WO2017113459A1 - 一种防蓝光光学树脂镜片及其制备方法 - Google Patents

一种防蓝光光学树脂镜片及其制备方法 Download PDF

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WO2017113459A1
WO2017113459A1 PCT/CN2016/072191 CN2016072191W WO2017113459A1 WO 2017113459 A1 WO2017113459 A1 WO 2017113459A1 CN 2016072191 W CN2016072191 W CN 2016072191W WO 2017113459 A1 WO2017113459 A1 WO 2017113459A1
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blue light
optical resin
resin lens
light absorber
absorber
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PCT/CN2016/072191
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English (en)
French (fr)
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费铮翔
严清波
贺建友
黄添鸟
曹根庭
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江苏康耐特光学有限公司
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Application filed by 江苏康耐特光学有限公司 filed Critical 江苏康耐特光学有限公司
Priority to US15/516,897 priority Critical patent/US10385187B2/en
Priority to EP16865267.5A priority patent/EP3399354B1/en
Publication of WO2017113459A1 publication Critical patent/WO2017113459A1/zh

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    • G—PHYSICS
    • G02—OPTICS
    • G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00—Optical parts
    • G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
    • G02C7/108—Colouring materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/132—Phenols containing keto groups, e.g. benzophenones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F18/24—Esters of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/109—Esters; Ether-esters of carbonic acid, e.g. R-O-C(=O)-O-R
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041—Lenses
    • G—PHYSICS
    • G02—OPTICS
    • G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00—Optical parts
    • G02C7/02—Lenses; Lens systems ; Methods of designing lenses
    • G—PHYSICS
    • G02—OPTICS
    • G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00—Optical parts
    • G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
    • G02C7/104—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses having spectral characteristics for purposes other than sun-protection

