WO2017159247A1 - 油性クレンジング化粧料 - Google Patents
油性クレンジング化粧料 Download PDFInfo
- Publication number
- WO2017159247A1 WO2017159247A1 PCT/JP2017/006514 JP2017006514W WO2017159247A1 WO 2017159247 A1 WO2017159247 A1 WO 2017159247A1 JP 2017006514 W JP2017006514 W JP 2017006514W WO 2017159247 A1 WO2017159247 A1 WO 2017159247A1
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- WIPO (PCT)
- Prior art keywords
- component
- oil
- based cleansing
- mass
- cleansing cosmetic
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/24—Thermal properties
- A61K2800/242—Exothermic; Self-heating; Heating sensation
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
Definitions
- the present invention relates to an oil-based cleansing cosmetic.
- Examples of cleansing cosmetics that remove makeup stains include aqueous cleansing cosmetics, oil-based cleansing cosmetics, and emulsifying cleansing cosmetics.
- oil-based cleansing cosmetics are widely used because of their excellent cleansing effect (so-called makeup stain removal effect), and various attempts have been proposed so far.
- an oil-based cleansing composition containing 50 to 97% by weight of liquid oil and 3 to 50% by weight of a specific nonionic surfactant see Patent Document 1
- polyglyceryl isononanoate an oily liquid cleansing composition containing a liquid or pasty oil at 25 ° C.
- Patent Document 2 polyoxyethylene-20 glyceryl triisostearate or polyoxyethylene-20 glyceryl trioleate
- An oil-based cleansing cosmetic composition containing decaglyceryl monoisostearate see Patent Document 3
- an oily component that is liquid at 20 ° C., 60 to 95% by mass and a non-compound containing 0.01 to 2% by mass of the specific compound
- Oil-based cleansing composition containing 3 to 20% by mass of an ionic surfactant see Patent Document 4
- an object of the present invention is to provide an oil-based cleansing cosmetic that sufficiently exhibits the cleansing effect that is an advantage of the cleansing cosmetic. Moreover, the objective of this invention is providing the oil-based cleansing cosmetics which have the outstanding storage stability of a formulation.
- this invention provides the oil-based cleansing cosmetic characterized by containing the following component (A), a component (B), and a component (C).
- Component (A) Oil selected from the group of hydrocarbon oils and silicone oils
- the content of the component (B) is 1 to 6% by mass
- the content of the component (C) is 1 to 6% by mass
- the sum of the content of the component (B) and the content of the component (C) is It is preferably 2 to 7% by mass.
- the mass ratio ((B) / (C)) of the component (B) to the component (C) is preferably 0.25 to 4.
- oil-based cleansing cosmetic preferably contains component (D): dipentaerythrityl tripolyhydroxystearate.
- oil-based cleansing cosmetic preferably contains component (E): a nonionic surfactant.
- the oil-based cleansing cosmetic composition of the present invention exhibits the effect that, by satisfying the above-described constituent requirements, there is no separation or separation (oil floating) of the preparation, and outstanding storage stability can be exhibited.
- the oil-based cleansing cosmetic of the present invention has good spreadability (elongation spread) during cleansing, and can exhibit a remarkably excellent cleansing effect (make-up stain removing effect).
- the oil-based cleansing cosmetic of the present invention contains the following component (A), component (B) and component (C).
- Component (A) Oil selected from the group of hydrocarbon oils and silicone oils
- Component (A) Oil agent
- the component (A) is an oil agent selected from the group of hydrocarbon oils and silicone oils.
- the outstanding cleansing effect which is the advantage of oil-based cleansing cosmetics can be exhibited by using a component (A).
- the “hydrocarbon oil” may be referred to as “component (A1)”.
- the “silicone oil” may be referred to as “component (A2)”.
- a component (A) may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
- component (A1) examples include, for example, liquid paraffin, squalane, polybutene, hydrogenated polyisobutene, isododecane, volatile isoparaffin, light isoparaffin, liquid isoparaffin, light liquid isoparaffin, heavy liquid isoparaffin, hydrogenated (tetradecenyl / Methylpentadecene) and the like.
