WO2015058683A1 - 一种水性防腐蚀树脂 - Google Patents

一种水性防腐蚀树脂 Download PDF

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WO2015058683A1
WO2015058683A1 PCT/CN2014/089107 CN2014089107W WO2015058683A1 WO 2015058683 A1 WO2015058683 A1 WO 2015058683A1 CN 2014089107 W CN2014089107 W CN 2014089107W WO 2015058683 A1 WO2015058683 A1 WO 2015058683A1
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acid
parts
substance
epoxy resin
resin
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PCT/CN2014/089107
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French (fr)
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程建军
秦文
王英
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北京金汇利应用化工制品有限公司
廊坊金汇利工业涂料有限公司
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Publication of WO2015058683A1 publication Critical patent/WO2015058683A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C08G18/581—Reaction products of epoxy resins with less than equivalent amounts of compounds containing active hydrogen added before or during the reaction with the isocyanate component
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2150/00—Compositions for coatings
    • C08G2150/90—Compositions for anticorrosive coatings

Definitions

  • the invention relates to an aqueous anti-corrosion resin, belonging to the field of anti-corrosion materials.
  • Waterborne epoxy resin has been widely used due to its low VOC content, low price and good construction performance.
  • the commonly used methods for water-based epoxy resin are mechanical method, reverse conversion method, and self-emulsification method.
  • the water-based epoxy resin prepared by the mechanical method and the reverse conversion method has a large particle size and contains an emulsifier, which affects the anti-corrosion effect.
  • the multi-functional amine curing agent is applied to the protection of the substrate such as cement concrete, and the metal corrosion protection. The field is rarely used.
  • the self-emulsification method is a method in which a hydrophilic substance such as a carboxylic acid group or a sulfonic acid group is introduced into an epoxy resin by a chemical method to form an aqueous solution by salt formation.
  • the waterborne epoxy resin obtained by this method has a smaller particle size, the coating film is more dense, and the corrosion resistance is improved to some extent, but some or all of the hydrophilic substances such as carboxylic acid and sulfonic acid remain in the coating film, and water is encountered. It becomes an ionic form again, which has a negative impact on the water resistance and corrosion resistance of the film.
  • the technical problem to be solved by the present invention is to provide a self-drying or baking type water-based anticorrosive resin, which solves the deficiencies in the prior art, obtains an epoxy resin having a small particle diameter, improves the density of film formation, and also enhances The coating film is resistant to water and corrosion.
  • an aqueous anti-corrosion resin synthesized from the following raw materials: 40 to 98 parts of epoxy resin, 0.5 to 50 parts of acid substance, 0 to 80 parts of modified substance, 0 to 60 An organic solvent and 0.2 to 18 parts of an organic amine, 0 to 110 parts of deionized water.
  • the modifying substance is selected from one or more of polycyanates, vinyl monomers, peroxides or organic acids.
  • the water-based anticorrosive resin and the water-based anticorrosive resin as described above preferably have a raw material range of 45 to 75 parts of an epoxy resin, 0.5 to 5 parts of an acid substance, 10 to 30 parts of a modifying substance, and 20 to 50 parts of an organic solvent. And 5 to 10 parts of organic amine, 50 to 100 parts of deionized water.
  • the epoxy resin is a bisphenol A epoxy resin or a bisphenol F epoxy resin, and has an epoxy equivalent range of 150 to 3,500.
  • the modifying substance includes toluene diisocyanate (TDI), hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI) or diphenylmethane diisocyanate (MDI), and an adduct thereof Or trimer, acrylic acid, methacrylic acid, methyl methacrylate, butyl acrylate, hydroxyethyl acrylate, styrene, soybean oleic acid, linoleic acid, dehydrated ricinoleic acid, leaf oleic acid, adipic acid One or several.
  • One or more of the organic solvent ethylene glycol monobutyl ether, propylene glycol methyl ether, propylene glycol methyl ether acetate, butanol or alcohol ester 12, N-methylpyrrolidone, diethylene glycol butyl ether.
  • the acid substance is one or more of hydrochloric acid, sulfuric acid, phosphoric acid, pyrophosphoric acid, polyphosphoric acid, citric acid or tartaric acid.