Definitions

  • the invention relates to a resin lens, in particular to an anti-blue light optical resin lens and a preparation method thereof
  • Blue light is a high-energy visible light with a wavelength of 380-500 nm. It has a very strong penetrating power and easily penetrates the retina to reach the macular area, causing the sensory cells to wither and not regenerate.
  • the chance of each person's exposure to blue light increases dramatically, which may result in impaired vision and macular degeneration.
  • the present invention provides an anti-blue light optical resin lens, A method for preparing the blue light-resistant optical resin lens is also provided, and the blue light absorption rate (380 to 500 nm) of the obtained blue light-proof optical resin lens is 15% to 40%.
  • the polymerization initiator is selected from tert-butyl peroxy-2-ethylhexyl carbonate, t-amyl peroxy-2-ethylhexyl carbonate, and 1,1-bis(tert-butylperoxy)-3,3,5- One or two of trimethylcyclohexane.
  • the benzophenone ultraviolet absorber is selected from the group consisting of 2-hydroxy-4-methoxybenzophenone (UV-9) and 2-hydroxy-4-octyloxybenzophenone (UV-531). , 2,2'-dihydroxy-4,4'-dimethoxybenzophenone (BP-6), 2,2',4,4'-tetrahydroxy-benzophenone (BP-2) And one of 2,2'-hydroxy-4-methoxybenzophenone (UV-24), the quinone blue light absorber is 2-cyano-3-(1-methyl-2- Methyl phenyl acrylate)
  • the mass ratio of bismuth, benzophenone ultraviolet absorbing agent to hydrazine type blue absorbing agent is from 0 to 50:0 to 10.
  • the blue light-proof optical resin lens further comprises 800 to 5000 mass ppm of a blue whitening agent for adjusting the color of the lens to avoid yellowing of the lens.
  • the preparation method of the above-mentioned anti-blue light optical resin lens comprises the following steps: (1) compounding: the resin monomer and the blue light absorber are uniformly mixed according to the ratio, and the polymerization agent is added after the blue light absorber is completely dissolved, and the vacuum stirring is performed at room temperature. Uniform, vacuumed through the filter element; (2) vertical pouring, heat curing molding: pouring the material prepared in step (1) into the combined mold, thermosetting; (3) mold opening, cleaning, (4) ) Secondary curing, inspection.
  • step (1) The specific process of the step (1) is as follows: the resin monomer and the blue light absorber are uniformly mixed and heated to 60 ° C, and the polymerization initiator is added after the blue light absorber is completely dissolved, and the room temperature and the vacuum degree are -0.1 MPa. The mixture was stirred for 2 hours, filtered through a 0.1 ⁇ m filter, stirred for 10 minutes, and evacuated under a vacuum of -0.1 MPa for 40 minutes.
  • a polymerization initiator is added, and then 800 to 5000 mass ppm of a blue brightener is added.
  • the heat curing temperature curve and the curing time in the step (2) are as follows: 30 to 35 ° C 3 h 80 to 95 ° C 10 h 85 to 95 ° C 7 h 95 to 110 ° C 1 h 110 to 120 ° C 1 h 110 to 120 ° C 1 to 60 to 75 °C.
  • the secondary curing temperature of the step (4) was 120 ° C, and the curing time was 1 h.
  • the invention has the beneficial effects that the use of a mixture of diethylene glycol carbonate and its multimer as a resin monomer reduces the activation energy of the open chain, so that a polymerization initiator having a lower oxidizing property can be used to initiate the oxidation. It is much lower than IPP and does not oxidize and destroy the absorption of blue light by benzophenone-based UV absorbers and quinone-based blue absorbers.
  • the blue light absorption rate (380 to 500 nm) of the blue light-proof optical resin lens produced by the method is 15% to 40%.
  • the resin monomer is selected from the diethylene glycol carbonate allyl ester produced by ACOMN Company and its multimer mixture (product code is RAV 7NG), and the benzophenone ultraviolet absorber is 2-hydroxy-4-methoxybiphenyl.
  • Ketone (UV-9) a polymerization initiator is selected from tert-butyl 2-ethylhexyl carbonate.
  • thermosetting, curing curve is 30 ° C 3h 80 ° C 10h 85 ° C 7h 110 ° C 1h 120 ° C 1h 120 ° C 1h 60 ° C mold opening and cleaning, lens After secondary curing: 120 ° C 1h , after inspection, the light absorption rate (380 ⁇ 500nm) was 26.9%.
  • the resin monomer is selected from the diethylene glycol carbonate allyl ester produced by ACOMN Company and its multimer mixture (product code is RAV 7NG), and the benzophenone ultraviolet absorber is selected from 2,2'-dihydroxy-4,4' -Dimethoxybenzophenone (BP-6), the initiator was selected from 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane.
  • RAV 7MC monomer 10 g of 2-cyano-3-(1-methyl-2-phenyl acrylate), 10 g of 2,2'-dihydroxy-4,4'-dimethoxy 220 g of benzophenone (BP-6), uniformly mixed, and heated to 60 ° C.
  • the resin monomer is selected from the diethylene glycol carbonate allyl ester and its multimer mixture (product code is LS) produced by PPG Company, and the 2,2'-dihydroxy-4,4' is used as the benzophenone ultraviolet absorber.
  • - Dimethoxybenzophenone (BP-6) the initiator is selected from t-amyl 2-ethylhexyl carbonate.
  • the resin monomer is selected from PGM's diethylene glycol carbonate allyl ester and its multimer mixture (product code is LS), and the initiator is 1,1-bis(t-butylperoxy)-3,3,5. - Trimethylcyclohexane.
  • LS monomer 2g of 2-cyano-3-(1-methyl-2-phenyl acrylate) oxime, mix well, raise the temperature to 60 ° C, and add 800g after the blue absorbing agent is completely dissolved.
  • the resin monomer is selected from the diethylene glycol carbonate allyl ester produced by ACOMN and its multimer mixture (product code is RAV 7NG), and the benzophenone ultraviolet absorber is 2-hydroxy-4-octyloxybenzophenone. Ketone (UV-531), the initiator is selected from t-amyl 2-ethylhexyl carbonate.

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Ophthalmology & Optometry (AREA)
  • General Health & Medical Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Optical Filters (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

一种防蓝光光学树脂镜片，包括树脂单体，蓝光吸收剂和聚合引发剂，树脂单体是二甘醇碳酸烯丙酯及其多聚体的混合物，蓝光吸收剂为二苯甲酮类紫外线吸收剂和/或吲哚类蓝光吸收剂，聚合引发剂为过氧化2-乙基己基碳酸叔丁酯、过氧化2-乙基己基碳酸叔戊酯和1,1-双（过氧化叔丁基）-3,3,5-三甲基环己烷中的一种或两种。

