WO2016089156A2 - 중합체 및 이를 포함하는 고분자 전해질막 - Google Patents
중합체 및 이를 포함하는 고분자 전해질막 Download PDFInfo
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- WO2016089156A2 WO2016089156A2 PCT/KR2015/013213 KR2015013213W WO2016089156A2 WO 2016089156 A2 WO2016089156 A2 WO 2016089156A2 KR 2015013213 W KR2015013213 W KR 2015013213W WO 2016089156 A2 WO2016089156 A2 WO 2016089156A2
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- 0 CC(C)c1cc(C)ccc1* Chemical compound CC(C)c1cc(C)ccc1* 0.000 description 2
- JEKYOIXTLBPQQS-UHFFFAOYSA-N CC(CC=C1)C=C1[IH]c1cc(C)cc(C)c1 Chemical compound CC(CC=C1)C=C1[IH]c1cc(C)cc(C)c1 JEKYOIXTLBPQQS-UHFFFAOYSA-N 0.000 description 1
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- C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
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Definitions
- the present specification relates to a polymer and a polymer electrolyte membrane including the same.
- a fuel cell is an energy conversion device that converts chemical energy of a fuel directly into electrical energy.
- a fuel cell is a power generation method that uses fuel gas and an oxidant and generates electric power by using electrons generated during the redox reaction.
- the membrane electrode assembly (MEA) of a fuel cell is a portion in which an electrochemical reaction between hydrogen and oxygen occurs and is composed of a cathode, an anode, and an electrolyte membrane, that is, an ion conductive electrolyte membrane.
- a redox flow battery (redox flow battery) is an electrochemical storage device that stores the chemical energy of an active material directly as electrical energy by charging and discharging the active material contained in the electrolyte. to be.
- the unit cell of the redox flow battery includes an electrode, an electrolyte, and an ion exchange membrane (electrolyte membrane).
- Fuel cells and redox flow cells are being researched and developed as next generation energy sources due to their high energy efficiency and eco-friendly features with low emissions.
- the key components of fuel cell and redox flow cell are polymer electrolyte membranes capable of cation exchange, including 1) excellent proton conductivity 2) prevention of crossover of electrolyte, 3) strong chemical resistance, 4) mechanical It is desirable to have properties of enhanced physical properties and / or 4) low swelling ratio.
- the polymer electrolyte membrane is classified into fluorine-based, partially fluorine-based, hydrocarbon-based, and the like, and the partial fluorine-based polymer electrolyte membrane has a fluorine-based main chain, which has advantages of excellent physical and chemical stability and high thermal stability.
- the partial fluorine-based polymer electrolyte membrane has a cation transfer functional group attached to the end of the fluorine-based chain, and thus has the advantages of a hydrocarbon-based polymer electrolyte membrane and a fluorine-based polymer electrolyte membrane.
- the partial fluorine-based polymer electrolyte membrane has a problem that the cation conductivity is relatively low because the fine phase separation of the cation transport functional group and the control of the aggregation phenomenon are not effectively performed. Therefore, research has been conducted toward securing high cationic conductivity through the control of the distribution of sulfonic acid groups and microphase separation.
- the present specification is to provide a polymer and a polymer electrolyte membrane including the same.
- A is -SO 3 H, -SO 3 - M + , -COOH, -COO - M + , -PO 3 H 2 , -PO 3 H - M + , -PO 3 2- 2M + , -O (CF 2 ) m SO 3 H, -O (CF 2 ) m SO 3 - M + , -O (CF 2 ) m COOH, -O (CF 2 ) m COO - M + , -O (CF 2 ) m PO 3 H 2, -O (CF 2) m PO 3 H - m + , or -O (CF 2) m PO 3 2- 2M + , and
- n 2 to 6
- M is a group 1 element
- R1 and R2 are the same as or different from each other, and each independently a halogen group
- n is an integer from 2 to 10
- the structures in the 2 to 10 parentheses are the same or different from each other
- X is S; O; CO; SO; SO 2 ; NR; Hydrocarbon-based or fluorine-based conjugates,
- l is an integer from 0 to 10
- Y1 and Y2 are the same as or different from each other, and each independently NRR; An aromatic ring substituted with one or two or more substituents selected from the group consisting of a hydroxy group and a halogen group; Or an aliphatic ring substituted with one or two or more substituents selected from the group consisting of a hydroxy group and a halogen group,
- R is an aromatic ring substituted with a halogen group; Or an aliphatic ring substituted with a halogen group,
- Z is a trivalent organic group.
- the present specification provides a polymer electrolyte membrane including the polymer.
- the present specification provides a reinforcing film comprising the polymer.
