WO2013127111A1 - 单腔双电极放电腔及准分子激光器 - Google Patents
单腔双电极放电腔及准分子激光器 Download PDFInfo
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- WO2013127111A1 WO2013127111A1 PCT/CN2012/073018 CN2012073018W WO2013127111A1 WO 2013127111 A1 WO2013127111 A1 WO 2013127111A1 CN 2012073018 W CN2012073018 W CN 2012073018W WO 2013127111 A1 WO2013127111 A1 WO 2013127111A1
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- H01S3/14—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range characterised by the material used as the active medium
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- H01S3/223—Gases the active gas being polyatomic, i.e. containing two or more atoms
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- H01S3/2383—Parallel arrangements
Definitions
- the present invention relates to the field of laser technologies, and in particular to a single-cavity two-electrode discharge chamber for lithography and an excimer laser including the same, and the discharge chamber of the present invention can also It is applied to devices where other gases are excited to generate energy radiation.
- Excimer lasers are conventional gas lasers for ultraviolet characterization applications and are currently considered to be the best source of light for lithography and are the primary source of work for the lithography industry of integrated circuits.
- the conventional discharge excitation excimer laser adopts a single cavity single electrode structure design.
- light sources are required to have narrower spectral widths (linewidths), higher repetition rates, and higher average power.
- Traditional single-cavity structures are difficult to meet these three requirements at the same time, which often leads to serious constraints on the pursuit of performance and cost-effectiveness in laser research.
- the difficulties in improving the single-cavity structure of conventional lasers are mainly due to the large energy loss of the linewidth narrowing module and the damage and life of optical components under high power laser radiation.
- a dual cavity structure is introduced into the design of the laser.
- the basic idea of this structure is to narrow the line width and increase the laser output power in different gas discharge modules (seed chamber, amplification chamber).
- the working process is as follows: The seed cavity generates narrow line width seed light with a certain repetition frequency to realize low power laser oscillation radiation; the amplification cavity completes the pulse energy amplification after the seed light is incident.
- the laser output based on the dual cavity design provides the narrow spectral control and higher single pulse energy output characteristics necessary for the lithographic light source.
- Lasers based on dual-cavity design can continuously optimize the main and amplification modules, and improve system output indicators, such as optimizing the composition and pressure of the working gas mixture and excitation operating voltage to obtain laser output with narrow linewidth and high power.
- the power amplifier based on the amplification cavity The large mechanism, the relatively low laser output in the main oscillator, can significantly increase the lifetime of the optical components in the linewidth narrowing module. Since the laser based on the dual cavity structure design has the above advantages, the "seed-amplification" mechanism laser structure design is widely used in the development of modern laser lithography light sources.
- the dual-cavity structure design is mainly divided into the following three categories: main oscillation cavity - double-cavity structure (MOPA, Master Oscillator Power Amplifier) of the main oscillation cavity power oscillation cavity (MOPO, Master Oscillator Power Oscillator) and Main Oscillator Power Regenerative Amplifier (MOPRA) based on the dual-cavity structure of the power amplifying cavity.
- MOPA main oscillation cavity - double-cavity structure
- MOPO Master Oscillator Power Oscillator
- MOPRA Main Oscillator Power Regenerative Amplifier
- a dual-cavity MOPA excimer laser includes a main oscillation cavity (MO cavity) 101, a power amplification cavity (PA cavity) 102, and a line width voltage.
- Narrow module (LNM) 103 wavelength analysis module (LAM) 104, MO optical path conversion control module (MO web) 105, PA optical path conversion control module (PA web) 106, optical pulse stretcher (OPS) 107, line width analysis module (BAM) 108, pentaprism 109, automatic shutter 110 and the like.
- the MOPA structure is the earliest application of the laser system design for the development of high-end lithographic light sources, which is described in the patents US2002/0044586A1, US20060126697AK US6690704B2. According to the literature "Development of ArF Excimer Laser Technology for Photolithography", pp. 523-524, in the MOPA structure, due to the limited magnification of the cavity, the limitation of the laser energy amplification makes the MO cavity (main oscillation cavity) more The high laser energy output can meet the requirements of the index parameters of the light source system.
- the MO cavity output needs about lmJ to transmit the seed light to the PA cavity (power amplification cavity), and the higher energy introduced by the line width narrowing mechanism Loss, conversion efficiency is relatively low, and high-energy discharge excitation makes the life of the MO cavity significantly lower.