- a component (A1) may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
- component (A2) include, for example, methylphenylpolysiloxane, methylhydrogenpolysiloxane, dimethiconol, dimethylpolysiloxane having a viscosity at 25 ° C. of, for example, 1 mPa ⁇ s to less than 10 mPa ⁇ s, and a viscosity at 25 ° C.
- a dimethylpolysiloxane of 10 mPa ⁇ s or more and less than 6,000 mPa ⁇ s, a viscosity at 25 ° C.
- Chain silicone oil such as polymerized dimethylpolysiloxane; Cyclic silicone oil such as methylcyclopolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane; aminopropylmethylsiloxa ⁇ Amino-modified silicone oil such as dimethylsiloxane copolymer, aminoethylaminopropylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer; carboxy-modified silicone oil, fatty acid ester-modified silicone oil, alcohol-modified Silicone oil, epoxy-modified silicone oil, fluorine
- the content of the component (A) in the oil-based cleansing cosmetic composition of the present invention is not particularly limited as long as the desired effect is sufficiently exhibited, but from the viewpoint of exerting the cleansing effect, 100% by mass of the oil-based cleansing cosmetic composition. Among them, the content is preferably 8% by mass or more, and more preferably 10% by mass or more. In addition, the content of the component (A) in the oil-based cleansing cosmetic of the present invention is preferably 70% by mass or less in 100% by mass of the oil-based cleansing cosmetic from the viewpoint of storage stability of the formulation, and 60% by mass. % Or less is more preferable. In addition, content of the said component (A) is a total amount of content of all the components (A) mix
- Component (B) Glyceryl tribehenate
- the component (B) is glyceryl tribehenate.
- component (B) Commercially available products can be used as the component (B).
- Examples of commercially available components (B) include the trade name “Synchrowax HR-C” (manufactured by Croda Japan), the trade name “Esteride GB” (manufactured by National Mimatsu), and the like.
- the content of the component (B) in the oil-based cleansing cosmetic of the present invention is not particularly limited as long as the desired effect is sufficiently exhibited, but from the viewpoint of exhibiting excellent storage stability of the formulation, the oil-based cleansing It is preferable that it is 0.5 mass% or more in 100 mass% of cosmetics, and it is more preferable that it is 1 mass% or more.
- the content of the component (B) in the oil-based cleansing cosmetic of the present invention is preferably 7% by mass or less in 100% by mass of the oil-based cleansing cosmetic from the viewpoint of spreadability during cleansing, and 6% by mass. % Or less is more preferable.
- the component (C) is (behenic acid / eicosanedioic acid) glyceryl.
- the component (C) in combination with the component (B), it is possible to prepare an oil-based cleansing cosmetic that exhibits outstanding storage stability of the preparation.
- component (C) Commercially available products can be used as the component (C).
- a commercial item of a component (C) a brand name "Nom coat HK-G” (made by Nisshin Oillio Group) etc. is mentioned, for example.
- the content of the component (C) in the oil-based cleansing cosmetic of the present invention is not particularly limited as long as the desired effect is sufficiently exhibited, but from the viewpoint of exhibiting excellent storage stability of the formulation, oil-based cleansing It is preferable that it is 0.5 mass% or more in 100 mass% of cosmetics, and it is more preferable that it is 1 mass% or more. Moreover, it is preferable that content of the component (C) in the oil-based cleansing cosmetic of this invention is 7 mass% or less in 100 mass% of oil-based cleansing cosmetics from a viewpoint of the extensibility at the time of cleansing, and 6 mass. % Or less is more preferable.
- the total content of the component (B) and the content of the component (C) is 1 to 8% by mass from the viewpoint of exhibiting more excellent storage stability of the preparation. It is preferably 2 to 7% by mass. If the total content of the component (B) and the component (C) is less than 1% by mass, it is not preferable because separation of the preparation and liquid separation (oil floating) are likely to occur. On the other hand, when the total content of the component (B) and the component (C) exceeds 8% by mass, the spreadability during cleansing is inferior.
