA200302305B ZA200302305A ZA200302305A ZA200302305B ZA 200302305 B ZA200302305 B ZA 200302305B ZA 200302305 A ZA200302305 A ZA 200302305A ZA 200302305 A ZA200302305 A ZA 200302305A ZA 200302305 B ZA200302305 B ZA 200302305B
- Authority
- ZA
- South Africa
- Prior art keywords
- catalyst
- dehydrogenation
- reaction
- hydrogen
- gas mixture
- Prior art date
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- 238000006356 dehydrogenation reaction Methods 0.000 title claims abstract description 108
- 238000000034 method Methods 0.000 title claims abstract description 63
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 46
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 46
- 239000003054 catalyst Substances 0.000 claims abstract description 172
- 238000006243 chemical reaction Methods 0.000 claims abstract description 65
- 239000001257 hydrogen Substances 0.000 claims abstract description 61
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 61
- 230000008569 process Effects 0.000 claims abstract description 55
- 239000000203 mixture Substances 0.000 claims abstract description 51
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 51
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000001301 oxygen Substances 0.000 claims abstract description 39
- 239000012495 reaction gas Substances 0.000 claims abstract description 36
- 238000002485 combustion reaction Methods 0.000 claims abstract description 25
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- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 23
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002841 Lewis acid Substances 0.000 claims abstract description 6
- 150000007517 lewis acids Chemical class 0.000 claims abstract description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
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Classifications
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- C—CHEMISTRY; METALLURGY
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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| DE10206845A1 (de) * | 2002-02-19 | 2003-08-28 | Basf Ag | Modifiziertes Verfahren zur Herstellung von Tensidalkoholen und Tensidalkoholethern, die hergestellten Produkte und ihre Verwendung |
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| US7767191B2 (en) * | 2003-12-11 | 2010-08-03 | The Ohio State University | Combustion looping using composite oxygen carriers |
| TWI314876B (en) * | 2004-11-18 | 2009-09-21 | Rohm And Haas Compan | Multi-staged catalyst systems and process for converting alkanes to alkenes and to their corresponding oxygenated products |
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| DE602009000800D1 (de) * | 2008-07-10 | 2011-04-14 | Rohm & Haas | Autothermisches katalytisches Hybrid-Verfahren zur Umwandlung von Alkanen in Alkene und Katalysatoren dafür |
| WO2010037011A2 (en) | 2008-09-26 | 2010-04-01 | The Ohio State University | Conversion of carbonaceous fuels into carbon free energy carriers |
| WO2010133565A1 (en) * | 2009-05-20 | 2010-11-25 | Basf Se | Monolith catalyst and use thereof |