- the output of the PA cavity is affected by the accuracy of the discharge of the MO cavity and the PA cavity, and the stability of the laser energy output needs to be further improved.
- the MOPO structure based on Injection Lock Technology and the MOPRA structure using Recirculating Ring Technology compensate for the above-mentioned shortcomings of the MOPA structure.
- 2 is a structural diagram of a prior art dual-cavity MOPO excimer laser.
- the dual-cavity MOPO excimer laser includes: a power oscillation cavity (PO cavity) 201, a power amplification cavity (PA cavity) 202, and a line width.
- Patent US2008/0285602A1 adopts MOPO double cavity structure design.
- FIG. 3 is a structural diagram of a prior art dual-cavity MOPRA excimer laser.
- the dual-cavity MOPRA excimer laser structure is an improvement on the MOPA structure, and the structure is like MOPA, but the PA optical path conversion control module is only
- the (PA web) 306 is aligned with the position of the linewidth analysis module (BAM) 308 so that the seed light can obtain multi-pass gain.
- BAM linewidth analysis module
- Patent US2010098120A1 adopts MOPRA annular cavity structure design.
- the seed light In the MOPA structure, the seed light only obtains a finite multi-pass gain in the PA cavity, and the MO cavity needs to inject about lmJ seed light into the PA cavity to obtain a laser output of about 10 mJ.
- the amplification cavity uses multi-pass power amplification technology instead of the finite multi-pass amplification such as the MOPA structure
- the PO cavity And the PRA cavity power regeneration cavity
- the seed light obtains the multi-pass gain, and only 15-200 ⁇ seed light injection is required to obtain the 15mJ laser output.
- the remarkable feature of the injection locking technique and the annular cavity technology is that after the seed light is injected, the resonance reciprocates in the amplification cavity, and the amplification cavity operates in a deep saturation state. Compared with MOPA technology, their advantages are mainly reflected in: greater energy and more stable output.
- the MOPA, MOPO, and MOPRA systems are all based on a dual discharge cavity type design.
- lasers with dual-cavity designs are more expensive, larger, and more complex to fabricate and operate.
- the laser designed based on the dual-cavity structure is required to ensure good energy amplification characteristics, and the discharge performance of the same is relatively high, which improves the technical difficulty in achieving the same-state discharge.
- the operation difficulty of peripheral mounting and the like is increased to some extent.
- the technical problem to be solved by the present invention is to propose a novel single-cavity two-electrode discharge chamber and a corresponding laser to solve the problem based on the double cavity.
- the structure of the laser has the disadvantages of high price, large volume, complicated manufacturing process and operation method, and can realize high-quality laser beam output with narrow line width and high power.
- the single-chamber two-electrode discharge chamber comprises a cavity and two sets of main discharge electrodes, the cavity comprising two left and right chambers to form a symmetrical double-chamber structure cavity shape, and each chamber has a cross-sectional shape that is small and small.
- the large shape, the left and right chambers meet and communicate at the symmetry plane of the entire discharge chamber; the two sets of main discharge electrodes are respectively located in the left and right chambers, and the discharge areas thereof are respectively located at the upper portions of the left and right chambers.
- Each of the main discharge electrodes includes an anode and a cathode, and a discharge region is formed between the anode and the discharge surface of the cathode.
- Each of the cathodes is mounted on an insulating plate, and the insulating plate is suspended from the top ends of the left and right chambers; each of the anodes is fixed on an anode base, and the anode base is fixed to the cavity Above, its position is such that the anode is parallel and facing the cathode.
- the single-chamber two-electrode discharge chamber of the present invention further includes a bead and a peaking capacitor, and the peaking capacitor (10) is used for discharging energy storage; the insulating plate is fixed to the discharge chamber by the bead; the bead is located at the The outer side of the insulating plate is connected to one end of the peaking capacitor through a copper piece, and forms a ground loop with the cavity.
- the other end of the peaking capacitor is connected to a high voltage pulse power supply through a metal strip.
- the single-chamber two-electrode discharge chamber of the present invention further includes a pre-ionization device located on both sides of the main discharge electrode.
- the pre-ionization device has two sets, which are respectively located on two sides of each set of main discharge electrodes.
- the pre-ionization device has a set that is located on either side of the main discharge electrode of the upstream discharge zone.
