WO2017073177A1 - Procédé de traitement d'eaux usées contenant un complexe de cyanure et agent de traitement pour utilisation dans ledit procédé - Google Patents

Procédé de traitement d'eaux usées contenant un complexe de cyanure et agent de traitement pour utilisation dans ledit procédé Download PDF

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Publication number
WO2017073177A1
WO2017073177A1 PCT/JP2016/076483 JP2016076483W WO2017073177A1 WO 2017073177 A1 WO2017073177 A1 WO 2017073177A1 JP 2016076483 W JP2016076483 W JP 2016076483W WO 2017073177 A1 WO2017073177 A1 WO 2017073177A1
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Prior art keywords
cyanide
compound
complex
cupric
cuprous
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PCT/JP2016/076483
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English (en)
Japanese (ja)
Inventor
村上　誠
一之 入佐
英則 平嶋
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株式会社片山化学工業研究所
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Application filed by 株式会社片山化学工業研究所 filed Critical 株式会社片山化学工業研究所
Priority to CN201680058302.1A priority Critical patent/CN108137358B/zh
Priority to KR1020187013511A priority patent/KR102071241B1/ko
Publication of WO2017073177A1 publication Critical patent/WO2017073177A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/722—Oxidation by peroxides

Definitions

  • the present invention relates to a method for treating complex cyanide-containing wastewater that can efficiently remove complex cyanide in wastewater from a complex cyanide-containing wastewater by a simple operation in a safe and inexpensive manner, and a treating agent for complex cyanide-containing wastewater used therefor.
  • cyan contained in waste water in various forms that is, among difficult-to-decompose cyan complex, easily-decomposable cyan complex and cyanide ion, particularly easily-decomposable and easily-decomposable cyan complex (complex cyan) is simplified. Can be processed with simple operations.
  • Cyan has a strong negative impact on ecosystems, and cyanide-containing wastewater (also referred to as “cyan wastewater”) cannot be released directly into nature.
  • Cyan drainage standards are established based on the Water Pollution Control Law. Cyan removal processing is performed so as to satisfy this standard (1 mg / L or less). Further, depending on the region, an additional drainage standard that is lower than the above-mentioned drainage standard value is set by regulations. Cyan is present in the wastewater in three forms of a hardly-decomposable cyanide complex, an easily-decomposable cyanide complex, and a cyanide ion, although there are some contents due to the origin of the wastewater.
  • Oxidative decomposition method such as electrolytic oxidation method (electrolysis method) in which cyanide is electrolyzed and an oxidation reaction is performed using an insoluble electrode;
  • cyanide-containing wastewater As a supply compound of iron ions, for example, ferrous sulfate is added to produce a poorly soluble ferri / ferrocyanide, and this is precipitated and removed.
  • “insoluble complex method” such as zinc white method for precipitating and removing insoluble complex and (6) reducing copper salt method for adding divalent copper salt and reducing agent and precipitating and removing generated insoluble complex; Microbes acclimated to cyanide (Biodegradation method) that decomposes cyanide into (decomposing bacteria); (8) Heat that keeps cyanate-containing wastewater at a high temperature to hydrolyze cyanide compounds into ammonia and formic acid, and precipitates coexisting heavy metals as simple substances or oxides
  • hydrolysis method and (9) cyanide decomposition there are “hydrothermal reaction” such as wet oxidation method that also oxidatively decomposes organic pollutants.
  • Patent Document 1 an aqueous solution containing a cyanide and / or cyano complex which may contain a solid is prepared by using Mn, Co, Ni, Cu, Cd, Zn.
  • the solution is oxidatively treated with the peroxide compound to give a pH value of 8-12.
  • alkali metal perborate and alkaline earth metal perborate alkali metal percarbonate and alkaline earth metal peroxide in a detoxifying process at a temperature from the freezing point of the solution to 80 ° C.
  • peroxide compounds are used, in which case the peroxide compounds should be detoxified in solid form or dissolved or suspended in water. Characterized in that it is added to the solution, or in this solution, the remaining forming components from the series of hydrogen peroxide and metaborate ions, alkali metal ions and alkaline earth metal ions are formed in situ. , A method for detoxifying an aqueous solution containing cyanide and / or cyano complex is disclosed.
  • Patent Document 2 Japanese Patent Application Laid-Open No. 2013-146696
  • a cyanine-containing wastewater has an amount of a manganese compound capable of removing cyan contained in the wastewater, and a copper compound and / or aluminum.
  • the wastewater is treated under a pH of 6 to 9.5, and the produced water-insoluble salt is removed from the wastewater to remove cyanide in the wastewater.
  • a method is disclosed.
  • the Water Pollution Control Law also establishes heavy metal drainage standards and, like cyan, can only be discharged into sewage or other wastewater if it is below the standards.
  • the copper drainage standard copper content