Description

一种防蓝光光学树脂镜片及其制备方法 技术领域
本发明涉及一种树脂镜片，具体是一种防蓝光光学树脂镜片及其制备方法
背景技术
蓝光是波长为380-500nm的高能量可见光，穿透力非常强，很容易穿透视网膜到达黄斑区，导致感官细胞枯萎，不可再生。人们每天使用的电子产品，比如电脑，智能手机、平板电脑、电视LED显示屏等会发出大量的蓝光。伴随着这些电子产品的普及并渗透到生活的方方面面，每个人接触蓝光的机会随之急剧增加，由此可能会导致视力受损，引发黄斑病变。
1.499树脂镜片常规工艺中，使用二甘醇碳酸烯丙脂(ADC)和过氧化二碳酸二异丙酯(IPP)，如果需要防蓝光，就需要加入蓝光吸收剂，常用的蓝光吸收剂有：苯并三唑类紫外线吸收剂、苯甲酮类紫外线吸收剂、荧光黄染料，苯并三唑类紫外线吸收剂、苯甲酮类紫外线吸收剂、荧光黄染料等，而二甘醇碳酸烯丙脂开链活化能高，需用强氧化性的引发剂，但是上述常用的蓝光吸收剂在强氧化剂作用下易被氧化失出吸收蓝光的特性，导致目前市场上1.490～1.510折射率的防蓝光光学树脂镜片极少。
发明内容
因此，为解决上述问题，本发明提供一种防蓝光光学树脂镜片， 还提供该防蓝光光学树脂镜片的制备方法，制得的防蓝光光学树脂镜片蓝光吸收率(380～500nm)为15％～40％。
本发明采用的技术方案是：一种防蓝光光学树脂镜片，包括树脂单体、蓝光吸收剂和聚合引发剂，质量比为树脂单体：蓝光吸收剂：聚合引发剂＝100：0.01～2.00：1.00～4.00，所述树脂单体是二甘醇碳酸烯丙脂及其多聚体的混合物，所述蓝光吸收剂为二苯甲酮类紫外线吸收剂和/或吲哚类蓝光吸收剂，所述聚合引发剂选取过氧化-2-乙基己基碳酸叔丁酯、过氧化-2-乙基己基碳酸叔戊酯和1,1-双(过氧化叔丁基)-3,3,5-三甲基环己烷中的一种或两种。
优选的，所述二苯甲酮类紫外线吸收剂选用2-羟基-4-甲氧基二苯甲酮(UV-9)、2-羟基-4-辛氧基二苯甲酮(UV-531)、2,2'-二羟基-4,4'-二甲氧基二苯甲酮(BP-6)、2,2',4,4'-四羟基-二苯甲酮(BP-2)和2,2'-羟基-4-甲氧基二苯甲酮(UV-24)中的一种，吲哚类蓝光吸收剂为2-氰基-3-(1-甲基-2-苯基丙烯酸甲酯)吲哚，二苯甲酮类紫外线吸收剂与吲哚类蓝光吸收剂的质量比为0～50：0～10。
优选的，所述防蓝光光学树脂镜片还包括800～5000质量ppm的蓝色增白剂，用于调节镜片颜色，避免镜片发黄。
上述防蓝光光学树脂镜片的制备方法，包括如下步骤：(1)配料：按比例称取树脂单体和蓝光吸收剂混合均匀，升温待蓝光吸收剂完全溶解后加入聚合引发剂，室温密封真空搅拌均匀，经滤芯过滤后抽真空；(2)立浇，热固化成型：把步骤(1)配好的料浇注入合好的模具中，热固成型；(3)开模、清洗，(4)二次固化，检验。
步骤(1)配料的具体过程为：按比例称取树脂单体和蓝光吸收剂混合均匀，升温至60℃，待蓝光吸收剂完全溶解后加入聚合引发剂，在室温及真空度为﹣0.1MPa条件下搅拌2小时，经0.1μm滤芯过滤后继续搅拌10分钟，在真空度为﹣0.1MPa条件下抽真空40分钟。
优选的，步骤(1)中，待蓝光吸收剂完全溶解后加入聚合引发剂，再加入800～5000质量ppm的蓝色增白剂。
优选的，步骤(2)中热固化温度曲线及固化时间如下：30～35℃3h 80～95℃10h 85～95℃7h 95～110℃1h 110～120℃1h 110～120℃1h 60～75℃。
步骤(4)的二次固化温度为120℃，固化时间是1h。
本发明的有益效果是：采用二甘醇碳酸烯丙脂及其多聚体的混合物作为树脂单体，降低了开链活化能，因此选用氧化性较低的聚合引发剂就可以引发，氧化性远低于IPP，且不会氧化破坏苯甲酮类紫外线吸收剂与吲哚类蓝光吸收剂吸收蓝光的特性。该方法制造的防蓝光光学树脂镜片蓝光吸收率(380～500nm)为15％～40％。
具体实施方式
为了加深对本发明的理解，下面将结合实施例对本发明作进一步详述，该实施例仅用于解释本发明，并不构成对本发明保护范围的限定。
实施例1
