WO2010047131A1 - Egrクーラ用フェライト系ステンレス鋼板 - Google Patents

Egrクーラ用フェライト系ステンレス鋼板 Download PDF

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Publication number
WO2010047131A1
WO2010047131A1 PCT/JP2009/005607 JP2009005607W WO2010047131A1 WO 2010047131 A1 WO2010047131 A1 WO 2010047131A1 JP 2009005607 W JP2009005607 W JP 2009005607W WO 2010047131 A1 WO2010047131 A1 WO 2010047131A1
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WO
WIPO (PCT)
Prior art keywords
less
stainless steel
ferritic stainless
brazing
steel sheet
Prior art date
Application number
PCT/JP2009/005607
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
平出信彦
高橋明彦
前田滋
Original Assignee
新日鐵住金ステンレス株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 新日鐵住金ステンレス株式会社 filed Critical 新日鐵住金ステンレス株式会社
Priority to KR1020117004305A priority Critical patent/KR101247906B1/ko
Priority to CN2009801333269A priority patent/CN102131946A/zh
Priority to EP09821831.6A priority patent/EP2351868B1/en
Priority to US12/998,242 priority patent/US20110176953A1/en
Publication of WO2010047131A1 publication Critical patent/WO2010047131A1/ja

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/20Ferrous alloys, e.g. steel alloys containing chromium with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M26/00Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
    • F02M26/11Manufacture or assembly of EGR systems; Materials or coatings specially adapted for EGR systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M26/00Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
    • F02M26/13Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories
    • F02M26/22Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories with coolers in the recirculation passage
    • F02M26/29Constructional details of the coolers, e.g. pipes, plates, ribs, insulation or materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • F28F19/02Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
    • F28F19/06Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings of metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/08Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
    • F28F21/081Heat exchange elements made from metals or metal alloys
    • F28F21/082Heat exchange elements made from metals or metal alloys from steel or ferrous alloys
    • F28F21/083Heat exchange elements made from metals or metal alloys from steel or ferrous alloys from stainless steel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/08Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
    • F28F21/089Coatings, claddings or bonding layers made from metals or metal alloys
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M26/00Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
    • F02M26/50Arrangements or methods for preventing or reducing deposits, corrosion or wear caused by impurities

Definitions

  • Patent Document 3 listed below discloses a pre-coated brazing coated metal sheet produced by suspending a Ni-based brazing material together with an organic binder, spray-coating it on the surface of a stainless steel plate, and heating.
  • Patent Document 5 C: 0.5% or less, Si: 2% or less, Mn: 3% or less, S: 0.2% or less, Ni: 8-18%, Cr: 12-25%, Mo : 0-4%, W: 0-2%, (Ni / Cu): 2 or more, Nb: 0-2.5%, substantially exhaust gas recirculation made of austenitic stainless cast steel Parts are disclosed.
  • the EGR cooler acidic condensed water composed of sulfuric acid, nitric acid, and organic acid is generated due to SOx, NOx, and HC contained in the exhaust gas.
  • the exhaust gas is directly under the engine and in front of the catalyst, and the exhaust gas before purification is targeted. Therefore, the acid concentration of the generated condensed water is also high.
  • the sulfuric acid concentration in the condensed water also increases.
  • Such an increase in acid concentration leads to a decrease in pH, and it is said that the pH of condensed water in the EGR cooler reaches about 1.5.
  • the plate thickness of the heat exchanging part of an EGR cooler is as thin as 0.1 to 0.5 mm, so that excellent corrosion resistance is required in a condensate having a pH of about 1.5 consisting of sulfuric acid, nitric acid, and organic acid. .
  • C + N 0.015% or more
  • C + N is set to 0.015% or more from the viewpoint of suppressing the strength decrease accompanying the coarsening of crystal grains during brazing.
  • C + N is desirably 0.02% or more. Since excessive addition of C and N reduces intergranular corrosion resistance and workability, it is desirable that C + N is 0.04% or less.
  • Ni (Ni: 3% or less) Ni can be contained in an amount of 3% or less as required in order to improve the corrosion resistance. It is 0.2% or more that a stable effect is obtained. However, excessive addition deteriorates processability and increases the cost because it is expensive. Therefore, it is preferable to contain 0.2 to 3%.
  • the wetting spread is “Good (good)”, and when the brazing area is less than twice The wetting spread was evaluated as “Bad (defect)”. Thereafter, the cross-sectional microstructure was observed. Then, the number of crystal grains existing in the plate thickness direction is measured over a range of 20 mm in length in parallel with the rolling direction, and the microstructure is “Good ( “Good” ”, the one having only one was evaluated as having a microstructure of“ Bad (defect) ”.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Manufacturing & Machinery (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Exhaust-Gas Circulating Devices (AREA)
PCT/JP2009/005607 2008-10-24 2009-10-23 Egrクーラ用フェライト系ステンレス鋼板 WO2010047131A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020117004305A KR101247906B1 (ko) 2008-10-24 2009-10-23 Egr 쿨러용 페라이트계 스테인리스 강판
CN2009801333269A CN102131946A (zh) 2008-10-24 2009-10-23 Egr冷却器用铁素体系不锈钢板
EP09821831.6A EP2351868B1 (en) 2008-10-24 2009-10-23 Ferritic stainless steel sheet for egr coolers
US12/998,242 US20110176953A1 (en) 2008-10-24 2009-10-23 Ferritic stainless steel sheet for egr coolers

