MX2009007863A - Metodo para regenerar un catalizador para deshidratar glicerina. - Google Patents

Metodo para regenerar un catalizador para deshidratar glicerina.

Info

Publication number
MX2009007863A
MX2009007863A MX2009007863A MX2009007863A MX2009007863A MX 2009007863 A MX2009007863 A MX 2009007863A MX 2009007863 A MX2009007863 A MX 2009007863A MX 2009007863 A MX2009007863 A MX 2009007863A MX 2009007863 A MX2009007863 A MX 2009007863A
Authority
MX
Mexico
Prior art keywords
glycerine
regenerating
catalyst
dehydrating
acrolein
Prior art date
Application number
MX2009007863A
Other languages
English (en)
Inventor
Klaus Huthmacher
Christoph Weckbecker
Hubert Redlingshoefer
Andreas Doerflein
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Publication of MX2009007863A publication Critical patent/MX2009007863A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/20—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
    • Y10S502/514—Process applicable either to preparing or to regenerating or to rehabilitating catalyst or sorbent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
    • Y10S502/515—Specific contaminant removal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La invención se relaciona con un método para la regeneración de un catalizador usado para la producción de acroleína a partir de glicerina, que contiene compuestos de tungsteno, con propiedades ácidas y al menos un promotor.
MX2009007863A 2007-01-29 2007-12-17 Metodo para regenerar un catalizador para deshidratar glicerina. MX2009007863A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007004350A DE102007004350A1 (de) 2007-01-29 2007-01-29 Verfahren zur Regenerierung eines Katalysators
PCT/EP2007/064080 WO2008092534A1 (de) 2007-01-29 2007-12-17 Verfahren zur regenerierung eines katalysators für die dehydratisierung von glycerin

Publications (1)

Publication Number Publication Date
MX2009007863A true MX2009007863A (es) 2009-07-31

Family

ID=39262761

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009007863A MX2009007863A (es) 2007-01-29 2007-12-17 Metodo para regenerar un catalizador para deshidratar glicerina.

Country Status (11)

Country Link
US (1) US7846861B2 (es)
EP (1) EP2114564B1 (es)
JP (1) JP5312347B2 (es)
CN (1) CN101594936B (es)
BR (1) BRPI0721357B1 (es)
DE (1) DE102007004350A1 (es)
ES (1) ES2611939T3 (es)
MX (1) MX2009007863A (es)
MY (1) MY145828A (es)
RU (1) RU2484895C2 (es)
WO (1) WO2008092534A1 (es)

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* Cited by examiner, † Cited by third party
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WO2009148105A1 (ja) * 2008-06-05 2009-12-10 昭和電工株式会社 アクロレインの製造方法及びアクリル酸の製造方法
FR2936962B1 (fr) * 2008-10-10 2011-05-06 Eurecat Sa Procede de regeneration de catalyseurs de traitement d'hydrocarbures.
DE102008060888A1 (de) * 2008-12-09 2010-06-10 Evonik Stockhausen Gmbh Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase
FR2939791B1 (fr) 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
BR112012006076A2 (pt) * 2009-09-18 2020-08-18 Nippon Kayaku Kabushiki Kaisha catalisador e processo para preparo de acroleína e /ou ácido acrílico por meio de reação de desidratação de glicerina
JP5798569B2 (ja) * 2009-12-18 2015-10-21 バテル・メモリアル・インスティテュート 多水酸基化合物脱水システム、触媒組成物及び方法
FR2954312B1 (fr) * 2009-12-21 2012-02-10 Adisseo France Sas Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerine
JP5721238B2 (ja) * 2010-03-01 2015-05-20 国立大学法人北海道大学 低品位グリセリンからのアリルアルコールとプロピレンの製造方法、及びそのための触媒
FR2961507B1 (fr) * 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine
JP5626161B2 (ja) * 2010-09-03 2014-11-19 三菱レイヨン株式会社 パラジウム含有触媒の製造方法、およびα，β−不飽和カルボン酸の製造方法
WO2013017904A1 (en) * 2011-07-29 2013-02-07 Arkema France Improved process of dehydration reactions
FR2989684B1 (fr) 2012-04-18 2014-10-31 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
FR2997398B1 (fr) * 2012-10-30 2014-11-21 Adisseo France Sas Procede de preparation de l’acroleine a partir de glycerol
WO2014195157A1 (de) 2013-06-03 2014-12-11 Evonik Degussa Gmbh Verfahren zur herstellung von acrolein
KR101774543B1 (ko) 2014-12-19 2017-09-04 주식회사 엘지화학 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
KR101805086B1 (ko) * 2015-03-02 2017-12-05 주식회사 엘지화학 글리세린 탈수 반응용 촉매의 제조 방법, 이를 이용하여 제조된 글리세린 탈수 반응용 촉매 및 아크롤레인의 제조 방법
US20160368861A1 (en) 2015-06-19 2016-12-22 Southern Research Institute Compositions and methods related to the production of acrylonitrile
CN105032419B (zh) * 2015-07-18 2017-12-22 黑龙江中医药大学 一种双金属修饰的多酸化合物及其制备方法和应用
KR102052708B1 (ko) * 2015-12-22 2019-12-09 주식회사 엘지화학 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
CN105749939B (zh) * 2016-03-09 2018-03-30 浙江工业大学之江学院 一种磷酸改性蒙脱石负载钨氧化物催化剂、制备方法和应用
CN106008188B (zh) * 2016-05-30 2018-05-29 浙江工业大学 一种甘油催化脱水制备丙烯醛的新方法
US9708249B1 (en) 2016-08-24 2017-07-18 Southern Research Institute Compositions and methods related to the production of acrylonitrile
CN109174075A (zh) * 2018-09-04 2019-01-11 中国科学院上海硅酸盐研究所 一种用于光催化降解VOCs的稀土元素改性二氧化钛纳米光催化材料及其制备方法
CN112778088B (zh) * 2021-01-14 2022-07-19 浙江工业大学 一种甘油同步制备丙烯酸和1,2-丙二醇的方法
CN114011457B (zh) * 2021-12-07 2023-09-19 万华化学集团股份有限公司 一种对乙氧基苯酚的制备方法

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US4837397A (en) * 1987-12-11 1989-06-06 Mobil Oil Corporation Nobile metal containing catalysts of improved stability
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FR2781393B1 (fr) * 1998-07-22 2000-08-25 Rhone Poulenc Fibres Procede de regeneration d'un catalyseur d'hydrolyse cyclisante d'un aminonitrile en lactame et utilisation du catalyseur regenere pour la fabrication de lactames
FR2841797B1 (fr) * 2002-07-03 2005-08-05 Centre Nat Rech Scient Catalyseurs a base de tungstene
FR2882053B1 (fr) 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
FR2882052B1 (fr) 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acroleine

Also Published As

Publication number Publication date
JP2010516462A (ja) 2010-05-20
DE102007004350A1 (de) 2008-07-31
EP2114564B1 (de) 2016-11-02
CN101594936A (zh) 2009-12-02
JP5312347B2 (ja) 2013-10-09
WO2008092534A1 (de) 2008-08-07
RU2484895C2 (ru) 2013-06-20
ES2611939T3 (es) 2017-05-11
RU2009132405A (ru) 2011-04-10
CN101594936B (zh) 2014-08-13
MY145828A (en) 2012-04-30
US7846861B2 (en) 2010-12-07
BRPI0721357A2 (pt) 2014-02-25
BRPI0721357B1 (pt) 2017-04-04
US20080214384A1 (en) 2008-09-04
EP2114564A1 (de) 2009-11-11

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