树脂单体选用ACOMN公司生产的二甘醇碳酸烯丙脂及其多聚 体混合物(产品代号是RAV 7NG)，二苯甲酮类紫外线吸收剂选用2-羟基-4-甲氧基二苯甲酮(UV-9)，聚合引发剂选用过氧化2-乙基己基碳酸叔丁酯。称取RAV 7NG单体20Kg，2-羟基-4-甲氧基二苯甲酮(UV-9)300g，混合均匀，升温至60℃，待蓝光吸收剂完全溶解后加入200g引发剂，50g蓝色增白剂，室温密封真空搅拌均匀，在室温及真空度为﹣0.1MPa条件下搅拌2小时，经0.1μm滤芯过滤后继续搅拌10分钟，在真空度为﹣0.1MPa条件下抽真空40分钟，立浇，把配好的料浇注入合好的模具中，热固成型，固化曲线为30℃3h 80℃10h 85℃7h 110℃1h 120℃1h 120℃1h 60℃开模并清洗，镜片经过二次固化：120℃1h，检验合格后入库，蓝光吸收率(380～500nm)为26.9％。
实施例2
树脂单体选用ACOMN公司生产的二甘醇碳酸烯丙脂及其多聚体混合物(产品代号是RAV 7NG)，二苯甲酮类紫外线吸收剂选用2,2'-二羟基-4,4'-二甲氧基二苯甲酮(BP-6)，引发剂选用1,1-双(过氧化叔丁基)-3,3,5-三甲基环己烷。称取RAV 7MC单体20Kg，2-氰基-3-(1-甲基-2-苯基丙烯酸甲酯)吲哚10g、2,2'-二羟基-4,4'-二甲氧基二苯甲酮(BP-6)220g，混合均匀，升温至60℃，待蓝光吸收剂完全溶解后加入600g引发剂，60g蓝色增白剂，室温密封真空搅拌均匀，在室温及真空度为﹣0.1MPa条件下搅拌2小时，经0.1μm滤芯过滤后继续搅拌10分钟，在真空度为﹣0.1MPa条件下抽真空40分钟，立浇，把配好的料浇注入合好的模具中，热固成型，固化 曲线为35℃3h 85℃10h 85℃7h 105℃1h 115℃1h 115℃1h 70℃开模并清洗，镜片经过二次固化：120℃1h，检验合格后入库，蓝光吸收率(380～500nm)为28.1％。
实施例3
树脂单体选用PPG公司的生产的二甘醇碳酸烯丙脂及其多聚体混合物(产品代号是LS)，二苯甲酮类紫外线吸收剂选用2,2'-二羟基-4,4'-二甲氧基二苯甲酮(BP-6)，引发剂选用过氧化2-乙基己基碳酸叔戊酯。称取LS单体20Kg，2-氰基-3-(1-甲基-2-苯基丙烯酸甲酯)吲哚16g、2,2'-二羟基-4,4'-二甲氧基二苯甲酮(BP-6)100g，混合均匀，升温至60℃，待蓝光吸收剂完全溶解后加入800g引发剂，90g蓝色增白剂，室温密封真空搅拌均匀，在室温及真空度为﹣0.1MPa条件下搅拌2小时，经0.1μm滤芯过滤后继续搅拌10分钟，在真空度为﹣0.1MPa条件下抽真空40分钟，立浇，把配好的料浇注入合好的模具中，热固成型，固化曲线为32℃3h 95℃10h 95℃7h 110℃1h120℃1h 120℃1h 75℃开模并清洗，镜片经过二次固化：120℃1h，检验合格后入库，蓝光吸收率(380～500nm)为26.4％。
实施例4
树脂单体选用PPG公司的生产的二甘醇碳酸烯丙脂及其多聚体混合物(产品代号是LS)，引发剂选用1,1-双(过氧化叔丁基)-3,3,5-三甲基环己烷。称取LS单体20Kg，2-氰基-3-(1-甲基-2-苯基丙烯酸甲酯)吲哚2g，混合均匀，升温至60℃，待蓝光吸收剂完全溶解后加入800g引发剂，100g蓝色增白剂，室温密封真空搅拌均匀，在 室温及真空度为﹣0.1MPa条件下搅拌2小时，经0.1μm滤芯过滤后继续搅拌10分钟，在真空度为﹣0.1MPa条件下抽真空40分钟，立浇，把配好的料浇注入合好的模具中，热固成型，固化曲线为32℃3h95℃10h 90℃7h 95℃1h 110℃1h 110℃1h 75℃开模并清洗，镜片经过二次固化：120℃1h，检验合格后入库，蓝光吸收率(380～500nm)为22.6％。
实施例5
树脂单体选用ACOMN公司生产的二甘醇碳酸烯丙脂及其多聚体混合物(产品代号是RAV 7NG)，二苯甲酮类紫外线吸收剂选用2-羟基-4-辛氧基二苯甲酮(UV-531)，引发剂选用过氧化2-乙基己基碳酸叔戊酯。称取RAV 7MC单体20Kg，2-羟基-4-辛氧基二苯甲酮(UV-531)400g，混合均匀，升温至60℃，待蓝光吸收剂完全溶解后加入480g引发剂，蓝色增白剂75g，室温密封真空搅拌均匀，在室温及真空度为﹣0.1MPa条件下搅拌2小时，经0.1μm滤芯过滤后继续搅拌10分钟，在真空度为﹣0.1MPa条件下抽真空40分钟，立浇，把配好的料浇注入合好的模具中，热固成型，固化曲线为35℃3h85℃10h 95℃7h 105℃1h 110℃1h 120℃1h 70℃开模并清洗，镜片经过二次固化：120℃1h，检验合格后入库，蓝光吸收率(380～500nm)为28.4％。
以上所述，仅是本发明的较佳实施例而已，并非是对本发明作任何其他形式的限制，而依据本发明的技术实质所作的任何修改或等同变化，仍属于本发明所要求保护的范围。

