MX2009007815A - Catalizadores que contienen compuestos de tungsteno y procedimiento para la deshidratacion de glicerina. - Google Patents

Catalizadores que contienen compuestos de tungsteno y procedimiento para la deshidratacion de glicerina.

Info

Publication number
MX2009007815A
MX2009007815A MX2009007815A MX2009007815A MX2009007815A MX 2009007815 A MX2009007815 A MX 2009007815A MX 2009007815 A MX2009007815 A MX 2009007815A MX 2009007815 A MX2009007815 A MX 2009007815A MX 2009007815 A MX2009007815 A MX 2009007815A
Authority
MX
Mexico
Prior art keywords
glycerine
containing tungsten
dehydrating
tungsten compounds
catalysts containing
Prior art date
Application number
MX2009007815A
Other languages
English (en)
Inventor
Klaus Huthmacher
Christoph Weckbecker
Hubert Redlingshoefer
Andreas Doerflein
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Publication of MX2009007815A publication Critical patent/MX2009007815A/es

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/30Tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/64Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652Chromium, molybdenum or tungsten
    • B01J23/6527Tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/888Tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/92Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/94Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/96Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/076Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04Mixing
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La invención se refiere a un procedimiento para producir acroleína a partir de glicerina utilizando un catalizador ácido de cuerpo sólido, el cual contiene compuestos de tungsteno y cuando menos otro promotor. Además se describe un procedimiento para la producción de mercaptopropionaldehído de metilo a partir de glicerina en la presencia de un catalizador.
MX2009007815A 2007-01-29 2007-12-17 Catalizadores que contienen compuestos de tungsteno y procedimiento para la deshidratacion de glicerina. MX2009007815A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007004351A DE102007004351A1 (de) 2007-01-29 2007-01-29 Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin
PCT/EP2007/064060 WO2008092533A1 (de) 2007-01-29 2007-12-17 Wolframverbindungen enthaltende katalysatoren und verfahren zur dehydratisierung von glycerin

Publications (1)

Publication Number Publication Date
MX2009007815A true MX2009007815A (es) 2009-07-31

Family

ID=39247085

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009007815A MX2009007815A (es) 2007-01-29 2007-12-17 Catalizadores que contienen compuestos de tungsteno y procedimiento para la deshidratacion de glicerina.

Country Status (10)

