YU48780B - Derivati 4-benzoilizoksazola, postupci za njihovo dobijanje, herbicidni preparati koji sadrže pomenute derivate i postupak za kontrolu rasta korova - Google Patents

Derivati 4-benzoilizoksazola, postupci za njihovo dobijanje, herbicidni preparati koji sadrže pomenute derivate i postupak za kontrolu rasta korova

Info

Publication number
YU48780B
YU48780B YU182891A YU182891A YU48780B YU 48780 B YU48780 B YU 48780B YU 182891 A YU182891 A YU 182891A YU 182891 A YU182891 A YU 182891A YU 48780 B YU48780 B YU 48780B
Authority
YU
Yugoslavia
Prior art keywords
group
carbon atoms
optionally substituted
group containing
normal
Prior art date
Application number
YU182891A
Other languages
English (en)
Other versions
YU182891A (sh
Inventor
Paul Alfred Cain
Susan Mary Cramp
David Alan Roberts
Original Assignee
Rhone-Poulenc Agriculture Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone-Poulenc Agriculture Ltd. filed Critical Rhone-Poulenc Agriculture Ltd.
Publication of YU182891A publication Critical patent/YU182891A/sh
Priority to BA970209A priority Critical patent/BA97209A/bs
Publication of YU48780B publication Critical patent/YU48780B/sh

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D261/00Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/06Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
    • C07D261/10Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D261/00Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/06Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
    • C07D261/08Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/08Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding porous substances
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D261/00Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/06Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
    • C07D261/10Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D261/18Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00267Materials permeable to vapours or gases
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00793Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0081Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/90Electrical properties
    • C04B2111/94Electrically conducting materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

4-benzoilizoksazol derivati formule I: gde: R predstavlja: normalnog ili racvastog lanca alkil, alkenil ili alkinil grupu, koja sadrzi do 6 atoma ugljenika koja je po izboru supstituisana sa jednim ili vise atoma halogena, ili cikloalkil grupu koja sadrzi od 3 do 6 atoma ugljenika po izboru supstituisanih sa jednim ili vise supstituenata odabranih iz grupe R5, jednim ili vise atoma halogena i grupom -CO2R3, ili grupu odabranu od -CO2R3, -COR5, cijano, nitro, -CONR31R4 ili halogen atom, R1 predstavlja: atom vodonika ili normalnog ili racvastog lanca alkil, alkenil ili alkinil grupu koja sadrzi do 6 atoma ugljenika koja je po izboru supstituisana sa jednim ili vise atoma halogena, ili cikloalkil grupu koja sadrzi od 3 do 6 atoma ugljenika po izboru supstituisanu sa jednim ili vise supstituenata odabranih iz grupe R5 i jednim ili vise halogen atoma, R2 predstavlja: halogen atom, ili grupu odabranu izmedu R5, -SR5, -SOR5, -SO2R5, -SO2NR31R4, -CO2R3, -COR5, -CONR31R4, -CSNR31R4, -OR5, nitro grupa, cijano grupa, -O(CH2)q-OR5 grupa ili normalnog ili racvastog lanca alkil grupa koja sadrzi od 6 atoma ugljenika i koja je supstituisana sa OR5, R3, R31 i R4, koji mogu biti isti ili razliciti svaki predstavlja: atom vodonika, ili normalnog ili racvastog lanca alkil grupu koja sadrzi do 6 atoma ugljenika koja je po izboru supstituisana sa jednim ili vise atoma halogena, R5 predstavlja: normalnog ili racvastog lanca alkil grupu koja sadrzi do 6 atoma ugljenika koja je po izboru supstituisana sa jednim ili vise atoma halogena, n predstavlja broj 1-5, q predstavlja broj 1-3, uz predpostavku da R i R1 ne predstavljaju istovremeno metil grupu i agrikulturno prihvatljive njihove soli. -Prijava sadrzi jos 3 nezavisna i 18 zavisnih zahteva.
YU182891A 1990-11-22 1991-11-22 Derivati 4-benzoilizoksazola, postupci za njihovo dobijanje, herbicidni preparati koji sadrže pomenute derivate i postupak za kontrolu rasta korova YU48780B (sh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
BA970209A BA97209A (bs) 1991-11-22 1997-04-30 4-Benzoil izoksazol derivati