| CN105762386A (zh) | 2009-09-08 | 2016-07-13 | 俄亥俄州国家创新基金会 | 具有集成的碳捕集的重整/水裂解和用于发电的电化学系统的集成 |
| US9518236B2 (en) | 2009-09-08 | 2016-12-13 | The Ohio State University Research Foundation | Synthetic fuels and chemicals production with in-situ CO2 capture |
| US8293670B2 (en) * | 2009-12-09 | 2012-10-23 | Uop Llc | Process for the production of propylene |
| CN102219632B (zh) * | 2010-04-15 | 2013-12-25 | 中国石油化工股份有限公司 | 用于丙烷脱氢过程中氢气选择氧化方法 |
| CN102219631B (zh) * | 2010-04-15 | 2013-12-25 | 中国石油化工股份有限公司 | 丙烷脱氢过程中氢气选择氧化催化方法 |
| CN103228354B (zh) | 2010-10-05 | 2015-08-12 | 太平洋工业发展公司 | 抗硫的催化剂载体材料 |
| EP2637777A1 (en) | 2010-11-08 | 2013-09-18 | The Ohio State University | Circulating fluidized bed with moving bed downcomers and gas sealing between reactors |
| WO2012155059A1 (en) | 2011-05-11 | 2012-11-15 | The Ohio State University | Oxygen carrying materials |
| CA2835419C (en) | 2011-05-11 | 2020-06-02 | Ohio State Innovation Foundation | Systems for converting fuel |
| EA201490316A1 (ru) * | 2011-08-02 | 2014-11-28 | Басф Се | Непрерывный способ проведения автотермического газофазного дегидрирования |
| CN102389810A (zh) * | 2011-09-28 | 2012-03-28 | 海尔集团公司 | 甲醛的氧化催化剂 |
| CN103030496B (zh) * | 2011-09-29 | 2015-02-11 | 中国石油化工股份有限公司 | 丙烷脱氢过程中氢气选择性氧化方法 |
| CN103028400B (zh) * | 2011-09-30 | 2015-06-10 | 中国石油化工股份有限公司 | 选择氧化催化剂及其制备方法 |
| US20130158327A1 (en) * | 2011-12-16 | 2013-06-20 | Uop Llc | Hydrocarbon dehydrogenation with inert diluent |
| US20130296585A1 (en) | 2012-03-30 | 2013-11-07 | Basf Corporation | Catalyst For Tetrahydrofuran Synthesis |
| CN103483123B (zh) * | 2012-06-08 | 2015-05-13 | 中国石油化工股份有限公司 | 一种由正构烷烃制备丁二烯的方法 |
| US10144640B2 (en) | 2013-02-05 | 2018-12-04 | Ohio State Innovation Foundation | Methods for fuel conversion |
| US9616403B2 (en) | 2013-03-14 | 2017-04-11 | Ohio State Innovation Foundation | Systems and methods for converting carbonaceous fuels |
| US9963407B2 (en) | 2013-06-18 | 2018-05-08 | Uop Llc | Fluidized catalyst circulation reactor for paraffin oxydative dehydrogenation |
| CN103521209A (zh) * | 2013-10-11 | 2014-01-22 | 中国海洋石油总公司 | 一种合成吡啶的催化剂制备方法 |
| US9701913B2 (en) * | 2013-12-17 | 2017-07-11 | Uop Llc | Fluid catalytic cracking process including adsorption of hydrogen and a catalyst for the process |
| US20150238915A1 (en) | 2014-02-27 | 2015-08-27 | Ohio State Innovation Foundation | Systems and methods for partial or complete oxidation of fuels |
| CN105478107B (zh) * | 2014-07-14 | 2017-12-15 | 天津大学 | 铂催化剂在丙烷制备丙烯中的应用 |
| CN104258855A (zh) * | 2014-08-20 | 2015-01-07 | 南京沃来德能源科技有限公司 | 一种双功能低碳烷烃脱氢催化剂的制法和用途 |
| US20160090337A1 (en) * | 2014-09-30 | 2016-03-31 | Uop Llc | Paraffin dehydrogenation with oxidative reheat |
| FR3038849B1 (fr) * | 2015-07-13 | 2019-11-29 | IFP Energies Nouvelles | Catalyseur oxyde mixte mesoporeux comprenant du silicium |
| KR102478028B1 (ko) * | 2015-11-03 | 2022-12-16 | 에스케이이노베이션 주식회사 | 원-폿으로 합성된 전이금속-귀금속 복합산화물 탈수소화 촉매 및 이의 용도 |
| US10662129B2 (en) * | 2016-01-21 | 2020-05-26 | Sabic Global Technologies B.V. | Methods for producing propylene by the dehydrogenation of propane |
