WO2010093208A3 - 하이드로포밀화 반응용 촉매 조성물 및 이를 이용하는 알데히드의 제조방법 - Google Patents

하이드로포밀화 반응용 촉매 조성물 및 이를 이용하는 알데히드의 제조방법 Download PDF

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WO2010093208A3
WO2010093208A3 PCT/KR2010/000921 KR2010000921W WO2010093208A3 WO 2010093208 A3 WO2010093208 A3 WO 2010093208A3 KR 2010000921 W KR2010000921 W KR 2010000921W WO 2010093208 A3 WO2010093208 A3 WO 2010093208A3
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hydroformylation
catalyst composition
same
aldehydes
preparing aldehydes
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PCT/KR2010/000921
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English (en)
French (fr)
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WO2010093208A2 (ko
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최재희
고동현
엄성식
홍무호
권오학
김대철
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(주) 엘지화학
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=42562207&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2010093208(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by (주) 엘지화학 filed Critical (주) 엘지화학
Priority to EP10741425.2A priority Critical patent/EP2404671B2/en
Priority to CN201080004413.7A priority patent/CN102271812B/zh
Priority to ES10741425.2T priority patent/ES2515266T5/es
Publication of WO2010093208A2 publication Critical patent/WO2010093208A2/ko
Publication of WO2010093208A3 publication Critical patent/WO2010093208A3/ko
Priority to US13/092,817 priority patent/US8426651B2/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
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    • B01J31/22—Organic complexes
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    • B01J31/2208—Oxygen, e.g. acetylacetonates
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
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    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/46—Phosphinous acids [R2POH], [R2P(= O)H]: Thiophosphinous acids including[R2PSH]; [R2P(=S)H]; Aminophosphines [R2PNH2]; Derivatives thereof
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
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    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/657109—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms esters of oxyacids of phosphorus in which one or more exocyclic oxygen atoms have been replaced by (a) sulfur atom(s)
    • C07F9/657127—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms esters of oxyacids of phosphorus in which one or more exocyclic oxygen atoms have been replaced by (a) sulfur atom(s) condensed with carbocyclic or heterocyclic rings or ring systems
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 트리아릴포스핀 리간드; 특정의 화학식으로 표시되는 포스핀 옥사이드 또는 포스핀 설파이드 리간드; 및 전이금속 촉매를 포함하는 하이드로포밀화 반응용 촉매 조성물 및 이를 이용하는 알데히드의 제조방법에 관한 것으로, 상기 촉매 조성물을 올레핀으로부터 알데히드를 제조하는 하이드로포밀화 반응에 이용할 경우 촉매 활성 및 안정성이 우수하고, 노르말-알데히드에 대한 높은 선택성을 보인다.
PCT/KR2010/000921 2009-02-12 2010-02-12 하이드로포밀화 반응용 촉매 조성물 및 이를 이용하는 알데히드의 제조방법 WO2010093208A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP10741425.2A EP2404671B2 (en) 2009-02-12 2010-02-12 Catalyst composition for hydroformylation and method for preparing aldehydes using the same
CN201080004413.7A CN102271812B (zh) 2009-02-12 2010-02-12 用于加氢甲酰化反应的催化剂组合物以及使用该催化剂组合物制备醛的方法
ES10741425.2T ES2515266T5 (es) 2009-02-12 2010-02-12 Composición de catalizador para hidroformilación y procedimiento para la preparación de aldehídos utilizando la misma
US13/092,817 US8426651B2 (en) 2009-02-12 2011-04-22 Catalyst composition for hydroformylation and method for producing aldehyde using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20090011408 2009-02-12
KR10-2009-0011408 2009-02-12

Related Child Applications (1)

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US13/092,817 Continuation US8426651B2 (en) 2009-02-12 2011-04-22 Catalyst composition for hydroformylation and method for producing aldehyde using the same

Publications (2)

Publication Number Publication Date
WO2010093208A2 WO2010093208A2 (ko) 2010-08-19
WO2010093208A3 true WO2010093208A3 (ko) 2010-11-25

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PCT/KR2010/000921 WO2010093208A2 (ko) 2009-02-12 2010-02-12 하이드로포밀화 반응용 촉매 조성물 및 이를 이용하는 알데히드의 제조방법

Country Status (6)