  • the copper content in the treated wastewater also needs to be below the drainage standard.
  • the drainage standard for hydrogen ion concentration (pH) is set at 5.0 to 9.0 for sea areas and 5.8 to 8.6 outside sea areas.
  • pH of wastewater is adjusted to acidic or alkaline
  • neutralization treatment is required to adjust not only the cyanide concentration of wastewater but also the pH within the drainage standard range before discharging into sewage etc. Sometimes it becomes.
  • the inventors of the present invention have made extensive studies to solve the above problems, and as a result, the complex cyanide-containing wastewater coexists with a cuprous compound and hydrogen peroxide under the conditions of pH 6 to 9, or pH 6 It has been found that cyanide in waste water can be efficiently treated by coexisting a cupric compound and hydrogen peroxide under the conditions of ⁇ 8, and the present invention has been completed.
  • the complex cyanide-containing wastewater is allowed to coexist with the cuprous compound and hydrogen peroxide under the condition of pH 6-9, or the cupric compound and hydrogen peroxide under the condition of pH 6-8.
  • a method for treating complex cyanide-containing wastewater comprising coexisting hydrogen peroxide and treating complex cyanide in the wastewater.
  • a treating agent for complex cyanine-containing wastewater used in the above-described method for treating complex cyanine-containing wastewater
  • the treating agent comprises a complex containing an aqueous hydrogen peroxide solution or an aqueous hydrogen peroxide supply compound as hydrogen peroxide, and an aqueous solution of a cuprous or cupric compound as a cuprous compound or cupric compound.
  • a treatment agent for cyanine-containing wastewater is provided.
  • the present invention it is possible to provide a method for treating complex cyanide-containing wastewater that can efficiently remove complex cyanide in wastewater from a complex cyanide-containing wastewater with a simple operation, safely and inexpensively, and a treatment agent used therefor. it can. Therefore, even if the wastewater treated by the method of the present invention is released into nature as it is, the influence on the environment can be very small, and therefore the method of the present invention is extremely useful industrially.
  • the complex cyanide-containing wastewater treatment method of the present invention exhibits the above-described effect more when any one of the following conditions is satisfied.
  • the complex cyanide concentration and the total cyan concentration in the complex cyanine-containing wastewater are 1 mg / L or more and 10 mg / L or less, respectively.
  • the cuprous compound or the cupric compound has a molar concentration of all cyans including complex cyan as 1, and is equivalent to 0.05 equivalent mole or more in terms of copper, and hydrogen peroxide includes complex cyanide. It is added to the complex cyanide-containing waste water so that the molar concentration of all cyan is 1, and the concentration is 1 equimolar or more.
  • the cuprous compound is a compound selected from cuprous chloride, cuprous fluoride, cuprous bromide, cuprous iodide, cuprous nitrate and cuprous sulfate
  • the dicopper compound is a compound selected from cupric chloride, cupric fluoride, cupric bromide, cupric iodide, cupric nitrate and cupric sulfate.
  • the total cyan concentration in the complex cyanide-containing wastewater after treatment is 1 mg / L or less.
  • the complex cyanide-containing wastewater treatment method of the present invention is a complex cyanide-containing wastewater, wherein the wastewater is allowed to coexist with a cuprous compound and hydrogen peroxide at pH 6-9. Alternatively, the complex cyanide in the wastewater is treated by coexisting a cupric compound and hydrogen peroxide under conditions of pH 6-8.
  • a coexistence of a cuprous compound or cupric compound and hydrogen peroxide means that a cuprous compound or cupric compound (hereinafter, both are also referred to as “copper compound”) and excess.
  • the coexistence may be by addition of a copper compound and hydrogen peroxide, or by generation in complex cyanide-containing wastewater, as will be described later. In the case of addition, the order is not particularly limited. It may be.
  • the mechanism (action mechanism) for removing complex cyanide in the method for treating wastewater containing complex cyanide of the present invention is not clear, but the inventors of the present invention consider as follows.
  • a peroxide compound such as hydrogen peroxide is added in the presence of a heavy metal containing copper to detoxify a cyan-containing aqueous solution. It is said that a detoxification (removal) effect can be obtained.
  • the removal efficiency of complex cyanide at pH 10 is inferior to that at pH 7-9.
  • the complex cyanide-containing wastewater treatment method of the present invention has a pH condition that exhibits an excellent complex cyanide removal effect, which tends to be contrary to Patent Document 1, and in this respect, the mechanism differs from Patent Document 1. It is considered a thing. Further, in the method of Patent Document 1, the cyan concentration in the cyan-containing aqueous solution to be treated is not particularly defined, and in this embodiment, a cyan-containing aqueous solution having a cyan concentration of 100 ppm (mg / L) is used. On the other hand, the method for treating complex cyanide-containing wastewater of the present invention is intended to treat complex cyanine-containing wastewater that has been conventionally difficult to remove, and has demonstrated its effect. This is probably due to a different mechanism.