| CN109195696B (zh) | 2016-04-12 | 2022-04-26 | 俄亥俄州立创新基金会 | 从含碳燃料化学循环生产合成气 |
| CN108722403B (zh) * | 2017-04-20 | 2019-09-27 | 中国石油化工股份有限公司 | 一种丙烷脱氢催化剂及其制备方法和丙烷脱氢制丙烯的方法 |
| EP3648881B1 (en) | 2017-07-31 | 2023-10-25 | Ohio State Innovation Foundation | Reactor system with unequal reactor assembly operating pressures |
| CN109384639B (zh) * | 2017-08-07 | 2021-05-11 | 中国石油化工股份有限公司 | 丙烷脱氢催化剂及其制备方法以及丙烷脱氢制丙烯的方法 |
| US10549236B2 (en) | 2018-01-29 | 2020-02-04 | Ohio State Innovation Foundation | Systems, methods and materials for NOx decomposition with metal oxide materials |
| KR101981886B1 (ko) * | 2018-02-01 | 2019-05-23 | 효성화학 주식회사 | 탈수소화 촉매 |
| WO2020033500A1 (en) | 2018-08-09 | 2020-02-13 | Ohio State Innovation Foundation | Systems, methods and materials for hydrogen sulfide conversion |
| EP3856409A1 (en) | 2018-09-28 | 2021-08-04 | Exelus, Inc. | Improved mixed metal oxide catalyst useful for paraffin dehydrogenation |
| EP3856408A1 (en) | 2018-09-28 | 2021-08-04 | Exelus, Inc. | Improved mixed metal oxide catalyst useful for paraffin dehydrogenation |
| WO2020210396A1 (en) | 2019-04-09 | 2020-10-15 | Ohio State Innovation Foundation | Alkene generation using metal sulfide particles |
| WO2020236707A1 (en) | 2019-05-17 | 2020-11-26 | Exelus, Inc. | Improved mixed metal oxide catalyst useful for paraffin dehydrogenation |
| US11168039B2 (en) | 2019-05-17 | 2021-11-09 | Exelus, Inc. | Mixed metal oxide catalyst useful for paraffin dehydrogenation |
| WO2020236738A1 (en) | 2019-05-17 | 2020-11-26 | Exelus, Inc. | Improved mixed metal oxide catalyst useful for paraffin dehydrogenation |
| US11364482B2 (en) | 2019-05-17 | 2022-06-21 | Exelus, Inc. | Mixed metal oxide catalyst useful for paraffin dehydrogenation |
| KR20240033021A (ko) | 2021-08-11 | 2024-03-12 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 촉매를 재생하는 방법 및 알칸 및/또는 알킬 방향족 탄화수소를 업그레이드하는 방법 |
| CN115055182B (zh) * | 2022-07-01 | 2023-09-15 | 中国科学院生态环境研究中心 | 一种丙烷氧化脱氢催化剂及其制备方法与应用 |
| CN115779894A (zh) * | 2022-12-27 | 2023-03-14 | 黄河三角洲京博化工研究院有限公司 | 以双金属氧化物为载体的Pt系催化剂及制备方法和应用 |
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| US3531543A (en) * | 1968-05-28 | 1970-09-29 | Chevron Res | Group viii noble metal,tin and solid inorganic refractory metal oxide catalyst composites and their use in hydrocarbon dehydrogenations |
| DE2446739C2 (de) * | 1974-10-01 | 1983-09-29 | W. Schlafhorst & Co, 4050 Mönchengladbach | Verfahren und Vorrichtung zur Entnahme fertig gewickelter Kreuzspulen bei einer Textilmaschine |
| US4376225A (en) * | 1981-08-05 | 1983-03-08 | Uop Inc. | Dehydrogenation process utilizing indirect heat exchange and direct combustion heating |
| US4788371A (en) * | 1987-12-30 | 1988-11-29 | Uop Inc. | Catalytic oxidative steam dehydrogenation process |
| JP2566814B2 (ja) * | 1988-05-13 | 1996-12-25 | 株式会社ジャパンエナジー | 炭化水素転化用固体酸触媒及びその製造方法 |
| US4886928A (en) * | 1988-09-26 | 1989-12-12 | Uop | Hydrocarbon dehydrogenation process |
| CA2094766A1 (en) * | 1992-04-27 | 1993-10-28 | Vincent A. Durante | Process and catalyst for dehydrogenation of organic compounds |
