MX2009007815A - Catalizadores que contienen compuestos de tungsteno y procedimiento para la deshidratacion de glicerina. - Google Patents
Catalizadores que contienen compuestos de tungsteno y procedimiento para la deshidratacion de glicerina.Info
- Publication number
- MX2009007815A MX2009007815A MX2009007815A MX2009007815A MX2009007815A MX 2009007815 A MX2009007815 A MX 2009007815A MX 2009007815 A MX2009007815 A MX 2009007815A MX 2009007815 A MX2009007815 A MX 2009007815A MX 2009007815 A MX2009007815 A MX 2009007815A
- Authority
- MX
- Mexico
- Prior art keywords
- glycerine
- containing tungsten
- dehydrating
- tungsten compounds
- catalysts containing
- Prior art date
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title abstract 6
- 239000003054 catalyst Substances 0.000 title abstract 3
- 235000011187 glycerol Nutrition 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 150000003658 tungsten compounds Chemical class 0.000 title abstract 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 abstract 2
- CLUWOWRTHNNBBU-UHFFFAOYSA-N 3-methylthiopropanal Chemical compound CSCCC=O CLUWOWRTHNNBBU-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000011973 solid acid Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6527—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
- C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La invención se refiere a un procedimiento para producir acroleína a partir de glicerina utilizando un catalizador ácido de cuerpo sólido, el cual contiene compuestos de tungsteno y cuando menos otro promotor. Además se describe un procedimiento para la producción de mercaptopropionaldehído de metilo a partir de glicerina en la presencia de un catalizador.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007004351A DE102007004351A1 (de) | 2007-01-29 | 2007-01-29 | Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin |
PCT/EP2007/064060 WO2008092533A1 (de) | 2007-01-29 | 2007-12-17 | Wolframverbindungen enthaltende katalysatoren und verfahren zur dehydratisierung von glycerin |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2009007815A true MX2009007815A (es) | 2009-07-31 |
Family
ID=39247085
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2009007815A MX2009007815A (es) | 2007-01-29 | 2007-12-17 | Catalizadores que contienen compuestos de tungsteno y procedimiento para la deshidratacion de glicerina. |
Country Status (10)
Country | Link |
---|---|
US (2) | US20080183019A1 (es) |
EP (1) | EP2114561B1 (es) |
JP (1) | JP5227339B2 (es) |
CN (1) | CN101652172B (es) |
BR (1) | BRPI0721034B1 (es) |
DE (1) | DE102007004351A1 (es) |
ES (1) | ES2611938T3 (es) |
MX (1) | MX2009007815A (es) |
MY (1) | MY146792A (es) |
WO (1) | WO2008092533A1 (es) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7872158B2 (en) * | 2007-08-24 | 2011-01-18 | Battelle Memorial Institute | Chemical production processes, systems, and catalyst compositions |
US8075642B2 (en) | 2008-04-14 | 2011-12-13 | Wisconsin Alumni Research Foundation | Single-reactor process for producing liquid-phase organic compounds from biomass |
US9206145B2 (en) | 2008-04-14 | 2015-12-08 | Wisconsin Alumni Research Foundation | Single-reactor process for producing liquid-phase organic compounds from biomass |