- the oil-based cleansing cosmetic of the present invention the component (C), the content of the component (B) and the content of the component (C) from the viewpoint of exhibiting the storage stability of the preparation that is remarkably excellent.
- the mass ratio ((B) / (C)) of the component (B) with respect to is preferably in the range of 0.2 to 5, more preferably 0.25 to 4.
- the mass ratio of the component (B) to the component (C) ((B) / (C)) is less than 0.2, the formulation is liable to be separated or separated (oil floating), resulting in poor storage stability of the formulation. Therefore, it is not preferable.
- the mass ratio ((B) / (C)) of the component (B) to the component (C) exceeds 5, it is not preferable because the spreadability during cleansing is poor.
- the oil-based cleansing cosmetic composition of the present invention is obtained by using glyceryl tribehenate as component (B) and glyceryl (behenic acid / eicosanedioic acid) as component (C) in combination. Separation and liquid separation (oil floating) can be suppressed, storage stability that is remarkably excellent can be exhibited, and spreadability during cleansing can be improved.
- the oil-based cleansing cosmetic of the present invention preferably contains component (D): dipentaerythrityl tripolyhydroxystearate.
- component (D) dipentaerythrityl tripolyhydroxystearate.
- component (D) Commercially available products can be used as the component (D).
- a brand name "Saracos WO-6" made by Nisshin Oillio Group) etc. are mentioned, for example.
- the content of the component (D) in the oil-based cleansing cosmetic composition of the present invention is not particularly limited as long as the desired effect is sufficiently exerted, but from the viewpoint of exhibiting a more excellent storage stability of the preparation, In 100% by mass of the oil-based cleansing cosmetic, it is preferably 0.1% by mass or more, and more preferably 0.3% by mass or more. In addition, the content of the component (D) in the oil-based cleansing cosmetic of the present invention is preferably 3% by weight or less in 100% by weight of the oil-based cleansing cosmetic from the viewpoint of spreadability and washing off. % Or less is more preferable.
- the oil-based cleansing cosmetic composition of the present invention preferably contains a component (E): a nonionic surfactant from the viewpoint of enhancing the wash-off after cleansing and further enhancing the cleansing effect.
- component (E) examples include glycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, fatty acid polyglyceryl, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene fatty acid, polyoxyethylene alkyl ether, and polyoxyethylene cured. Castor oil and the like.
- the HLB value of component (E) is not particularly limited as long as a desired effect is exhibited, but it is preferably 5 to 20, more preferably 8 to 16, from the viewpoint of enhancing washing off.
- a component (E) may be used individually by 1 type, and may be used in combination of 2 or more types as appropriate.
- fatty acid polyglyceryl it is preferable to use fatty acid polyglyceryl, polyoxyethylene glycerin fatty acid ester, and polyoxyethylene sorbitan fatty acid ester from the viewpoint of enhancing washing after cleansing and further enhancing the cleansing effect.
- suitable components (E) it is more preferable to use polyoxyethylene glycerin fatty acid ester.
- the fatty acid constituting the polyoxyethylene glycerin fatty acid ester is not particularly limited as long as the desired effect is exhibited, whether it is a straight-chain fatty acid or a branched fatty acid, from the viewpoint of enhancing washing off, A branched fatty acid is preferred. Moreover, the branched fatty acid is not particularly limited as long as the desired effect is exhibited, whether it is a single chain type or a multi-chain type. From the viewpoint of enhancing the feeling during cleansing, the branched chain fatty acid is not limited. A mold is preferred. That is, the oil-based cleansing cosmetic of the present invention most preferably uses a single-chain branched fatty acid polyoxyethylene glyceryl as the component (E).
- suitable component (E) include, for example, PEG-5 glyceryl isostearate (HLB value: 8), PEG-6 glyceryl isostearate (HLB value: 8), PEG-8 glyceryl isostearate (HLB value: 10), PEG-10 glyceryl isostearate (HLB value: 10), PEG-15 glyceryl isostearate (HLB value: 12), PEG-20 glyceryl isostearate (HLB value: 13), PEG-25 glyceryl isostearate (HLB) Value: 14), PEG-30 glyceryl isostearate (HLB value: 15), PEG-40 glyceryl isostearate (HLB value: 15), PEG-50 glyceryl isostearate (HLB value: 16), PEG-60 glyceryl isostearate (HLB value: 1 ), And the like.