  • the organic amine is one or more of triethylamine, monomethylethanolamine, N,N-dimethylethanolamine or triethanolamine.
  • the preparation method of the aqueous anti-corrosion resin as described above includes the following steps:
  • the aqueous anti-corrosion resin is obtained by dropwise addition of 0 to 110 parts of deionized water.
  • the invention has the beneficial effects that the aqueous anti-corrosion resin of the invention is prepared by a self-emulsification method, and at the same time, the hydrophilic group can be deactivated with the metal substrate, and is adsorbed on the metal substrate in an orderly manner, thereby improving the coating.
  • the film is resistant to water and corrosion.
  • Pencil hardness ⁇ 4H Impact resistance (cm) 50 Flexibility First level Adhesion ⁇ 1 level Salt spray resistance ⁇ 1000hr
  • the waterborne anticorrosive resin consists of the following weight components: E12 epoxy resin 98g, soybean 16 g of oil fatty acid, 60 g of propylene glycol methyl ether, 0.5 g of tartaric acid, 0.2 g of N,N dimethylethanolamine, and 73 g of deionized water.
  • the preparation method of the aqueous anticorrosive resin comprises the following steps:
  • a water-based anticorrosive resin was obtained by slowly adding 73 g of deionized water at 70 to 80 °C.
  • the aqueous anticorrosive resin was composed of the following components: 82 g of E51 epoxy resin, 70 g of adipic acid, 10 g of urethane monomer diphenylmethane diisocyanate (MDI), 25 g of tartaric acid, and 18 g of N,N dimethylethanolamine.
  • MDI urethane monomer diphenylmethane diisocyanate
  • the preparation method of the aqueous anticorrosive resin comprises the following steps:
  • the aqueous anticorrosive resin was composed of the following components: E03 epoxy resin 75 g, ethylene glycol monobutyl ether 40 g, phosphoric acid 3 g, triethylamine 8 g, and deionized water 100 g.
  • the preparation method of the aqueous anticorrosive resin comprises the following steps:
  • the aqueous anticorrosive resin is composed of the following components: E20 epoxy resin 60g, ethylene glycol monobutyl ether 10g, phosphoric acid 32g, styrene 15g, butyl acrylate 10g, benzoyl peroxide 0.5g, triethylamine 3g, Deionized water 55g.
