WO2010047131A1 - Egrクーラ用フェライト系ステンレス鋼板 - Google Patents
Egrクーラ用フェライト系ステンレス鋼板 Download PDFInfo
- Publication number
- WO2010047131A1 WO2010047131A1 PCT/JP2009/005607 JP2009005607W WO2010047131A1 WO 2010047131 A1 WO2010047131 A1 WO 2010047131A1 JP 2009005607 W JP2009005607 W JP 2009005607W WO 2010047131 A1 WO2010047131 A1 WO 2010047131A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- less
- stainless steel
- ferritic stainless
- brazing
- steel sheet
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/20—Ferrous alloys, e.g. steel alloys containing chromium with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/11—Manufacture or assembly of EGR systems; Materials or coatings specially adapted for EGR systems
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/13—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories
- F02M26/22—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories with coolers in the recirculation passage
- F02M26/29—Constructional details of the coolers, e.g. pipes, plates, ribs, insulation or materials
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
- F28F19/02—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
- F28F19/06—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings of metal
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
- F28F21/081—Heat exchange elements made from metals or metal alloys
- F28F21/082—Heat exchange elements made from metals or metal alloys from steel or ferrous alloys
- F28F21/083—Heat exchange elements made from metals or metal alloys from steel or ferrous alloys from stainless steel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
- F28F21/089—Coatings, claddings or bonding layers made from metals or metal alloys
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/50—Arrangements or methods for preventing or reducing deposits, corrosion or wear caused by impurities
Definitions
- Patent Document 3 listed below discloses a pre-coated brazing coated metal sheet produced by suspending a Ni-based brazing material together with an organic binder, spray-coating it on the surface of a stainless steel plate, and heating.
- Patent Document 5 C: 0.5% or less, Si: 2% or less, Mn: 3% or less, S: 0.2% or less, Ni: 8-18%, Cr: 12-25%, Mo : 0-4%, W: 0-2%, (Ni / Cu): 2 or more, Nb: 0-2.5%, substantially exhaust gas recirculation made of austenitic stainless cast steel Parts are disclosed.
- the EGR cooler acidic condensed water composed of sulfuric acid, nitric acid, and organic acid is generated due to SOx, NOx, and HC contained in the exhaust gas.
- the exhaust gas is directly under the engine and in front of the catalyst, and the exhaust gas before purification is targeted. Therefore, the acid concentration of the generated condensed water is also high.
- the sulfuric acid concentration in the condensed water also increases.
- Such an increase in acid concentration leads to a decrease in pH, and it is said that the pH of condensed water in the EGR cooler reaches about 1.5.
- the plate thickness of the heat exchanging part of an EGR cooler is as thin as 0.1 to 0.5 mm, so that excellent corrosion resistance is required in a condensate having a pH of about 1.5 consisting of sulfuric acid, nitric acid, and organic acid. .
- C + N 0.015% or more
- C + N is set to 0.015% or more from the viewpoint of suppressing the strength decrease accompanying the coarsening of crystal grains during brazing.
- C + N is desirably 0.02% or more. Since excessive addition of C and N reduces intergranular corrosion resistance and workability, it is desirable that C + N is 0.04% or less.
- Ni (Ni: 3% or less) Ni can be contained in an amount of 3% or less as required in order to improve the corrosion resistance. It is 0.2% or more that a stable effect is obtained. However, excessive addition deteriorates processability and increases the cost because it is expensive. Therefore, it is preferable to contain 0.2 to 3%.
- the wetting spread is “Good (good)”, and when the brazing area is less than twice The wetting spread was evaluated as “Bad (defect)”. Thereafter, the cross-sectional microstructure was observed. Then, the number of crystal grains existing in the plate thickness direction is measured over a range of 20 mm in length in parallel with the rolling direction, and the microstructure is “Good ( “Good” ”, the one having only one was evaluated as having a microstructure of“ Bad (defect) ”.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Manufacturing & Machinery (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Exhaust-Gas Circulating Devices (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020117004305A KR101247906B1 (ko) | 2008-10-24 | 2009-10-23 | Egr 쿨러용 페라이트계 스테인리스 강판 |
CN2009801333269A CN102131946A (zh) | 2008-10-24 | 2009-10-23 | Egr冷却器用铁素体系不锈钢板 |
EP09821831.6A EP2351868B1 (en) | 2008-10-24 | 2009-10-23 | Ferritic stainless steel sheet for egr coolers |
US12/998,242 US20110176953A1 (en) | 2008-10-24 | 2009-10-23 | Ferritic stainless steel sheet for egr coolers |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008-274553 | 2008-10-24 | ||
JP2008274553 | 2008-10-24 | ||
JP2009-241500 | 2009-10-20 | ||
JP2009241500A JP5462583B2 (ja) | 2008-10-24 | 2009-10-20 | Egrクーラ用フェライト系ステンレス鋼板 |
Publications (1)
Publication Number | Publication Date |
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WO2010047131A1 true WO2010047131A1 (ja) | 2010-04-29 |
Family
ID=42119182
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2009/005607 WO2010047131A1 (ja) | 2008-10-24 | 2009-10-23 | Egrクーラ用フェライト系ステンレス鋼板 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20110176953A1 (zh) |
EP (1) | EP2351868B1 (zh) |
JP (1) | JP5462583B2 (zh) |
KR (1) | KR101247906B1 (zh) |
CN (1) | CN102131946A (zh) |
WO (1) | WO2010047131A1 (zh) |
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US10458013B2 (en) | 2014-12-24 | 2019-10-29 | Jfe Steel Corporation | Ferritic stainless steel and process for producing same |
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- 2009-10-20 JP JP2009241500A patent/JP5462583B2/ja active Active
- 2009-10-23 WO PCT/JP2009/005607 patent/WO2010047131A1/ja active Application Filing
- 2009-10-23 KR KR1020117004305A patent/KR101247906B1/ko active IP Right Grant
- 2009-10-23 US US12/998,242 patent/US20110176953A1/en not_active Abandoned
- 2009-10-23 CN CN2009801333269A patent/CN102131946A/zh active Pending
- 2009-10-23 EP EP09821831.6A patent/EP2351868B1/en active Active
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016017123A1 (ja) * | 2014-07-31 | 2016-02-04 | Jfeスチール株式会社 | フェライト系ステンレス鋼およびその製造方法 |
JP6044743B2 (ja) * | 2014-07-31 | 2016-12-14 | Jfeスチール株式会社 | フェライト系ステンレス鋼およびその製造方法 |
US10450625B2 (en) | 2014-07-31 | 2019-10-22 | Jfe Steel Corporation | Ferritic stainless steel and method for producing same |
US10458013B2 (en) | 2014-12-24 | 2019-10-29 | Jfe Steel Corporation | Ferritic stainless steel and process for producing same |
Also Published As
Publication number | Publication date |
---|---|
KR20110036753A (ko) | 2011-04-08 |
CN102131946A (zh) | 2011-07-20 |
KR101247906B1 (ko) | 2013-03-26 |
EP2351868A1 (en) | 2011-08-03 |
JP5462583B2 (ja) | 2014-04-02 |
US20110176953A1 (en) | 2011-07-21 |
EP2351868A4 (en) | 2016-11-30 |
JP2010121208A (ja) | 2010-06-03 |
EP2351868B1 (en) | 2020-06-03 |
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