WO2009099666A1 - Extrusion reduction in imprint lithography - Google Patents

Extrusion reduction in imprint lithography Download PDF

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Publication number
WO2009099666A1
WO2009099666A1 PCT/US2009/000803 US2009000803W WO2009099666A1 WO 2009099666 A1 WO2009099666 A1 WO 2009099666A1 US 2009000803 W US2009000803 W US 2009000803W WO 2009099666 A1 WO2009099666 A1 WO 2009099666A1
Authority
WO
WIPO (PCT)
Prior art keywords
energy
polymerizable material
substrate
mesa
wavelength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2009/000803
Other languages
English (en)
French (fr)
Inventor
Niyaz Khusnatdinov
Christopher E. Jones
Joseph G. Perez
Dwayne L. Labrake
Ian Matthew Mcmackin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Canon Nanotechnologies Inc
Original Assignee
Molecular Imprints Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Molecular Imprints Inc filed Critical Molecular Imprints Inc
Priority to JP2010545889A priority Critical patent/JP5216871B2/ja
Priority to KR1020167011654A priority patent/KR102065400B1/ko
Priority to CN200980104592.9A priority patent/CN101939704B/zh
Priority to KR1020197030480A priority patent/KR102171030B1/ko
Priority to EP09707380A priority patent/EP2240826A4/en
Publication of WO2009099666A1 publication Critical patent/WO2009099666A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00Photographic processes or agents therefor; Regeneration of such processing agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/005Repairing damaged coatings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/026Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing of layered or coated substantially flat surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y10/00Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0002Lithographic processes using patterning methods other than those involving the exposure to radiation, e.g. by stamping
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20Exposure; Apparatus therefor
    • G03F7/2022Multi-step exposure, e.g. hybrid; backside exposure; blanket exposure, e.g. for image reversal; edge exposure, e.g. for edge bead removal; corrective exposure

Definitions

  • An imprint lithography technique disclosed in each of the aforementioned U.S. patent publications and patent includes formation of a relief pattern in a formable (polymerizable) layer and transferring a pattern corresponding to the relief pattern into an underlying substrate.
  • the substrate may be coupled to a motion stage to obtain a desired positioning to facilitate the patterning process.
  • the patterning process uses a template spaced apart from the substrate and a formable liquid applied between the template and the substrate.
  • the formable liquid is solidified to form a rigid layer that has a pattern conforming to a shape of the surface of the template that contacts the formable liquid.
  • the template is separated from the rigid layer such that the template and the substrate are spaced apart.
  • the substrate and the solidified layer are then subjected to additional processes to transfer a relief image into the substrate that corresponds to the pattern in the solidified layer.
  • FIG. 5A and 5B illustrate simplified side view of an exemplary masking system for use in a lithographic system.
  • FIG. 6 illustrates a flow chart of an exemplary method for preventing extrusion formation during imprint lithography using a masking system.
  • FIG. 7C illustrates a flow chart of an exemplary method for preventing extrusion formation using a filtering system.
  • energy 40a passing through mask 102 may reflect and/or diffract as it propagates.
  • energy 40a passing through mask 102 may diffract as it propagates the separation distance between mask 102 and template 18.
  • Such reflection and/or diffraction may result in blurring.
  • projection optics for lithography may be used to reduce or eliminate blurring.
  • projection option for 0.5 ⁇ m lithography may be used.
  • mask 102 may be placed in close proximity to template 18 to reduce and/or eliminate blurring.
  • Filters 132 and 134 may be any suitable filter (e.g., optical filter).
  • second filter 134 may be positioned adjacent to template 18.
  • band 132 is greater than a length L 4 of second filter 134.
  • length L 4 of second filter 134 may be less than length L 3 of first filter 132 creating a band 104b.
  • Band 104b may have a width W 2 .
  • a minimal width W 2 of band 104b may be between approximately 2-10 ⁇ m. It should be noted that the width w 2 may be larger depending on application and design considerations. [0048] Positioning of the first filter 132 relative to the second filter 134 may create band 104b.
  • FIGS. 10A and 10B illustrate an exemplary system 250 to block one or more curved areas 252 of substrate 12 to provide step-to-edge exposure control during edge-field imprinting.
  • system 250 includes an electrochromic film 254. At least one region 256 of electrochromic film 254 may turn opaque to energy 40 in response to voltage.
  • FIG. 11 illustrates maze pattern 300 having square features 304.
  • Square features 304 have a length L 7 (e.g., 2 ⁇ m) a width W 7 (e.g., 2 ⁇ m), and a height h 7 (e.g., 100 nm).
  • Features 304 may be distanced apart from other features by a distance d 7 (e.g., 0.8 ⁇ m).
  • Features 304 may be aligned as illustrated in FIG. 11A or staggered as illustrated in FIG. 11 B.
  • Features may be patterned on substrate 12 using techniques including, but no limited to, imprint lithography,
  • fill factor f is a ratio between the total area of features 304 within a portion of maze pattern 300 and the entire area of that portion of maze pattern
  • fractal structures 500 may be used in system 10.
  • fractal structures 500 may be patterned on template mesa 20 to reduce and/or prevent propagation of polymerizable material 34 during imprinting.
  • fractal structures 500 may reduce or increase the total length of the periphery of all the features 502 in the area under consideration for polymerizable material 34, increase surface energy of polymerizable material 34 due to increased/decreased capillary paths, and/or absorb excess volume V of polymerizable material 34 resulting in reduced propagation of polymerizable material 34.
  • polymerizable material 34 may have a high surface energy when in contact with fractal structure 500.
  • bridges 504 between features 502 of fractal pattern 500 may act as gas barriers.
  • propagation of polymerizable material 34 may be reduced.
  • reducing the size of features 502 may improve gas trapping.
  • fractal pattern 500b of FIG. 17A provides iterations of features 502 with reduced linear sizes towards the center.
  • Polymerizable material 34 may fill the smaller areas faster due to stronger capillary forces (e.g. material fills at faster rate in the center region). This may lead to entrapment of gas in the larger areas where polymerizable material 34 may still be flowing.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Nanotechnology (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Manufacturing & Machinery (AREA)
  • Theoretical Computer Science (AREA)
  • Mathematical Physics (AREA)
  • Mechanical Engineering (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
  • Micromachines (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
PCT/US2009/000803 2008-02-08 2009-02-09 Extrusion reduction in imprint lithography Ceased WO2009099666A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2010545889A JP5216871B2 (ja) 2008-02-08 2009-02-09 インプリント・リソグラフィにおけるはみ出し低減
KR1020167011654A KR102065400B1 (ko) 2008-02-08 2009-02-09 임프린트 리소그래피에서 압출물 감소
CN200980104592.9A CN101939704B (zh) 2008-02-08 2009-02-09 在刻印光刻技术中减少突出物
KR1020197030480A KR102171030B1 (ko) 2008-02-08 2009-02-09 임프린트 리소그래피에서 압출물 감소
EP09707380A EP2240826A4 (en) 2008-02-08 2009-02-09 EXTRUSION REDUCTION IN PRECISEITHOGRAPHY