- a suitable component (E) may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate
- the content of the component (E) in the oil-based cleansing cosmetic composition of the present invention is not particularly limited as long as the desired effect is sufficiently exerted, but the viewpoint of enhancing washing after cleansing and the cleansing effect are further improved. From the viewpoint of enhancing, it is preferably 5% by mass or more, more preferably 8% by mass or more, in 100% by mass of the oil-based cleansing cosmetic. In addition, the content of the component (E) in the oil-based cleansing cosmetic of the present invention is preferably 30% by mass or less in 100% by mass of the oil-based cleansing cosmetic from the viewpoint of eye irritation during cleansing, and 20% by mass. % Or less is more preferable. In addition, content of the said component (E) is a total amount of content of all the components (E) mix
- the oil-based cleansing cosmetic of the present invention can be blended with components that are usually used in cosmetics in addition to the components described above.
- Other components include, for example, polyhydric alcohols, fatty acid ester oils other than the above components (B) and (C), vegetable oils, thickening polymers, higher alcohols, lipids, fragrances, antiseptic / disinfectants, moisturizers, cooling agents Agents and the like.
- the said other component can be mix
- polyhydric alcohol examples include ethylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol, 1,3-butylene glycol, glycerin, concentrated glycerin, diglycerin, triglycerin, glucose, maltose, maltitol, sucrose, and mannitol. Sorbitol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol and the like.
- a polyhydric alcohol may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
- fatty acid ester oils other than the above component (B) and component (C) include, for example, ester oils of linear fatty acids and lower alcohols, ester oils of linear fatty acids and linear higher alcohols, linear fatty acids and branched alcohols. And ester oils of branched fatty acids and linear higher alcohols, ester oils of branched fatty acids and branched alcohols, and ester oils of fatty acids and polyhydric alcohols.
- Fatty acid ester oil may be used individually by 1 type, and may be used in combination of 2 or more types as appropriate.
- fatty acid ester oils other than the above component (B) and component (C) include, for example, ethyl oleate, isopropyl myristate, isopropyl palmitate, butyl stearate, myristyl myristate, cetyl myristate, cetyl palmitate, stearic acid Stearyl, decyl oleate, oleyl oleate, octyldodecyl myristate, octyldodecyl oleate, ethyl isostearate, isocetyl stearate, isopropyl isostearate, isocetyl isostearate, propylene glycol isostearate, cetyl 2-ethylhexanoate, 2- Cetostearyl ethylhexanoate, neopentyl glycol dicaprate, neopentyl glycol dioctan
- Examples of the vegetable oil include orange oil, olive oil, camellia oil, macadamia nut oil, jojoba oil, rose oil, lavender oil, and tea tree oil.
- a vegetable oil may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
- thickening polymer examples include natural polymers, semi-synthetic polymers, synthetic polymers, and clay minerals.
- One type of thickening polymer may be used alone, or two or more types may be used in appropriate combination.
- thickening polymers examples include natural polymers such as gum arabic, tragacanth gum, guar gum, xanthan gum, locust bean gum, karaya gum, iris moss, quince seed, gelatin, shellac, rosin, and casein; sodium carboxymethyl cellulose, hydroxyethyl cellulose, Semi-synthetic polymers such as methylcellulose, ethylcellulose, sodium alginate, ester gum, nitrocellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, crystalline cellulose; acrylic acid / alkyl methacrylate copolymer, acrylic acid / polyoxyethylene alkylitaconic acid co Polymer, alkyl acrylate / methacrylic acid polyoxyethylene alkyl ether copolymer, acrylic acid / acrylic acid hydroxy Synthetic polymers such as alkyl copolymers, acrylic acid / methacrylic acid polyoxyethylene alkyl ether crosspolymers, acrylic acid / vinyl neo
- higher alcohol examples include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, and behenyl alcohol.