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US (1) US8426651B2 (ko)
EP (1) EP2404671B2 (ko)
KR (1) KR101150557B1 (ko)
CN (1) CN102271812B (ko)
ES (1) ES2515266T5 (ko)
WO (1) WO2010093208A2 (ko)

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DE102012014396B4 (de) * 2012-07-13 2018-01-11 Oxea Gmbh Verfahren zur Herstellung eines Vinylestergemisches aus einem Gemisch stellungsisomerer aliphatischer Isononansäuren ausgehend von 2-Ethylhexanol
WO2015046924A1 (ko) * 2013-09-30 2015-04-02 (주) 엘지화학 히드로포밀화 반응용 촉매 조성물 및 이를 이용한 올레핀의 히드로포밀화 방법
KR101615028B1 (ko) 2013-09-30 2016-04-22 주식회사 엘지화학 히드로포밀화 반응용 촉매 조성물 및 이를 이용한 올레핀의 히드로포밀화 방법
KR101962092B1 (ko) 2015-10-05 2019-03-26 주식회사 엘지화학 인계 리간드를 포함하는 촉매 조성물 및 이를 이용한 하이드로포밀화 방법
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WO2018008928A1 (ko) 2016-07-08 2018-01-11 (주) 엘지화학 하이드로포밀화 촉매, 이를 포함하는 촉매 조성물 및 이를 이용한 알데히드 제조방법
KR102073732B1 (ko) 2016-07-08 2020-02-05 주식회사 엘지화학 하이드로포밀화 촉매, 이를 포함하는 촉매 조성물 및 이를 이용한 알데히드 제조방법
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EP3466540B1 (en) 2017-05-29 2022-04-06 LG Chem, Ltd. Catalyst composition for hydroformylation reaction and method for preparing aldehyde using same
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JP2021525166A (ja) * 2018-05-30 2021-09-24 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー モノホスフィン、テトラホスフィン配位子の組み合わせを含む触媒組成物、およびそれを使用するヒドロホルミル化プロセス
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KR20230115563A (ko) 2022-01-27 2023-08-03 주식회사 엘지화학 알코올의 제조방법
KR20230115558A (ko) 2022-01-27 2023-08-03 주식회사 엘지화학 하이드로포밀화 방법
KR20230115501A (ko) 2022-01-27 2023-08-03 주식회사 엘지화학 알코올의 제조방법
KR20230115560A (ko) 2022-01-27 2023-08-03 주식회사 엘지화학 하이드로포밀화용 용매의 제조방법 및 알데히드의 제조방법

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US4528403A (en) * 1982-10-21 1985-07-09 Mitsubishi Chemical Industries Ltd. Hydroformylation process for preparation of aldehydes and alcohols
US6040483A (en) * 1997-05-27 2000-03-21 Institut Francais Du Petrole Process for hydroformylating olefins
US20050119495A1 (en) * 2001-11-09 2005-06-02 The Penn State Research Foundation P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions

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JPS5829928B2 (ja) * 1978-08-07 1983-06-25 株式会社クラレ オレフイン性化合物のカルボニル化方法
KR100596365B1 (ko) 2004-06-12 2006-07-03 주식회사 엘지화학 인을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
KR100547587B1 (ko) * 2004-06-12 2006-01-31 주식회사 엘지화학 인을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
KR100744477B1 (ko) † 2004-09-15 2007-08-01 주식회사 엘지화학 인 화합물을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법

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US4408078A (en) * 1981-12-23 1983-10-04 Shell Oil Company Process for the hydroformylation of olefins
US4528403A (en) * 1982-10-21 1985-07-09 Mitsubishi Chemical Industries Ltd. Hydroformylation process for preparation of aldehydes and alcohols
US6040483A (en) * 1997-05-27 2000-03-21 Institut Francais Du Petrole Process for hydroformylating olefins
US20050119495A1 (en) * 2001-11-09 2005-06-02 The Penn State Research Foundation P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions

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US20110201844A1 (en) 2011-08-18
EP2404671B1 (en) 2014-09-10
KR101150557B1 (ko) 2012-06-01
WO2010093208A2 (ko) 2010-08-19
EP2404671B2 (en) 2018-07-25
US8426651B2 (en) 2013-04-23
ES2515266T5 (es) 2018-12-03
ES2515266T3 (es) 2014-10-29
CN102271812B (zh) 2014-04-02
KR20100092399A (ko) 2010-08-20
EP2404671A4 (en) 2012-05-09
CN102271812A (zh) 2011-12-07

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