- the present specification is an anode; Cathode; And it provides a membrane-electrode assembly comprising the above-described polymer electrolyte membrane provided between the anode and the cathode.
- the present specification is an anode; Cathode; And it provides a membrane-electrode assembly comprising the above-described reinforcement film provided between the anode and the cathode.
- the present specification includes two or more of the aforementioned membrane-electrode assemblies; A stack comprising a bipolar plate provided between the membrane-electrode assemblies; A fuel supply unit supplying fuel to the stack; And it provides a polymer electrolyte fuel cell comprising an oxidant supply unit for supplying an oxidant to the stack.
- the present specification is a positive electrode cell comprising a positive electrode and a positive electrode electrolyte;
- a cathode cell comprising a cathode and a cathode electrolyte; And it provides a redox flow battery comprising the above-described polymer electrolyte membrane provided between the cathode cell and the anode cell.
- the present specification is a positive electrode cell comprising a positive electrode and a positive electrode electrolyte;
- a cathode cell comprising a cathode and a cathode electrolyte; And it provides a redox flow battery comprising the above-described reinforcement film provided between the positive electrode cell and the negative electrode cell.
- a polymer electrolyte membrane including a polymer according to one embodiment of the present specification easily forms a hydrophilic-hydrophobic phase separation structure.
- the polymer electrolyte membrane effectively forms a hydrophilic channel in the polymer electrolyte membrane by controlling the phase separation structure.
- the polymer electrolyte membrane has excellent proton conductivity.
- the result is a high performance of fuel cells and / or redox flow cells comprising the same.
- FIG. 1 is a schematic diagram illustrating a principle of electricity generation of a fuel cell.
- FIG. 2 is a view schematically showing an embodiment of a redox flow battery.
- FIG 3 is a view schematically showing an embodiment of a fuel cell.
- 5 is a diagram showing the reactivity according to the bonding position of the polymer of the present invention.
- an S atom is used as the linker of the [] structure and the benzene ring in Chemical Formula 1.
- S atom due to the electron withdrawing character of-[CR1R2] n -A linked by S atoms, it is possible to provide a polymer that is easy to form and stable.
- R1 and R2 are the same as or different from each other, and are each independently a halogen group. Specifically, R1 and R2 are each independently F; Cl; Br; And I can be selected from the group consisting of.
- n is an integer of 2 to 10. In another embodiment of the present specification, n is an integer of 2 to 6.
- a monomer including a unit of Formula 1 may control the number of n.
- it may serve to facilitate the phase separation phenomenon of the polymer electrolyte membrane, it is possible to facilitate the movement of hydrogen ions in the polymer electrolyte membrane.
- n is 2.
- n 3.
- n 4.
- n is 5.
- n is 6.
- n 7.
- n 8.
- n 9.
- n 10
- A is -SO 3 H or -SO 3 - M + .
- A is -SO 3 H.
- any of formulas A 1 -SO 3 H or -SO 3 - M + may be the case, form a stable polymer chemically.
- M is a Group 1 element.
- the Group 1 element may be Li, Na, or K.
- the unit represented by Chemical Formula 1 is represented by any one of the following Chemical Formulas 1-1 to 1-9.
- the polymer is a random polymer.
- a polymer having a high molecular weight can be obtained by a simple polymerization method.
- the polymer includes 0.001 wt% to 10 wt% of the unit represented by Chemical Formula 1.
- the brancher derived from the compound represented by Formula 2 or the brancher represented by Formula 3 includes 0.001% by weight to 10% by weight.
- the content of the unit represented by the formula (1) and / or different from the unit represented by the formula (1) is 80% by weight to 99.8% by weight.
- Units different from the unit represented by the formula (1) in the present specification may be selected from the unit that improves the mechanical strength of the polymer, if the unit that can improve the mechanical strength is not limited to the kind thereof.
- the unit represented by Formula 1 serves to control the ionic conductivity of the separator.
- the random polymer includes a brancher (brancher).
- Branchers herein serve to link or crosslink the polymer chains.
- the brancher may directly constitute the main chain of the polymer and may improve the mechanical density of the thin film.
- the unit derived from the compound may mean a unit connected to the main chain of the polymer.
- the unit may be included in the main chain in the polymer to constitute the polymer.
- the brancher derived from the compound of Formula 4 in the present specification is an aromatic ring substituted with a halogen group of each of the Y1 and Y2; Or a halogen group in the aliphatic ring substituted with a halogen group may act as a branch while being separated from the aromatic ring or aliphatic ring. Specifically, two or more halogen groups may fall off and act as a brancher in the polymer.