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US2715308P 2008-02-08 2008-02-08
US61/027,153 2008-02-08
US9409208P 2008-09-04 2008-09-04
US61/094,092 2008-09-04
US12/367,079 2009-02-06
US12/367,079 US8361371B2 (en) 2008-02-08 2009-02-06 Extrusion reduction in imprint lithography

Publications (1)

Publication Number Publication Date
WO2009099666A1 true WO2009099666A1 (en) 2009-08-13

Family

ID=40938224

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/000803 Ceased WO2009099666A1 (en) 2008-02-08 2009-02-09 Extrusion reduction in imprint lithography

Country Status (7)

Country Link
US (2) US8361371B2 (enExample)
EP (1) EP2240826A4 (enExample)
JP (1) JP5216871B2 (enExample)
KR (3) KR20100123698A (enExample)
CN (1) CN101939704B (enExample)
TW (1) TWI430015B (enExample)
WO (1) WO2009099666A1 (enExample)

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US10101663B2 (en) 2012-07-24 2018-10-16 Canon Kabushiki Kaisha Imprint apparatus and method of manufacturing article
US10118317B2 (en) 2015-05-27 2018-11-06 Toshiba Memory Corporation Template and pattern formation method
US11480872B2 (en) 2019-10-30 2022-10-25 Canon Kabushiki Kaisha Imprint apparatus, imprint method, and method for manufacturing article
US11904522B2 (en) 2017-09-29 2024-02-20 Canon Kabushiki Kaisha Imprint apparatus and method for manufacturing article
US12099295B2 (en) 2017-10-17 2024-09-24 Canon Kabushiki Kaisha Imprint apparatuses and article manufacturing methods applying viscosity increases without curing of imprint material

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JP6361238B2 (ja) * 2013-04-23 2018-07-25 大日本印刷株式会社 インプリント用モールドおよびインプリント方法
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US8361371B2 (en) 2013-01-29
KR20160054631A (ko) 2016-05-16
US20090200710A1 (en) 2009-08-13
KR102065400B1 (ko) 2020-01-13
TWI430015B (zh) 2014-03-11
KR102171030B1 (ko) 2020-10-28
CN101939704B (zh) 2014-03-12
CN101939704A (zh) 2011-01-05
JP5216871B2 (ja) 2013-06-19
TW200938949A (en) 2009-09-16
KR20190120443A (ko) 2019-10-23
EP2240826A1 (en) 2010-10-20
KR20100123698A (ko) 2010-11-24
US20130241109A1 (en) 2013-09-19

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