  • the preparation method of the aqueous anticorrosive resin comprises the following steps:
  • the aqueous anticorrosive resin was composed of the following components: 40 g of E51 epoxy resin, 52 g of coconut oil fatty acid, 25 g of propylene glycol methyl ether, 50 g of phosphoric acid, 5 g of N,N dimethylethanolamine, and 36 g of deionized water.
  • the preparation method of the aqueous anticorrosive resin comprises the following steps:
  • a water-based anticorrosive resin was obtained by slowly adding 36 g of deionized water at 70 to 80 °C.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Resins (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

本发明涉及一种水性防腐蚀树脂，由以下组分合成：40～98份环氧树脂，0.5～50份酸类物质，0～80份改性物质，0～60份有机溶剂和0.2～18份有机胺，去离子水0～110份，所述改性物质选自多氰酸酯类，乙烯基类单体、过氧化物或者有机酸中的一种或几种，此发明得到粒径较小的环氧树脂，从而提高了成膜的致密程度，同时也增强了涂膜耐水及耐腐蚀性能，用于自干型或者烘烤型防腐蚀涂料树脂。

Description

一种水性防腐蚀树脂 技术领域
本发明涉及一种水性防腐蚀树脂，属于防腐蚀材料领域。
背景技术
水性环氧树脂因VOC含量低，价格低廉，施工性能好，已被广泛应用。目前常用的环氧树脂水性化的方法有机械法、相反转法、自乳化法。其中机械法、相反转法制备的水性环氧树脂，粒径较大，且含有乳化剂，影响了其防腐蚀效果，多配合胺类固化剂应用于水泥混凝土等基材保护，在金属防腐蚀领域很少使用。自乳化法是通过化学方法在环氧树脂中，引入羧酸基，磺酸基等亲水物质通过成盐的方式实现水性化。这种方法得到的水性环氧树脂粒径较小，涂膜更致密，耐腐蚀性能得到了一定的提高，但羧酸、磺酸等亲水物质部分或全部残留在涂膜，遇到水会再度变为离子形式，对涂膜的耐水，耐腐蚀性能造成了负面影响。
发明内容
本发明所要解决的技术问题是提供一种自干或烘烤型水性防腐树脂，解决现有技术中的不足，得到粒径较小的环氧树脂，提高了成膜的致密程度，同时也增强了涂膜耐水及耐腐蚀性能。
本发明达到以上技术效果的技术方案如下：一种水性防腐蚀树脂，由以下原料合成：40～98份环氧树脂，0.5～50份酸类物质，0～80份改性物质，0～60份有机溶剂和0.2～18份有机胺，0～110份去离子水。所述改性物质选自多氰酸酯类，乙烯基类单体、过氧化物或者有机酸中的一种或几种。
如上所述之水性防腐蚀树脂，水性防腐蚀树脂，其原料优选范围为：45～75份环氧树脂，0.5～5份酸类物质，10～30份改性物质，20～50份有机溶剂和5～10份有机胺，50～100份去离子水。
所述环氧树脂为双酚A类环氧树脂或双酚F类环氧树脂，其环氧当量范围为150～3500。
进一步，所述改性物质包括甲苯二异氰酸酯(TDI)、六亚甲基二异氰酸酯(HDI)、异佛尔酮二异氰酸酯(IPDI)或二苯基甲烷二异氰酸酯(MDI)，以及其加成物或三聚体，丙烯酸，甲基丙烯酸，甲基丙烯酸甲酯，丙烯酸丁酯，丙烯酸羟乙酯、苯乙烯、大豆油酸、亚麻油酸，脱水蓖麻油酸、叶子油酸、己二酸中的一种或几种。
所述有机溶剂乙二醇单丁醚、丙二醇甲醚、丙二醇甲醚醋酸酯、丁醇或醇酯十二、N-甲基吡咯烷酮，二乙二醇丁醚中的一种或几种。
所述酸类物质为盐酸、硫酸、磷酸、焦磷酸、多聚磷酸、柠檬酸或酒石酸中的一种或几种。
所述有机胺为三乙胺、单甲基乙醇胺、N,N二甲基乙醇胺或三乙醇胺中的一种或几种。
如上所述水性防腐蚀树脂的制备方法，包括以下步骤：
(1)加入40～98份环氧树脂，0～80份改性物质，升温至90℃～150℃下搅拌反应至酸值小于3mgKOH/g；
(2)添加0～60份有机溶剂，
(3)在90～150℃加入0.5～50份酸类物质，在90～150℃下保温搅拌2～3hr；
(4)降温至70～80℃，滴加0.2～18份的有机胺，搅拌保温30～50min；
(5)滴加去离子水0～110份乳化即得到所述水性防腐蚀树脂。