- substituted means that a hydrogen atom bonded to a carbon atom of the compound is replaced with another substituent, and the position to be substituted is not limited to a position where the hydrogen atom is substituted, that is, a position where a substituent can be substituted, if two or more substituted , Two or more substituents may be the same or different from each other.
- the hydrocarbon-based means an organic compound consisting of only carbon and hydrogen, and includes a straight chain, branched chain, cyclic hydrocarbon, and the like, but is not limited thereto. In addition, it may include a single bond, a double bond or a triple bond, but is not limited thereto.
- the hydrocarbon system may mean CH 2 .
- the fluorine-based conjugate means that some or all of the carbon-hydrogen bonds in the hydrocarbon system are substituted with fluorine.
- the aromatic ring may be an aromatic hydrocarbon ring or an aromatic hetero ring, and may be monocyclic or polycyclic.
- aromatic hydrocarbon ring monocyclic aromatic and naphthyl groups, binaphthyl groups, anthracenyl groups, phenanthrenyl groups, pyrenyl groups, peryllenyl groups, tetrasenyl groups, chrysenyl groups such as phenyl groups, biphenyl groups and terphenyl groups
- polycyclic aromatics such as fluorenyl group, acenaphthasenyl group, triphenylene group, and fluoranthene group, and the like.
- the aromatic heterocycle means a structure including one or more hetero atoms such as O, S, N, Se, or the like instead of a carbon atom in the aromatic hydrocarbon ring.
- thiophene group, furan group, pyrrole group, imidazole group, thiazole group, oxazole group, oxadiazole group triazole group, pyridyl group, bipyridyl group, pyrimidyl group, triazine group, triazole group, acridil group, Pyridazine group, pyrazinyl group, quinolinyl group, quinazoline group, quinoxalinyl group, phthalazinyl group, pyrido pyrimidinyl group, pyrido pyrazinyl group, pyrazino pyrazinyl group, isoquinoline group, indole group, Carbazole group, benzoxazole group, benzoimid
- the aliphatic ring may be an aliphatic hydrocarbon ring or an aliphatic hetero ring, and may be monocyclic or polycyclic.
- Examples of the aliphatic ring include a cyclopentyl group, a cyclohexyl group, and the like, but are not limited thereto.
- an organic group an alkyl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, an aryl group, an aralkyl group, etc. are mentioned.
- This organic group may contain the bond and substituents other than hydrocarbon groups, such as a hetero atom, in the said organic group.
- the organic group may be any of linear, branched and cyclic.
- the trivalent organic group means a trivalent group having three bonding positions in an organic compound.
- the organic group may form a cyclic structure, may form a cyclic structure, and may include a hetero atom to form a bond as long as the effects of the invention are not impaired.
- the bond containing hetero atoms such as an oxygen atom, a nitrogen atom, and a silicon atom
- hetero atoms such as an oxygen atom, a nitrogen atom, and a silicon atom
- the cyclic structure may include the aforementioned aromatic ring, aliphatic ring, and the like, and may be monocyclic or polycyclic.
- the alkyl group may be linear or branched chain, carbon number is not particularly limited, but is preferably 1 to 50. Specific examples include, but are not limited to, methyl, ethyl, propyl, isopropyl, butyl, t-butyl, pentyl, hexyl and heptyl groups.
- the alkenyl group may be linear or branched chain, the carbon number is not particularly limited, but is preferably 2 to 40.
- Specific examples include vinyl, 1-propenyl, isopropenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 3-methyl-1- Butenyl, 1,3-butadienyl, allyl, 1-phenylvinyl-1-yl, 2-phenylvinyl-1-yl, 2,2-diphenylvinyl-1-yl, 2-phenyl-2- ( Naphthyl-1-yl) vinyl-1-yl, 2,2-bis (diphenyl-1-yl) vinyl-1-yl, stilbenyl group, styrenyl group and the like, but are not limited thereto.
- the cycloalkyl group is not particularly limited, but preferably has 3 to 60 carbon atoms, and especially cyclopentyl group, cyclohexyl group, and the like, but is not limited thereto.
- l is 3 or more.
- X is S.
- X is a haloalkyl group.
- X is CH 2 .
- X is NR.
- Y1 and Y2 are the same as or different from each other, and are each independently a halogen substituted aromatic ring.
- Y1 and Y2 are the same as or different from each other, and are each independently a fluorine-substituted aromatic hydrocarbon ring.
- Y1 and Y2 are the same as or different from each other, and are NRR.
- Y1 and Y2 are each a fluorine substituted phenyl group.
- 2,4-phenyl, 2,6-phenyl, 2,3-phenyl, 3,4-phenyl and the like are not limited thereto.
- the compound represented by Formula 2 may be represented by any one of the following structures.