- the pre-ionization device includes upper and lower portions, each portion including a ceramic tube and a pre-ionization electrode, and the pre-ionization electrode is located inside the ceramic tube.
- the ceramic tube of the upper pre-ionization device is fixed to the cathode by an insulator, and the ceramic tube of the lower pre-ionization device is fixed to the anode through an insulator.
- Each of the anodes is coupled to a cavity of the discharge chamber by a set of copper sheets.
- the single-chamber two-electrode discharge chamber of the present invention also includes a fan system that drives the gas within the discharge chamber.
- the single-chamber two-electrode discharge chamber of the present invention further includes a heat dissipation system that dissipates heat from the discharge chamber.
- the single-chamber two-electrode discharge chamber of the present invention further includes a dust removal system that dedusts the gas in the discharge chamber.
- the single-chamber two-electrode discharge chamber of the present invention further includes a noise reduction system for performing noise reduction processing on the discharge chamber.
- the present invention also provides a single cavity dual electrode MOPA laser comprising the single cavity dual electrode discharge chamber previously described.
- the present invention also provides a single cavity dual electrode MOPO laser comprising the single cavity dual electrode discharge chamber previously described.
- the present invention also provides a single cavity dual electrode MOPRA laser comprising the single cavity dual electrode discharge chamber previously described.
- the invention changes two single-cavity single-electrode structures in a MOPA, MOPRA or MOPO laser system into a single-chamber two-electrode structure, so that MOPA (single-cavity MOPA) and MOPO (single-chamber MOPO) can be realized by a single-chamber structure.
- MOPA single-cavity MOPA
- MOPO single-chamber MOPO
- the dual-cavity function of the structure not only reduces the complexity of the system, but also ensures the discharge homogeneity of the discharge chamber.
- the use of a single-cavity structure facilitates the integration and assembly of optical components on the periphery of the discharge chamber, which simplifies the laser system.
- a single-cavity, two-electrode laser can also achieve two laser outputs simultaneously.
- the single-chamber two-electrode structure can effectively reduce the complexity of the laser system, thereby Reduce the difficulty of peripheral adjustment operations.
- a single-cavity, two-electrode laser can achieve the output of two narrow linewidth, high power, superior laser beams.
- FIG. 1 is a structural diagram of a prior art dual cavity MOPA excimer laser
- FIG. 2 is a structural diagram of a prior art dual cavity MOPO excimer laser
- FIG. 3 is a structural diagram of a prior art dual cavity MOPRA excimer laser
- FIG. 4 is a structural diagram of a discharge chamber of a single-cavity two-electrode excimer laser according to an embodiment of the present invention
- FIG. 5 is a detailed structural view of a discharge region of a laser according to an embodiment of the present invention.
- FIG. 6 is a structural diagram of noise reduction of a discharge region of a laser according to an embodiment of the present invention.
- FIG. 7 is a schematic diagram of pre-ionization of a laser discharge chamber of an embodiment of the present invention.
- FIG. 8 is a structural diagram of a single-cavity MOPA excimer laser according to an embodiment of the present invention
- FIG. 9 is a structural diagram of a single-cavity MOPRA excimer laser according to an embodiment of the present invention
- FIG. 10 is a single-chamber MOPO excimer laser structure according to an embodiment of the present invention.
- 11 is a two-channel laser output system of a single-cavity two-electrode excimer laser according to an embodiment of the invention.
- the discharge chamber mainly comprises a discharge chamber body 1, two sets of main discharge electrodes, two sets of gas circulation systems, a heat dissipation system, a dust removal device and a high voltage pulse charging module 4.
- the discharge chamber 1 is a closed gas container designed to perform a relevant standard for a pressure vessel for storing a corrosive mixed gas of 3 to 6 atm, such as an excimer-containing halogen gas including F 2 gas. .
- the discharge chamber of the present invention comprises two chambers on the left and the right to form a symmetrical bi-chamber structure, and the cross-sectional shape of each chamber is a shape that is small and large, such as a "pear" shape as shown in Fig. 4.
- the dual chambers interface and communicate at the symmetry plane of the entire discharge chamber.
- the discharge chamber of the present invention comprises two sets of main discharge electrodes, which are respectively located in the left and right chambers.
- the main discharge electrode is positioned to ensure that its discharge zone 2 is located at the upper portion of the left and right chambers.