  • the complex cyanide-containing wastewater to be treated in the present invention is not particularly limited as long as it is wastewater containing complex cyanide. A remarkable cyan removal effect is obtained when the complex cyanide concentration and the total cyan concentration in the complex cyanine-containing wastewater are 1 mg / L or more and 10 mg / L or less, respectively.
  • Examples of complex cyanide-containing wastewater include complex cyanides including metal cyanide, cyanide, cyanide complex, and cyano complex ion discharged from steel factories, chemical factories, plating factories, coke factories, metal surface treatment factories, and the like. Examples of such wastewater include complex cyanide-containing wastewater discharged in a treatment process of radioactively contaminated water, and complex cyanine-containing wastewater discharged from a soil treatment apparatus.
  • the copper compound used in the present invention is not particularly limited as long as it is a cuprous compound and a cupric compound that are soluble or easily dispersed in water and can form monovalent or divalent copper ions in water.
  • Either an organic copper compound or an inorganic copper compound may be used.
  • the organic copper compound include cupric compounds selected from cupric acetate, cupric benzoate, cupric citrate, copper naphthenate, and cupric oleate.
  • the inorganic copper compound examples include cuprous chloride, cuprous fluoride, cuprous bromide, cuprous iodide, cuprous nitrate and cuprous sulfate, and chloride.
  • examples include cupric compounds selected from cupric, cupric fluoride, cupric bromide, cupric iodide, cupric nitrate, and cupric sulfate. Since the organic copper compound may increase the COD in the complex cyanide-containing wastewater after the treatment, among the above copper compounds, the inorganic copper compound is preferable, and the effect of removing complex cyanide and the treatment cost of the complex cyanine-containing wastewater are preferred. Inorganic cuprous compounds are more preferable, cuprous chloride and cuprous sulfate are more preferable, and cuprous chloride is particularly preferable.
  • the above copper compound may be treated with a metal scavenger so as to have a desired copper equivalent concentration when added to the complex cyanide-containing wastewater. Further, it may be used after diluting or dissolving with water such as industrial water.
  • a metal scavenger a liquid chelating agent etc. are mentioned, for example.
  • the cuprous compound is a cuprous salt
  • a cuprous salt solution containing hydrogen chloride water, an aqueous alkali metal halide solution or ethanol as a solvent is used to stabilize the cuprous salt. It is preferable from the point.
  • the cuprous compound the cupric compound is added to the complex cyanide-containing wastewater together with the reducing agent, or the cupric compound is added to the reducing complex cyanide-containing wastewater, A cuprous ion supply compound produced by reducing a cupric compound is included.
  • the reducing agent include sulfites, divalent iron salts, hydrazine, and the like.
  • hydrogen peroxide examples include a hydrogen peroxide aqueous solution having a concentration of 3 to 60%, which is commercially available mainly for industrial use.
  • hydrogen peroxide generated from a hydrogen peroxide supply compound also referred to as a “hydrogen peroxide generator”
  • hydrogen peroxide generated by electrolysis of water or an alkaline solution can be used.
  • the hydrogen peroxide supplying compound include inorganic peracids such as percarbonate, perboric acid and peroxysulfuric acid capable of releasing hydrogen peroxide in water, organic peracids such as peracetic acid, and salts thereof. Examples of these salts include sodium percarbonate and sodium perborate.
  • the above hydrogen peroxide and hydrogen peroxide supply compound may be diluted or dissolved with water such as industrial water so that a desired hydrogen peroxide concentration is obtained upon addition.
  • the concentration of the copper compound in the complex cyanide-containing wastewater may be appropriately set depending on the conditions of the wastewater, but the copper compound is generally 0.05 equivalent mole in terms of copper, where the molar concentration of all cyanide including complex cyan is 1. It is preferable to add to cyanide-containing wastewater so as to have the above concentration.
  • the specific copper compound concentration is, for example, 0.005, 0.01, 0.02, 0.03, 0.04 in terms of copper (equal mole), where the molar concentration of all cyan including complex cyan is 1.
  • a more preferable copper compound is 0.1 to 2 equimolar, more preferably 0.2 to 1 equimolar in terms of copper, where the molar concentration of all cyan including complex cyan is 1.
