WO2010093208A3 - 하이드로포밀화 반응용 촉매 조성물 및 이를 이용하는 알데히드의 제조방법 - Google Patents

하이드로포밀화 반응용 촉매 조성물 및 이를 이용하는 알데히드의 제조방법 Download PDF

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WO2010093208A3
WO2010093208A3 PCT/KR2010/000921 KR2010000921W WO2010093208A3 WO 2010093208 A3 WO2010093208 A3 WO 2010093208A3 KR 2010000921 W KR2010000921 W KR 2010000921W WO 2010093208 A3 WO2010093208 A3 WO 2010093208A3
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hydroformylation
catalyst composition
same
aldehydes
preparing aldehydes
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PCT/KR2010/000921
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English (en)
French (fr)
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WO2010093208A2 (ko
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최재희
고동현
엄성식
홍무호
권오학
김대철
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(주) 엘지화학
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=42562207&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2010093208(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by (주) 엘지화학 filed Critical (주) 엘지화학
Priority to CN201080004413.7A priority Critical patent/CN102271812B/zh
Priority to EP10741425.2A priority patent/EP2404671B2/en
Priority to ES10741425.2T priority patent/ES2515266T5/es
Publication of WO2010093208A2 publication Critical patent/WO2010093208A2/ko
Publication of WO2010093208A3 publication Critical patent/WO2010093208A3/ko
Priority to US13/092,817 priority patent/US8426651B2/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
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    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
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    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/46—Phosphinous acids [R2POH], [R2P(= O)H]: Thiophosphinous acids including[R2PSH]; [R2P(=S)H]; Aminophosphines [R2PNH2]; Derivatives thereof
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5022—Aromatic phosphines (P-C aromatic linkage)
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    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
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    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/657109—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms esters of oxyacids of phosphorus in which one or more exocyclic oxygen atoms have been replaced by (a) sulfur atom(s)
    • C07F9/657127—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms esters of oxyacids of phosphorus in which one or more exocyclic oxygen atoms have been replaced by (a) sulfur atom(s) condensed with carbocyclic or heterocyclic rings or ring systems
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 트리아릴포스핀 리간드; 특정의 화학식으로 표시되는 포스핀 옥사이드 또는 포스핀 설파이드 리간드; 및 전이금속 촉매를 포함하는 하이드로포밀화 반응용 촉매 조성물 및 이를 이용하는 알데히드의 제조방법에 관한 것으로, 상기 촉매 조성물을 올레핀으로부터 알데히드를 제조하는 하이드로포밀화 반응에 이용할 경우 촉매 활성 및 안정성이 우수하고, 노르말-알데히드에 대한 높은 선택성을 보인다.
PCT/KR2010/000921 2009-02-12 2010-02-12 하이드로포밀화 반응용 촉매 조성물 및 이를 이용하는 알데히드의 제조방법 WO2010093208A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201080004413.7A CN102271812B (zh) 2009-02-12 2010-02-12 用于加氢甲酰化反应的催化剂组合物以及使用该催化剂组合物制备醛的方法
EP10741425.2A EP2404671B2 (en) 2009-02-12 2010-02-12 Catalyst composition for hydroformylation and method for preparing aldehydes using the same
ES10741425.2T ES2515266T5 (es) 2009-02-12 2010-02-12 Composición de catalizador para hidroformilación y procedimiento para la preparación de aldehídos utilizando la misma
US13/092,817 US8426651B2 (en) 2009-02-12 2011-04-22 Catalyst composition for hydroformylation and method for producing aldehyde using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20090011408 2009-02-12
KR10-2009-0011408 2009-02-12

Related Child Applications (1)

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US13/092,817 Continuation US8426651B2 (en) 2009-02-12 2011-04-22 Catalyst composition for hydroformylation and method for producing aldehyde using the same

Publications (2)

Publication Number Publication Date
WO2010093208A2 WO2010093208A2 (ko) 2010-08-19
WO2010093208A3 true WO2010093208A3 (ko) 2010-11-25

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PCT/KR2010/000921 WO2010093208A2 (ko) 2009-02-12 2010-02-12 하이드로포밀화 반응용 촉매 조성물 및 이를 이용하는 알데히드의 제조방법

Country Status (6)

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US (1) US8426651B2 (ko)
EP (1) EP2404671B2 (ko)
KR (1) KR101150557B1 (ko)
CN (1) CN102271812B (ko)
ES (1) ES2515266T5 (ko)
WO (1) WO2010093208A2 (ko)

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KR20210004392A (ko) 2019-07-04 2021-01-13 주식회사 엘지화학 하이드로포밀화 반응용 촉매 조성물 및 이를 이용한 알데히드의 제조방법
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CN102271812A (zh) 2011-12-07
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US8426651B2 (en) 2013-04-23
EP2404671A2 (en) 2012-01-11
EP2404671A4 (en) 2012-05-09
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EP2404671B2 (en) 2018-07-25
ES2515266T3 (es) 2014-10-29
CN102271812B (zh) 2014-04-02
WO2010093208A2 (ko) 2010-08-19
US20110201844A1 (en) 2011-08-18
KR20100092399A (ko) 2010-08-20

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