- Z in Chemical Formula 3 may be represented by any one of the following Chemical Formulas 3-1 to 3-4.
- L1 To L7 are the same as or different from each other, and each independently a direct bond; -S-; -O-; -CO-; Or -SO 2- ,
- R10 to R20 are the same as or different from each other, and each independently hydrogen; heavy hydrogen; Halogen group; Cyano group; Nitrile group; Nitro group; Hydroxyl group; Substituted or unsubstituted alkyl group; A substituted or unsubstituted cycloalkyl group; Substituted or unsubstituted alkoxy group; Substituted or unsubstituted alkenyl group; Substituted or unsubstituted aryl group; Or a substituted or unsubstituted heteroaryl group,
- a, b, c, f, h, i and j are each an integer of 1 to 4,
- d, e and g are each an integer of 1 to 3
- k is an integer from 1 to 6
- L1 is CO
- L1 is SO 2 .
- L1 is S.
- L2 is CO
- L2 is SO 2 .
- L2 is S.
- L3 is CO.
- L3 is SO 2 .
- L3 is S.
- L4 is CO
- L4 is SO 2 .
- L5 is a direct bond
- L6 is a direct bond
- L7 is a direct bond
- R10 to R20 are hydrogen.
- R16 is a halogen group.
- R16 is fluorine
- brancher represented by Chemical Formula 3 may be represented by any one of the following structures.
- the weight average molecular weight of the polymer is 500 g / mol to 5,000,000 g / mol.
- the mechanical properties of the electrolyte membrane including the polymer are not lowered, and the solubility of the polymer may be maintained to facilitate the preparation of the electrolyte membrane.
- the present disclosure provides a polymer electrolyte membrane including the polymer described above.
- electrolyte membrane is a membrane capable of exchanging ions, such as membrane, ion exchange membrane, ion transfer membrane, ion conductive membrane, separator, ion exchange membrane, ion transfer membrane, ion conductive separator, ion exchange electrolyte membrane, ion And a transfer electrolyte membrane or an ion conductive electrolyte membrane.
- the polymer electrolyte membrane according to one embodiment of the present specification may be manufactured using materials and / or methods known in the art, except for including the polymer including the unit represented by Chemical Formula 1.
- the ion conductivity of the polymer electrolyte membrane is 0.01 S / cm to 0.5 S / cm. In another exemplary embodiment, the ion conductivity of the polymer electrolyte membrane is 0.01 S / cm or more and 0.3 S / cm or less.
- the ionic conductivity of the polymer electrolyte membrane may be measured under humidification conditions.
- the humidification condition may mean 10% to 100% relative humidity (RH).
- the ion exchange capacity (IEC) value of the polymer electrolyte membrane is 0.01 mmol / g to 5 mmol / g.
- IEC ion exchange capacity
- the thickness of the polymer electrolyte membrane is 1 ⁇ m to 500 ⁇ m.
- the polymer electrolyte membrane having the above range thickness lowers electric short and crossover of electrolyte material, and may exhibit excellent cation conductivity characteristics. If the thickness is too thin, the exchange of hydrogen ions is easy, but problems such as a decrease in mechanical strength and / or an increase in vanadium migration may occur. Within this range, it is possible to easily exchange hydrogen ions and maintain appropriate mechanical strength.
- the substrate In one embodiment of the present specification, the substrate; And it provides a reinforcing film comprising the polymer described above.
- the 'reinforcement membrane' is an electrolyte membrane including a substrate that is a reinforcing material, and a membrane capable of exchanging ions, and includes a substrate, an ion exchange membrane, an ion transfer membrane, and an ion conductive membrane.
- Separator ion exchange membrane, ion transfer membrane, ion conductive separator, ion exchange electrolyte membrane, ion transfer electrolyte membrane or ion conductive electrolyte membrane and the like.
- the substrate may mean a support having a three-dimensional network structure
- the reinforcing film including the substrate and the polymer may include one surface of the polymer, a surface facing the surface, and a pore region inside the substrate. It may mean that it is included in at least part of. That is, the reinforcing film of the present specification may be provided in a form in which the polymer is impregnated into the substrate.
- the polymer is the same as described above.
- the reinforcing membrane according to the exemplary embodiment of the present specification includes a polymer including the unit represented by Chemical Formula 1, has high mechanical strength and high ionic conductivity, and may facilitate phase separation of the reinforcing membrane.
- the reinforcing film according to the exemplary embodiment of the present specification may include a substrate, thereby increasing chemical resistance and durability, and thus improving the life of the device.
- the substrate is one or two species in the group consisting of polypropylene (PP), polytetrafluoroethylene (PTFE), polyethylene (PE) and polyvinylidene difluoride (PVDF) Is selected.