- Each set of main discharge electrodes includes an anode 6 and a cathode 3, the cathode is mounted on the insulating plate 5 by bolts, the insulating plate 5 is hoisted at the top end of the left and right chambers, and the anode 6 is fixed to the anode base 14 by screws,
- the anode base is fixed to the cavity 1 of the discharge chamber in such a position that the anode 6 and the cathode 3 are mounted in parallel with each other.
- the spacing between the two sets of main discharge electrodes ensures that the gas in the discharge zone 2 has sufficient energy density and can meet the output size requirements of the laser, and usually needs to be set to 10 ⁇ 30mm.
- the discharge chamber of the present invention further includes a high voltage pulse charging module 4 as a high voltage power source for injecting sufficient energy into the discharge region 2 of the discharge chamber, the high voltage pulse charging module 4 being located above the main discharge electrode and passing through the peaking capacitor 10 Energy is injected into the cathodes of the two sets of main discharge electrodes to provide a discharge voltage sufficient to break the working gas in the discharge zone.
- the high voltage pulse charging module 4 uses a related design based on all solid state pulsed power technology.
- the discharge region 2 refers to a space region between the anode and the cathode discharge surface, the length of which is approximately equal to the length of the electrode, and the height is equal to the cathode and anode working surfaces.
- the pitch is slightly larger than the width of the discharge surface of the electrode.
- each of the main discharge electrodes includes a cathode 3 and an anode 6, and the cathode 3 is connected to the high voltage pulse charging module 4.
- Each of the cathodes 3 is fixed to an insulating plate 5 by bolts and supported by the insulating plate 5, which is made of a material resistant to corrosion by F 2 or the like, such as a high-purity A1 2 3 3 ceramic.
- Each anode 6 is connected to a cavity 1 of a discharge chamber through a set of copper sheets 13 while the discharge chamber is grounded. At the same time, the copper sheet 13 also has the effect of homogenizing the flow field and reducing the impedance between the anode 6 and the ground.
- the discharge chamber of the present invention further comprises a bead 9 and a peaking capacitor 10, each of the insulating plates 5 being fixed to the discharge chamber by two bead 9 and sealed by a 0-ring, the bead 9 being located outside the insulating plate, and
- the copper piece is connected to one end of the peaking capacitor 10 to form a ground loop with the discharge cavity, the peaking capacitor 10 is used for discharging energy storage, and the other end is connected to the high voltage pulse power source 4 through the metal bus bar 21.
- the discharge chamber of the present invention further includes a pre-ionization device, and the pre-ionization device is located on both sides of each of the main discharge electrodes.
- the pre-ionization device comprises upper and lower parts, each part comprising a ceramic tube 7 and a pre-ionization electrode 8, the ceramic tube 7 being an insulator material, and the pre-ionization electrode 8 is located inside the ceramic tube 7, upper portion
- the ceramic tube 7 of the pre-ionization device is fixed to the cathode 3 through an insulator 17 to ensure the accuracy of the mounting position.
- the ceramic tube 7 of the lower pre-ionization device is fixed to the anode 6 through an insulator 20 to ensure the accuracy of the mounting position.
- the working gas in the laser cavity is a highly corrosive gas
- all the cavities, insulators, electrodes, etc. in contact with the gas are made of corrosion-resistant materials, wherein the cavity 1 can be made of alloy aluminum material, electrodes 3, 6, 8 Brass or aluminum bronze materials can be used, which can react with highly corrosive gases to form a dense oxide film to prevent them from reacting with highly corrosive gases for protection purposes.
- the newly produced laser cavity requires a period of passivation of the cavity 1 of the discharge chamber, such as fluorine passivation.
- pre-ionization device of the laser discharge chamber of the embodiment of the present invention Before the formation of the main discharge, a certain amount of initial electron distribution is generated by pre-ionization, causing the electrons to collapse uniformly distributed in the discharge space.
- the purpose of pre-ionization is to prevent the formation of a stream and achieve a uniform discharge.
- the flow direction of the working gas in the discharge zone is defined as upstream and downstream, wherein, in the A diagram of FIG. 7, a pre-ionization device is disposed in both the upstream discharge zone 2 and the downstream discharge zone 2,
- the so-called upstream and downstream refer to the position of the working gas in the flow process according to the sequence of the discharge zone.