- a higher alcohol may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
- the oil-based cleansing cosmetic of the present invention does not contain water from the viewpoint of making an oil-based cosmetic, or contains water and the content of water in 100% by mass of the oil-based cleansing cosmetic is 1% by mass or less. Preferably there is. That is, the water content in the oil-based cleansing cosmetic of the present invention is preferably 0 to 1% by mass, and more preferably 0 to 0.5% by mass.
- the production method of the oil-based cleansing cosmetic composition of the present invention is not particularly limited as long as it is a production method capable of preparing an oil-based cleansing cosmetic composition.
- the above-described constituent components are mixed and a known method such as a disperser is prepared.
- the method of stirring using a mixer, a homomixer, a disper mill etc. is mentioned.
- the oil-based cleansing cosmetic of the present invention is filled in a container that can be easily taken out, such as a tube container or a wide-mouth jar container.
- the blending amount represents “% by mass” unless otherwise specified, and all blending components were converted to pure. All the evaluations were performed under constant conditions of 23 ° C. and 60% humidity.
- Liquid paraffin Trade name “CARNATION” (Sonneborn)
- Isododecane Trade name “Marcazole R” (manufactured by Maruzen Petrochemical Co., Ltd.)
- Dimethylpolysiloxane Trade name “KF-96A-10cs” (manufactured by Shin-Etsu Chemical Co., Ltd.)
- Methylphenylpolysiloxane trade name “SF558MD” (manufactured by Dow Corning Toray)
- Decamethylcyclopentasiloxane Trade name “KF-995” (manufactured by Shin-Etsu Chemical Co., Ltd.)
- Concentrated glycerin Trade name “Concentrated glycerin for cosmetics” (manufactured by Sakamoto Pharmaceutical Co., Ltd.) Cetyl 2-ethylhexanoate: trade name “CIO-N” (manufactured by Nippon Surfactant Kogyo Co., Ltd.) Orange oil: Trade name "ORANGE (DECO) -CS OIL IT” (manufactured by Ogawa Fragrance)
- Test Example 1 Evaluation of storage stability
- Each sample obtained in Examples and Comparative Examples was filled in a 30 g capacity transparent glass container, and the state of the system after being stored in a 50 ° C. constant temperature bath for 4 weeks was visually observed and visually evaluated according to the following evaluation criteria. .
- the oil-based cleansing cosmetics of each example have much superior storage stability compared to those of each comparative example, with no separation or separation (oil floating) of the preparation. You can see that it is demonstrating. Moreover, it turns out that the oil-based cleansing cosmetic of each Example has the extensibility (elongation spread) at the time of cleansing, and has exhibited the outstanding cleansing effect (make dirt removal effect).
- Comparative Example 1 that does not contain the component (A), which is an essential component of the present invention, cannot sufficiently exhibit the effects of the present invention. Further, in Comparative Example 2 that does not contain the component (B) that is an essential constituent of the present invention, or in Comparative Example 3 that does not contain the component (C) that is an essential constituent of the present invention, a clear separation was observed, It can be seen that the storage stability is extremely bad.
- Comparative Examples 4 to 5 in which the component (B), which is an essential component of the present invention, is replaced with other similar components are also inferior in storage stability and cannot fully exhibit the spreadability and cleansing effect. I understand that. Incidentally, in Comparative Example 6 in which the component (C), which is an essential component of the present invention, was replaced with other similar components, each evaluation test was not performed because it was not uniformly dissolved and could not be formed as an agent.