- PP polypropylene
- PTFE polytetrafluoroethylene
- PE polyethylene
- PVDF polyvinylidene difluoride
- the content of the polymer is 10 parts by weight to 99 parts by weight with respect to 100 parts by weight of the reinforcing film.
- the polymer content is 10 parts by weight to 99 parts by weight with respect to 100 parts by weight of the reinforcing film, and the content of the substrate is 1 part by weight to 90 parts by weight.
- the crossover of vanadium ions may be reduced, and as the content of the polymer increases, the performance of the battery may be improved.
- the ion conductivity of the reinforcing film is 0.001 S / cm or more and 0.5 S / cm or less. In another exemplary embodiment, the ion conductivity of the reinforcing film is 0.001 S / cm or more and 0.3 S / cm or less.
- the ion conductivity may be measured under the same conditions as the aforementioned method.
- the ion exchange capacity (IEC) value of the reinforcing membrane is 0.01 mmol / g to 5.0 mmol / g.
- IEC ion exchange capacity
- the thickness of the reinforcement film is 0.01 ⁇ m to 10,000 ⁇ m.
- the thickness of the reinforcement film may reduce the electric short and the crossover of the electrolyte material, and may exhibit excellent cationic conductivity characteristics.
- the present disclosure also provides a method for preparing a substrate; And it provides a method for producing a strengthening film comprising the step of impregnating the substrate with a polymer comprising a unit represented by the formula (1).
- Impregnation in the present specification means that the polymer permeates into the substrate.
- the impregnation may be performed by dipping the substrate into the polymer, using a slot dye coating, bar casting, or the like.
- immersion may be expressed in terms such as dip coating or dipping method.
- the reinforcing film may have a directionality.
- the substrate may be manufactured by uniaxial stretching or biaxial stretching, and the orientation of the substrate by the stretching may determine the orientation of the reinforcing film. Therefore, the reinforcing film according to the exemplary embodiment of the present specification may have a directionality of the machine direction (MD) and the vertical direction of the machine direction (MD), and the reinforcing film may be stressed and elongated according to the direction.
- MD machine direction
- MD vertical direction of the machine direction
- the physical properties of can represent a difference.
- the present disclosure also provides a method for preparing a substrate; And it provides a method for producing a reinforcing film comprising the step of immersing the substrate in the polymer.
- the substrate and the polymer are as described above.
- the present specification also relates to an anode; Cathode; And it provides a membrane-electrode assembly comprising the above-described polymer electrolyte membrane provided between the anode and the cathode.
- the present specification also relates to an anode; Cathode; And it provides a membrane-electrode assembly comprising the above-described reinforcement film provided between the anode and the cathode.
- Membrane-electrode assembly is an electrode (cathode and anode) in which the electrochemical catalysis of fuel and air occurs and a polymer membrane in which hydrogen ions are transferred.
- the electrode (cathode and anode) and the electrolyte membrane are bonded together. It is a single unitary unit.
- the membrane-electrode assembly of the present specification is a form in which the catalyst layer of the anode and the catalyst layer of the cathode are in contact with the electrolyte membrane, and may be prepared according to conventional methods known in the art.
- the cathode; Anode; And it may be prepared by thermocompression bonding at 100 °C to 400 °C in a state in which the electrolyte membrane located between the cathode and the anode in close contact.
- the anode electrode may include an anode catalyst layer and an anode gas diffusion layer.
- the anode gas diffusion layer may again include an anode microporous layer and an anode electrode substrate.
- the cathode electrode may include a cathode catalyst layer and a cathode gas diffusion layer.
- the cathode gas diffusion layer may further include a cathode microporous layer and a cathode electrode substrate.
- FIG. 1 schematically illustrates the principle of electricity generation of a fuel cell.
- the most basic unit for generating electricity is a membrane electrode assembly (MEA), which is an electrolyte membrane 100 and the electrolyte membrane 100. It consists of an anode (200a) and a cathode (200b) electrode formed on both sides of the.
- MEA membrane electrode assembly
- an anode 200a generates an oxidation reaction of a fuel such as hydrogen or a hydrocarbon such as methanol and butane to generate hydrogen ions (H +) and electrons (e ⁇ ). Hydrogen ions move to the cathode 200b through the electrolyte membrane 100.
- water is generated by reacting hydrogen ions transferred through the electrolyte membrane 100 with an oxidant such as oxygen and electrons. This reaction causes the movement of electrons in the external circuit.
- the catalyst layer of the anode electrode is where the oxidation reaction of the fuel occurs, the catalyst is selected from the group consisting of platinum, ruthenium, osmium, platinum-ruthenium alloy, platinum-osmium alloy, platinum-palladium alloy and platinum-transition metal alloy. Can be used.