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2008-274553 2008-10-24
JP2008274553 2008-10-24
JP2009-241500 2009-10-20
JP2009241500A JP5462583B2 (ja) 2008-10-24 2009-10-20 Egrクーラ用フェライト系ステンレス鋼板

Publications (1)

Publication Number Publication Date
WO2010047131A1 true WO2010047131A1 (ja) 2010-04-29

Family

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PCT/JP2009/005607 WO2010047131A1 (ja) 2008-10-24 2009-10-23 Egrクーラ用フェライト系ステンレス鋼板

Country Status (6)

Country Link
US (1) US20110176953A1 (zh)
EP (1) EP2351868B1 (zh)
JP (1) JP5462583B2 (zh)
KR (1) KR101247906B1 (zh)
CN (1) CN102131946A (zh)
WO (1) WO2010047131A1 (zh)

Cited By (2)

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WO2016017123A1 (ja) * 2014-07-31 2016-02-04 Jfeスチール株式会社 フェライト系ステンレス鋼およびその製造方法
US10458013B2 (en) 2014-12-24 2019-10-29 Jfe Steel Corporation Ferritic stainless steel and process for producing same

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JP5796397B2 (ja) * 2010-10-26 2015-10-21 Jfeスチール株式会社 熱疲労特性と耐酸化性に優れたフェライト系ステンレス鋼
CN105296860B (zh) 2011-03-29 2017-04-05 新日铁住金不锈钢株式会社 生物燃料供给系统部件用铁素体系不锈钢以及生物燃料供给系统部件
JP6037882B2 (ja) 2012-02-15 2016-12-07 新日鐵住金ステンレス株式会社 耐スケール剥離性に優れたフェライト系ステンレス鋼板及びその製造方法
JP6071608B2 (ja) 2012-03-09 2017-02-01 新日鐵住金ステンレス株式会社 耐酸化性に優れたフェライト系ステンレス鋼板
JP5918008B2 (ja) * 2012-05-08 2016-05-18 昭和電工株式会社 冷却器の製造方法
JP5885884B2 (ja) 2013-03-27 2016-03-16 新日鐵住金ステンレス株式会社 フェライト系ステンレス熱延鋼板とその製造方法及び鋼帯
CN103305766B (zh) * 2013-05-10 2018-05-25 宝钢不锈钢有限公司 一种高强高塑性铁素体不锈钢及其制造方法
EP3095888B1 (en) * 2014-01-14 2019-08-14 Nippon Steel & Sumikin Stainless Steel Corporation Ferritic stainless steel sheet excellent in electrical conductivity and adhesion of oxide film
CN106103773B (zh) 2014-03-20 2018-02-27 杰富意钢铁株式会社 铁素体类不锈钢及其制造方法
JP6302395B2 (ja) * 2014-03-27 2018-03-28 株式会社ティラド ヘッダープレートレス熱交換器
JP6295155B2 (ja) * 2014-07-22 2018-03-14 新日鐵住金ステンレス株式会社 フェライト系ステンレス鋼およびその製造方法、並びにフェライト系ステンレス鋼を部材とする熱交換器
US20180195157A1 (en) * 2014-09-02 2018-07-12 Jfe Steel Corporation Ferritic stainless steel sheet for urea scr casing (as amended)
JP6159775B2 (ja) * 2014-10-31 2017-07-05 新日鐵住金ステンレス株式会社 耐排ガス凝縮水腐食性とろう付け性に優れたフェライト系ステンレス鋼及びその製造方法
WO2016068291A1 (ja) * 2014-10-31 2016-05-06 新日鐵住金ステンレス株式会社 耐排ガス凝縮水腐食性とろう付け性に優れたフェライト系ステンレス鋼及びその製造方法
US10975459B2 (en) 2015-09-29 2021-04-13 Jfe Steel Corporation Ferritic stainless steel
CN108699645B (zh) 2016-02-17 2020-06-16 新日铁住金不锈钢株式会社 铁素体-奥氏体系二相不锈钢材及其制造方法
US11261512B2 (en) 2016-09-02 2022-03-01 Jfe Steel Corporation Ferritic stainless steel
JP6418338B2 (ja) * 2016-09-02 2018-11-07 Jfeスチール株式会社 フェライト系ステンレス鋼
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KR101835021B1 (ko) * 2016-09-28 2018-03-09 주식회사 포스코 카본 슬러지 흡착이 저감된 배기계 열교환기용 페라이트계 스테인리스강 및 이의 제조 방법
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KR102389026B1 (ko) 2018-02-14 2022-04-20 제이에프이 스틸 가부시키가이샤 페라이트계 스테인리스강
US11022077B2 (en) 2019-08-13 2021-06-01 Caterpillar Inc. EGR cooler with Inconel diffuser
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JP5462583B2 (ja) 2014-04-02
US20110176953A1 (en) 2011-07-21
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