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Abstract
Description
成分(A):炭化水素油およびシリコーン油の群から選ばれる油剤
成分(B):トリベヘン酸グリセリル
成分(C):(ベヘン酸/エイコサン二酸)グリセリル
成分(A):炭化水素油およびシリコーン油の群から選ばれる油剤
成分(B):トリベヘン酸グリセリル
成分(C):(ベヘン酸/エイコサン二酸)グリセリル
上記成分(A)は、炭化水素油およびシリコーン油の群から選ばれる油剤である。本発明では、成分(A)を用いることにより、油性クレンジング化粧料の長所である優れたクレンジング効果を発揮させることができる。本明細書において、上記「炭化水素油」を「成分(A1)」と称する場合がある。また、上記「シリコーン油」を「成分(A2)」と称する場合がある。成分(A)は、1種を単独で用いても良く、2種以上を適宜組み合わせて用いても良い。
上記成分(B)は、トリベヘン酸グリセリルである。本発明では、成分(B)を用いることにより、優れた製剤の保存安定性を発揮する油性クレンジング化粧料を調製することが可能となる。
上記成分(C)は、(ベヘン酸/エイコサン二酸)グリセリルである。本発明では、成分(C)を用い、上記成分(B)と併用することにより、格段に優れた製剤の保存安定性を発揮する油性クレンジング化粧料を調製することが可能となる。
本発明の油性クレンジング化粧料は、上記した成分(A)、成分(B)および成分(C)に加えて、成分(D):トリポリヒドロキシステアリン酸ジペンタエリスリチルを配合させることが好ましい。本発明では、成分(D)を用いることにより、より一層優れた製剤の保存安定性を発揮させることができる。また、しっとりとした後肌感を付与することができる。
本発明の油性クレンジング化粧料は、クレンジング後の洗い落ちを高める観点、並びにクレンジング効果をより一層高める観点から、成分(E):非イオン性界面活性剤を配合させることが好ましい。
本発明の油性クレンジング化粧料には、本発明の効果をより一層高める観点から、上記した成分の他に通常化粧料に用いられる成分を配合することができる。他成分としては、例えば、多価アルコール、上記成分(B)および成分(C)以外の脂肪酸エステル油、植物油、増粘性高分子、高級アルコール、脂質、香料、防腐・殺菌剤、保湿剤、清涼剤などが挙げられる。上記他成分は、適宜、その用途、目的に応じて配合することができる。
流動パラフィン:商品名「CARNATION」(Sonneborn社製)
イソドデカン:商品名「マルカゾールR」(丸善石油化学社製)
ジメチルポリシロキサン:商品名「KF-96A-10cs」(信越化学工業社製)
メチルフェニルポリシロキサン:商品名「SF558MD」(東レ・ダウコーニング社製)
デカメチルシクロペンタシロキサン:商品名「KF-995」(信越化学工業社製)
トリベヘン酸グリセリル:商品名「シンクロワックス HR-C」(クローダジャパン社製)
(ベヘン酸/エイコサン二酸)グリセリル:商品名「ノムコート HK-G」(日清オイリオグループ社製)
トリポリヒドロキシステアリン酸ジペンタエリスリチル:商品名「サラコス WO-6」(日清オイリオグループ社製)
イソステアリン酸PEG-8グリセリル:商品名「ブラウノン RGL-8MISE」(青木油脂工業社製)
イソステアリン酸PEG-20グリセリル:商品名「EMALEX GWIS-120」(日本エマルジョン社製)
濃グリセリン:商品名「化粧用濃グリセリン」(阪本薬品工業社製)
2-エチルヘキサン酸セチル:商品名「CIO-N」(日本サーファクタント工業社製)
オレンジ油:商品名「ORANGE(DECO)-CS OIL IT」(小川香料社製)
表1~表2に記した組成に従い、実施例1~8および比較例1~6の油性クレンジング化粧料を調製し、下記評価試験に供した。結果をそれぞれ表1~表2に併記する。
実施例および比較例で得られた各試料を、30g容量の透明ガラス容器に夫々充填し、50℃の恒温槽に4週間保管後の系の状態を目視観察して下記評価基準に従い目視評価した。
◎(非常に良好):製造直後と対比して、均一状態を維持している(変化が全く認められない)
○(良好):製造直後と対比して、均一状態を維持しているが、表面にごく僅かな油浮き(離液)が認められる
△(不十分):製造直後と対比して、均一状態を維持しておらず、明らかな油浮き(離液)が認められる
×(不良):明らかな分離が認められる