- the catalyst layer of the cathode electrode is where the reduction reaction of the oxidant occurs, platinum or platinum-transition metal alloy may be preferably used as a catalyst.
- the catalysts can be used on their own as well as supported on a carbon-based carrier.
- the introduction of the catalyst layer may be carried out by conventional methods known in the art, for example, the catalyst ink may be directly coated on the electrolyte membrane or coated on the gas diffusion layer to form the catalyst layer.
- the coating method of the catalyst ink is not particularly limited, but spray coating, tape casting, screen printing, blade coating, die coating or spin coating may be used.
- Catalytic inks can typically consist of a catalyst, a polymer ionomer, and a solvent.
- the gas diffusion layer serves as a passage for the reaction gas and water together with a role as a current conductor, and has a porous structure. Therefore, the gas diffusion layer may include a conductive substrate. As the conductive substrate, carbon paper, carbon cloth, or carbon felt may be preferably used.
- the gas diffusion layer may further include a microporous layer between the catalyst layer and the conductive substrate. The microporous layer may be used to improve the performance of the fuel cell in low-humidity conditions, and serves to reduce the amount of water flowing out of the gas diffusion layer so that the electrolyte membrane is in a sufficient wet state.
- One embodiment of the present specification includes two or more membrane-electrode assemblies; A stack comprising a bipolar plate provided between the membrane-electrode assemblies; A fuel supply unit supplying fuel to the stack; And it provides a polymer electrolyte fuel cell comprising an oxidant supply unit for supplying an oxidant to the stack.
- the membrane-electrode assembly includes the aforementioned polymer electrolyte membrane or includes a reinforcement membrane.
- a fuel cell is an energy conversion device that converts chemical energy of a fuel directly into electrical energy.
- a fuel cell is a power generation method that uses fuel gas and an oxidant and generates electric power by using electrons generated during the redox reaction.
- the fuel cell can be manufactured according to conventional methods known in the art using the membrane-electrode assembly (MEA) described above.
- MEA membrane-electrode assembly
- it may be prepared by configuring a membrane electrode assembly (MEA) and a bipolar plate (bipolar plate) prepared above.
- the fuel cell of the present specification includes a stack, a fuel supply unit and an oxidant supply unit.
- FIG. 3 schematically illustrates the structure of a fuel cell, in which the fuel cell includes a stack 60, an oxidant supply unit 70, and a fuel supply unit 80.
- the stack 60 includes one or two or more membrane electrode assemblies as described above, and includes two or more separators interposed therebetween when two or more membrane electrode assemblies are included.
- the separator serves to prevent the membrane electrode assemblies from being electrically connected and to transfer fuel and oxidant supplied from the outside to the membrane electrode assembly.
- the oxidant supply unit 70 serves to supply the oxidant to the stack 60.
- Oxygen is typically used as the oxidizing agent, and may be used by injecting oxygen or air into the pump 70.
- the fuel supply unit 80 serves to supply fuel to the stack 60, and to the fuel tank 81 storing fuel and the pump 82 supplying fuel stored in the fuel tank 81 to the stack 60.
- fuel hydrogen or hydrocarbon fuel in gas or liquid state may be used.
- hydrocarbon fuels include methanol, ethanol, propanol, butanol or natural gas.
- the fuel cell may be a polymer electrolyte fuel cell, a direct liquid fuel cell, a direct methanol fuel cell, a direct formic acid fuel cell, a direct ethanol fuel cell, or a direct dimethyl ether fuel cell.
- the electrolyte membrane according to one embodiment of the present specification is used as an ion exchange membrane of a fuel cell, the above-described effects can be obtained.
- an exemplary embodiment of the present specification includes a positive electrode cell including a positive electrode and a positive electrode electrolyte; A cathode cell comprising a cathode and a cathode electrolyte; And it provides a redox flow battery comprising a polymer electrolyte membrane according to one embodiment of the present specification provided between the cathode cell and the anode cell.
- a positive electrode cell including a positive electrode and a positive electrode electrolyte;
- a cathode cell comprising a cathode and a cathode electrolyte; And it provides a redox flow battery comprising a reinforcing film according to an embodiment of the present disclosure provided between the positive electrode and the negative electrode cell.
- the redox flow battery (redox flow battery) is an electrochemical storage device that stores the chemical energy of an active material directly as electrical energy. It is a system in which the active material contained in the electrolyte is oxidized, reduced, and charged and discharged. to be.
- the redox flow battery uses a principle that charges and discharges are exchanged when electrons containing active materials having different oxidation states meet with an ion exchange membrane interposed therebetween.