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB909025469A GB9025469D0 (en) 1990-11-22 1990-11-22 New compositions of matter

Publications (2)

Publication Number Publication Date
YU182891A YU182891A (sh) 1994-01-20
YU48780B true YU48780B (sh) 1999-12-27

Family

ID=10685849

Family Applications (1)

Application Number Title Priority Date Filing Date
YU182891A YU48780B (sh) 1990-11-22 1991-11-22 Derivati 4-benzoilizoksazola, postupci za njihovo dobijanje, herbicidni preparati koji sadrže pomenute derivate i postupak za kontrolu rasta korova

Country Status (34)

Country Link
EP (1) EP0487357B1 (sh)
JP (1) JP3081321B2 (sh)
KR (1) KR100188571B1 (sh)
CN (2) CN1040940C (sh)
AT (1) ATE154933T1 (sh)
AU (1) AU642785B2 (sh)
BG (1) BG60585B1 (sh)
BR (1) BR9105146A (sh)
CA (1) CA2056044C (sh)
CZ (1) CZ280706B6 (sh)
DE (1) DE69126696T2 (sh)
DK (1) DK0487357T3 (sh)
EG (1) EG19891A (sh)
ES (1) ES2103786T3 (sh)
FI (1) FI102750B1 (sh)
GB (1) GB9025469D0 (sh)
GR (1) GR3024000T3 (sh)
HU (1) HU208963B (sh)
IE (1) IE914055A1 (sh)
IL (1) IL100046A (sh)
MA (1) MA22345A1 (sh)
MX (1) MX9102172A (sh)
MY (1) MY114222A (sh)
NZ (1) NZ240625A (sh)
OA (1) OA09403A (sh)
PT (1) PT99575B (sh)
RO (1) RO110819B1 (sh)
RU (1) RU2057750C1 (sh)
SK (1) SK278353B6 (sh)
TR (1) TR25654A (sh)
TW (1) TW201739B (sh)
UA (1) UA29380C2 (sh)
YU (1) YU48780B (sh)
ZA (1) ZA919215B (sh)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9017539D0 (en) * 1990-08-10 1990-09-26 Rhone Poulenc Agriculture New compositions of matter
GB9115377D0 (en) * 1991-07-17 1991-09-04 Rhone Poulenc Agriculture New compositions of matter
GB9116834D0 (en) * 1991-08-05 1991-09-18 Rhone Poulenc Agriculture Compositions of new matter
IL102674A (en) * 1991-08-05 1996-11-14 Rhone Poulenc Agriculture 4-Benzoyl isoxazole derivatives process for their preparation and herbicidal compositions containing them
US5334753A (en) * 1992-03-12 1994-08-02 Rhone-Poulenc Agriculture Ltd Processes for preparing ortho-substituted benzoic acids
HRP930105A2 (en) * 1992-03-12 1996-04-30 Rhone Poulenc Agriculture New herbicides
GB9215551D0 (en) * 1992-07-22 1992-09-02 Rhone Poulenc Agriculture New compositions of matter
GB9219779D0 (en) * 1992-09-18 1992-10-28 Rhone Poulenc Agriculture Compositions of new matter
DE69319618T2 (de) * 1992-12-18 1998-11-05 Rhone Poulenc Agriculture 4-benzoylisoxazole-derivate und ihre verwendung als herbizide
GB9302071D0 (en) * 1993-02-03 1993-03-24 Rhone Poulenc Agriculture Compositions of matter
GB9302049D0 (en) * 1993-02-03 1993-03-24 Rhone Poulenc Agriculture Compositions of new matter
GB9302072D0 (en) * 1993-02-03 1993-03-24 Rhone Poulenc Agriculture New compositions of matter
CA2117413C (en) * 1993-07-30 2006-11-21 Neil Geach Herbicidal isoxazole-4-yl-methanone derivatives
GB9316689D0 (en) * 1993-08-11 1993-09-29 Rhone Poulenc Agriculture New compositions of matter
GB9325284D0 (en) * 1993-12-10 1994-02-16 Rhone Poulenc Agriculture Herbicidal compositions
US5962370A (en) * 1993-12-10 1999-10-05 Rhone-Poulenc Agriculture Ltd Herbicidal compositions comprising a 4-benzoylisoxazole and a triazine herbicide
GB9325618D0 (en) * 1993-12-15 1994-02-16 Rhone Poulenc Agriculture New herbicides
AU1758495A (en) * 1994-02-25 1995-09-11 Rhone-Poulenc Agrochimie New pesticidal method