Claims (8)

  1. 一种防蓝光光学树脂镜片，其特征在于，包括树脂单体、蓝光吸收剂和聚合引发剂，质量比为树脂单体：蓝光吸收剂：聚合引发剂＝100：0.01～2.00：1.00～4.00，所述树脂单体是二甘醇碳酸烯丙脂及其多聚体的混合物，所述蓝光吸收剂为二苯甲酮类紫外线吸收剂和/或吲哚类蓝光吸收剂，所述聚合引发剂选取过氧化2-乙基己基碳酸叔丁酯、过氧化2-乙基己基碳酸叔戊酯和1,1-双(过氧化叔丁基)-3,3,5-三甲基环己烷中的一种或两种。
  2. 根据权利要求1所述的一种防蓝光光学树脂镜片，其特征在于，所述二苯甲酮类紫外线吸收剂选用2-羟基-4-甲氧基二苯甲酮、2-羟基-4-辛氧基二苯甲酮、2,2'-二羟基-4,4'-二甲氧基二苯甲酮、2,2',4,4'-四羟基-二苯甲酮和2,2'-羟基-4-甲氧基二苯甲酮中的一种，吲哚类蓝光吸收剂为2-氰基-3-(1-甲基-2-苯基丙烯酸甲酯)吲哚，二苯甲酮类紫外线吸收剂与吲哚类蓝光吸收剂的质量比为0～50：0～10。
  3. 根据权利要求1所述的一种防蓝光光学树脂镜片，其特征在于，所述防蓝光光学树脂镜片还包括800～5000质量ppm的蓝色增白剂。
  4. 如权利要求1所述的一种防蓝光光学树脂镜片的制备方法，其特征在于，包括如下步骤：(1)配料：按比例称取树脂单体和蓝光吸收剂混合均匀，升温待蓝光吸收剂完全溶解后加入聚合引发剂，室温密封真空搅拌均匀，经滤芯过滤后抽真空；(2)立浇，热固化成型：把步骤(1)配好的料浇注入合好的模具中，热固成型；(3)开模、清洗，(4)二次固化，检验。
  5. 根据权利要求4所述的一种防蓝光光学树脂镜片的制备方法，其特征在于，步骤(1)配料的具体过程为：按比例称取树脂单体和蓝光吸收剂混合均匀，升温至60℃，待蓝光吸收剂完全溶解后加入聚合引发剂，在室温及真空度为﹣0.1MPa条件下搅拌2小时，经0.1μm滤芯过滤后继续搅拌10分钟，在真空度为﹣0.1MPa条件下抽真空40分钟。
  6. 根据权利要求4或5所述的一种防蓝光光学树脂镜片的制备方法，其特征在于，步骤(1)中，待蓝光吸收剂完全溶解后加入聚合引发剂，再加入800～5000质量ppm的蓝色增白剂。
  7. 根据权利要求4所述的一种防蓝光光学树脂镜片的制备方法，其特征在于，步骤(2)中热固化温度曲线及固化时间如下：30～35℃ 3h 80～95℃ 10h 85～95℃ 7h 95～110℃ 1h 110～120℃ 1h 110～120℃ 1h 60～75℃。
  8. 根据权利要求4所述的一种防蓝光光学树脂镜片的制备方法，其特征在于，步骤(4)的二次固化温度为120℃，固化时间是1h。
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