本发明的有益效果是：本发明的水性防腐蚀树脂采用自乳化方法制得，同时其亲水性基团可以与金属基材发生钝化，有序的吸附在金属基材上，提高了涂膜的耐水、耐腐蚀性能。
具体实施方式
以下对本发明的原理和特征进行描述，所举实例只用于解释本发明，并非用于限定本发明的范围。
本发明水性防腐树脂基本性能见表1。
表1
检测指标： 数据：
乳液粒径： ≤10um
PH: 7～9
50℃热储: ＞100天
运用本发明水性防腐树脂制备出的涂料基本性能见表2。
表2
检测指标 性能
铅笔硬度 ≥4H
耐冲击(厘米) 50
柔韧性 一级
附着力 ≤1级
耐盐雾 ≥1000hr
实施例1
水性防腐树脂由以下重量的组分组成：E12环氧树脂98g、大豆 油脂肪酸16g、丙二醇甲醚60g、酒石酸0.5g、N,N二甲基乙醇胺0.2g、去离子水73g。
水性防腐树脂的制备方法包括以下步骤：
(1)向装有搅拌器加热套的三口瓶中加入98gE12环氧树脂和16g大豆油脂肪酸；
(2)升温至140℃在搅拌的状态下反应至酸值≤3mgKOH/g；
(3)加入60g丙二醇甲醚，降温至80℃；
(4)加入0.5g酒石酸，升温至120℃保温3hr；
(5)降温至75℃，滴加0.2gN,N二甲基乙醇胺，在不停的搅拌下，保温30min；
(6)在70～80℃缓慢的加入73g去离子水即得到水性防腐树脂。
实施例2
水性防腐树脂由以下重量的组分组成：E51环氧树脂82g、己二酸70g、聚氨酯单体二苯基甲烷二异氰酸酯(MDI)10g、酒石酸25g、N,N二甲基乙醇胺18g。
水性防腐树脂的制备方法包括以下步骤：
(1)向装有搅拌器加热套的三口瓶中加入82gE51环氧树脂和70g己二酸；
(2)升温至140℃在搅拌的状态下反应至酸值≤3mgKOH/g；
(3)降温至110℃，滴加10g二苯基甲烷二异氰酸酯(MDI)单体，40min滴加完毕，95～100℃保温2hr；
(4)加入150g乙二醇单丁醚，降温至80℃；
(5)加入25g酒石酸，升温至120℃保温3hr；
(6)降温至75℃，滴加18gN,N二甲基乙醇胺，在不停的搅拌下，保温30min即得到水性防腐蚀树脂。
实施例3
水性防腐树脂由以下重量的组分组成：E03环氧树脂75g、乙二醇单丁醚40g、磷酸3g、三乙胺8g、去离子水100g。
水性防腐树脂的制备方法包括以下步骤：
(1)向装有搅拌器加热套的三口瓶中加入75gE03环氧树脂和40g乙二醇单丁醚升温至140℃，保温30min；
(2)升温至150℃，滴加入10g磷酸,150℃保温2hr；
(3)降温至90℃加入7.5g三乙胺，搅拌30min；
(4)滴加100g去离子水乳化得到水性防腐蚀环氧树脂。
实施例4
水性防腐树脂由以下重量的组分组成：E20环氧树脂60g、乙二醇单丁醚10g、磷酸32g、苯乙烯15g、丙烯酸丁酯10g、过氧化苯甲酰0.5g、三乙胺3g、去离子水55g。
水性防腐树脂的制备方法包括以下步骤：
(1)向装有搅拌器加热套的三口瓶中加入60gE20环氧树脂和10g乙二醇单丁醚升温至110℃保温；
(2)将15g苯乙烯，10g丙烯酸丁酯，0.5g过氧化苯甲酰混合均匀，缓慢均匀的滴加到三口瓶中，2hr滴加完毕。滴加完毕后110℃保温2hr；
(3)升温至150℃，滴加入32g磷酸,150℃保温2hr；
(4)降温至90℃加入3g三乙胺，搅拌30min；
(5)滴加55g去离子水乳化至所需乳液。
实施例5
水性防腐树脂由以下重量的组分组成：E51环氧树脂40g、椰子油脂肪酸52g、丙二醇甲醚25g、磷酸50g、N,N二甲基乙醇胺5g、去离子水36g。
水性防腐树脂的制备方法包括以下步骤：
(1)向装有搅拌器加热套的三口瓶中加入40gE51环氧树脂和52g椰子油脂肪酸；
(2)升温至140℃在搅拌的状态下反应至酸值≤3mgKOH/g；
(3)加入25g丙二醇甲醚，降温至80℃；
(4)加入50g磷酸，升温至120℃保温3hr；
(5)降温至75℃，滴加5gN,N二甲基乙醇胺，在不停的搅拌下，保温30min；
(6)在70～80℃缓慢的加入36g去离子水即得到水性防腐树脂。
以上所述仅为本发明的较佳实施例，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (7)

  1. 一种水性防腐蚀树脂，其特征在于，由以下原料合成：40～98份环氧树脂，0.5～50份酸类物质，0～80份改性物质，0～60份有机溶剂和0.2～18份有机胺，0～110份去离子水；所述改性物质选自多氰酸酯类，乙烯基类单体、过氧化物或者有机酸中的一种或几种。
  2. 如权利要求1所述之水性防腐蚀树脂，其特征在于，其原料范围为：45～75份环氧树脂，0.5～5份酸类物质，10～30份改性物质，20～50份有机溶剂和5～10份有机胺，50～100份去离子水。
  3. 如权利要求1或2所述之水性防腐蚀树脂，其特征在于：所述环氧树脂为双酚A类环氧树脂或双酚F类环氧树脂，其环氧当量范围为150～3500。