WO1995022904A1 (en) * 1994-02-25 1995-08-31 Rhone Poulenc Agrochimie Pesticidal method
GB9409944D0 (en) * 1994-05-17 1994-07-06 Rhone Poulenc Agriculture New compositions of matter
US5795846A (en) * 1994-08-01 1998-08-18 Rhone-Poulenc Agriculture Limited Herbicidal compositions
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US5627131A (en) * 1995-01-09 1997-05-06 Zeneca Limited Herbicidal compositions of 4-benzoylisoxazole and antidotes therefor
US6043267A (en) * 1995-06-19 2000-03-28 Rhone-Poulenc Agrochimie Fungicidal compositions and the use thereof
WO1997000014A1 (en) * 1995-06-19 1997-01-03 Rhone-Poulenc Agrochimie Use of 4-benzoylisoxazoles for the protection of turfgrass
ZA9610348B (en) * 1995-12-20 1997-07-11 Rhone Poulenc Agriculture Herbicidal compositions
US6235942B1 (en) 1996-02-01 2001-05-22 Rhone-Poulenc Agrochimie Process for preparing diketone compounds
GB9603127D0 (en) * 1996-02-15 1996-04-17 Rhone Poulenc Agriculture New process for preparing intermediates
DK0882028T3 (da) * 1996-02-16 2002-04-29 Aventis Cropscience Sa Nye mellemprodukter til pesticider
GB9606015D0 (en) * 1996-03-22 1996-05-22 Rhone Poulenc Agriculture New herbicides
DE19614858A1 (de) * 1996-04-16 1997-10-23 Basf Ag Herbizide heterocyclisch substituierte Benzoylisothiazole
US6297198B1 (en) 1996-05-14 2001-10-02 Syngenta Participations Ag Isoxazole derivatives and their use as herbicides
GB9705039D0 (en) * 1997-03-12 1997-04-30 Rhone Poulenc Agriculture Herbicidal method
AU7916498A (en) * 1997-05-15 1998-12-08 Rhone-Poulenc Agriculture Limited Herbicidal methods and derivatives
DK0987945T3 (da) 1997-06-10 2001-11-19 Aventis Cropscience Sa Nye herbicide blandinger
WO1999003856A1 (en) * 1997-07-18 1999-01-28 Rhone-Poulenc Agriculture Limited 4-benzoyl-isoxazole- and -pyrazole derivatives and 2-cyano 1,3-dione derivatives as herbicides
US5863865A (en) * 1997-10-28 1999-01-26 Zeneca Limited Herbicidal 4-benzoylisoxazoles derivatives
US5905057A (en) * 1997-11-06 1999-05-18 Rhone-Poulenc Agrochimie Herbicidal 4-benzoylisoxazole-3-carboxylate liquid compositions comprising N-alkylpyrrolidinone stabilizer
GB9804986D0 (en) 1998-03-09 1998-05-06 Rhone Poulenc Agrochimie New herbicidal compositions
DE69909990T2 (de) * 1998-04-02 2004-05-27 Syngenta Participations Ag Isoxazole derivate und ihre verwendung als herbizide
DE19920791A1 (de) 1999-05-06 2000-11-09 Bayer Ag Substituierte Benzoylisoxazole
PL201229B1 (pl) * 1999-09-08 2009-03-31 Aventis Cropscience Uk Ltd Sposób zmniejszania fitotoksyczności
FR2815969B1 (fr) 2000-10-30 2004-12-10 Aventis Cropscience Sa Plantes tolerantes aux herbicides par contournement de voie metabolique
CN102060800B (zh) * 2010-12-31 2012-11-21 浙江工业大学 一种5-氯-4-甲酰基噁唑的合成方法
CN104262278A (zh) * 2014-09-02 2015-01-07 北京颖泰嘉和生物科技有限公司 一种异噁唑草酮的制备方法
CN104262279B (zh) * 2014-09-02 2016-06-22 北京颖泰嘉和生物科技股份有限公司 一种异噁唑化合物及异噁唑草酮的制备方法
CN104817510B (zh) * 2015-03-10 2017-07-07 北京颖泰嘉和生物科技股份有限公司 一种异噁唑化合物的制备方法
CN115215773A (zh) * 2021-04-14 2022-10-21 潍坊中农联合化工有限公司 制备苯甲酸类化合物的方法
KR20250088717A (ko) * 2022-10-17 2025-06-17 바스프 아그로 비.브이. 4-클로로-2-(트리플루오로메틸)페닐 그리나드 화합물 및 이의 유도체의 제조 방법
CN115745905B (zh) * 2022-11-21 2023-11-24 安徽宁亿泰科技有限公司 一种异噁唑草酮及其中间体的合成方法