US8742169B2 (en) * | 2008-06-05 | 2014-06-03 | Showa Denko K.K. | Acrolein manufacturing method and acrylic acid manufacturing method |
FR2938535B1 (fr) * | 2008-11-20 | 2012-08-17 | Arkema France | Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables |
DE102008060888A1 (de) * | 2008-12-09 | 2010-06-10 | Evonik Stockhausen Gmbh | Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase |
FR2939791B1 (fr) | 2008-12-16 | 2011-01-14 | Adisseo France Sas | Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute |
DE102009027420A1 (de) | 2009-07-02 | 2011-01-05 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Acrolein |
CN101941878B (zh) * | 2009-07-06 | 2013-07-17 | 中国石油化工股份有限公司 | 乙醇脱水的方法 |
EP2512663A2 (en) | 2009-12-18 | 2012-10-24 | Battelle Memorial Institute | Multihydric compound dehydration systems, catalyst compositions, and methods |
FR2954312B1 (fr) * | 2009-12-21 | 2012-02-10 | Adisseo France Sas | Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerine |
EP2554258A4 (en) * | 2010-03-31 | 2014-08-06 | Nippon Catalytic Chem Ind | GLYCEROL DEHYDRATION CATALYST AND PROCESS FOR PRODUCING ACROLEIN, PROCESS FOR PRODUCING ACRYLIC ACID, AND PROCESS FOR PRODUCING HYDROPHILIC RESIN, EACH USING THE CATALYST |
CN101829593B (zh) * | 2010-04-13 | 2011-08-31 | 中国地质大学(武汉) | 过硫酸基二氧化钛负载丝光沸石固体超强酸催化剂的制备方法 |
FR2961507B1 (fr) | 2010-06-17 | 2016-03-04 | Adisseo France Sas | Procede de preparation d'acroleine a partir de glycerol ou de glycerine |
EP2468709A1 (en) * | 2010-11-30 | 2012-06-27 | BioFuel-Solution AB | A process for producing acrolein |
KR101268459B1 (ko) * | 2011-04-14 | 2013-06-04 | 서울대학교산학협력단 | 글리세롤의 탈수반응을 통한 아크롤레인 생산 반응용 촉매 및 그 제조방법 |
EP2606967A1 (de) * | 2011-12-19 | 2013-06-26 | Evonik Degussa GmbH | Katalysator zur Synthese von Alkylmercaptanen und Verfahren zu seiner Herstellung |
US10155908B2 (en) * | 2012-03-07 | 2018-12-18 | Research Triangle Institute | Catalyst compositions and use thereof in catalytic biomass pyrolysis |
EP3004041B1 (de) | 2013-06-03 | 2020-05-06 | Evonik Operations GmbH | Verfahren zur herstellung von acrolein |
CN105709837B (zh) * | 2014-12-02 | 2018-04-10 | 中国石油化工股份有限公司 | 杂多酸铵盐催化剂及其制法 |
US20160368861A1 (en) * | 2015-06-19 | 2016-12-22 | Southern Research Institute | Compositions and methods related to the production of acrylonitrile |
KR102044428B1 (ko) * | 2015-12-23 | 2019-12-02 | 주식회사 엘지화학 | 글리세린으로부터 아크릴산의 제조방법 |
CN106008188B (zh) * | 2016-05-30 | 2018-05-29 | 浙江工业大学 | 一种甘油催化脱水制备丙烯醛的新方法 |
US9708249B1 (en) | 2016-08-24 | 2017-07-18 | Southern Research Institute | Compositions and methods related to the production of acrylonitrile |
CN109305899B (zh) * | 2017-07-28 | 2021-09-03 | 中国石油化工股份有限公司 | 甘油脱水生产丙烯醛的方法 |
CN109261179A (zh) * | 2018-10-09 | 2019-01-25 | 宁波蒙曼生物科技有限公司 | 一种甲醇汽油催化剂及其制备方法和应用 |
CN109317172A (zh) * | 2018-11-07 | 2019-02-12 | 东北师范大学 | 一种铂-二氧化钛/磷钨酸复合膜的制备方法及应用 |
CN111375373B (zh) * | 2018-12-29 | 2022-08-12 | 中国石油化工股份有限公司 | 一种以活性炭为载体的吸附剂及其制备方法 |
CN112778088B (zh) * | 2021-01-14 | 2022-07-19 | 浙江工业大学 | 一种甘油同步制备丙烯酸和1,2-丙二醇的方法 |