顔にメイクを施した女性官能評価パネル16名により、上記保存安定性の評価において、「◎(非常に良好)」、「○(良好)」、「△(不十分)」の結果が得られた各試料を用いてメイクアップ除去剤の形態での使用試験を行った。具体的には、乾いた手の平に試料3gを取り、メイク汚れに馴染ませるように顔全体に塗布後、メイク汚れが気になる箇所を中心に指先で小さな円を描くように1分間クレンジングしてもらい、その後40℃の温水で十分に洗い流してタオルドライにより顔の水分を拭き取ってもらった。
◎(非常に良好):16名中13名以上が、延展時の伸び広がりが良く、剤の「ヨレ」を感じないと回答
○(良好):16名中9~12名が、延展時の伸び広がりが良く、剤の「ヨレ」を感じないと回答
△(不十分):16名中5~8名が、延展時の伸び広がりが良く、剤の「ヨレ」を感じないと回答
×(不良):16名中4名以下が、延展時の伸び広がりが良く、剤の「ヨレ」を感じないと回答
◎(非常に良好):16名中13名以上が、クレンジング効果(メイク汚れ除去効果)に優れると回答
○(良好):16名中9~12名が、クレンジング効果(メイク汚れ除去効果)に優れると回答
△(不十分):16名中5~8名が、クレンジング効果(メイク汚れ除去効果)に優れると回答
×(不良):16名中4名以下が、クレンジング効果(メイク汚れ除去効果)に優れると回答
Claims (5)
- 下記成分(A)、成分(B)および成分(C)を含有することを特徴とする油性クレンジング化粧料。
成分(A):炭化水素油およびシリコーン油の群から選ばれる油剤
成分(B):トリベヘン酸グリセリル
成分(C):(ベヘン酸/エイコサン二酸)グリセリル - 前記成分(B)の含有量が1~6質量%、前記成分(C)の含有量が1~6質量%であり、成分(B)の含有量と成分(C)の含有量の総和が2~7質量%である請求項1に記載の油性クレンジング化粧料。
- 前記成分(C)に対する前記成分(B)の質量割合((B)/(C))が0.25~4である請求項1又は2に記載の油性クレンジング化粧料。
- さらに、下記成分(D)を含有することを特徴とする請求項1~3の何れか一項に記載の油性クレンジング化粧料。
成分(D):トリポリヒドロキシステアリン酸ジペンタエリスリチル - さらに、下記成分(E)を含有することを特徴とする請求項1~4の何れか一項に記載の油性クレンジング化粧料。
成分(E):非イオン性界面活性剤
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JP6893485B2 (ja) * | 2018-03-13 | 2021-06-23 | 株式会社マンダム | クレンジング化粧料 |
WO2019230578A1 (ja) * | 2018-05-29 | 2019-12-05 | 株式会社 資生堂 | 温感化粧料 |
JP7181646B2 (ja) * | 2021-02-08 | 2022-12-01 | 株式会社アイテック | 液晶乳化物 |
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CN108024930A (zh) | 2018-05-11 |
CN108024930B (zh) | 2024-04-19 |
WO2017159249A1 (ja) | 2017-09-21 |
CN108024931A (zh) | 2018-05-11 |
KR20180030165A (ko) | 2018-03-21 |
KR102002908B1 (ko) | 2019-07-23 |
KR20180030129A (ko) | 2018-03-21 |
KR102028429B1 (ko) | 2019-11-04 |
JPWO2017159249A1 (ja) | 2018-07-26 |
JP6482722B2 (ja) | 2019-03-13 |
JP6482721B2 (ja) | 2019-03-13 |
JPWO2017159248A1 (ja) | 2018-07-05 |
KR20180026536A (ko) | 2018-03-12 |
JP6482723B2 (ja) | 2019-03-13 |
WO2017159248A1 (ja) | 2017-09-21 |
JPWO2017159247A1 (ja) | 2018-06-28 |
CN108024929A (zh) | 2018-05-11 |
KR102029189B1 (ko) | 2019-10-07 |
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