  • the concentration of hydrogen peroxide in the complex cyanide-containing wastewater may be appropriately set depending on the conditions of the wastewater, etc., but hydrogen peroxide is usually 1 in terms of hydrogen peroxide, where the molar concentration of all cyan including complex cyan is 1. It is preferable to add to cyanide-containing wastewater so as to have a concentration of equimolar or higher. If hydrogen peroxide is less than 1 mole, assuming that the molar concentration of all cyan including complex cyan is 1, sufficient cyan removal effect may not be obtained.
  • the specific concentration of hydrogen peroxide is, for example, 1.0, 1.5, 2.0, 2.5, in terms of hydrogen peroxide (equivalent mole), where the molar concentration of all cyan including complex cyan is 1.
  • More preferable hydrogen peroxide is 1 to 10 equimolar, more preferably 2 to 5 equimolar, assuming that the molar concentration of all cyan including complex cyan is 1.
  • the aqueous solution of hydrogen peroxide or hydrogen peroxide supply compound as hydrogen peroxide in the complex cyanine-containing wastewater.
  • a copper compound aqueous solution as a copper compound may be added simultaneously or separately.
  • the hydrogen peroxide supply compound include the compounds exemplified in the section of (hydrogen peroxide).
  • the copper compound and hydrogen peroxide in the form of an aqueous solution, the concentration of which is added to the complex cyanide-containing wastewater, along with an effective amount for the total cyanide concentration in the wastewater.
  • the reactivity between the complex cyanide and the added compound, etc. may be appropriately determined.
  • the complex cyanide-containing wastewater treatment method of the present invention allows a complex cyanide-containing wastewater to coexist with a cuprous compound and hydrogen peroxide under the conditions of pH 6 to 9, or pH 6 to And a complex cyanide in the wastewater is treated by coexisting a cupric compound and hydrogen peroxide under the condition of No. 8.
  • the mixed solution it is preferable to stir the mixed solution uniformly at the time of addition of the copper compound and hydrogen peroxide and at the time of reaction of these added compounds and complex cyanate in terms of the effect of removing complex cyanide.
  • This stirring is preferably carried out every time each drug is added.
  • the temperature of the mixed solution is preferably heated to some extent, but about 20 to 60 ° C. is sufficient.
  • the time required for the reaction during stirring varies depending on the amount of cyanide-containing wastewater, the type and concentration of cyanide, the form of the treatment apparatus and the scale thereof, and so on, so that cyan and the added compound are in sufficient contact. Just decide.
  • the stirring time may be 10 minutes to 6 hours, more preferably 20 to 60 minutes.
  • the complex cyanide-containing wastewater is subjected to the condition of pH 6 to 9, or after the addition of the cupric compound and hydrogen peroxide, If water-insoluble salts produced under the conditions of pH 6-8 of cyan-containing wastewater are present, they may be removed.
  • the pH of the complex cyanine-containing wastewater is not in the range of 6-9 or 6-8, the pH of the treated wastewater may be adjusted to the above range by a known method.
  • an acid or alkali that does not interfere with the reaction in the treatment of the present invention such as sulfuric acid or sodium hydroxide, may be added to the treatment wastewater.
  • known agents such as an antifoaming agent, a polymer flocculant, a rust inhibitor, a corrosion inhibitor, a scale dispersant, and a slime control agent are used within the range not inhibiting the effects of the present invention. May be used in combination.
  • a known apparatus such as a thickener and a turbidity sedimentation basin can be used, and a surfactant may be added to the treated wastewater as long as the effects of the present invention are not hindered.
  • the total cyan concentration including complex cyanide can be reduced to 1.5 mg / L or less, preferably 1 mg / L or less, and the copper concentration is reduced to 3 mg / L or less, preferably 1 mg / L or less. be able to.
  • cyan-containing water having the water quality shown in Table 1 prepared as follows was used as cyan-containing waste water.
  • Cyan-containing water was prepared using an aqueous potassium ferrocyanide solution, an aqueous potassium cyanide solution, an aqueous calcium chloride dihydrate solution, an aqueous sodium chloride solution, an aqueous sodium sulfate solution, and an aqueous sodium hydrogen carbonate solution.
  • aqueous solution was used as an additive agent.
  • Cuprous aqueous solution 70% of 35% hydrochloric acid (special grade reagent, manufactured by Kishida Chemical Co., Ltd.), cuprous chloride 20 g (special grade reagent, manufactured by Kishida Chemical Co., Ltd.) and 10 g of water are dissolved and used.
  • Cupric aqueous solution cupric sulfate pentahydrate (reagent, manufactured by Kishida Chemical Co., Ltd.
  • sodium bisulfite was added to the cyan waste water as a reducing agent so as to be 100 mg / L.
  • test water was used with a stirrer (manufactured by Miyamoto Seisakusho Co., Ltd., jar tester (sample water agglomeration reactor), model: MJS-6, stirrer blade shape: two blades, stirrer blade maximum diameter 60 mm). And stirred for 60 minutes at 120 rpm. After stirring, the test water was No. It filtered with 5C filter paper, the total cyan density