- the pre-ionization device shown in Figure 7 of Figure 7 has the advantage of fully ionizing the working gas and ensuring discharge. More even. Found in the test, In the downstream discharge zone, heat accumulation is more likely to occur, so we can also use the pre-ionization apparatus shown in FIG.
- the pre-ionization apparatus employs a structure in which the insulated ceramic tube 7 has the pre-ionization electrode 8 built therein.
- the single chamber dual electrode discharge chamber in accordance with the present invention also includes a fan system. Since the laser is a pulsed discharge, in order to ensure that the gas in the discharge section is continuously updated to fresh gas during discharge, the embodiment of the present invention provides two sets of fan impellers 15 in the cavity 1 of the discharge chamber to drive the gas 16 to ensure that each The gas passing through the discharge zone 2 is a fresh gas.
- each impeller 15 is driven by a single motor or a dual motor, and the main and passive magnetic couplers are used for non-contact transmission to ensure that corrosive harmful gases in the discharge chamber are not leaked.
- the fan impeller 15 uses a cross-flow fan impeller.
- the cross-flow fan impeller is a very mature product.
- the preferred arrangement in the selection is a continuation or symmetrical structure to improve the uniformity of the flow field.
- the energy injected into the discharge chamber is relatively high, so it is required to be actively cooled.
- the present invention adopts a water-cooling method, including a heat sink 11, which is fabricated by copper processing, and the number of the heat sink 11 is based on the heat dissipation requirement. For one, it can be multiple.
- the mounting position of the heat sink can be installed at the air inlet of the impeller 15 or downstream of the flow field channel of the discharge area to ensure good heat dissipation.
- the embodiment of the heat sink is shown in the embodiment shown in FIG. Location, but the invention is not limited thereto. 5. Dust removal system for single-chamber two-electrode discharge chamber
- the gas stored in the discharge chamber generates consumables of the cavity and the electrode material during the discharge process. These impurities are irreversible and exist in the form of particles.
- electrostatic dust removal in the discharge chamber.
- Device 12 to ensure that the discharge product does not act on the electrode, Contamination caused by optical components such as Brewster windows.
- the dust removing device 12 is disposed at the downwind of the flow path of the discharge zone, as shown in FIG.
- the present invention performs noise reduction processing on the discharge chamber, and the cavity structure member near the discharge region 2 is processed into a bump.
- the uneven surface 18 prevents the shock generated by the discharge from being reflected back to the discharge area.
- a corresponding sound absorbing device 19 such as a sound absorbing plate or a sound wire mesh, is provided for absorbing shock waves generated by the discharge.
- the dual-chamber structure optical system schemes suitable for the existing MOPA, MOPO, etc. are all adapted to the single-chamber two-electrode discharge chamber of the present invention, and the discharge chamber can realize all functions of MOPA and MOPO, and also simplify the structure of the discharge chamber.
- the system improves the reliability of the system.
- Figure 8 is a structural diagram of a single-chamber two-electrode MOPA laser
- Figure 9 is a structural diagram of a single-chamber two-electrode MOPRA laser
- Figure 10 is a structural diagram of a single-chamber two-electrode MOPO laser.
- Each of the three single-chamber two-electrode lasers introduces a single-chamber two-electrode discharge chamber in place of the prior art dual-chamber structure.
- FIG. 8 is a block diagram of a single-cavity MOPA excimer laser incorporating a single-chamber two-electrode discharge chamber.
- the system includes a single-chamber two-electrode discharge chamber (DDC) 801, a linewidth narrowing module (LNM) 802, and a wavelength analysis module (LAM).
- DDC single-chamber two-electrode discharge chamber
- LNM linewidth narrowing module
- LAM wavelength analysis module
- MO web MO optical path conversion control module
- PA optical path conversion control module PA optical path conversion control module (PAweb) 805, optical pulse stretcher (OPS) 806, line width analysis module (BAM) 807, pentaprism 808, automatic shutter 809, etc.
- PPS optical pulse stretcher
- the single-chamber two-electrode discharge chamber (DDC) 801 mainly comprises a discharge chamber cavity, two sets of main discharge electrodes, two sets of gas circulation systems, a heat dissipation system, a dust removal device and a high-voltage pulse charging module.