Country Link
US (2) US20080183019A1 (es)
EP (1) EP2114561B1 (es)
JP (1) JP5227339B2 (es)
CN (1) CN101652172B (es)
BR (1) BRPI0721034B1 (es)
DE (1) DE102007004351A1 (es)
ES (1) ES2611938T3 (es)
MX (1) MX2009007815A (es)
MY (1) MY146792A (es)
WO (1) WO2008092533A1 (es)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7872158B2 (en) * 2007-08-24 2011-01-18 Battelle Memorial Institute Chemical production processes, systems, and catalyst compositions
US8075642B2 (en) 2008-04-14 2011-12-13 Wisconsin Alumni Research Foundation Single-reactor process for producing liquid-phase organic compounds from biomass
US9206145B2 (en) 2008-04-14 2015-12-08 Wisconsin Alumni Research Foundation Single-reactor process for producing liquid-phase organic compounds from biomass
US8742169B2 (en) * 2008-06-05 2014-06-03 Showa Denko K.K. Acrolein manufacturing method and acrylic acid manufacturing method
FR2938535B1 (fr) * 2008-11-20 2012-08-17 Arkema France Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables
DE102008060888A1 (de) * 2008-12-09 2010-06-10 Evonik Stockhausen Gmbh Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase
FR2939791B1 (fr) 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
DE102009027420A1 (de) 2009-07-02 2011-01-05 Evonik Degussa Gmbh Verfahren zur Herstellung von Acrolein
CN101941878B (zh) * 2009-07-06 2013-07-17 中国石油化工股份有限公司 乙醇脱水的方法
EP2512663A2 (en) 2009-12-18 2012-10-24 Battelle Memorial Institute Multihydric compound dehydration systems, catalyst compositions, and methods
FR2954312B1 (fr) * 2009-12-21 2012-02-10 Adisseo France Sas Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerine
EP2554258A4 (en) * 2010-03-31 2014-08-06 Nippon Catalytic Chem Ind GLYCEROL DEHYDRATION CATALYST AND PROCESS FOR PRODUCING ACROLEIN, PROCESS FOR PRODUCING ACRYLIC ACID, AND PROCESS FOR PRODUCING HYDROPHILIC RESIN, EACH USING THE CATALYST
CN101829593B (zh) * 2010-04-13 2011-08-31 中国地质大学(武汉) 过硫酸基二氧化钛负载丝光沸石固体超强酸催化剂的制备方法
FR2961507B1 (fr) 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine
EP2468709A1 (en) * 2010-11-30 2012-06-27 BioFuel-Solution AB A process for producing acrolein
KR101268459B1 (ko) * 2011-04-14 2013-06-04 서울대학교산학협력단 글리세롤의 탈수반응을 통한 아크롤레인 생산 반응용 촉매 및 그 제조방법
EP2606967A1 (de) * 2011-12-19 2013-06-26 Evonik Degussa GmbH Katalysator zur Synthese von Alkylmercaptanen und Verfahren zu seiner Herstellung
US10155908B2 (en) * 2012-03-07 2018-12-18 Research Triangle Institute Catalyst compositions and use thereof in catalytic biomass pyrolysis
EP3004041B1 (de) 2013-06-03 2020-05-06 Evonik Operations GmbH Verfahren zur herstellung von acrolein
CN105709837B (zh) * 2014-12-02 2018-04-10 中国石油化工股份有限公司 杂多酸铵盐催化剂及其制法
US20160368861A1 (en) * 2015-06-19 2016-12-22 Southern Research Institute Compositions and methods related to the production of acrylonitrile
KR102044428B1 (ko) * 2015-12-23 2019-12-02 주식회사 엘지화학 글리세린으로부터 아크릴산의 제조방법
CN106008188B (zh) * 2016-05-30 2018-05-29 浙江工业大学 一种甘油催化脱水制备丙烯醛的新方法
US9708249B1 (en) 2016-08-24 2017-07-18 Southern Research Institute Compositions and methods related to the production of acrylonitrile
CN109305899B (zh) * 2017-07-28 2021-09-03 中国石油化工股份有限公司 甘油脱水生产丙烯醛的方法
CN109261179A (zh) * 2018-10-09 2019-01-25 宁波蒙曼生物科技有限公司 一种甲醇汽油催化剂及其制备方法和应用
CN109317172A (zh) * 2018-11-07 2019-02-12 东北师范大学 一种铂-二氧化钛/磷钨酸复合膜的制备方法及应用
CN111375373B (zh) * 2018-12-29 2022-08-12 中国石油化工股份有限公司 一种以活性炭为载体的吸附剂及其制备方法
CN112778088B (zh) * 2021-01-14 2022-07-19 浙江工业大学 一种甘油同步制备丙烯酸和1,2-丙二醇的方法
CN115608353B (zh) * 2022-10-12 2024-03-01 山东新和成氨基酸有限公司 用于合成烷基硫醇的催化剂及其制备方法、烷基硫醇的制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4067915A (en) * 1974-06-05 1978-01-10 Toray Industries, Inc. Method for producing cyclohexane derivatives directly from aromatic hydrocarbons
US4642394A (en) * 1985-07-16 1987-02-10 Celanese Corporation Production of propanediols
DE3930534A1 (de) 1989-09-13 1991-03-21 Degussa Verfahren zur herstellung von acrolein durch katalytische gasphasenoxidation von propen
DE4238493C1 (de) 1992-11-14 1994-04-21 Degussa Verfahren zur Herstellung von Acrolein und dessen Verwendung
DE4238492C2 (de) 1992-11-14 1995-06-14 Degussa Verfahren zur Herstellung von 1,2- und 1,3-Propandiol
US5382731A (en) * 1993-07-22 1995-01-17 Mobil Oil Corp. Combined paraffin isomerization/ring opening process
US6127432A (en) * 1998-01-29 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates and catalysts therefor
JP4227776B2 (ja) * 2002-08-15 2009-02-18 新日本石油株式会社 金属担持固体超強酸触媒を用いた水蒸気改質用触媒および水蒸気改質方法
ES2341950T3 (es) * 2002-09-25 2010-06-30 Haldor Topsoe A/S Proceso de isomerizacion de parafinas c7+ y catalizador para el mismo.
DE102005003990A1 (de) * 2005-01-28 2006-08-03 Degussa Ag Herstellung von 3-(Alkylthio)propanal
FR2882052B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acroleine
FR2882053B1 (fr) 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
JP4909526B2 (ja) * 2005-04-12 2012-04-04 花王株式会社 アクロレインの製造方法