  4. 如权利要求1或2所述之水性防腐蚀树脂，其特征在于：所述改性物质包括甲苯二异氰酸酯(TDI)、六亚甲基二异氰酸酯(HDI)、异佛尔酮二异氰酸酯(IPDI)或二苯基甲烷二异氰酸酯(MDI)，以及其加成物或三聚体，丙烯酸，甲基丙烯酸，甲基丙烯酸甲酯，丙烯酸丁酯，丙烯酸羟乙酯、苯乙烯、大豆油酸、亚麻油酸，脱水蓖麻油酸、叶子油酸、己二酸、过氧化苯甲酰中的一种或几种。
  5. 如权利要求1或2所述之水性防腐蚀树脂，其特征在于：所述有机溶剂乙二醇单丁醚、丙二醇甲醚、丙二醇甲醚醋酸酯、丁醇或醇酯十二、N-甲基吡咯烷酮，二乙二醇丁醚中的一种或几种。
  6. 如权利要求1或2所述之水性防腐蚀树脂，其特征在于：所述酸类物质为盐酸、硫酸、磷酸、焦磷酸、多聚磷酸、柠檬酸或酒石酸中的一种或几种。
  7. 如权利要求1或2所述之水性防腐蚀树脂，其特征在于：所述 有机胺为三乙胺、单甲基乙醇胺、N,N二甲基乙醇胺或三乙醇胺中的一种或几种。
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106047106A (zh) * 2016-07-19 2016-10-26 成都拜迪新材料有限公司 利用回收油脂制作水性有机硅改性绦纶树脂乳液的方法
CN112239527A (zh) * 2019-07-18 2021-01-19 中石化石油工程技术服务有限公司 一种适用于抗co2腐蚀水泥浆体系的防腐蚀剂及制备方法
CN116023859A (zh) * 2023-03-02 2023-04-28 广州翔铭环保新材料有限公司 一种用于保护钢材质的水性钢结构漆的制备方法

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103554409A (zh) * 2013-10-21 2014-02-05 北京金汇利应用化工制品有限公司 一种水性防腐树脂及其制备方法
CN104193963B (zh) * 2014-09-17 2017-06-23 上海涂料有限公司技术中心 一种阳离子型水性环氧乳液
CN104628987A (zh) * 2014-12-30 2015-05-20 武汉源长科工贸有限责任公司 一种乙烯基环氧磷酸聚氨酯的配方及其制备工艺
CN104611691B (zh) * 2015-02-05 2017-03-29 陕西凯利清洗有限公司 一种用于碳钢管道或碳钢管件的有机钝化剂及其应用方法
CN105037687B (zh) * 2015-08-22 2018-02-23 深圳市优和新材料有限公司 一种水溶性异氰酸酯改性环氧树脂及其生产工艺
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CN116042073B (zh) * 2023-02-10 2024-03-26 中国科学院长春应用化学研究所 一种二氧化碳基水性聚氨酯锈转化树脂及其制备方法
CN117625027A (zh) * 2023-12-18 2024-03-01 山东冠彩包装印务有限公司 一种高强度海洋运输用化工桶防腐缓蚀剂及其制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007070435A (ja) * 2005-09-06 2007-03-22 Furukawa Sky Kk 親水性被覆下地用樹脂組成物、アルミニウム合金塗装板及びその製造方法
CN101117377A (zh) * 2007-09-18 2008-02-06 天津大学 水性环氧树脂的制备方法
CN101838396A (zh) * 2009-03-19 2010-09-22 上海涂料有限公司技术中心 一种自乳化水性环氧乳液的制备方法
CN101899196A (zh) * 2010-07-29 2010-12-01 华南理工大学 一种水性酚醛环氧树脂乳液及其制备方法
CN102161731A (zh) * 2010-09-30 2011-08-24 山东斯泰普力高新建材有限公司 水性环氧树脂乳液的制备方法及其应用方法
CN102786774A (zh) * 2012-07-23 2012-11-21 张家港市丰昌防腐材料有限公司 一种烘烤涂料用水分散环氧树脂及其制备方法
CN103554409A (zh) * 2013-10-21 2014-02-05 北京金汇利应用化工制品有限公司 一种水性防腐树脂及其制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4442246A (en) * 1978-06-12 1984-04-10 Scm Corporation Aqueous coating composition comprising self-emulsifiable ester of epoxy and acid containing addition polymer