- a redox flow battery is composed of a tank containing an electrolyte solution, a battery cell in which charging and discharging occurs, and a circulation pump for circulating the electrolyte solution between the tank and the battery cell, and the unit cell of the battery cell includes an electrode, an electrolyte, and an ion. Exchange membrane.
- the electrolyte membrane according to one embodiment of the present specification is used as an ion exchange membrane of a redox flow battery, the above-described effects may be exhibited.
- the redox flow battery of the present specification may be manufactured according to conventional methods known in the art, except for including the polymer electrolyte membrane according to one embodiment of the present specification.
- the redox flow battery is divided into the positive electrode cell 32 and the negative electrode cell 33 by the electrolyte membrane 31.
- the anode cell 32 and the cathode cell 33 include an anode and a cathode, respectively.
- the anode cell 32 is connected to the anode tank 10 for supplying and discharging the anode electrolyte 41 through a pipe.
- the cathode cell 33 is also connected to the cathode tank 20 for supplying and discharging the cathode electrolyte 42 through a pipe.
- the electrolyte is circulated through the pumps 11 and 21, and an oxidation / reduction reaction (that is, a redox reaction) in which the oxidation number of ions changes occurs, thereby causing charge and discharge at the anode and the cathode.
- an oxidation / reduction reaction that is, a redox reaction
- Example 1 2,5-dihydroxybenzenesulfonic acid (2,5-dihydroxybenzenesulfonic acid) is used instead of the unit represented by Formula 1 of the present specification, and [1,1'-biphenyl] -4,4 4,4 '-(9H-fluorene-9,9-diyl) diphenol (4,4'- instead of' -diol ([1,1'-biphenyl] -4,4'-diol) Hydrocarbon polymer was polymerized except that (9H-fluorene-9,9-diyl) diphenol) was used.
- Figure 4 is a view showing the ion conductivity at the humidification conditions of Examples and Comparative Examples.
- the ion conductivity of the comparative example is 0.56 mS / cm
- the ion conductivity of the polymer of the example is 4.4 mS / cm, which is about 8 times the performance of the comparative example. You can see the improvement. Therefore, it can be confirmed that the polymer electrolyte membrane including the polymer according to one embodiment of the present specification has high ionic conductivity.
- N / A means not available, and it can be seen that the polymer is not formed.
- Example 1 the monomer having a functional group substituted in the 2,5 position that is commonly used in the prior art, the reactivity is significantly different during the polymerization reaction, depending on the nature of the functional group substituted in the other position Nevertheless, it has been used commercially without consideration of reactivity.
- the 2,4-difluoro halogenated compound according to an exemplary embodiment of the present specification has a characteristic that the functional group of Formula 1, which is dependent on a pendant, exhibits the properties of the electron attractor as a whole.
- the reactivity is greatly improved and it can be seen that there is an advantage in obtaining a high molecular weight polymer.
- 5 is a diagram showing the reactivity according to the bonding position of the polymer of the present invention.
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Abstract
Description
부분 불소계막 | Mn (g/mol) | Mw (g/mol) | Mw/Mn |
실시예 1 | 84,000 | 622,000 | 7.40 |
비교예 2 | N/A | N/A | N/A |
비교예 3 | N/A | N/A | N/A |
Claims (16)
- 하기 화학식 1로 표시되는 단위; 및하기 화학식 2 로 표시되는 화합물로부터 유래되는 브랜쳐 또는 하기 화학식 3으로 표시되는 브랜쳐를 포함하는 랜덤 중합체:[화학식 1][화학식 2][화학식 3]상기 화학식 1 내지 3에 있어서,A는 -SO3H, -SO3 -M+, -COOH, -COO-M+, -PO3H2, -PO3H-M+, -PO3 2-2M+, -O(CF2)mSO3H, -O(CF2)mSO3 -M+, -O(CF2)mCOOH, -O(CF2)mCOO-M+, -O(CF2)mPO3H2, -O(CF2)mPO3H-M+ 또는 -O(CF2)mPO3 2-2M+이고,m은 2 내지 6의 정수이며,M은 1족 원소이고,R1 및 R2는 서로 동일하거나 상이하고, 각각 독립적으로 할로겐기이며,n은 2 내지 10의 정수이며, 2 내지 10 개의 괄호 내의 구조는 서로 동일하거나 상이하고,X는 S; O; CO; SO; SO2; NR; 탄화수소계 또는 불소계 결합체이며,l은 0 내지 10의 정수이고,l이 2 이상인 경우, 2 이상의 X는 서로 동일하거나 상이하며,Y1 및 Y2는 서로 동일하거나 상이하고, 각각 독립적으로 NRR; 히드록시기 및 할로겐기로 이루어진 군에서 선택되는 치환기로 1 또는 2 이상 치환된 방향족고리; 또는 히드록시기 및 할로겐기로 이루어진 군에서 선택되는 치환기로 1 또는 2 이상 치환된 지방족 고리이며,R은 할로겐기로 치환된 방향족고리; 또는 할로겐기로 치환된 지방족 고리이고,Z는 3가의 유기기이다.