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Removal Of Specific Substances (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

L'invention concerne un procédé de traitement d'eaux usées contenant un complexe de cyanure, le procédé comprenant l'ajout, aux eaux usées contenant un complexe de cyanure, d'un mélange d'un composé cuivreux et de peroxyde d'hydrogène dans des conditions de pH de 6 à 9, ou d'un mélange d'un composé cuprique et de peroxyde d'hydrogène dans des conditions de pH de 6 à 8, afin de traiter le complexe de cyanure contenu dans les eaux usées.
PCT/JP2016/076483 2015-10-29 2016-09-08 Procédé de traitement d'eaux usées contenant un complexe de cyanure et agent de traitement pour utilisation dans ledit procédé WO2017073177A1 (fr)

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CN201680058302.1A CN108137358B (zh) 2015-10-29 2016-09-08 含氰配合物废水的处理方法及用于该方法的处理剂
KR1020187013511A KR102071241B1 (ko) 2015-10-29 2016-09-08 시아나이드 착물 함유 폐수의 처리방법 및 그것에 사용하는 처리제

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JP2015-213328 2015-10-29
JP2015213328A JP6145682B2 (ja) 2015-10-29 2015-10-29 錯シアン含有廃水の処理方法およびそれに用いる処理剤

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CN113307350A (zh) * 2021-04-21 2021-08-27 南昌航空大学 一种电镀废水中重金属快速沉淀和cod高效去除的高级氧化工艺

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JP7290511B2 (ja) 2018-08-24 2023-06-13 日鉄環境株式会社 シアン含有水の処理方法及び処理設備
JP7157192B2 (ja) * 2020-03-04 2022-10-19 日鉄環境株式会社 水処理方法
KR20230065575A (ko) 2021-11-05 2023-05-12 신태욱 시안화수소 함유 배기가스 및 폐수 처리방법
JP7454092B1 (ja) 2023-08-08 2024-03-21 日鉄環境株式会社 集塵水の処理方法

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CN113307350A (zh) * 2021-04-21 2021-08-27 南昌航空大学 一种电镀废水中重金属快速沉淀和cod高效去除的高级氧化工艺

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CN108137358B (zh) 2021-03-23
JP2017080699A (ja) 2017-05-18
CN108137358A (zh) 2018-06-08
KR102071241B1 (ko) 2020-01-30
KR20180069852A (ko) 2018-06-25
JP6145682B2 (ja) 2017-06-14

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