Also Published As

Publication number Publication date
EP2114561A1 (de) 2009-11-11
US20100113833A1 (en) 2010-05-06
EP2114561B1 (de) 2016-11-02
JP2010516461A (ja) 2010-05-20
CN101652172B (zh) 2014-03-05
ES2611938T3 (es) 2017-05-11
MY146792A (en) 2012-09-28
WO2008092533A1 (de) 2008-08-07
JP5227339B2 (ja) 2013-07-03
CN101652172A (zh) 2010-02-17
DE102007004351A1 (de) 2008-07-31
US7790934B2 (en) 2010-09-07
BRPI0721034A2 (pt) 2014-07-29
BRPI0721034B1 (pt) 2017-04-04
RU2009132406A (ru) 2011-05-10
US20080183019A1 (en) 2008-07-31

Similar Documents

Publication Publication Date Title
MX2009007815A (es) Catalizadores que contienen compuestos de tungsteno y procedimiento para la deshidratacion de glicerina.
MX2009007863A (es) Metodo para regenerar un catalizador para deshidratar glicerina.
ZA200806644B (en) Acrylic acid preparation method
FR2897058B1 (fr) Procede de preparation d'acroleine
MY157693A (en) Method for preparing acrylic acid from glycerol
MX2009005433A (es) Proceso para producir alquenos de oxigenados utilizando catalizadores de heteropoliacidos soportados.
MY161602A (en) PRODUCING a,B-UNSATURATED ALDEHYDES BY MEANS OF A REACTION MIXING PUMP
TW200706526A (en) Process for the conversion of hydrocarbons to C2-oxygenates
WO2011012226A3 (de) Verfahren zur herstellung von chlor durch gasphasenoxidation an nanostrukturierten rutheniumträgerkatalysatoren
MY148339A (en) Process for producing propylene glycol
WO2010058129A3 (fr) Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres premieres renouvelables
WO2009097082A8 (en) Spray-dried transition metal zeolite and its use
WO2006023189A3 (en) Treatment of air to a catalyst regenerator to maintain catalyst activity
WO2010144871A3 (en) Production of glutaric acid and derivatives from carbohydrate-containing materials
MY150056A (en) Method for producing hydrogenolysis product of polyhydric alcohol
WO2011010891A3 (ko) 새로운 포스트 메탈로센형 전이금속 화합물
MX351029B (es) Procesos de epoxidación.
WO2011050953A3 (de) Verfahren zur herstellung eines kompositmaterials
WO2009019395A3 (fr) Utilisation de filtres a particules pour limiter la desactivation de catalyseurs
WO2011075743A3 (en) Multihydric compound dehydration systems, catalyst compositions, and methods
HUE050367T2 (hu) Eljárás metanol formaldehiddé történõ oxidációjára fix katalizátorágyon
EP1968928A4 (en) METHOD FOR SYNTHESIS OF A HETEROPOLYIC ACID CATALYST FOR THE OXIDATION OF UNSATURATED ALDEHYDE TO UNSATURATED CARBOXYLIC ACIDS
WO2012106453A3 (en) Materials and methods for improving selectivity in heterogeneous catalysts and products thereof
WO2008148549A3 (en) Novel reaction with a gold catalyst
LV14490A (lv) Selektīvi katalizatori pienskābes iegūšanai no glicerīna

Legal Events

Date Code Title Description
FG Grant or registration