- FIG. 9 is a structural diagram of a dual-cavity MOPO excimer laser incorporating a single-chamber two-electrode laser, the system comprising: a single-cavity two-electrode discharge chamber 901, a power oscillation chamber (PO cavity), a power amplification cavity (PA cavity), and a line width pressure a narrow module (LNM) 902, a concave mirror 903, a convex mirror 904, wherein the single-chamber two-electrode discharge chamber 901 mainly comprises a discharge chamber cavity, two sets of main discharge electrodes, two sets of gas circulation systems, a heat dissipation system, a dust removal device and a high voltage Pulse charging module.
- the single-chamber two-electrode discharge chamber 901 mainly comprises a discharge chamber cavity, two sets of main discharge electrodes, two sets of gas circulation systems, a heat dissipation system, a dust removal device and a high voltage Pulse charging module.
- Figure 10 is a structural diagram of a single-cavity MOPRA excimer laser introduced into a single-cavity two-electrode discharge chamber.
- the system composition is like MOPA, but the position of the PA optical path conversion control module (PA web) 1005 and the line width analysis module (BAM) 1007 is made. The alignment is adjusted so that the seed light can obtain multi-path gain.
- PA web PA optical path conversion control module
- BAM line width analysis module
- the output of the two lasers is realized by the single-cavity two-electrode laser.
- the system includes two high-reflection mirrors HR1102 and 1103, two output mirrors 1104 and 1105, and a single-chamber two-electrode discharge chamber 1101. .
- the output of the laser also includes two pairs of Brewster windows, as well as an output mirror, which uses the prior art to achieve the output of the two lasers.
- the single-cavity, two-electrode laser power supply is based on an all-solid-state pulsed power supply technology.
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Abstract
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Priority Applications (6)
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DK12869793.5T DK2690723T3 (en) | 2012-03-02 | 2012-03-26 | SINGLE Cavity Dual Electrode Discharge Cavity and EXCIMER LASER |
KR1020137020724A KR101493807B1 (ko) | 2012-03-02 | 2012-03-26 | 단일 챔버 이중 전극 형태의 방전 챔버 및 엑시머 레이저 기기 |
RU2013146022/07A RU2592065C2 (ru) | 2012-03-02 | 2012-03-26 | Однополостная двухэлектродная разрядная камера и эксимерный лазер |
EP12869793.5A EP2690723B1 (en) | 2012-03-02 | 2012-03-26 | Single-cavity dual-electrode discharge cavity and excimer laser |
JP2014501423A JP2014511036A (ja) | 2012-03-02 | 2012-03-26 | 単一チャンバの二重電極放電チャンバ及びエキシマレーザー |
US14/040,490 US9252557B2 (en) | 2012-03-02 | 2013-09-27 | Single cavity dual-electrode discharge cavity and excimer laser |
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CN2012100530579A CN102810810A (zh) | 2012-03-02 | 2012-03-02 | 单腔双电极放电腔及准分子激光器 |
CN201210053057.9 | 2012-03-02 |
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US14/040,490 Continuation US9252557B2 (en) | 2012-03-02 | 2013-09-27 | Single cavity dual-electrode discharge cavity and excimer laser |
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US (1) | US9252557B2 (zh) |
EP (1) | EP2690723B1 (zh) |
JP (1) | JP2014511036A (zh) |
KR (1) | KR101493807B1 (zh) |
CN (2) | CN102810810A (zh) |
DK (1) | DK2690723T3 (zh) |
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CN115912022B (zh) * | 2021-08-31 | 2024-03-29 | 北京科益虹源光电技术有限公司 | 一种双腔准分子激光器及其能量调节方法 |
Also Published As
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KR101493807B1 (ko) | 2015-02-16 |
DK2690723T3 (en) | 2019-03-11 |
JP2014511036A (ja) | 2014-05-01 |
CN103151679B (zh) | 2016-03-16 |
CN103151679A (zh) | 2013-06-12 |
RU2013146022A (ru) | 2015-04-20 |
EP2690723A1 (en) | 2014-01-29 |
RU2592065C2 (ru) | 2016-07-20 |
EP2690723B1 (en) | 2018-11-21 |
KR20140019319A (ko) | 2014-02-14 |
EP2690723A4 (en) | 2014-12-31 |
US9252557B2 (en) | 2016-02-02 |
CN102810810A (zh) | 2012-12-05 |
US20140023101A1 (en) | 2014-01-23 |
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