CN115608353B (zh) * | 2022-10-12 | 2024-03-01 | 山东新和成氨基酸有限公司 | 用于合成烷基硫醇的催化剂及其制备方法、烷基硫醇的制备方法 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4067915A (en) * | 1974-06-05 | 1978-01-10 | Toray Industries, Inc. | Method for producing cyclohexane derivatives directly from aromatic hydrocarbons |
US4642394A (en) * | 1985-07-16 | 1987-02-10 | Celanese Corporation | Production of propanediols |
DE3930534A1 (de) | 1989-09-13 | 1991-03-21 | Degussa | Verfahren zur herstellung von acrolein durch katalytische gasphasenoxidation von propen |
DE4238493C1 (de) | 1992-11-14 | 1994-04-21 | Degussa | Verfahren zur Herstellung von Acrolein und dessen Verwendung |
DE4238492C2 (de) | 1992-11-14 | 1995-06-14 | Degussa | Verfahren zur Herstellung von 1,2- und 1,3-Propandiol |
US5382731A (en) * | 1993-07-22 | 1995-01-17 | Mobil Oil Corp. | Combined paraffin isomerization/ring opening process |
US6127432A (en) * | 1998-01-29 | 2000-10-03 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for preparing oxygenates and catalysts therefor |
JP4227776B2 (ja) * | 2002-08-15 | 2009-02-18 | 新日本石油株式会社 | 金属担持固体超強酸触媒を用いた水蒸気改質用触媒および水蒸気改質方法 |
ES2341950T3 (es) * | 2002-09-25 | 2010-06-30 | Haldor Topsoe A/S | Proceso de isomerizacion de parafinas c7+ y catalizador para el mismo. |
DE102005003990A1 (de) * | 2005-01-28 | 2006-08-03 | Degussa Ag | Herstellung von 3-(Alkylthio)propanal |
FR2882052B1 (fr) * | 2005-02-15 | 2007-03-23 | Arkema Sa | Procede de deshydratation du glycerol en acroleine |
FR2882053B1 (fr) | 2005-02-15 | 2007-03-23 | Arkema Sa | Procede de deshydratation du glycerol en acrolene |
JP4909526B2 (ja) * | 2005-04-12 | 2012-04-04 | 花王株式会社 | アクロレインの製造方法 |
-
2007
- 2007-01-29 DE DE102007004351A patent/DE102007004351A1/de not_active Withdrawn
- 2007-12-17 BR BRPI0721034A patent/BRPI0721034B1/pt not_active IP Right Cessation
- 2007-12-17 EP EP07857691.5A patent/EP2114561B1/de not_active Not-in-force
- 2007-12-17 JP JP2009547555A patent/JP5227339B2/ja not_active Expired - Fee Related
- 2007-12-17 ES ES07857691.5T patent/ES2611938T3/es active Active
- 2007-12-17 MY MYPI20093111A patent/MY146792A/en unknown
- 2007-12-17 CN CN200780050642.0A patent/CN101652172B/zh not_active Expired - Fee Related
- 2007-12-17 MX MX2009007815A patent/MX2009007815A/es active IP Right Grant
- 2007-12-17 WO PCT/EP2007/064060 patent/WO2008092533A1/de active Application Filing
-
2008
- 2008-01-22 US US12/017,873 patent/US20080183019A1/en not_active Abandoned
-
2010
- 2010-01-15 US US12/687,909 patent/US7790934B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP2114561A1 (de) | 2009-11-11 |
US20100113833A1 (en) | 2010-05-06 |
EP2114561B1 (de) | 2016-11-02 |
JP2010516461A (ja) | 2010-05-20 |
CN101652172B (zh) | 2014-03-05 |
ES2611938T3 (es) | 2017-05-11 |
MY146792A (en) | 2012-09-28 |
WO2008092533A1 (de) | 2008-08-07 |
JP5227339B2 (ja) | 2013-07-03 |
CN101652172A (zh) | 2010-02-17 |
DE102007004351A1 (de) | 2008-07-31 |
US7790934B2 (en) | 2010-09-07 |
BRPI0721034A2 (pt) | 2014-07-29 |
BRPI0721034B1 (pt) | 2017-04-04 |
RU2009132406A (ru) | 2011-05-10 |
US20080183019A1 (en) | 2008-07-31 |
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Legal Events
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---|---|---|---|
FG | Grant or registration |