TW502043B (en) * 1999-08-09 2002-09-11 Chinese Petroleum Corp Process for preparing self-emulsified aqueous epoxy resin dispersion, single-pack double curable aqueous resin composition comprising the same and single-pack curable composition of aqueous hybrid resin comprising the same
CN100532480C (zh) * 2002-10-24 2009-08-26 同济大学 一种水性环氧树脂涂料及其制备方法
CN101157751B (zh) * 2007-09-28 2010-05-19 西安交通大学 水性环氧树脂及制备方法、用水性环氧树脂制备清漆的方法
CN101864146B (zh) * 2010-06-13 2012-02-15 宏昌电子材料股份有限公司 印刷电路覆铜板用环氧树脂组合物
CN101899136A (zh) * 2010-07-22 2010-12-01 中科院广州化灌工程有限公司 一种改性酚醛树脂及其在防腐涂料中应用
CN102225986A (zh) * 2011-04-21 2011-10-26 苏州巨峰电气绝缘系统股份有限公司 环保型无溶剂浸渍树脂及其制备方法
CN102432831B (zh) * 2011-08-30 2013-07-24 华南理工大学 一种常温自干的单组份水性环氧树脂乳液及其制备方法
CN102504494B (zh) * 2011-09-22 2013-06-12 长春工业大学 一种单组分环氧树脂灌封料及其制备方法
CN103554386B (zh) * 2013-10-22 2016-06-01 北京金汇利应用化工制品有限公司 一种自乳化双组份环氧树脂的制备方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007070435A (ja) * 2005-09-06 2007-03-22 Furukawa Sky Kk 親水性被覆下地用樹脂組成物、アルミニウム合金塗装板及びその製造方法
CN101117377A (zh) * 2007-09-18 2008-02-06 天津大学 水性环氧树脂的制备方法
CN101838396A (zh) * 2009-03-19 2010-09-22 上海涂料有限公司技术中心 一种自乳化水性环氧乳液的制备方法
CN101899196A (zh) * 2010-07-29 2010-12-01 华南理工大学 一种水性酚醛环氧树脂乳液及其制备方法
CN102161731A (zh) * 2010-09-30 2011-08-24 山东斯泰普力高新建材有限公司 水性环氧树脂乳液的制备方法及其应用方法
CN102786774A (zh) * 2012-07-23 2012-11-21 张家港市丰昌防腐材料有限公司 一种烘烤涂料用水分散环氧树脂及其制备方法
CN103554409A (zh) * 2013-10-21 2014-02-05 北京金汇利应用化工制品有限公司 一种水性防腐树脂及其制备方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
HU , DENGHUA ET AL.: "Synthesis of Self-emulsifying Aqueous Epoxy Resin", JOURNAL OF WUHAN INSTITUTE OF TECHNOLOGY, vol. 33, no. 8, 31 August 2011 (2011-08-31), pages 45 - 48 *
SHEN, XIN ET AL.: "Exploratory Research on Self-Emulsified Epoxy Emulsion for Waterborne Anti-Corrosive Coatings", MODERN PAINT & FINISHING, 31 December 2005 (2005-12-31), pages 11 - 13 *
YANG, XUNLAN ET AL.: "Study on Properties of Methacrylate-modified Epoxy Resin Latex", ADHESION, vol. 27, no. 1, 31 December 2006 (2006-12-31), pages 20 - 22 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106047106A (zh) * 2016-07-19 2016-10-26 成都拜迪新材料有限公司 利用回收油脂制作水性有机硅改性绦纶树脂乳液的方法
CN112239527A (zh) * 2019-07-18 2021-01-19 中石化石油工程技术服务有限公司 一种适用于抗co2腐蚀水泥浆体系的防腐蚀剂及制备方法
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