WO2009022639A1 - ハードコートフィルム - Google Patents

ハードコートフィルム Download PDF

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Publication number
WO2009022639A1
WO2009022639A1 PCT/JP2008/064284 JP2008064284W WO2009022639A1 WO 2009022639 A1 WO2009022639 A1 WO 2009022639A1 JP 2008064284 W JP2008064284 W JP 2008064284W WO 2009022639 A1 WO2009022639 A1 WO 2009022639A1
Authority
WO
WIPO (PCT)
Prior art keywords
hard coat
inorganic particles
reactive inorganic
coat layer
boundary face
Prior art date
Application number
PCT/JP2008/064284
Other languages
English (en)
French (fr)
Inventor
Emi Shimano
Toshio Yoshihara
Original Assignee
Dai Nippon Printing Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2007209785A external-priority patent/JP5186834B2/ja
Priority claimed from JP2007209780A external-priority patent/JP5320703B2/ja
Application filed by Dai Nippon Printing Co., Ltd. filed Critical Dai Nippon Printing Co., Ltd.
Priority to CN2008801027593A priority Critical patent/CN101790695B/zh
Priority to US12/672,556 priority patent/US8597780B2/en
Priority to KR1020107002872A priority patent/KR101197459B1/ko
Publication of WO2009022639A1 publication Critical patent/WO2009022639A1/ja
Priority to US13/525,588 priority patent/US20120251778A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/022—Mechanical properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/006—Anti-reflective coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11—Anti-reflection coatings
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14—Protective coatings, e.g. hard coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/30—Fillers, e.g. particles, powders, beads, flakes, spheres, chips
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/584—Scratch resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/72—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/08—Dimensions, e.g. volume
    • B32B2309/10—Dimensions, e.g. volume linear, e.g. length, distance, width
    • B32B2309/105—Thickness
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y10T428/2438—Coated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/256—Heavy metal or aluminum or compound thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Laminated Bodies (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)

Abstract

　本発明は、耐擦傷性に優れるハードコートフィルム及び耐けん化性にハードコートフィルムを提供する。第一局面のハードコートフィルムにおいて、ハードコート層は、平均粒径が５ｎｍ以上３０ｎｍ以下の反応性無機微粒子Ａを含有する硬化性樹脂組成物の硬化物からなり、当該ハードコート層の透明基材フィルムとは反対側の界面及びその近傍の表層領域に、前記反応性無機微粒子Ａが局在するスキン層を有している。一方、第二局面のハードコートフィルムにおいて、ハードコート層は、平均粒径が３０ｎｍ以上１００ｎｍ以下の反応性無機微粒子Ａを含有する硬化性樹脂組成物の硬化物からなり、当該ハードコート層の厚み方向に前記反応性無機微粒子Ａの密度分布を有し、当該ハードコート層の透明基材フィルム側とは反対側の界面において前記反応性無機微粒子Ａの密度が最も低く、且つ当該ハードコート層の透明基材フィルム側界面又はその近傍において前記反応性無機微粒子Ａの密度が最も高い。
PCT/JP2008/064284 2007-08-10 2008-08-08 ハードコートフィルム WO2009022639A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2008801027593A CN101790695B (zh) 2007-08-10 2008-08-08 硬涂膜
US12/672,556 US8597780B2 (en) 2007-08-10 2008-08-08 Hard coat film
KR1020107002872A KR101197459B1 (ko) 2007-08-10 2008-08-08 하드 코트 필름
US13/525,588 US20120251778A1 (en) 2007-08-10 2012-06-18 Hard coat film

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007209785A JP5186834B2 (ja) 2007-08-10 2007-08-10 ハードコートフィルム
JP2007-209785 2007-08-10
JP2007-209780 2007-08-10
JP2007209780A JP5320703B2 (ja) 2007-08-10 2007-08-10 ハードコートフィルム

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/525,588 Division US20120251778A1 (en) 2007-08-10 2012-06-18 Hard coat film

Publications (1)

Publication Number Publication Date
WO2009022639A1 true WO2009022639A1 (ja) 2009-02-19

Family

ID=40350692

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/064284 WO2009022639A1 (ja) 2007-08-10 2008-08-08 ハードコートフィルム

Country Status (5)

Country Link
US (2) US8597780B2 (ja)
KR (1) KR101197459B1 (ja)
CN (1) CN101790695B (ja)
TW (1) TWI409311B (ja)
WO (1) WO2009022639A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
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JP2011102977A (ja) * 2009-10-16 2011-05-26 Dainippon Printing Co Ltd 光学フィルム及びディスプレイパネル
US20120045594A1 (en) * 2009-02-27 2012-02-23 Lg Chem, Ltd. Outstandingly abrasion resistant and pollution resistant coating composition and coating film
US20120141695A1 (en) * 2009-07-31 2012-06-07 Sumitomo Bakelite Co., Ltd. Multilayered resin product and image display panel
CN102549078A (zh) * 2009-09-30 2012-07-04 富士胶片株式会社 硬化性组合物、硬化性膜、硬化性积层体、永久图案形成方法以及印刷基板
US20120243115A1 (en) * 2009-09-30 2012-09-27 Dai Nippon Printing Co., Ltd. Optical layered body and method for producing optical layered body
CN102713686A (zh) * 2009-12-28 2012-10-03 大日本印刷株式会社 光学薄膜、光学薄膜的制造方法、偏振板、显示面板及显示器
US20140349052A1 (en) * 2012-01-11 2014-11-27 Lg Hausys, Ltd. Hard coating composition and decorative film with reduced yellowing comprising the same

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US20120251778A1 (en) 2012-10-04
US20110217541A1 (en) 2011-09-08
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TW200918618A (en) 2009-05-01

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