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GB2201672A (en) * 1986-12-18 1988-09-07 Shell Int Research Diphenyl ether compounds
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GB9017539D0 (en) * 1990-08-10 1990-09-26 Rhone Poulenc Agriculture New compositions of matter

Also Published As

Publication number Publication date
CA2056044C (en) 2002-07-16
TW201739B (sh) 1993-03-11
CS352791A3 (en) 1992-06-17
NZ240625A (en) 1994-01-26
EG19891A (en) 1996-03-31
AU8797791A (en) 1992-05-28
UA29380C2 (uk) 2000-11-15
MX9102172A (es) 1992-06-01
ZA919215B (en) 1992-11-25
ES2103786T3 (es) 1997-10-01
TR25654A (tr) 1993-07-01
CN1040940C (zh) 1998-12-02
FI102750B (fi) 1999-02-15
CZ280706B6 (cs) 1996-04-17
FI915487L (fi) 1992-05-23
JPH04300875A (ja) 1992-10-23
KR100188571B1 (ko) 1999-06-01
PT99575A (pt) 1992-10-30
KR920009804A (ko) 1992-06-25
DE69126696T2 (de) 1997-12-18
EP0487357A1 (en) 1992-05-27
PT99575B (pt) 1999-04-30
OA09403A (fr) 1992-09-15
IL100046A (en) 1996-01-19
HU208963B (en) 1994-02-28
HUT60254A (en) 1992-08-28
FI102750B1 (fi) 1999-02-15
BG60585B1 (bg) 1995-09-29
AU642785B2 (en) 1993-10-28
ATE154933T1 (de) 1997-07-15
HU913640D0 (en) 1992-02-28
YU182891A (sh) 1994-01-20
DK0487357T3 (da) 1997-09-29
CN1061596A (zh) 1992-06-03
BR9105146A (pt) 1992-07-21
CA2056044A1 (en) 1992-05-23
IL100046A0 (en) 1992-08-18
CN1183411A (zh) 1998-06-03
BG95508A (bg) 1993-12-24
MY114222A (en) 2002-09-30
DE69126696D1 (de) 1997-08-07
JP3081321B2 (ja) 2000-08-28
RU2057750C1 (ru) 1996-04-10
SK278353B6 (en) 1997-01-08
GR3024000T3 (en) 1997-10-31
FI915487A0 (fi) 1991-11-21
RO110819B1 (ro) 1996-04-30
CN1093537C (zh) 2002-10-30
EP0487357B1 (en) 1997-07-02
MA22345A1 (fr) 1992-07-01
IE914055A1 (en) 1992-06-03
GB9025469D0 (en) 1991-01-09

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