| US5733518A (en) | 1992-04-27 | 1998-03-31 | Sun Company, Inc. (R&M) | Process and catalyst for dehydrogenation of organic compounds |
| IT1254988B (it) * | 1992-06-23 | 1995-10-11 | Eniricerche Spa | Procedimento per la deidrogenazione di paraffine leggere in un reattore a letto fluido |
| NO179131C (no) | 1993-06-14 | 1996-08-14 | Statoil As | Katalysator, fremgangsmåte for dens fremstilling og fremgangsmåte for dehydrogenering av lette paraffiner |
| US5527979A (en) | 1993-08-27 | 1996-06-18 | Mobil Oil Corporation | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
| US5530171A (en) * | 1993-08-27 | 1996-06-25 | Mobil Oil Corporation | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
| IT1286045B1 (it) | 1996-10-25 | 1998-07-07 | Lucchini Centro Ricerche E Svi | Acciaio a grano austenitico fine risolforato migliorato e relativo procedimento per ottenerlo |
| DE19654391A1 (de) * | 1996-12-27 | 1998-07-02 | Basf Ag | Katalysator zur selektiven Herstellung von Propylen aus Propan |
| DE19756292C2 (de) * | 1997-12-10 | 1999-10-28 | Mannesmann Ag | Katalysator zur Umwandlung paraffinischer Kohlenwasserstoffe in korrespondierende Olefine |
| DE19937106A1 (de) * | 1999-08-06 | 2001-02-08 | Basf Ag | Multikomponenten-Katalysatoren |
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- 2001-09-14 EP EP01982292A patent/EP1322578B1/de not_active Expired - Lifetime
- 2001-09-14 DE DE50109177T patent/DE50109177D1/de not_active Expired - Lifetime
- 2001-09-14 KR KR1020037004288A patent/KR100770496B1/ko active IP Right Grant
- 2001-09-14 WO PCT/EP2001/010673 patent/WO2002026668A1/de active IP Right Grant
- 2001-09-14 CN CNB018163394A patent/CN1220659C/zh not_active Expired - Fee Related
- 2001-09-14 AU AU2002213917A patent/AU2002213917A1/en not_active Abandoned
- 2001-09-14 JP JP2002531057A patent/JP4846183B2/ja not_active Expired - Fee Related
- 2001-09-14 EA EA200300404A patent/EA004599B1/ru not_active IP Right Cessation
- 2001-09-14 DK DK01982292T patent/DK1322578T3/da active
- 2001-09-25 SA SA01220388A patent/SA01220388B1/ar unknown
-
2003
- 2003-03-25 ZA ZA200302305A patent/ZA200302305B/en unknown
- 2003-03-25 NO NO20031351A patent/NO20031351L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1322578A1 (de) | 2003-07-02 |
| EA200300404A1 (ru) | 2003-10-30 |
| EA004599B1 (ru) | 2004-06-24 |
| TWI286131B (en) | 2007-09-01 |
| CZ2003875A3 (cs) | 2003-10-15 |
| KR20030036833A (ko) | 2003-05-09 |
| CN1220659C (zh) | 2005-09-28 |
| ATE319670T1 (de) | 2006-03-15 |
| ES2257451T3 (es) | 2006-08-01 |
| EP1322578B1 (de) | 2006-03-08 |
| MY128587A (en) | 2007-02-28 |
| JP2004509936A (ja) | 2004-04-02 |
| NO20031351D0 (no) | 2003-03-25 |
| DE10047642A1 (de) | 2002-04-11 |
| CN1466558A (zh) | 2004-01-07 |
| US20040030214A1 (en) | 2004-02-12 |
| US7087802B2 (en) | 2006-08-08 |
| DE50109177D1 (de) | 2006-05-04 |
| KR100770496B1 (ko) | 2007-10-25 |
| AU2002213917A1 (en) | 2002-04-08 |
| SA01220388B1 (ar) | 2006-11-14 |
| WO2002026668A1 (de) | 2002-04-04 |
| DK1322578T3 (da) | 2006-05-29 |
| JP4846183B2 (ja) | 2011-12-28 |
| BR0114116A (pt) | 2003-07-29 |
| NO20031351L (no) | 2003-03-25 |
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