- 청구항 1에 있어서,A는 -SO3H 또는 -SO3 -M+ 인 것인 랜덤 중합체.
- 청구항 1에 있어서,n은 2 내지 6의 정수인 것인 랜덤 중합체.
- 청구항 1에 있어서,상기 랜덤 중합체의 중량평균분자량은 500 g/mol 내지 5,000,000 g/mol 인 것인 중합체.
- 청구항 1 내지 6 중 어느 한 항에 따른 랜덤 중합체를 포함하는 고분자 전해질막.
- 기재; 및청구항 1 내지 6 중 어느 한 항에 따른 랜덤 중합체를 포함하는 강화막.
- 청구항 7에 있어서,상기 고분자 전해질막의 이온 전도도는 0.01 S/cm 내지 0.5 S/cm 인 것인 고분자 전해질막.
- 청구항 7에 있어서,상기 고분자 전해질막의 이온교환용량(IEC) 값은 0.01 mmol/g 내지 5 mmol/g 인 것인 고분자 전해질막.
- 애노드; 캐소드; 및 상기 애노드와 상기 캐소드 사이에 구비된 청구항 7의 고분자 전해질막을 포함하는 막-전극 접합체.
- 2 이상의 청구항 11에 따른 막-전극 접합체;상기 막-전극 접합체들 사이에 구비되는 바이폴라 플레이트를 포함하는 스택;상기 스택으로 연료를 공급하는 연료공급부; 및상기 스택으로 산화제를 공급하는 산화제공급부를 포함하는 고분자 전해질형 연료전지.
- 양극 및 양극 전해액을 포함하는 양극 셀;음극 및 음극 전해액을 포함하는 음극 셀; 및상기 양극 셀과 상기 음극 셀 사이에 구비되는 청구항 7의 고분자 전해질막을 포함하는 레독스 플로우 전지.
- 애노드; 캐소드; 및 상기 애노드와 상기 캐소드 사이에 구비된 청구항 8의 강화막을 포함하는 막-전극 접합체.
- 2 이상의 청구항 14에 따른 막-전극 접합체;상기 막-전극 접합체들 사이에 구비되는 바이폴라 플레이트를 포함하는 스택;상기 스택으로 연료를 공급하는 연료공급부; 및상기 스택으로 산화제를 공급하는 산화제공급부를 포함하는 고분자 전해질형 연료전지.
- 양극 및 양극 전해액을 포함하는 양극 셀;음극 및 음극 전해액을 포함하는 음극 셀; 및상기 양극 셀과 상기 음극 셀 사이에 구비되는 청구항 8의 강화막을 포함하는 레독스 플로우 전지.
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EP15864737.0A EP3228643B1 (en) | 2014-12-04 | 2015-12-04 | Polymer and polymer electrolyte membrane comprising same |
JP2017526701A JP6447942B2 (ja) | 2014-12-04 | 2015-12-04 | 重合体およびこれを含む高分子電解質膜 |
US15/531,662 US10407521B2 (en) | 2014-12-04 | 2015-12-04 | Polymer and polymer electrolyte membrane comprising same |
CN201580066214.1A CN107001623B (zh) | 2014-12-04 | 2015-12-04 | 聚合物和包含该聚合物的聚合物电解质膜 |
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EP (1) | EP3228643B1 (ko) |
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KR (1) | KR101973693B1 (ko) |
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KR20160067720A (ko) | 2014-12-04 | 2016-06-14 | 주식회사 엘지화학 | 중합체 및 이를 포함하는 고분자 전해질막 |
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EP3228643A4 (en) | 2018-04-25 |
JP6447942B2 (ja) | 2019-01-09 |
EP3228643B1 (en) | 2019-10-09 |
KR20160067792A (ko) | 2016-06-14 |
CN107001623B (zh) | 2019-03-05 |
CN107001623A (zh) | 2017-08-01 |
JP2018504463A (ja) | 2018-02-15 |
WO2016089156A3 (ko) | 2016-07-21 |
US10407521B2 (en) | 2019-09-10 |
KR101973693B1 (ko) | 2019-04-29 |
US20170327607A1 (en) | 2017-11-16 |
EP3228643A2 (en) | 2017-10-11 |
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